Rare Earth Elements What Do We Know About Them?

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The document discusses what rare earth elements are, their common uses, where they are found and mined, and some of the environmental impacts of rare earth element mining.

Rare earth elements are a group of metals that are used in many technologies. They are found in things like magnets, batteries, and screens. Some of their main uses include in catalysts, alloys, electronics, magnets, and phosphors.

Rare earth elements are found in alkaline igneous rocks, pegmatites, and carbonatite intrusions. They are most commonly mined from deposits of bastnasite and monazite, typically using open pit mining. The largest reserves are found in China and the United States.

Rare Earth Elements

What do we know about them?


Rare Earth Elements
What Are They?

– The 30 rare earth elements are composed of the


lanthanide and actinide series.
• One element of the lanthanide series and most of the
elements in the actinide series are called trans-uranium,
which means synthetic or man-made.
– 17 common rare earth elements found in nature:
cerium, dysprosium, erbium, europium, gadolinium,
holmium, lanthanum, lutetium, neodymium,
praseodymium, samarium, terbium, thulium, ytterbium,
yttrium, ferrocerium, monazite, bastnasite, mischmetal
Rare Earth Elements
Present and Future Uses
• Estimated 2009 distribution of rare earths by end use, in decreasing order,
was as follows (USGS 2011):
– chemical catalysts, 22%;
– metallurgical applications and alloys, 21%;
– petroleum refining catalysts, 14%;
– automotive catalytic converters, 13%;
– glass polishing and ceramics, 9%;
– rare-earth phosphors for computer monitors, lighting, radar, televisions, and x-ray-intensifying film,
8%;
– permanent magnets, 7%;
– electronics, 3%;
– and other, 3%.
• The trend appears to be for a continued increase in the use of rare earths in
many applications, especially automotive catalytic converters, permanent
magnets, and rechargeable batteries for electric and hybrid vehicles.
Rare Earth Elements
Occurrence
– First discovered in the 19th Century in Sweden, they were believed to be some of the most
uncommon elements.
– Rare-earths have been found to be relatively abundant in the Earth's crust, but rarely
concentrated.
– High cost of extraction means that only deposits with high concentrations are likely to be
developed.

Rare earth minerals are usually found in association with alkaline to peralkaline igneous
complexes, in pegmatites associated with alkaline magmas and in or associated with
carbonatite intrusives. Perovskite mineral phases are common hosts to rare earth
elements within the alkaline complexes. Mantle derived carbonate melts also are
carriers of the rare earths. Hydrothermal deposits associated with alkaline magmatism
contain a variety of rare earth minerals.
Rare Earth Elements
Mine Production and Reserves
Country/Region Mine Production Reserves

2009 2010 Total

United States — — 13,000,000

Australia — — 1,600,000

Brazil 550 550 48,000

China 129,000 130,000 55,000,000

Commonwealth of Independent States — — 19,000,000

India 2,700 2,700 3,100,000

Malaysia 350 350 30,000

Other countries — — 22,000,000

World total (rounded) 133,000 130,000 110,000,000

USGS 2011
Rare Earth Elements
World Resources
• Rare earths are relatively abundant in the Earth’s crust, but discovered
minable concentrations are less common than for most other ores.
• U.S. and world resources are contained primarily in bastnäsite and
monazite.
• Bastnäsite deposits in China and the United States constitute the largest
percentage of the world’s rare-earth economic resources, while monazite
deposits in Australia, Brazil, China, India, Malaysia, South Africa, Sri Lanka,
Thailand, and the United States constitute the second largest segment.
• Apatite, cheralite, eudialyte, loparite, phosphorites, rare-earth-bearing (ion
adsorption) clays, secondary monazite, spent uranium solutions, and
xenotime make up most of the remaining resources.
• Undiscovered resources are thought to be very large relative to expected
demand.
• A very large resource enriched in heavy rare-earth elements is inferred for
phosphorites of the Florida Phosphate District.
USGS 2011
Rare Earth Elements
Future Mines
• Exploration efforts to develop rare earths projects surged
in 2010, and investment and interest increased
dramatically.
• Economic assessments continued in North America at
Bear Lodge in Wyoming; Diamond Creek in Idaho; Elk
Creek in Nebraska; Hoidas Lake in Saskatchewan, Canada;
Lemhi Pass in Idaho-Montana; and Nechalacho (Thor
Lake) in Northwest Territories, Canada.
• Other economic assessments took place in other locations
around the world, including Dubbo Zirconia in New South
Wales, Australia; Kangankunde in Malawi; Mount Weld in
Western Australia, Australia; and Nolans Project in
Northern Territory, Australia.
Rare Earth Elements
Mining, Processing and Refining
• Typically mined by bulk tonnage open pit methods
– Higher grade deposits could be mined underground
• Mineral processing typically done on-site using
flotation and gravity processing
– Other processes may also be applicable
• Refining is most difficult/toxic step
– acid or alkaline leach methods
– Pyrometallurgy
• Environmental Impacts
– Typical to hardrock mining (water, air, soil contamination)
– Strong association with deposit type (acid or alkaline)
Rare Earth Elements
Environmental Toxicity
• Few toxicological data are available compared to
other elements (e.g. lead, cadmium, chromium,
mercury, nickel, zinc, arsenic, selenium) for
either human or other ecological receptors
• Some suggestion of chronic exposure impacts
and strong suggestion of impacts when exposed
to compounds (metallurgical and chemical,
possible ecological)
• Possible effects include:
– lung disease, liver disease, eye and skin irritation,
other effects
Rare Earth Elements
Conclusions
• Rare Earth mining will increase but is likely to
occur in only limited circumstances
– High grade and high tech with large funding required
– Sector is highly vulnerable to promotions and scams
• In more suitable locations with good practices
should be possible with minimal impacts
– Potential opportunity to work with industry?
– 100% from reprocessed tailings and waste rock?
• Need more environmental data
– Human health impacts (workforce and local residents)
– Ecological impacts (aquatic life, wildlife, riparian)

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