Carbon Nanotubes, Inorganic Nanowires and Functionalization: Dr. Anita S. Ethiraj Associate Professor

Download as pptx, pdf, or txt
Download as pptx, pdf, or txt
You are on page 1of 8

* EEE514

CARBON NANOTUBES,
INORGANIC NANOWIRES
AND FUNCTIONALIZATION

Dr. Anita S. Ethiraj


Associate Professor
*CONTENTS
* WHAT IS A CARBON NANOTUBE?
* DISCOVERY OF CARBON NANOTUBES
* TYPES OF CARBON NANOTUBES
* PROPERTIES OF CARBON NANOTUBES
* PREPARATION OF CARBON NANOTUBES
* PROBLEMS RELATED TO CARBON NANOTUBES
* POTENTIAL APPLICATION OF CARBON NANOTUBES
* FUNCTIONALIZATION OF CARBON NANOTUBES
* IMPORTANT CARBON BASED MATERIALS
* FULLERENE
* GRAPHENE
* NANODIAMOND
* INORGANIC NANOSTRUCTURES
WHAT IS A CARBON NANOTUBES ?
* A Carbon Nanotube is a tube-shaped material, made of carbon, having a
diameter measuring on the nanometer scale.
* Nanotubes are members of the fullerene structural family.
* Fullerenes are a class of allotropes of carbon which are graphene sheets
rolled into tubes or spheres. Buckminsterfullerene C60, also known as the
buckyball, is the smallest member of the fullerene family.

Resemblance
* Carbon nanotubes (CNTs) are allotropes of carbon.
* Allotropes: Different forms of the same element. Due to different
bonding arrangements between atoms result in different
structures with different chemical and physical properties.

*Their name is derived from their long, hollow structure with the
walls formed by one atom thick sheets of carbon, called graphene.

*These cylindrical carbon molecules have interesting properties


that make them potentially useful in many applications in
nanotechnology, electronics, optics and other fields of materials
science, as well as potential uses in architectural fields. They
exhibit extraordinary strength and unique electrical properties,
and are efficient conductors of heat.
* Carbon nanotubes are hexagonally shaped arrangements of carbon
atoms that have been rolled into tubes. These tiny straw-like cylinders of
pure carbon have useful electrical properties.
HISTORY OF CARBON NANOTUBES
*1952 Radushkevich and Lukyanovich publish a paper in the Soviet
Journal of Physical Chemistry showing hollow graphitic carbon
fibers that are 50 nanometers in diameter.
* 1970 Morinobu Endo- First carbon filaments of nanometer
dimensions as a part of his Ph.D Studies at the University of
Orleans in France. He used vapor-growth technique for growing
carbon technique of about 7 nm in diameter . Because filaments
were not recognized as nanotubes
*1979 John Abrahamson presented evidence of carbon nanotubes at
the 14th Biennial Conference of Carbon at Pennsylvania State
University.
*1981 A group of Soviet scientists published the results of chemical
and structural characterization of carbon nanoparticles produced
by a thermocatalytical disproportionation of carbon monoxide.
HISTORY OF CARBON NANOTUBES
*1985, a molecule called buckminsterfullerene was discovered
by a group of researchers at Rice University. This molecule
consisted of 60 carbon atoms in sp2 hybridized bonds arranged
in a surprisingly symmetric fashion. The Nobel Prize was
awarded to Richard Smalley, Robert Curl, and Harry Kroto for
this discovery.
* 1991, Discovery of multiwall carbon nanotubes by S. Iijima
* 1993, Discovery of single wall nanotubes by S. Iijima and T
Ichihashi
* 1998, Synthesis of Nanotube peapods by B. W. Smith, M.
Monthioux, and D. E. Luzzi
* In 2000, Professor Tang Zikang and Wang Ning created the
smallest, stable carbon nanotubes in the world at just 0.4nm in
diameter .
Discovery of Carbon Nanotubes
 In 1991, carbon nanotubes
were discovered in the soot
during the arc-evaporation
synthesis of fullerenes. The
central core of the cathodic
deposit contained a variety of
closed graphitic structures
including nanoparticles and
nanotubes.

Sumio Iijima  Their morphology is considered


equivalent to a graphene sheet
rolled into a seamless tube
capped on both ends

High resolution TEM Image of a Nanotube Cap

You might also like