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Table Of Contents 
I. Introduction. 1 
II. The Molecular Formula. 2 
III. Production. 3 
IV. Types Of SBR. 4 
V. Buna S. 4 
VI. Properties Of SBR. 5 
VII.Appilications. 6 
VIII.Flow Sheet. 7 
22-Dec-13 Made By Kareem Tharaa
I.Introduction: 
• Styrene-butadiene or styrene-butadiene 
rubber (SBR) describe families of synthetic 
rubbers derived from styrene and butadiene. 
• These materials have good abrasion 
resistance and good aging stability when 
protected by additives. 
• About 50% of car tires are made from types 
of SBR. 
• The styrene/butadiene ratio influences the 
properties of the polymer: with high styrene 
content, the rubbers are harder and less 
rubbery. 
22-Dec-13 Made By Kareem Tharaa
II.The Molecular Formula : 
22-Dec-13 Made By Kareem Tharaa
III.Production: 
From ethanol 
In other parts of the world, including South America, Eastern Europe, China, 
and India, butadiene was also produced from ethanol. While not competitive with 
steam cracking for producing large volumes of butadiene, lower capital costs make 
production from ethanol a viable option for smaller-capacity plants. Two processes 
were in use. 
In the single-step process developed by Sergei Lebedev, ethanol is converted to 
butadiene, hydrogen, and water at 400–450 °C over any of a variety of metal oxide 
catalysts. 
2 CH3CH2OH → CH2=CH-CH=CH2 + 2 H2O + H2
IV.Types of SBR: 
SBR is derived from two monomers, styrene and butadiene. The mixture of these two 
monomers are polymerized by two basically different processes: from solution (S-SBR) or 
as an emulsion (E-SBR). 
1. Emulsion polymerization: 
E-SBR produced by emulsion polymerization is initiated 
by free radicals. 
2. Solution polymerization 
Solution-SBR is produced by an anionic polymerization 
process. 
V.Buna S: 
The material was initially marketed with the brand name Buna S. Its 
name derives Bu for butadiene and Na for sodium (natrium in several 
languages including Latin, German and Dutch), and S for styrene. 
22-Dec-13 Made By Kareem Tharaa
VI.The Properties Of SBR: 
Property E-SBR 
Tensile Strength 19 
Elongation at tear 635 
Glass Transition 
Temperature 
-50 
Property S-SBR 
Tensile Strength 18 
Elongation at tear 565 
Glass Transition 
Temperature 
-65 
22-Dec-13 Made By Kareem Tharaa
VII.Applications: 
1. The elastomer is used widely in 
pneumatic tires, shoe heels and 
soles, gaskets and even chewing gum. 
2. It is a commodity material which competes 
with natural rubber. 
3. Latex (emulsion) SBR is extensively used 
in coated papers, being one of the most cost-effective 
resins to bind pigmented coatings. 
4. It is also used in building applications, as a 
sealing and binding agent behind renders as an 
alternative to PVA, but is more expensive. 
22-Dec-13 Made By Kareem Tharaa 7
VIII.Flow Sheet:

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Styrene butadiene rubber

  • 1. Table Of Contents I. Introduction. 1 II. The Molecular Formula. 2 III. Production. 3 IV. Types Of SBR. 4 V. Buna S. 4 VI. Properties Of SBR. 5 VII.Appilications. 6 VIII.Flow Sheet. 7 22-Dec-13 Made By Kareem Tharaa
  • 2. I.Introduction: • Styrene-butadiene or styrene-butadiene rubber (SBR) describe families of synthetic rubbers derived from styrene and butadiene. • These materials have good abrasion resistance and good aging stability when protected by additives. • About 50% of car tires are made from types of SBR. • The styrene/butadiene ratio influences the properties of the polymer: with high styrene content, the rubbers are harder and less rubbery. 22-Dec-13 Made By Kareem Tharaa
  • 3. II.The Molecular Formula : 22-Dec-13 Made By Kareem Tharaa
  • 4. III.Production: From ethanol In other parts of the world, including South America, Eastern Europe, China, and India, butadiene was also produced from ethanol. While not competitive with steam cracking for producing large volumes of butadiene, lower capital costs make production from ethanol a viable option for smaller-capacity plants. Two processes were in use. In the single-step process developed by Sergei Lebedev, ethanol is converted to butadiene, hydrogen, and water at 400–450 °C over any of a variety of metal oxide catalysts. 2 CH3CH2OH → CH2=CH-CH=CH2 + 2 H2O + H2
  • 5. IV.Types of SBR: SBR is derived from two monomers, styrene and butadiene. The mixture of these two monomers are polymerized by two basically different processes: from solution (S-SBR) or as an emulsion (E-SBR). 1. Emulsion polymerization: E-SBR produced by emulsion polymerization is initiated by free radicals. 2. Solution polymerization Solution-SBR is produced by an anionic polymerization process. V.Buna S: The material was initially marketed with the brand name Buna S. Its name derives Bu for butadiene and Na for sodium (natrium in several languages including Latin, German and Dutch), and S for styrene. 22-Dec-13 Made By Kareem Tharaa
  • 6. VI.The Properties Of SBR: Property E-SBR Tensile Strength 19 Elongation at tear 635 Glass Transition Temperature -50 Property S-SBR Tensile Strength 18 Elongation at tear 565 Glass Transition Temperature -65 22-Dec-13 Made By Kareem Tharaa
  • 7. VII.Applications: 1. The elastomer is used widely in pneumatic tires, shoe heels and soles, gaskets and even chewing gum. 2. It is a commodity material which competes with natural rubber. 3. Latex (emulsion) SBR is extensively used in coated papers, being one of the most cost-effective resins to bind pigmented coatings. 4. It is also used in building applications, as a sealing and binding agent behind renders as an alternative to PVA, but is more expensive. 22-Dec-13 Made By Kareem Tharaa 7