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Sodium chloride

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This article is about the chemical. For its familiar form, common table salt, see Salt. For the medical solutions, see Saline (medicine). For the mineral, see Halite.
"NaCl" redirects here. For other uses, see NaCl (disambiguation).

Sodium chloride

Sodium chloride crystals in a form of halite

Crystal structure with sodium in purple and chloride in green[1]
Names
IUPAC name
Sodium chloride
Other names
  • common salt, regular salt
  • halite, rock salt
  • table salt, sea salt
  • saline
Identifiers
3D model (JSmol)
3534976
ChEBI
ChEMBL
ChemSpider
ECHA InfoCard 100.028.726 Edit this at Wikidata
EC Number
  • 231-598-3
13673
KEGG
MeSH Sodium+chloride
RTECS number
  • VZ4725000
UNII
  • InChI=1S/ClH.Na/h1H;/q;+1/p-1 checkY
    Key: FAPWRFPIFSIZLT-UHFFFAOYSA-M checkY
  • InChI=1/ClH.Na/h1H;/q;+1/p-1
    Key: FAPWRFPIFSIZLT-REWHXWOFAE
  • [Na+].[Cl-]
Properties
NaCl
Molar mass 58.443 g/mol[2]
Appearance Colorless cubic crystals[2]
Odor Odorless
Density 2.17 g/cm3[2]
Melting point 800.7 °C (1,473.3 °F; 1,073.8 K)[2]
Boiling point 1,465 °C (2,669 °F; 1,738 K)[2]
360 g/L (25°C)[2]
Solubility in ammonia 21.5 g/L
Solubility in methanol 14.9 g/L
−30.2·10−6 cm3/mol[3]
1.5441 (at 589 nm)[4]
Structure[5]
Face-centered cubic
(see text), cF8
Fm3m (No. 225)
a = 564.02 pm
4
octahedral at Na+
octahedral at Cl−
Thermochemistry[6]
50.5 J/(K·mol)
72.10 J/(K·mol)
−411.120 kJ/mol
Pharmacology
A12CA01 (WHO) B05CB01 (WHO), B05XA03 (WHO), S01XA03 (WHO)
Hazards
NFPA 704 (fire diamond)
NFPA 704 four-colored diamondHealth 0: Exposure under fire conditions would offer no hazard beyond that of ordinary combustible material. E.g. sodium chlorideFlammability 0: Will not burn. E.g. waterInstability 0: Normally stable, even under fire exposure conditions, and is not reactive with water. E.g. liquid nitrogenSpecial hazards (white): no code
0
0
0
Lethal dose or concentration (LD, LC):
3 g/kg (oral, rats)[7]
Related compounds
Other anions
 Sodium fluoride
Sodium bromide
Sodium iodide
Sodium astatide
Other cations
 Lithium chloride
Potassium chloride
Rubidium chloride
Caesium chloride
Francium chloride
Supplementary data page
Sodium chloride (data page)
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
☒N verify (what is checkY☒N ?)

Sodium chloride /ˌsoʊdiəm ˈklɔːraɪd/,[8] commonly known as edible salt, is an ionic compound with the chemical formula NaCl, representing a 1:1 ratio of sodium and chlorine ions. It is transparent or translucent, brittle, hygroscopic, and occurs as the mineral halite. In its edible form, it is commonly used as a condiment and food preservative. Large quantities of sodium chloride are used in many industrial processes, and it is a major source of sodium and chlorine compounds used as feedstocks for further chemical syntheses. Another major application of sodium chloride is deicing of roadways in sub-freezing weather.

Uses

In addition to the familiar domestic uses of salt, more dominant applications of the approximately 250 million tonnes per year production (2008 data) include chemicals and de-icing.[9]

Chemical functions

Salt is used, directly or indirectly, in the production of many chemicals, which consume most of the world's production.[10]

Chlor-alkali industry

See also: Chloralkali process

It is the starting point for the chloralkali process, the industrial process to produce chlorine and sodium hydroxide, according to the chemical equation

This electrolysis is conducted in either a mercury cell, a diaphragm cell, or a membrane cell. Each of those uses a different method to separate the chlorine from the sodium hydroxide. Other technologies are under development due to the high energy consumption of the electrolysis, whereby small improvements in the efficiency can have large economic paybacks. Some applications of chlorine include PVC thermoplastics production, disinfectants, and solvents.

Sodium hydroxide is extensively used in many different industries enabling production of paper, soap, and aluminium etc.

Soda-ash industry

Sodium chloride is used in the Solvay process to produce sodium carbonate and calcium chloride. Sodium carbonate, in turn, is used to produce glass, sodium bicarbonate, and dyes, as well as a myriad of other chemicals. In the Mannheim process, sodium chloride is used for the production of sodium sulfate and hydrochloric acid.

Miscellaneous industrial uses

Sodium chloride is heavily used, so even relatively minor applications can consume massive quantities. In oil and gas exploration, salt is an important component of drilling fluids in well drilling.[11] It is used to flocculate and increase the density of the drilling fluid to overcome high downwell gas pressures. Whenever a drill hits a salt formation, salt is added to the drilling fluid to saturate the solution in order to minimize the dissolution within the salt stratum.[9] Salt is also used to increase the curing of concrete in cemented casings.[10]

In textiles and dyeing, salt is used as a brine rinse to separate organic contaminants,[12] to promote "salting out" of dyestuff precipitates, and to blend with concentrated dyes to increase yield in dyebaths and make the colors look sharper. One of its main roles is to provide the positive ion charge to promote the absorption of negatively charged ions of dyes.[10]

For use in the pulp and paper industry, it is used to manufacture sodium chlorate, which is then reacted with sulfuric acid and a reducing agent such as methanol to manufacture chlorine dioxide, a bleaching chemical that is widely used to bleach wood pulp.

In tanning and leather treatment, salt is added to animal hides to inhibit microbial activity on the underside of the hides and to attract moisture back into the hides.[10]

In rubber manufacture, salt is used to make buna, neoprene, and white rubber types. Salt brine and sulfuric acid are used to coagulate an emulsified latex made from chlorinated butadiene.[10][9]

Salt also is added to secure the soil and to provide firmness to the foundation on which highways are built. The salt acts to minimize the effects of shifting caused in the subsurface by changes in humidity and traffic load.[10]

Water softening

Hard water contains calcium and magnesium ions that interfere with action of soap and contribute to the buildup of a scale or film of alkaline mineral deposits in household and industrial equipment and pipes. Commercial and residential water-softening units use ion-exchange resins to remove ions that cause the hardness. These resins are generated and regenerated using sodium chloride.[10][9]

Road salt

The second major application of salt is for deicing and anti-icing of roads, both in grit bins and spread by winter service vehicles. In anticipation of snowfall, roads are optimally "anti-iced" with brine (concentrated solution of salt in water), which prevents bonding between the snow-ice and the road surface. This procedure obviates the heavy use of salt after the snowfall. For de-icing, mixtures of brine and salt are used, sometimes with additional agents such as calcium chloride and/or magnesium chloride. The use of salt or brine becomes ineffective below −10 °C (14 °F).

Mounds of road salt for use in winter

Salt for de-icing in the United Kingdom predominantly comes from a single mine in Winsford in Cheshire. Prior to distribution it is mixed with <100 ppm of sodium ferrocyanide as an anticaking agent, which enables rock salt to flow freely out of the gritting vehicles despite being stockpiled prior to use. In recent years this additive has also been used in table salt. Other additives had been used in road salt to reduce the total costs. For example, in the US, a byproduct carbohydrate solution from sugar-beet processing was mixed with rock salt and adhered to road surfaces about 40% better than loose rock salt alone. Because it stayed on the road longer, the treatment did not have to be repeated several times, saving time and money.[10]

In the technical terms of physical chemistry, the minimum freezing point of a water-salt mixture is −21.12 °C (−6.02 °F) for 23.31 wt% of salt. Freezing near this concentration is however so slow that the eutectic point of −22.4 °C (−8.3 °F) can be reached with about 25 wt% of salt.[13]

Environmental effects

Road salt ends up in fresh-water bodies and could harm aquatic plants and animals by disrupting their osmoregulation ability.[14] The omnipresence of salt in coastal areas poses a problem in any coating application, because trapped salts cause great problems in adhesion. Naval authorities and ship builders monitor the salt concentrations on surfaces during construction. Maximal salt concentrations on surfaces are dependent on the authority and application. The IMO regulation is mostly used and sets salt levels to a maximum of 50 mg/m2 soluble salts measured as sodium chloride. These measurements are done by means of a Bresle test. Salinization (increasing salinity, aka freshwater salinization syndrome) and subsequent increased metal leaching is an ongoing problem throughout North America and European fresh waterways.[15]

In highway de-icing, salt has been associated with corrosion of bridge decks, motor vehicles, reinforcement bar and wire, and unprotected steel structures used in road construction. Surface runoff, vehicle spraying, and windblown salt also affect soil, roadside vegetation, and local surface water and groundwater supplies. Although evidence of environmental loading of salt has been found during peak usage, the spring rains and thaws usually dilute the concentrations of sodium in the area where salt was applied.[10] A 2009 study found that approximately 70% of the road salt being applied in the Minneapolis-St Paul metro area is retained in the local watershed.[16]

Substitution

Some agencies are substituting beer, molasses, and beet juice instead of road salt.[17] Airlines utilize more glycol and sugar rather than salt-based solutions for deicing.[18]

Food industry and agriculture

Main article: Salt

Salt is added to food, either by the food producer or by the consumer, as a flavor enhancer, preservative, binder, fermentation-control additive, texture-control agent, and color developer. The salt consumption in the food industry is subdivided, in descending order of consumption, into other food processing, meat packers, canning, baking, dairy, and grain mill products. Salt is added to promote color development in bacon, ham and other processed meat products. As a preservative, salt inhibits the growth of bacteria. Salt acts as a binder in sausages to form a binding gel made up of meat, fat, and moisture. Salt also acts as a flavor enhancer and as a tenderizer.[10]

It is used as a cheap and safe desiccant because of its hygroscopic properties, making salting an effective method of food preservation historically; the salt draws water out of bacteria through osmotic pressure, keeping it from reproducing, a major source of food spoilage. Even though more effective desiccants are available, few are safe for humans to ingest. Many microorganisms cannot live in a salty environment: water is drawn out of their cells by osmosis. For this reason salt is used to preserve some foods, such as bacon, fish, or cabbage.

In many dairy industries, salt is added to cheese as a color-, fermentation-, and texture-control agent. The dairy subsector includes companies that manufacture creamery butter, condensed and evaporated milk, frozen desserts, ice cream, natural and processed cheese, and specialty dairy products. In canning, salt is primarily added as a flavor enhancer and preservative. It also is used as a carrier for other ingredients, dehydrating agent, enzyme inhibitor and tenderizer. In baking, salt is added to control the rate of fermentation in bread dough. It also is used to strengthen the gluten (the elastic protein-water complex in certain doughs) and as a flavor enhancer, such as a topping on baked goods. The food-processing category also contains grain mill products. These products consist of milling flour and rice and manufacturing cereal breakfast food and blended or prepared flour. Salt is also used a seasoning agent, e.g. in potato chips, pretzels, and cat and dog food.[10]

Sodium chloride is used in veterinary medicine as emesis-causing agent. It is given as warm saturated solution. Emesis can also be caused by pharyngeal placement of small amount of plain salt or salt crystals.

Medicine

Main article: Saline (medicine)

Sodium chloride is used together with water as one of the primary solutions for intravenous therapy. Nasal spray often contains a saline solution.

Sodium chloride is also available as an oral tablet, and is taken to treat low sodium levels.[19]

Firefighting

A class-D fire extinguisher for various metals

Sodium chloride is the principal extinguishing agent in dry-powder fire extinguishers that are used on combustible metal fires, for metals such as magnesium, zirconium, titanium, and lithium (Class D extinguishers). The salt forms an oxygen-excluding crust that smothers the fire.[20]

Cleanser

Since at least medieval times, people have used salt as a cleansing agent rubbed on household surfaces. It is also used in many brands of shampoo, toothpaste, and popularly to de-ice driveways and patches of ice.

Infrared optics

Sodium chloride crystals have a transmittance of at least 90% (through 1 mm) for infrared light having wavelengths in the range 0.2– 18 μm.[21] They were used in optical components such as windows and lenses, where few non-absorbing alternatives existed in that spectral range. While inexpensive, NaCl crystals are soft and hygroscopic – when exposed to the water in ambient air, they gradually cover with "frost". This limits application of NaCl to dry environments, vacuum-sealed areas, or short-term uses such as prototyping. Materials that are mechanically stronger and less sensitive to moisture, such as zinc selenide and chalcogenide glasses, more widely used than NaCl.

Chemistry

Sodium chloride crystal under microscope.
NaCl octahedra. The yellow stipples represent the electrostatic force between the ions of opposite charge

Solid sodium chloride

See also: Cubic crystal system

In solid sodium chloride, each ion is surrounded by six ions of the opposite charge as expected on electrostatic grounds. The surrounding ions are located at the vertices of a regular octahedron. In the language of close-packing, the larger chloride ions (167 pm in size[22]) are arranged in a cubic array whereas the smaller sodium ions (116 pm[22]) fill all the cubic gaps (octahedral voids) between them. This same basic structure is found in many other compounds and is commonly known as the NaCl structure or rock salt crystal structure. It can be represented as a face-centered cubic (fcc) lattice with a two-atom basis or as two interpenetrating face centered cubic lattices. The first atom is located at each lattice point, and the second atom is located halfway between lattice points along the fcc unit cell edge.

Solid sodium chloride has a melting point of 801 °C and liquid sodium chloride boils at 1465 °C. Atomic-resolution real-time video imaging allows visualization of the initial stage of crystal nucleation of sodium chloride.[23]

The Thermal conductivity of sodium chloride as a function of temperature has a maximum of 2.03 W/(cm K) at 8 K (−265.15 °C; −445.27 °F) and decreases to 0.069 at 314 K (41 °C; 106 °F). It also decreases with doping.[24]

View of one slab of hydrohalite, NaCl·2H2O. (red = O, white = H, green = Cl, purple = Na).[25]

From cold (sub-freezing) solutions, salt crystallises with water of hydration as hydrohalite (the dihydrate NaCl·2H2O).[26]

In 2023, it was discovered that under pressure, sodium chloride can form the hydrates NaCl·8.5H2O and NaCl·13H2O.[27]

Aqueous solutions

Phase diagram of water–NaCl mixture

The attraction between the Na+ and Cl− ions in the solid is so strong that only highly polar solvents like water dissolve NaCl well.

When dissolved in water, the sodium chloride framework disintegrates as the Na+ and Cl− ions become surrounded by polar water molecules. These solutions consist of metal aquo complex with the formula [Na(H2O)8]+, with the Na–O distance of 250 pm. The chloride ions are also strongly solvated, each being surrounded by an average of six molecules of water.[28] Solutions of sodium chloride have very different properties from pure water. The eutectic point is −21.12 °C (−6.02 °F) for 23.31% mass fraction of salt, and the boiling point of saturated salt solution is near 108.7 °C (227.7 °F).[13]

pH of sodium chloride solutions

The pH of a sodium chloride solution remains ≈7 due to the extremely weak basicity of the Cl− ion, which is the conjugate base of the strong acid HCl. In other words, NaCl has no effect on system pH[29] in diluted solutions where the effects of ionic strength and activity coefficients are negligible.

Solubility of NaCl
(g NaCl / 1 kg of solvent at 25 °C (77 °F))[30]
Water 360
Formamide 94
Glycerin 83
Propylene glycol 71
Formic acid 52
Liquid ammonia 30.2
Methanol 14
Ethanol 0.65
Dimethylformamide 0.4
Propan-1-ol 0.124
Sulfolane 0.05
Butan-1-ol 0.05
Propan-2-ol 0.03
Pentan-1-ol 0.018
Acetonitrile 0.003
Acetone 0.00042

Stoichiometric and structure variants

Common salt has a 1:1 molar ratio of sodium and chlorine. In 2013, compounds of sodium and chloride of different stoichiometries have been discovered; five new compounds were predicted (e.g., Na3Cl, Na2Cl, Na3Cl2, NaCl3, and NaCl7). The existence of some of them has been experimentally confirmed at high pressures and other conditions: cubic and orthorhombic NaCl3, two-dimensional metallic tetragonal Na3Cl and exotic hexagonal NaCl.[31] This indicates that compounds violating chemical intuition are possible, in simple systems under non-ambient conditions.[32]

Occurrence

Salt is found in the Earth's crust as the mineral halite (rock salt), and a tiny amount exists as suspended sea salt particles in the atmosphere.[33] These particles are the dominant cloud condensation nuclei far out at sea, which allow the formation of clouds in otherwise non-polluted air.[34]

Production

Salt is currently mass-produced by evaporation of seawater or brine from brine wells and salt lakes. Mining of rock salt is also a major source. China is the world's main supplier of salt.[10] In 2017, world production was estimated at 280 million tonnes, the top five producers (in million tonnes) being China (68.0), United States (43.0), India (26.0), Germany (13.0), and Canada (13.0).[35] Salt is also a byproduct of potassium mining.

See also

References

  1. ^ "Sodium Chloride (NaCl) Crystal". PhysicsOpenLab. Retrieved 23 August 2021.
  2. ^ a b c d e f Haynes, 4.89
  3. ^ Haynes, 4.135
  4. ^ Haynes, 10.241
  5. ^ Haynes, 4.148
  6. ^ Haynes, 5.8
  7. ^ Tucker, R. K.; Haegele, M. A. (1971). "Comparative acute oral toxicity of pesticides to six species of birds". Toxicology and Applied Pharmacology. 20 (1): 57–65. doi:10.1016/0041-008x(71)90088-3. ISSN 0041-008X. PMID 5110827.
  8. ^ Wells, John C. (2008), Longman Pronunciation Dictionary (3rd ed.), Longman, pp. 143 and 755, ISBN 9781405881180
  9. ^ a b c d Westphal, Gisbert et al. (2002) "Sodium Chloride" in Ullmann's Encyclopedia of Industrial Chemistry, Wiley-VCH, Weinheim doi:10.1002/14356007.a24_317.pub4.
  10. ^ a b c d e f g h i j k l Kostick, Dennis S. (October 2010). "Salt" (PDF). U.S. Geological Survey, 2008 Minerals Yearbook.
  11. ^ Caenn, Ryen; Darley, H. C. H.; Gray, George Robert; Gray, George Robert (2011). Composition and properties of drilling and completion fluids (6th ed.). Amsterdam ; Boston, MA: Gulf Professional Pub. ISBN 978-0-12-383858-2.
  12. ^ Partal, Recep; Basturk, Irfan; Murat Hocaoglu, Selda; Baban, Ahmet; Yilmaz, Ecem (2022). "Recovery of water and reusable salt solution from reverse osmosis brine in textile industry: A case study". Water Resources and Industry. 27: 100174. doi:10.1016/j.wri.2022.100174.
  13. ^ a b Elvers, B. et al. (ed.) (1991) Ullmann's Encyclopedia of Industrial Chemistry, 5th ed. Vol. A24, Wiley, p. 319, ISBN 978-3-527-20124-2.
  14. ^ Rastogi, Nina Shen (16 February 2010). "Salting the Earth". Slate. ISSN 1091-2339. Retrieved 11 March 2023.
  15. ^ "Saltier waterways are creating dangerous 'chemical cocktails'". phys.org.
  16. ^ "Most Road Salt Is Making It into Lakes And Rivers". www.sciencedaily.com. University of Minnesota. 20 February 2009. Retrieved 27 September 2015.
  17. ^ Casey, Michael. "Turning to beet juice and beer to address road salt danger". phys.org.
  18. ^ "EASA Cautions on Organic Salt Deicing Fluid". MRO Network. 9 December 2016.
  19. ^ "Sodium Chloride for oral solution". Cleveland Clinic. Retrieved 9 March 2024.
  20. ^ Bagot, Keith; Subbotin, Nicholas; Kalberer, Jennifer (November 2006). "Evaluation of a New Liquid Fire-Extinguishing Agent for Combustible Metal Fires" (PDF). Federal Aviation Administration. U.S. Department of Transportation. Retrieved 1 May 2024.
  21. ^ Waynant, Ronald W.; Ediger, Marwood N. (2000). "Chapter 11: Optical Materials: Visible and Infrared". Electro-optics Handbook. New York: McGraw-Hill Professional Publishing. p. 11.20. ISBN 0-07-068716-1.
  22. ^ a b R. D. Shannon (1976). "Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides". Acta Crystallogr A. 32 (5): 751–767. Bibcode:1976AcCrA..32..751S. doi:10.1107/S0567739476001551.
  23. ^ Nakamuro, Takayuki; Sakakibara, Masaya; Nada, Hiroki; Harano, Koji; Nakamura, Eiichi (2021). "Capturing the Moment of Emergence of Crystal Nucleus from Disorder". Journal of the American Chemical Society. 143 (4): 1763–1767. doi:10.1021/jacs.0c12100. PMID 33475359.
  24. ^ Sirdeshmukh, Dinker B.; Sirdeshmukh, Lalitha & Subhadra, K. G. (2001). Alkali halides: a handbook of physical properties. Springer. pp. 65, 68. ISBN 978-3-540-42180-1.
  25. ^ Klewe, B; Pedersen (1974). "The crystal structure of sodium chloride dihydrate". Acta Crystallogr. B30 (10): 2363–2371. Bibcode:1974AcCrB..30.2363K. doi:10.1107/S0567740874007138.
  26. ^ Water-NaCl phase diagram. Lide, CRC Handbook of Chemistry and Physics, 86 ed (2005-2006), CRC pages 8-71, 8-116
  27. ^ University of Washington. "Newly discovered form of salty ice could exist on surface of extraterrestrial moons". Phys.org.
  28. ^ Lincoln, S. F.; Richens, D. T. and Sykes, A. G. (2003) "Metal Aqua Ions" Comprehensive Coordination Chemistry II Volume 1, pp. 515–555. doi:10.1016/B0-08-043748-6/01055-0.
  29. ^ "Acidic, Basic, and Neutral Salts". Flinn Scientific Chem Fax. 2016. Retrieved 18 September 2018. Neutralization of a strong acid and a strong base gives a neutral salt.
  30. ^ Burgess, J (1978). Metal Ions in Solution. New York: Ellis Horwood. ISBN 978-0-85312-027-8.
  31. ^ Tikhomirova, K. A.; Tantardini, C.; Sukhanova, E. V.; Popov, Z. I.; Evlashin, S. A.; Tarkhov, M. A.; Zhdanov, V. L. (2020). "Exotic Two-Dimensional Structure: The first case of Hexagonal NaCl". The Journal of Physical Chemistry Letters. 11 (10): 3821–3827. doi:10.1021/acs.jpclett.0c00874. PMID 32330050. S2CID 216130640.
  32. ^ Zhang, W.; Oganov, A. R.; Goncharov, A. F.; Zhu, Q.; Boulfelfel, S. E.; Lyakhov, A. O.; Stavrou, E.; Somayazulu, M.; Prakapenka, V. B.; Konôpková, Z. (2013). "Unexpected Stable Stoichiometries of Sodium Chlorides". Science. 342 (6165): 1502–1505. arXiv:1310.7674. Bibcode:2013Sci...342.1502Z. doi:10.1126/science.1244989. PMID 24357316. S2CID 15298372.
  33. ^ Finlayson-Pitts, Barbara J.; Hemminger, John C. (1 December 2000). "Physical Chemistry of Airborne Sea Salt Particles and Their Components". The Journal of Physical Chemistry A. 104 (49): 11463–11477. doi:10.1021/jp002968n. ISSN 1089-5639.
  34. ^ Mason, B. J. (2006). "The role of sea-salt particles as cloud condensation nuclei over the remote oceans". Quarterly Journal of the Royal Meteorological Society. 127 (576): 2023–32. Bibcode:2001QJRMS.127.2023M. doi:10.1002/qj.49712757609. S2CID 121846285.
  35. ^ Bolen, Wallace P. (January 2018). "Salt" (PDF). U.S. Geological Survey, 2018 Mineral Commodity Summaries.

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