Sodium deuteroxide

Sodium deuteroxide^[1]
Names
	IUPAC name Sodium deuteroxide
	Other names Deuterated sodium hydroxide; Sodium hydroxide-d;
Identifiers
CAS Number	14014-06-3;
3D model (JSmol)	Interactive image;
ChemSpider	9193979;
ECHA InfoCard	100.034.373
EC Number	237-825-2;
PubChem CID	23676750;
CompTox Dashboard (EPA)	DTXSID80930715 ;
	InChI InChI=1S/Na.H2O/h;1H2/q+1;/p-1/i/hD Key: HEMHJVSKTPXQMS-DYCDLGHISA-M;
	SMILES [Na+].[O-][2H];
Properties
Chemical formula	NaOD or NaO2H
Molar mass	41.003 g/mol
Appearance	White solid
Solubility in water	Soluble
Hazards
	GHS labelling:
Pictograms
Signal word	Danger
Hazard statements	H290, H314
Precautionary statements	P260, P264, P280, P301+P330+P331, P303+P361+P353, P304+P340, P305+P351+P338, P310, P321, P363, P405, P501
NFPA 704 (fire diamond)	3 0 1
Related compounds
Related compounds	Sodium hydroxide
	Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). Infobox references

Sodium deuteroxide or deuterated sodium hydroxide is a chemical compound with the formula Na O D or NaO²H. IUPAC recommends that the symbol for deuterium should be ²H,^[2] although most chemists use the term NaOD. It is a white solid very similar to sodium hydroxide, of which it is an isotopologue. It is used as a strong base and deuterium source in the production of other deuterated compounds. For example, reaction with chloral hydrate gives deuterated chloroform,^[3] and reaction with N-nitrosodimethylamine gives the deuterated analog of that compound.^[4]^{[full citation needed]} Sodium deuteroxide is an ionic compound, consisting of sodium cations Na⁺ and deuteroxide anions ⁻OD (or ⁻O²H).

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[1]
"Sodium deuteroxide". Sigma aldrich. Retrieved 30 April 2021.
[2]
"Provisional Recommendations". Nomenclature of Inorganic Chemistry. Chemical Nomenclature and Structure Representation Division. IUPAC. § IR-3.3.2. Archived from the original on 27 October 2006. Retrieved 2024-08-01.
[3]
Breuer, F. W. (1935). "Chloroform-d (Deuteriochloroform)". Journal of the American Chemical Society. 57 (11): 2236–2237. doi:10.1021/ja01314a058.
[4]
National Cancer Institute (U.S.) (1973). Journal (51 ed.). the University of Michigan.

[1] [1]
"Sodium deuteroxide". Sigma aldrich. Retrieved 30 April 2021.

[2] [2]
"Provisional Recommendations". Nomenclature of Inorganic Chemistry. Chemical Nomenclature and Structure Representation Division. IUPAC. § IR-3.3.2. Archived from the original on 27 October 2006. Retrieved 2024-08-01.

[3] [3]
Breuer, F. W. (1935). "Chloroform-d (Deuteriochloroform)". Journal of the American Chemical Society. 57 (11): 2236–2237. doi:10.1021/ja01314a058.

[4] [4]
National Cancer Institute (U.S.) (1973). Journal (51 ed.). the University of Michigan.

[2]

[3]

[4]

[1]

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Sodium deuteroxide

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Notes

References

Names

IUPAC name Sodium deuteroxide
Other names Deuterated sodium hydroxide Sodium hydroxide-d
Identifiers
CAS Number	14014-06-3
3D model (JSmol)	Interactive image
ChemSpider	9193979
ECHA InfoCard	100.034.373
EC Number	237-825-2
PubChem CID	23676750
CompTox Dashboard (EPA)	DTXSID80930715
InChI InChI=1S/Na.H2O/h;1H2/q+1;/p-1/i/hD Key: HEMHJVSKTPXQMS-DYCDLGHISA-M
SMILES [Na+].[O-][2H]
Properties
Chemical formula	NaOD or NaO²H
Molar mass	41.003 g/mol
Appearance	White solid
Solubility in water	Soluble
Hazards
GHS labelling:
Pictograms
Signal word	Danger
Hazard statements	H290, H314
Precautionary statements	P260, P264, P280, P301+P330+P331, P303+P361+P353, P304+P340, P305+P351+P338, P310, P321, P363, P405, P501
NFPA 704 (fire diamond)	3 0 1
Related compounds
Related compounds	Sodium hydroxide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). Infobox references