Water interaction with other molecules

It is well known the tendency of polysaccharides to associate in aqueous solution. These molecular associations can deeply affect their function in a particular application due to their influence on molecular weight, shape and size, which determines how molecules interact with other molecules and water. There are several factors such as hydrogen bonding, hydrophobic association, an association mediated by ions, electrostatic interactions, which depend on the concentration and the presence of protein components that affect the ability to form supramolecular complexes. [Pg.8]

In many products, the spin-relaxation properties of the components can be different due to molecular sizes, local viscosity and interaction with other molecules. Macromolecules often exhibit rapid FID decay and short T2 relaxation time due to its large molecular weight and reduced rotational dynamics [18]. Mobile water protons, on the other hand, are often found to have long relaxation times due to their small molecular weight and rapid diffusion. As a result, relaxation properties, such as T2, have been used extensively to quantify water/moisture content, fat contents, etc. [20]. For example, oil content in seeds is determined via the spin-echo technique as described according to international standards [64]. [Pg.176]

When methanol interacts with other molecules, there are some characteristic differences to water [36]. For example, methanol can symmetrically bind two HC1 molecules to its lone pairs without significant energy penalty compared to a cooperative ring arrangement [61]. This is not the case for water, because its... [Pg.28]

The orientation of molecules at the interface depends on an interaction with both the surface and the molecules in the liquid phase, and also on the interaction within the adsorbed layer. The interaction of molecules with the electrode is stronger the weaker their interaction with other molecules in the bulk. The correlation between and 0 is linear but different for the transition metals and the sp metals. Owing to the tendency to form chemisorption bonds, transition metals bind water molecules more strongly than the sp metals. [Pg.18]

A mechanism that explains the high apparent ionic mobilities of protons and hydroxide ions in terms of hydrogen bond-making/-breaking steps along extended chains of water molecules. Solvation of a proton can be represented simply as H30, and this hydronium ion strongly interacts with other molecules in a hydrogen-bond network. [Pg.325]

Feldmann and others have developed a series of teaching tools for macromolecular structure using color-coded molecular graphics-derived images 24 28). Connolly and others have improved upon this approach by clearly showing which portions of the protein surface are indeed accessible to a water molecule, as opposed to those portions which are inaccessible, such as in clefts, etc 27). Images based on the Connolly methods directly show those regions of the protein surface which can be expected to interact with other molecules. It provides immediate, comprehensible information about steric complimentarity. [Pg.11]

This final hybrid mechanism may be responsible for the formation of the dimer Ion of the dodecanucleotlde (1) or of water clusters (17). Each molecular unit ejects Intact and then Interacts with other molecules In the near surface region to form the cluster entitles. In the case of (H20)2 clusters our calculations Indicate that the two H2O molecules originate from mostly adjacent sites on the surface (15). This Is a consequence of the relatively weak H2O-H2O Interaction. Ionic clusters such as (H20)H+, however, can form from an H2O molecule and an H Ion that were further apart on the surface. [Pg.46]

Great. Now if we only knew what acids and bases are There are a number of ways to define acids and bases, and Til give you two of them here. Before doing that, I need to remind you of how water interacts with other chemicals. Water molecules are polar, with one end being positive and the other negative. See Figure 4.6. [Pg.72]

It was assumed in the kinetic theory of gases that molecules are materially unchanged as a result of interactions with other molecules, and collisions are instantaneous events as would occur if the molecules were impenetrable and perfectly elastic. As a result, it seemed quite natural that the trajectories of molecules would sometimes undergo discontinuous changes. Robert Brown, in 1827, observed the random motion of a speck of pollen immersed in a water droplet. Discontinuous changes in the speed and direction of the motion of the pollen mote were observed, but the mechanism causing these changes was not understood. [Pg.53]

Hydration is the process of transferring a molecule from the gas phase, where it is assumed that there are no interactions with other molecules, into an infinite bath of water. The energy of a molecule in solution, relative to our reference state, is ... [Pg.239]

A multitude of noncovalent interactions, such as hydrogen bonding, hydrophobic, electrostatic, i/r-cation, and van der Waals interactions, contributes to the stability of biological assemblies and to the specificity of interaction with other molecules (Figure 1). The hydrophobic effect removes large nonpolar surface areas away from water resulting in supramolecular structures. Although this is... [Pg.3462]

The solubilities of fluorinated surfactants are related to the unusual properties of the fluorine atom and the C—F bond. Fluorine is the most electronegative element and is very difficult to polarize. Fluorine can form a very stable bond with hydrogen or carbon (see Section 3.1). The rigidity of the C— F bond causes stiffening of the perfluoroalkane chain and limits interactions with other molecules. Because of their small size, fluorine atoms can shield the perfluorinated carbon atom without steric stresses. Perfluoromethyl or perfluoromethylene groups therefore form compounds with very weak intermolecular forces. As a consequence of weak interactions, perfluoroalkanes are insoluble in common organic solvents. Perfluo-roalkanes are more hydrophobic than hydrocarbons, evidenced by solubility data CF4 is seven times less soluble in water than CH4 [1,2]. Water is almost 7 times less soluble in perfluoroheptane than in heptane on a equal weight basis [3] and 25 times more on a molar basis. [Pg.198]

Some surfactants are used as emulsifiers in processed foods such as bottled salad dressing. An emulsifier causes normally incompatible liquids such as the oil and water in salad dressing to disperse in each other, by forming molecular connections between the liquids. The hydrophobic tails of emulsifier molecules Interact with oil molecules, while the hydrophilic heads on the emulsifier molecules interact with water molecules. [Pg.874]

Polar compounds and compounds that ionize can dissolve readily in water. These compounds are said to be hydrophilic. In contrast to hydrophilic substances, hydrocarbons and other nonpolar substances have very low solubility in water because it is energetically more favorable for water molecules to interact with other water molecules rather than with nonpolar molecules. As a result, water molecules tend to exclude nonpolar substances, forcing them to associate with themselves in forming drops, thereby minimizing the contact area between... [Pg.25]

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