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- MoOPH (oder Oxodiperoxymolybdän-pyridin-hexamethylphosphorsäuretriamid) ist ein Molybdänkomplex der von als Reagenz für die Organische Synthese vorgestellt wurde. Der Komplex dient zur Oxidation von Carbanionen. (de)
- MoOPH, also known as oxodiperoxymolybdenum(pyridine)-(hexamethylphosphoric triamide), is a reagent used in organic synthesis. It contains a molybdenum(VI) center with multiple oxygen ligands, coordinated with pyridine and HMPA ligands. It is an electrophilic source of oxygen that reacts with enolates and related structures, and thus can be used for alpha-hydroxylation of carbonyl-containing compounds. Other reagents used for alpha-hydroxylation via enol or enolate structures include Davis oxaziridine, oxygen, and various peroxyacids (see Rubottom oxidation). This reagent was first utilized by Edwin Vedejs as an efficient alpha-hydroxylating agent in 1974 and an effective preparative procedure was later published in 1978. (en)
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- Vedejs Reagent (en)
- Oxodiperoxymolybdenum(pyridine)(hexamethylphosphoric triamide) (en)
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- 7158 (xsd:nonNegativeInteger)
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- Vedejs Reagent (en)
- Oxodiperoxymolybdenum (en)
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- MoOPH (oder Oxodiperoxymolybdän-pyridin-hexamethylphosphorsäuretriamid) ist ein Molybdänkomplex der von als Reagenz für die Organische Synthese vorgestellt wurde. Der Komplex dient zur Oxidation von Carbanionen. (de)
- MoOPH, also known as oxodiperoxymolybdenum(pyridine)-(hexamethylphosphoric triamide), is a reagent used in organic synthesis. It contains a molybdenum(VI) center with multiple oxygen ligands, coordinated with pyridine and HMPA ligands. It is an electrophilic source of oxygen that reacts with enolates and related structures, and thus can be used for alpha-hydroxylation of carbonyl-containing compounds. Other reagents used for alpha-hydroxylation via enol or enolate structures include Davis oxaziridine, oxygen, and various peroxyacids (see Rubottom oxidation). This reagent was first utilized by Edwin Vedejs as an efficient alpha-hydroxylating agent in 1974 and an effective preparative procedure was later published in 1978. (en)
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