Effects of Lanthanum on Fe-25Cr Alloys under Cyclic Oxidation

Article Preview

Abstract:

Fe-Cr binary model alloys (Cr: 25 wt %) with additions of 0.09 wt% lanthanum were subjected to cyclic oxidation experiments at 700oC. All model alloys were exposed in five different gases; Ar-20O2, Ar-20O2-5H2O, Ar-5O2-20H2O, Ar-10H2-5H2O (pO2 = 3.64 x 10-22 atm) and Ar-10H2-20H2O (pO2 = 7.37 x 10-21 atm) all in volume %. Very low weight gains were observed in all gases of Fe-25Cr-0.09La. However, breakaway oxidation occurred on La-free alloy experienced increased weight gain in Ar-5O2-20H2O due to formation of iron-rich oxide. The addition of La (<0.1 wt%) to the Fe25Cr retarded the growth of iron-rich oxide in Ar-5O2-20H2O.

You might also be interested in these eBooks

Info:

Periodical:

Advanced Materials Research (Volumes 97-101)

Pages:

1212-1215

Citation:

Online since:

March 2010

Export:

Price:

Сopyright:

© 2010 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] P. Huczkowski, S. Ertl, J. Piron-Abellan, N. Christiansen, T. Hofler, V. Shemet, L. Singheiser, W. J. Quadakkers, Microscopy of Oxidation, Science Reviews (2005) 79-88.

DOI: 10.1115/1.1782925

Google Scholar

[2] W. J. Quadakkers, J. P. Abellan, V. Shemet, L. Singheiser, Materials High Temperature 20 (2003) 115.

Google Scholar

[3] S. P. S. Badwal, R. Deller, K. Foger, Y. Ramprakash, J. P. Zhang, Solid State Ionics 99 (1997) 297-310.

DOI: 10.1016/s0167-2738(97)00247-6

Google Scholar

[4] T. Brylewski, M. Nanko, T. Maruyama, K. Przybylski, Solid State Ionics 143 (2001) 131-150.

Google Scholar

[5] K. Przyblski, G. J. Yurek, Materials Science Forum 43 (1989) 1-74.

Google Scholar

[6] H. Nagai, Materials Science Forum 43 (1989) 75-130.

Google Scholar

[7] J. Stringer, Materials Science and Engineering A 120-121 (1989) 129-137.

Google Scholar

[8] F. H. Stott, G. C. Wood, J. Stringer, Oxidation of Metals 44 (1995) 113-145.

Google Scholar

[9] B. A. Pint, Oxidation of Metals 45 (1996) 1-37.

Google Scholar

[10] S. Chevalier, C. Valot, G. Bonnet, J. C. Colson, J. P. Larpin, Materials Science and Engineering A 343 (2003) 257-264.

DOI: 10.1016/s0921-5093(02)00359-3

Google Scholar

[11] S. Mrowec, J. Jedlinski, A. Gil, Materials Science and Engineering A 120-121 (1989) 169-173.

Google Scholar

[12] J. Quadakkers, L. Singheiser, Materials Science Forum 369-372 (2001) 77.

Google Scholar

[13] D. R. Lide, CRC Handbook of Chemistry and Physics, 78th ed., Edited by David R. Lide, (1997).

Google Scholar