Sodium ozonide (NaO3) is an oxygen-rich compound of sodium. As an ozonide, it contains the ozonide anion (O3−).
| Names | |
|---|---|
| IUPAC name
Sodium ozonide
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| Identifiers | |
3D model (JSmol)
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| Properties | |
| NaO3 | |
| Appearance | Intensely red solid[1] |
| Structure[1] | |
| Sodium nitrite structure (orthorhombic) | |
| Im2m (No. 44) | |
a = 3.5070 Å, b = 5.7703 Å, c = 5.2701 Å
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Lattice volume (V)
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106.777 Å3 |
Formula units (Z)
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2 |
| Related compounds | |
Other anions
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Sodium fluoride Sodium chloride Sodium bromide Sodium iodide |
Other cations
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Potassium ozonide Rubidium ozonide Caesium ozonide |
| Sodium oxide Sodium peroxide Sodium superoxide | |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Some experiments report creating sodium ozonide by applying ozone to sodium hydroxide,[2] but the substance was not pure, and the claimed stability at room temperature was contradicted by other reports.[3] This is in contrast to potassium ozonide, rubidium ozonide, and caesium ozonide, which can be synthesized applying ozone directly to the metal. Instead, it is made in ammonia solution using ion exchange and cryptands.[1][4]
The compound is unstable at room temperature and decomposes at -10 °C to sodium superoxide and oxygen.[5]
- 2 NaO3 → 2 NaO2 + O2
However, the compound can be stored for months at -18 °C.[1]
References
edit- ^ a b c d Klein, Wilhelm; Armbruster, Klaus; Jansen, Martin (1998). "Synthesis and crystal structure determination of sodium ozonide". Chemical Communications (6). Royal Society of Chemistry (RSC): 707–708. doi:10.1039/a708570b. ISSN 1359-7345.
- ^ McLachlan, A. D.; Symons, M. C. R.; Townsend, M. G. (1959). "193. Unstable intermediates. Part V. Ozonides and superoxides". Journal of the Chemical Society (Resumed). Royal Society of Chemistry (RSC): 952. doi:10.1039/jr9590000952. ISSN 0368-1769.
- ^ Solomon, I. J.; Kacmarek, A. J. (1960). "Sodium Ozonide". The Journal of Physical Chemistry. 64 (1). American Chemical Society (ACS): 168–169. doi:10.1021/j100830a507. ISSN 0022-3654.
- ^ Korber, Nikolaus; Jansen, Martin (1992). "Synthesewege zu neuen ionischen Ozoniden" [Synthetic Routes to New Ionic Ozonides]. Chemische Berichte (in German). 125 (6). Wiley: 1383–1388. doi:10.1002/cber.19921250613. ISSN 0009-2940.
- ^ Tokareva, S. A.; Pilipenko, G. P. (1964). "Thermal decomposition of sodium ozonide". Bulletin of the Academy of Sciences, USSR Division of Chemical Science. 13 (4). Springer Science and Business Media LLC: 686–688. doi:10.1007/bf00845322. ISSN 0568-5230.
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