CALCULOS PRACTICA 1 Termo 3
CALCULOS PRACTICA 1 Termo 3
CALCULOS PRACTICA 1 Termo 3
ln = −
= 10
= −
+
bibliogra)a:
KORETSKY, Milo D. Engineering and chemical Termodynamics. WILEY John wiley e sons INC. printed
in the united states of America, 2004. ISBN 0-4710-452470-8
temperatura ambiente
25.9°C
25.9 Celsius
78.62 farenheit
299.05 kelvin
contantes de antoine
sustancia a b c
Metanol 11.9673 3626.55 -34.29
Agua 11.3834 3816.44 -46.13
etanol 12.2917 3803.98 -41.68
SECCION DE RESULTADOS
Para el calculo de las temperaturas de ebullición en el caso del agua, metanol y etanol u?lizaremos
la ecuación de Antoine.
ln = −
= 10
= −
+
3626.55
%&' ( = − −34.29 = 343.7554 5& 67
*+,--./.01
11.9673 + ln 0.779936
:;<=.>>
89 *+,--./.01 = − −46.13 = 370.91555& 67
<<.:;:> ?@ A.BBCC:=
3803.98
D' ( = − −41.68 = 357.5423 5& 67
*+,--./.01
12.2917 + ln 0.779936
Bibliogra)a:
F− G H − G
=
F− G H − G
regresión lineal
SUSTANCIA Tref (Y) T ins (x) X^2 XY
metanol 70.6054 58.836 3461.6749 4154.13931
agua 97.7655 92.4447 8546.02256 9037.90232
etanol 84.3923 72.2443 5219.23888 6096.86264
hielo 0.002317 -0.119565 0.01429579 -0.000277
suma 252.765517 223.405435 17226.9506 19288.904
∑ LNM ∑ OM − ∑ LM ∑ LM OM
J=
P ∑ LNM − ∑ LM N
P ∑ LM OM − ∑ LM ∑ OM
Q=
P ∑ LNM − ∑ LM N
U = 0.9085V − 1.5559
60
40
20
0
0 20 40 60 80 100 120
-20
- metanol (promedio)
-hielo (promedio)
y = 0.0044(-0.1195)2 + 0.5087(-0.1195) - 0.0705 = -0.1312599°C
PROMEDIO
Z[[\[]^S_^[J`a[J = ]bJcbacJdJ − ]^e_^[MS^P`Jc
Error de temperatura promedio
sustancia Tcalculada Texperimental error
hielo -0.131259924 -0.119565217 -0.0116947
metanol 45.090832 58.83608696 -13.745255
agua 84.55872737 92.44478261 -7.8860552
etanol 59.64488123 72.24434783 -12.599467
Agua
Z[[\[]^S_^[J`a[J = 84.499524 − 92.4 = −7.900476°k
Z[[\[]^S_^[J`a[J = 84.4863062 − 92.39 = −7.9036938°k
Z[[\[]^S_^[J`a[J = 85.188060 − 92.92 = −7.7319398°k
Etanol
Z[[\[]^S_^[J`a[J = 59.617019 − 72.22 = −12.602981°k
Z[[\[]^S_^[J`a[J = 59.617019 − 72.22 = −12.602981°k
Z[[\[]^S_^[J`a[J = 59.6284618 − −12.601538 = −12.601538°k
Hielo
−0.1060874 − −0.07
%D ( = V100 = 34.0166 %
−0.1060874
−0.1111678 − −0.08
%D ( = V100 = 28.0367 %
−0.1111678
−0.1162474 − −0.09
%D ( = V100 = 22.5788 %
−0.1162474
Metanol
45.24892144 − 58.99
%D ( = V100 = −30.3677 %
45.24892144
45.23864376 − 58.98
%D ( = V100 = −30.37526 %
45.23864376
45.22836696 − 58.97
%D ( = V100 = −30.3827 %
45.22836696
Agua
84.499524 − 92.4
%D ( = V100 = −9.34972 %
84.499524
84.4863062 − 92.39
%D ( = V100 = −9.35499 %
84.4863062
85.1880602 − 92.92
%D ( = V100 = −9.07631 %
85.1880602
Etanol
59.617019 − 72.22
%D ( = V100 = −21.1399%
59.617019
59.617019 − 72.22
%D ( = V100 = −21.1399%
59.617019
59.6284618 − 72.23
%D ( = V100 = −21.1334
59.6284618
Hielo
T calculada Texperimental % error
-0.1060874 -0.07 34.01669415
-0.1111678 -0.08 28.03674156
-0.1162474 -0.09 22.57888695
Metanol
T calculada Texperimental % error
45.24892144 58.99 -30.36774827
45.23864376 58.98 -30.37526128
45.22836696 58.97 -30.38277516
Etanol
T calculada Texperimental % error
59.617019 72.22 -21.139905
59.617019 72.22 -21.139905
59.6284618 72.23 -21.133428
Agua
T calculada Texperimental % error
84.499524 92.4 -9.3497284
84.4863062 92.39 -9.3549998
85.1880602 92.92 -9.0763187
Agua
2126.23
Ť = = 92.4447°
{,
23
Etanol
1661.62
Ť* = = 72.2443°
10-
23
1 1
9 =| ∗~ − R
* +
−1 .y<
.
Hielo
1
9 =| ∗ −0.07 − −0.119565 R = 0.002456°C
* +
23 − 1
1
=|
R
∗ •−0.08 − −0.119565 € = 0.001565 °C
* +
23 − 1
1
=| ∗ −0.09 − −0.119565 R = 0.000874 °C
* +
23 − 1
Metanol
1
9 =| ∗ 58.99 − 58.8360 R = 0.02368921 °C
* +
23 − 1
1
=|
R
9 ∗ •58.98 − 58.8360 € = 0.02071095 °C
* +
23 − 1
1
9 =| ∗ 58.87 − 58.8360 R = 0.01793269 °C
* +
23 − 1
Agua
1
9 =| ∗ 92.4 − 92.4447 R = 0.00200548°C
* +
23 − 1
1
=|
R
9 ∗ •92.39 − 92.4447 € = 0.00300113°C
* +
23 − 1
1
9 =| ∗ 92.92 − 92.4447 R = 0.22583158°C
* +
23 − 1
Etanol
1
9 =| ∗ 72.22 − 72.2443 R = 0.00059282°C
* +
23 − 1
1
9 =| ∗ 72.22 − 72.2443 R = 0.00059282°C
* +
23 − 1
1
9 =| ∗ 72.23 − 72.2443 R = 0.00020586°C
* +
23 − 1
/ -.+ = ∗ .
R
+ ∗ . −•
ƒ R
ƒ R
ƒ R
ƒ R
= |‚
R R R
9 „ •9 € +‚ „ 9 +‚ „ •9 • € + ‚ „ •9 €
/ -.+ / -.+ R / -.+ / -.+
/ -.+
ƒ ƒ ƒ• ƒ .
.
= …
R R R
9 / -.+ .
R R
•9 € + †
R 9 R + −1 R •9 • € + 2 . + 1 R •9 . €
Hielo
9 / -.+ = 8.0429D − 05 °
9 / -.+ =6.2829E-05 °C
9 / -.+ = 4.5934D − 05 °
Metanol
9 / -.+ = 1.03921 °C
9 / -.+ = 0.971369 °C
9 / -.+ = 0.90357 °C
Agua
9 / -.+ = 0.7329500 °
9 / -.+ = 0.896426°
9 / -.+ = 0.864657 °C
Etanol
9 / -.+ = ‡ 5215.7284 R 3.40945 D − 15 R + 72.22 R 1.57406 D − 16 R + −1 R 3.40945 D − 15 R + 2 0.0044 72.22 + 1 R 0.244901272 R
9 / -.+ = 0.244901°C
9 / -.+ = 0.244901 °C
9 / -.+ = 0.14435 °C
Calculo de la incer dumbre estándar en la temperatura
= …•9
R R R
9 * + € + •9 o* 0- € + •9 / -.+ €
9 o* 0- = 0.01°
9 * + = 0.225831577°
9 / -.+ =