1pmet208-Pregunta 4

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Cr2O3 + 3CO(g) = 2Cr + 3CO2(g)

T deltaH deltaS deltaG K Log(K)


C kJ J/K kJ
0.000 286.844 17.873 281.962 1.190E-054 -53.924
50.000 284.551 10.201 281.255 3.417E-046 -45.466
100.000 282.716 4.896 280.889 4.754E-040 -39.323
150.000 281.376 1.519 280.734 2.201E-035 -34.657
200.000 280.230 -1.045 280.724 1.014E-031 -30.994
250.000 279.172 -3.172 280.831 9.072E-029 -28.042
300.000 278.207 -4.935 281.035 2.429E-026 -25.615
350.000 277.395 -6.295 281.318 2.612E-024 -23.583
400.000 276.711 -7.351 281.660 1.387E-022 -21.858
450.000 276.138 -8.173 282.049 4.220E-021 -20.375
500.000 275.668 -8.803 282.474 8.208E-020 -19.086
550.000 275.292 -9.274 282.927 1.109E-018 -17.955
600.000 275.007 -9.612 283.399 1.108E-017 -16.955
650.000 274.810 -9.831 283.886 8.621E-017 -16.064
700.000 274.710 -9.938 284.381 5.425E-016 -15.266
750.000 274.702 -9.945 284.878 2.851E-015 -14.545
800.000 274.787 -9.865 285.374 1.284E-014 -13.891
850.000 274.962 -9.706 285.863 5.060E-014 -13.296
900.000 275.228 -9.474 286.343 1.776E-013 -12.751
950.000 275.586 -9.176 286.810 5.633E-013 -12.249
1000.000 276.036 -8.816 287.260 1.634E-012 -11.787

Formula FM Conc. Amount Amount Volume


g/mol wt-% mol g l or ml
Cr2O3 151.990 64.397 1.000 151.990 29.117 ml
CO(g) 28.010 35.603 3.000 84.031 67.241 l
g/mol wt-% mol g l or ml
Cr 51.996 44.060 2.000 103.992 14.463 ml
CO2(g) 44.010 55.940 3.000 132.029 67.241 l

* Si ∆G es negativa, el valor de Kp será pequeño.


* Si ∆G es positiva, el valor de Kp será más grande.
PbO + CO(g) = Pb + CO2(g)
T deltaH deltaS deltaG K Log(K)
C kJ J/K kJ
0.000 -64.619 13.205 -68.226 1.117E+013 13.048
50.000 -65.172 11.341 -68.837 1.342E+011 11.128
100.000 -65.665 9.923 -69.367 5.141E+009 9.711
150.000 -66.101 8.824 -69.835 4.181E+008 8.621
200.000 -66.489 7.957 -70.253 5.708E+007 7.756
250.000 -66.835 7.261 -70.633 1.130E+007 7.053
300.000 -67.144 6.696 -70.982 2.948E+006 6.470
350.000 -62.593 14.270 -71.485 9.833E+005 5.993
400.000 -62.829 13.906 -72.190 4.001E+005 5.602
450.000 -63.074 13.555 -72.876 1.838E+005 5.264
500.000 -63.332 13.211 -73.545 9.315E+004 4.969
550.000 -63.606 12.866 -74.197 5.114E+004 4.709
600.000 -63.902 12.518 -74.832 3.000E+004 4.477
650.000 -64.218 12.166 -75.449 1.860E+004 4.269
700.000 -64.556 11.810 -76.049 1.209E+004 4.082
750.000 -64.916 11.449 -76.630 8.175E+003 3.913
800.000 -65.300 11.083 -77.193 5.723E+003 3.758
850.000 -65.710 10.709 -77.738 4.128E+003 3.616
900.000 -91.740 -11.752 -77.953 2.959E+003 3.471
950.000 -92.433 -12.331 -77.351 2.012E+003 3.304
1000.000 -93.122 -12.883 -76.720 1.406E+003 3.148

Formula FM Conc. Amount Amount Volume


g/mol wt-% mol g l or ml
PbO 223.199 88.850 1.000 223.199 23.421 ml
CO(g) 28.010 11.150 1.000 28.010 22.414 l
g/mol wt-% mol g l or ml
Pb 207.200 82.481 1.000 207.200 18.265 ml
CO2(g) 44.010 17.519 1.000 44.010 22.414 l

rá pequeño.
á más grande.