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Chromium, 24 Cr Chromium Appearance sillery metallic Standard atomic weight A r, std (Cr) 7001519961000000000♠ 51.9961(6)[ 1] Chromium in the periodic cairt
Atomic nummer (Z ) 24 Group group 6 Period period 4 Block d-block Element category Transeetion metal Electron confeeguration [Ar ] 3d5 4s1 Electrons per shell 2, 8, 13, 1 Pheesical properties Phase at STP solit Meltin pynt 2180 K (1907 °C, 3465 °F) Bylin pynt 2944 K (2671 °C, 4840 °F) Density (near r.t. ) 7.19 g/cm3 when liquid (at m.p. ) 6.3 g/cm3 Heat o fusion 21.0 kJ/mol Heat o vapourisation 339.5 kJ/mol Molar heat capacity 23.35 J/(mol·K) Vapour pressur
P (Pa)
1
10
100
1 k
10 k
100 k
at T (K)
1656
1807
1991
2223
2530
2942
Atomic properties Oxidation states −4, −2, −1, 0, +1, +2 , +3 , +4, +5, +6 (dependin on the oxidation state, an acidic, basic, or amphoteric oxide) Electronegativity Pauling scale: 1.66 Ionisation energies Atomic radius empirical: 128 pm Covalent radius 139±5 pm Colour lines in a spectral range Spectral lines o chromiumIther properties Naitural occurrence primordial Creestal structur body-centred cubic (bcc) Speed o soond thin rod 5940 m/s (at 20 °C) Thermal expansion 4.9 µm/(m·K) (at 25 °C) Thermal conductivity 93.9 W/(m·K) Electrical resistivity 125 n Ω·m (at 20 °C) Magnetic orderin AFM (rather: SDW [ 2] ) Young's modulus 279 GPa Shear modulus 115 GPa Bulk modulus 160 GPa Poisson ratio 0.21 Mohs haurdness 8.5 Vickers haurdness 1060 MPa Brinell haurdness 1120 MPa CAS Nummer 7440-47-3 History Diskivery Louis Nicolas Vauquelin (1797) First isolation Louis Nicolas Vauquelin (1798) Main isotopes o chromium
Decay modes in parentheses are predictit, but hae nae yet been observed | references
Chromium is a chemical element whilk haes the seembol Cr an atomic nummer 24. It is the first element in Group 6 . It is a steely-gray, lustrous , haurd an brickle metal [ 3] whilk taks a heich polish, resists tarnishin, an haes a heich meltin pynt. The name o the element is derived frae the Greek wird χρῶμα, chrōma , meanin colour ,[ 4] acause mony o its compoonds is odious coloured.
Ferrochromium alloy is commercially produced frae chromite bi silicothermic or aluminothermic reactions an chromium metal bi roastin an leachin processes follaed bi reduction wi caurbon an then aluminium . Chromium metal is o heich vailyie for its heich corrosion resistance an haurdness . A major development in steel production wis the diskivery that steel coud be made heichly resistant tae corrosion an discolouration bi addin metallic chromium tae form stainless steel . Stainless steel an chrome platin (electroplatin wi chromium) thegither comprise 85% o the commercial uise.
Trivalent chromium (Cr(III)) ion is an essential nutrient in trace amoonts in humans for insulin , succar an lipid metabolism , awtho the issue is debatit.[ 5]
While chromium metal an Cr(III) ions are nae conseedert toxic, hexavalent chromium (Cr(VI)) is toxic an carcinogenic . Abandont chromium production steids eften require environmental cleanup .
↑ Meija, Juris; et al. (2016). "Atomic weights of the elements 2013 (IUPAC Technical Report)" . Pure and Applied Chemistry . 88 (3): 265–91. doi :10.1515/pac-2015-0305 .
↑ Fawcett, Eric (1988). "Spin-density-wave antiferromagnetism in chromium". Reviews of Modern Physics . 60 : 209. Bibcode :1988RvMP...60..209F . doi :10.1103/RevModPhys.60.209 .
↑ Brandes, E. A.; Greenaway, H. T.; Stone, H. E. N. (1956). "Ductility in Chromium". Nature . 178 (587): 587. Bibcode :1956Natur.178..587B . doi :10.1038/178587a0 .
↑ χρῶμα , Henry George Liddell, Robert Scott, A Greek-English Lexicon , on Perseus
↑ "Chromium" . Office of Dietary Supplements, US National Institutes of Health. 2016. Retrieved 26 Juin 2016 .