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Question
Chemistry
The correct order of acid strengths of benzoic acid (X), peroxybenzoic acid (Y) and p-nitrobenzoic acid (Z) is
Q. The correct order of acid strengths of benzoic acid
(
X
)
, peroxybenzoic acid
(
Y
)
and
p
-nitrobenzoic acid
(
Z
)
is
2284
192
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A
Y
>
Z
>
X
6%
B
Z
>
Y
>
X
19%
C
Z
>
X
>
Y
62%
D
Y
>
X
>
Z
12%
Solution:
∵
In
p
-nitrobenzoic acid
(
Z
)
−
N
O
2
present as electron withdrawing group, thus is most acidic
(
X
)
∵
Benzoic acid is stabilised via resonance, thus is more acidic than per oxybenzoic acid.
(
Y
)
peroxy benzoic acid does not show any such resonance.
Thus is least acidic.
Hence, correct order is
Z
>
X
>
Y
.