DPP For IIT JEE CHEMISTRY By:PJOY From KOTA

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CLASS TEST - 3 (INORGANIC)
IIT-JEE
CHEMISTRY
P. JOY
Dear student following is an Easy level [ ] test paper. A score of 23 marks in 10 minutes would be a satisfactory performance: Q.No. 1 to 11 (+3, 1). (M.M. 33) Single option correct Q.1 When BF3 + NH3 BF3NH3, how does the hybridization of the boron atom change, if at all ? (A) sp3 sp2 (B) sp2 sp3d (C) No change (D) sp2 sp3 Choose the pair in which carbon of each molecule shows more than one hybridisation state : (A) HC CH, CH2 = CH2 (B) CH2 = CH CH = CH2, CH3 CH3 (C) CH3 CH = CH2, CH2 = C = CH2 (D) (CH3)2 CH CH3, CH2 = CH2. The formal charge on the central oxygen atom in O3 molecule is : (A) 0 (B) +1 (C) 1 (D) 2 Which statement is incorrect for OSF4 : (A) S atom has sp3d hybridisation (B) S atom has steric number = 5 (C) O atom is at one of the two axial positions having S=O bond. (D) O atom is at one of the equatorial position having S=O bond. How many bond(s) is/ are present between carbon atoms in the compound given below
H H O H O N H H | H N
Q.7
The percentage of p-character in the orbitals forming S-S bonds in S8 is (A) 25 (B) 33 (C) 50 (D) 75 What is the geometry of the short lived CH22+ ion. (A) Linear (C) T-shaped (B) Tetrahedral (D) Trigonal planar
Q.2
Q.8
Q.9
Q.3
Q.4
Which of the following corresponds to hybridisation having 'd' orbitals(1) AX6 (2) AX5E (3) AX4E2 (4) AX3E2 Note : E-denotes lone pair X-denotes bonded pair (A) Only 1 (B) Only 1 & 2 (C) Only 2, 3 & 4 (D) All of these Statement-1 : ICl3 has T-shaped. Statement-2 : Cl is more electronegative than I. (A) Statement-1 is true, Statement-2 is True; Statemen-2 is a correct explanation for statment-1. (B) Statement-1 is true, Statement-2 is True; Statement-2 is NOT a correct explanation for Statement-1. (C) Statement-1 is True, Statment-2 is False (D) Statement-1 is False, Statement-2 is True
Q.10
Q.5
N N H | H H Caffeine
(A) 4 Q.6
(B) 2
(C) 1
+
(D) 3 Q.11
Choose the incorrect statment (A) Both H 2 O and H3 O have same hybridisation (B) Both NH 3 and NH4 have same hybridisation (C) Both BF 3 and BF 4 have same hybridisation (D) All of the above
+
Choose the correct statement (A) Linear shape is assumed by only those molecule which has steric number two (B) Both CO2 & BeCl2 have linear shape (C) Both XeF2 and XeF6 have same no. of lone pairs of electron around Xe. (D) All of the above
&
CHEMISTRY IIT JEE (CLASS TEST - 3) (INORGANIC) ANSWER KEY
Name : .......................................................................................................... A 1. 2. 3. 4. B C D 5. 6. 7. 8. A B C D 9. 10. 11.
&
M.M. 33
Roll No. : .................................. A B C D
CLASS TEST - 3 (INORGANIC)

Que. Ans. 1 D 2 C 3 B 4 C 5 C
IIT-JEE
CHEMISTRY
P. JOY
8 A 9 D 10 B 11 B
6 C
7 D
Sol.1 (D)
sp BF3 + NH3
2
H3N:
sp BF3
Sol.2 (C) (A) H C C H , CH2 = CH2

3 3 sp sp sp sp sp sp (B) CH2 = CH CH = CH2 , CH3 CH3
2 sp sp sp sp sp sp (C) CH3 CH = CH2 , CH2 = C = CH2
Sol.7 (D) In S8 molecule, S has sp3 hybridisation state. So percentage of p-character in SS bond orbitals is 25 & 75 respectively.
2
sp sp
2
sp
sp
.. : S .. S .. .. S ..
.. S ..
.. S .. S8 molecule
.. S ..
.. S ..
.. S:
sp CH3 (D) sp3 CH3
sp sp sp sp CH CH3 , CH2 = CH2
Sol.8 (A) CH22+ ion has linear geometry. [H C H]2+ Sol.9 (D)
S.No. 1. 2. 3. 4. Formula AX6 AX5E AX4E2 AX3E2 N = s + l.p. N=6+0=6 N=5+1=6 N=4+2=6 N=3+2=5 Hybridization sp3d2/d2sp3 sp3d2/d2sp3 sp3d2/d2sp3 sp3d/dsp3
In options (A), (B), (D) in both compounds, C shows only one type of hybridisation state while in option (C), C has more than one hybridisation state in both compounds. Sol.3 (B)
:O ..
.. O
Formal charge on central oxygen atom = 6 (3 + 2) = 6 5 = 1. Sol.4 (C)

F O S F F F (sp d hybridisation with steric no.-5)
3
.. O: ..
Sol.10 (B) Applying VSEPR theory for ICl3 molecule

Cl
..
I
..
Cl
Steric number = b.p. + l.p. = 3 + 2 = 5 Molecular geometry = Trigonal bipyramidal Electronic geometry = T-shaped. Sol.11 (B) (A) Molecules having steric number - 5 can also have linear geometry.
Eg. :XeF2, I3 have linear geometry. . ..
Cl
Trigonal bipyramidal geometry. Sol.5 (C) Caffeine has only one C = C -bond.
H H O H O N H H | H N
..
(B) According to VSEPR theory

O=C=O
N N H | H H Caffeine
Steric number = b.p. + l.p. = 2 + 0 = 2 (sp hybridisation) Molecular geometry = electronic geometry = Linear geometry.
Cl Be Cl
Sol.6 (C)
H + H
+ H H sp
3
Steric number = b.p. + l.p.

sp
3
(A)
:O:
sp H
= 2 + 0 = 2 (sp hybridisation) Molecular geometry = electronic geometry = Linear geometry. CO2 & BeCl2 have linear shape so this is correct statement. (C) In XeF 2 , Xe has 3 lone pairs around it and in XeF6 , Xe has only I lone pair around it.
.. ..
(B) H
.. N H
sp H ,
H H N H H B H
..
sp
(C) F
F F
sp ,

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For more such DPPs SMSs us at : 099828-12345 or E-mail : joy@visionkota.

CLASS TEST - 3 (INORGANIC)

Sol.2 (C) (A) H C C H , CH2 = CH2

sp CH3 (D) sp3 CH3

sp sp sp sp CH CH3 , CH2 = CH2

Formal charge on central oxygen atom = 6 (3 + 2) = 6 5 = 1. Sol.4 (C)

Sol.10 (B) Applying VSEPR theory for ICl3 molecule

(B) According to VSEPR theory

Steric number = b.p. + l.p.

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