Lesson 1.2 How Do Batteries Work

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AVTC Model Based Design

Curriculum Development
Project

An Introduction to
Modeling an
Energy Storage System (ESS)
Lesson 1.2
How Do Batteries Work?
Donald Docimo
Mohammad Ghanaatpishe
Hosam Fathy

The Basic Battery Cell


Electrodes: Electronic
conductors with different
potentials [1].

Separator: Material that allows


ions to pass through it, but not
electrons [2].

Electrolyte: Ionic conductor to


allow the movement of ions [1].

Current Collectors: Provide a


path for electrons to flow through
to the external circuit [2].
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Anode and Cathode Definitions


Anode: The electrode where negative ions
flow towards, building up a negative charge
[2].
Cathode: The electrode where the positive
ions flow towards, building up a positive
charge [2].
The charges of the anode and cathode create
a cell voltage v(t) [2].
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Discharge
Negative electrode = Anode [2].
Positive electrode = Cathode [2].
Positive ions flow through
electrolyte and separator from
the anode to cathode [2].
Negative ions flow in the
opposite direction [2].
A cell voltage v(t) is created due
to this difference.
Electrons flow through an
external circuit from the anode
to the cathode. Positive current
flows in the opposite direction of
electrons as a convention [2].

Charge
Negative electrode = Cathode [2].
Positive electrode = Anode [2].
Ions and electrons flow in
opposite direction as compared
to discharge [2].
The negative electrode has a
higher potential, which allows
the storage of energy.

Reasons for Ion Movement


Diffusion
Electrolyte will have a concentration gradient due to
ions being produced from electrodes [2].
Ions will flow to balance the concentration [2].

Migration
An electric field is present, and moves positive ions to
the cathode, and negative ions to the anode [1].

Convection:
Bulk fluid motion, which mixes the electrolyte solution
[1].
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References
[1] J.S. Newman and K.E. Thomas-Alyea.
Electrochemical Systems. 3rd ed. Hoboken,
NJ: J. Wiley, 2004.
[2] C. Rahn and C.Y. Wang. Battery Systems
Engineering. Chichester: John Wiley &
Sons, 2013.

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