Chemistry NSEC
Chemistry NSEC
Chemistry NSEC
6. A correct answer carries 3 marks whereas 1 mark will be deducted for each wrong
answer.
7. Any rough work should be done only in the space provided.
8. Periodic Table is provided at the end of the question paper.
9. Use of non-programmable calculator is allowed.
10. No candidate should leave the examination hall before the completion of the
examination.
11. After submitting your answer paper, take away the Candidates copy for your reference.
Please DO NOT make any mark other than filling the appropriate
bubbles properly in the space provided on the answer sheet.
Answer sheets are evaluated using machine, hence CHANGE OF
ENTRY IS NOT ALLOWED.
Scratching or overwriting may result in a wrong score.
DO NOT WRITE ON THE BACK SIDE OF THE ANSWER SHEET.
QP CODE C 244
N H2
(A)
(B)
HOH2 C
CH2 OH
COOH
COOH
(C)
COOH
(D)
CH2 OH
H2 N
COOH
(3)
H
CH2 OH
N H2
(2)
NH2
(B) [Fe(H2O)6]3+
(C) [Co(H2O)6]2+
(D) [Co(H2O)6]3+
Solubility products of silver chloride and silver thiocyanate are 1.2 x1010 and
7.1 x1013 respectively. The equilibrium constant for the reaction
AgCl (s) + CNS1(aq) AgCNS (s) + Cl1 (aq) is
(A) 0.0625
(4)
(B) 169
(C) 13
I.
II.
(5)
(B)
(C)
(D)
QP CODE C 244
(6)
Helium can be singly ionized by losing one electron to become the He+ cation. Which
of the following statements is true concerning this helium cation?
(A) The line spectrum of this helium cation will resemble the line spectrum of a
hydrogen atom.
(B) The line spectrum of this helium cation will resemble the line spectrum of a
lithium cation.
(C) The line spectrum of this helium cation will remain the same as for unionized
helium.
(D) The line spectrum of this helium cation will resemble the line spectrum of a
hydrogen ion.
(7)
(8)
(C) F
(D) Al3+
The colourless salt that gives white precipitate with BaCl2 in aqueous HCl is
(A) K2SO4
(9)
(B) Na+
(B) K2SO3
(C) KNO3
(D) KBr
-1368 kJ
(B) 450
(C) 72
(D) 45
QP CODE C 244
..
(13) The magnetic moment of a divalent ion of an element with atomic number 24 in an
aqueous solution is
(A) 4.90 BM
(B) 2.45 BM
(C) 2.83 BM
(D) 1.73 BM
(16) The colligative property used in the determination of molar mass of a polymer is
(A) lowering of the vapour pressure
(17) From the following the species that are isoelectronic are
(I) NH3,
(II) CH3+,
(III) NH2,
(IV) NH4+
QP CODE C 244
(18) The pair of equimolar compounds that would give a single condensation product
when treated with an alkali is
(19) In electrophoresis,
(A) the colloidal particles migrate in an applied electric field.
(B) the medium migrates in an applied electric field.
(C) both colloidal particles and the medium migrate.
(D) neither the particles nor the medium migrate.
(20) When a person suffers from typhoid, the metabolic process stimulated in the body to
fight against this disease is synthesis of
(A) Lipid
(B) carbohydrate
(C) Protein (D) DNA
(21) If a weak base has the dissociation constant, Kb, then the value of the dissociation
constant, Ka, of its conjugate acid is given by
(A) 1/Kb
(B) Kw/Kb
(C) Kb/Kw
(D) KwKb
(A) 3-chloroaniline
(B) 4-bromochlorobenzene
(C) 3-bromochlorobenzene
(D) 3-bromoaniline
QP CODE C 244
(24) In the cyanide extraction process of silver from Argentite ore, the oxidizing and the
reducing agents used are respectively
(A) O2 and CO
(26)
(27) The graph that wrongly represents the Boyles law for an ideal gas is
PV
1/V
II
PV
III
(A) II
(B) I
IV
(C)
IV
(D) III
QP CODE C 244
(A)
(B)
NaNH2
propyne
NaNH2
ethyne
(C) 1-hexyne
NaNH2
(D) 1-pentyne
NaNH2
n-C 4H9Br
n-C5 H11 Br
CH3Br
C2H5Br
H2 O, Hg 2+
H2SO4
H2 O, Hg 2+
H2 SO4
H2 O, Hg 2+
H2 SO4
H2 O, Hg 2+
H2SO4
(B) 6
(C) 1.67
(D) 3
(D) diasteromers
(B) sp2 to sp
(C) sp to sp2
(33) Aluminum carbide (Al4C3) liberates methane on treatment with water. The grams of
aluminum carbide required to produce 11.2 L of methane under STP conditions is
[Given Al = 27]
(A) 48
(B) 72
(C) 144
(D) 24
8
QP CODE C 244
(B) methoxybenzene
(C) phenol
(D) toluene
(36) Ionic salt AX grows in face centered cubic lattice with cell length a. The ratio
r A+ / r x for this salt will be:
(A) 0.155
(B) 0.225
(C) 0.414
(D) 0.732
(37) The hybridization of boron in the stable borane having the lowest molecular weight
is(A) sp2
(B) sp3
(D) sp3d
(C) sp
(39) The specific gravity of a HNO3 solution is 1.42 and it is 70% w/w. The molar
concentration of HNO3 is
(A) 15.8
(B) 31.6
(C) 11.1
(D) 14.2
(40) Bleaching powder contains a salt of an oxoacid as one of its components. The
anhydride of that acid is
(A) Cl2O
(B) Cl2O7
(C) ClO2
(D) Cl2O6
QP CODE C 244
base
(42) The unit cell of a compound made up of the three elements X, Y and Z is given
below.
(B) XY3Z
(C) XYZ3
(D) X3YZ2
(43) N2 gas stored in a cylinder, fixed with a movable piston, undergoes adiabatic
ad
expansion. The statement that is true for the given situation is
(A) q= w
(B) U = w
(C) U= 0
(D)U= q
(B) 0.598V
(C) 0.251V
(D) 0.764 V
(II) HF
(III) HI
(IV) HBr
10
QP CODE C 244
(46) The correct order of dipole moment for the following molecules is
(B) CH3CH2Br
(C) (CH3)2CH-Br
(D) CH3COCH2CH2Br
(48) The enthalpy of vaporization of benzene is +35.3 kJ/mol at its boiling point of 80C.
The entropy change in the transition of vapour to liquid at its boiling point is
(A) 100
(B) +100
(C) +342
(D) 342
(49) For a strong electrolyte, the change in the molar conductance with concentration is
represented by
(I)
(II)
(III)
(IV)
(A) I
(B) II
(C) III
(D) IV
(II) Ph-NH2
(III) Ph-CH2-NH2
(IV) p-OCH3Ph-NH2
11
QP CODE C 244
(51) The specific conductance of 0.01M solution of the weak monobasic acid is
0.20 10-3 S cm1. The dissociation constant of the acid is:
Given: 0 HA = 400 S cm2 mol1
(A) 5 102
(C) 5 104
(52) The set of quantum numbers that cannot be allotted to an electron in an atom is
(A) n = 3, l = 2, ml = +2, ms = -1/2
(C) n = 1, l = 0, ml = 0, ms = +1/2
(D) n = 4, l = 3, ml = 0, ms = -1/2
It is prepared by polymerization of
(A) CH2=CH-OH
(B) CH2=CH-OCOCH3, followed by hydrolysis
(C) CH2=CH-CN, followed by hydrolysis
(D) CH2=CH-COOCH3, followed by hydrolysis
(54) For SF4, the molecular geometry and hybridization of the central atom respectively
are
(A) Square planar, dsp2
(55) If the energy of an electron in the 1st and 2nd energy levels of an H atom are 13.6 eV
and 3.4eV, respectively, the energy required in eV to excite an electron from the 1st
to the 2nd energy level is
(A) 17.0
(B) 17.0
(C) 10.2
(D) 10.2
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QP CODE C 244
(56) The pKa values of the acids A to D are found to be 4.19, 3.41, 4.46 and 4.76. The acid
having pKa of 3.41 is
(57) The reaction given below is the cell reaction in a galvanic cell.
Cd(s) + Sn2+ (aq) Cd2+(aq) + Sn(s),
Where, [Cd2+] = 0.1M and [Sn2+] = 0.025M
E0 Sn2+/ Sn = 0.136V, F = 96485 Cmol1
(B) 54.96 KJ
(C) 100.58KJ
(D) 107.46 KJ
(58) Triethylamine is reacted with a peracid to obtain X. The nitrogen atom in X has
formal charge
(A) 0
(B) +1
(C) 1
(D) +2
(C) SF6
(D) AlF63
(B) BF63
(60) The experimental observations for the following reaction are given below
P + Q Product.
[P]/ M
[Q]/ M
Initial Rate/mol s1
0.2
0.5
8x10 3
0.4
0.5
3.2 x10 2
0.2
0.25
4x10 3
(C) Two
(D) Three
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QP CODE C 244
(B) 0.4
(C) 0.6
(D) 0.8
(B) ClO4
(C) ClO2
(D) ClO
(B) tautomers
(A)
+ 42 01n + X
56
26 Fe
(B)
55
25 Mn
(C)
56
25 Mn
(D)
55
26 Fe
(65) As part of a diagnostic procedure for a thyroid disorder, a patient is given a certain
amount of iodine-131. The half life of this radioactive iodine-131 is 8.0 days. The
percent fraction of iodine-131 that will remain in the body after 32 days, if there is no
elimination of iodine through the body is
(A) 6.25
(B) 0.0625
(C) 2.77
(D) 25
(66) 1-Phenoxypropane is treated with excess of conc. HI at 0oC and the mixture of
products is treated with thionyl chloride. The products formed are(A) n-propanol + Chlorobenzene
14
QP CODE C 244
(67) The compound which undergoes hydrolysis on just warming with water and forms the
corresponding hydroxyl derivative is
(A) 2,4,6trinitrochlorobenzene
(B) 2chloro1butene
(D) 2,4dimethoxychlorobenzene
(68) The pair of compounds that will not react with each other in an aqueous solution, at
room temperature is
(A) FeCl3, SnCl2
(D) FeCl3, KI
(69) At 700K, for the reaction 2SO2 (g) + O2 (g) 2SO3(g) the KP is 3.2 104 . At the
same temperature the KP for the reaction SO3 (g) SO2 (g) + 0.5O2 (g) is
(A) 3.125 105
(70) Amylose and cellulose are polymers of glucose in which glucose units are joined to
each other respectively by linkages of the type
(A) ,
(B) ,
(C) ,
(D) ,
(71) 2-methylpentane is
H
(A)
H
H3 C
(B)
CH3
H
CH2 CH3
H
H3 C
CH3
(C)
H
H
(D)
C H3
CH3
C H3
CH2 CH3
CH 2CH 3
C H3
(B) CH4
(C) NH3
(D) NF3
15
QP CODE C 244
(73) Two samples A and B of an ideal gas, initially at same temperature and pressure, are
compressed from volume V to V/2, isothermally for A and adiabatically for B. The
final pressure of A will be
(A) greater than that of B
(B) CH3CH2CONHCH2CH3
(C) (CH3COO)(CH3CH2NH3+)
(D) (CH3CH2COO)(CH3NH3+)
(B) NO3
(C) AlCl3
(D) SbH3
(77) The order of acidity in aqueous solution for the following acids is
(A) H2S < H2Se < H2Te
(A) 5-bromo-3-(bromomethyl)pent-1-ene
(B) 3-(1-bromopropyl)-4-bromobut-1-ene
(C) 1,4-dibromo-3-ethenylbutane
(D) 1-bromo-3-(bromomethyl)but-4-ene
16
QP CODE C 244
(79) To a solution containing one mole MCl3.4NH3, on addition of excess silver nitrate
solution, it was found that two moles of AgCl are precipitated. This observation
suggests that the secondary valence of M in this complex is
(A) 3
(B) 5
(C) 6
(D) 2
(B) N
(C) P
(D) Q
17
QP CODE C 244
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QP CODE C 244
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QP CODE C 244
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