Chemistry in Power Plant
Chemistry in Power Plant
Chemistry in Power Plant
BY
P. SRIVASTAVA
SR. MANAGER(CHEM.)
1
WATER CHEMISTRY IN
POWER PLANT
PRODUCTION OF : --- D.M. WATER FOR BOILER MAKE-UP.
--- FILTER WATER FOR SOFTENING PLANT, D.M.
PLANT, DRINKING WATER AND A.C. COOLING
SYSTEM.
MONITORING OF STEAM/ WATER PARAMETERS
H.P./L.P. DOSING.
TESTING OF COAL.
TESTING OF LUB OIL.
WATER CHEMISTRY IN
POWER PLANT
CIRCULATING
WATER TREATMENT
POLLUTION MONITORING
STACK MONITORING
AMBIENT AIR
WATER EFFLUENT
EFFLUENT
TREATMENT PLANT
COMMISSIONING ACTIVITES
4
CLARIFLOCC
ULATOR
D.M.
PLANT
U/G STORAGE
TANK
SOFTENING
PLANT
DRINKING
WATER
COOLING
WATER
August 21, 2015
GRAVITY
FILTER
BOILER
MAKEUP
C.W.
MAKEUP
D.M. PLANT
ACF
WEAK
BASE
ANION
WEAK
ACID
CATION
STRONG
ACID
CATION
STRONG
BASE
ANION
MIXED
BED
DEGASSER
D.M.
WATER
STORAGE
TANK
- 7.0 0.2
< 0.1 mho
- NIL
< 20 ppb
D.M. WATER
LP TURBINE
RFT
LP STEAM
CONDENSER
D/A
LP BOILER
LP BFP
H.P. DOSING
HP TURBINE
HP STEAM
HP BOILER
HP BFP
August 21, 2015
AMMONIA
DOSING
CEP
D.M. WATER
TURBINE
CST
STEAM
CONDENSER
D/A
BOILER
BFP
T.S.P. DOSING
WATER/STEAM CHEMISTRY
PARAMETERS MONITORED
10
pH
Silica
Conductivity
After Cation Conductivity
Dissolved Oxygen
Sodium
Copper
Iron
August 21, 2015
WATER QUALITY
FEED
11
WATER
ACC
pH
Total Iron+Copper
Silica
Dissolved Oxygen
<0.2 uS/cm
8.8-9.2
<0.02 ppm
<0.02 ppm
<7 ppb
WATER QUALITY
CONDENSATE
12
WATER
ACC
<0.2 uS/cm
pH
8.8-9.2
Silica
<0.02 ppm
Dissolved Oxygen
<40 ppb
WATER QUALITY
13
BOILER WATER
Conductivity
<30 uS/cm
pH
9.2-9.6
Silica
<0.300 ppm
Phosphate
2-4 ppm
WATER QUALITY
STEAM
14
ACC
pH
Total Iron+Copper
Silica
Sodium
<0.2 uS/cm
8.8-9.2
<0.02 ppm
<0.02 ppm
<10 ppb
15
194 Kg/Cm2
130 ppb
176 Kg/Cm2
220 ppb
159 Kg/Cm2
290 ppb
134 Kg/Cm2
500 ppb
117 Kg/Cm2
1000 ppb
100 Kg/Cm2
2220 ppb
65 Kg/Cm2
4000 ppb
Boiller Drum Pressure is to be maintined as
such,Silica value in Main Steam maintain
bellow 20 ppb.
August 21, 2015
--
PARTITION COEFFICIENT Kp
PARTITION COEFFICIENT AT
DIFFERENT PRESSURES
100
10-1
SiO
2
10-2
10-3
Na
OH
10-4
Na
Cl
10-5
10-6
10-7
226
16
220
200
180
160
140
120
100
PRESSURE ( BAR)
August 21, 2015
50
40
30
17
EFFECTS OF SILICA
Silica
Silica
18
H.P. DOSING
COORDINATED PHOSPHATE CONTROL
Na3PO4+H2O
Na2HPO4+H2O
Na2HPO4 + NaOH
NaH2PO4 + NaOH
19
NaCl + H2O
L.P.DOSING
AMMONIA & HYDRAZINE HYDRATE DOSING
21
CORROSION OF COPPER
22
- Limits
below 10 PPb
23
- Limits
2 to 5 PPM
24
25