Statistical Molecular Thermodynamics: Christopher J. Cramer
Statistical Molecular Thermodynamics: Christopher J. Cramer
Statistical Molecular Thermodynamics: Christopher J. Cramer
Thermodynamics
Christopher J. Cramer
Video 2.2
Non-ideal Gas Equations of State
PV = nRT
V
PV = RT, V =
n
or
molar volume
H2
273.15 K measurements
At low pressures, all gases
converge to ideal behavior
PV (273.15) = 22.414 L atm mol1
N2
CO2
compressibility (unitless)
CH4
300 K
a
P + 2 (V b) = RT
b (dm3mol-1)
0.024
0.037
RT a
P =
2
V b V
Redlich-Kwong
RT
A
P =
1/ 2
V B T V V + B
Peng-Robinson
RT
P =
V V V + + V
) (
Redlich-Kwong
expt (solid)
Peng-Robinson
V 1 =
1
mol
L
(
)
1 L = 1 dm3
V
P1 <
liquid/vapor
equilibrium
V
L
P2 <
P3
RT a
P =
2
V b V
=
lim
RT a 2