Part-A: Q.1 To Q.7 Has Four Choices (A), (B), (C), (D) Out of Which ONLY ONE Is Correct. (Q. No.1 To Q.No.4 3 Marks)

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PHYSICS

XII (ABC/SMS) RT-1 [Paper-II] Page # 1


PART-A
[SINGLE CORRECT CHOICE TYPE]
Q.1 to Q.7 has four choices (A), (B), (C), (D) out of which ONLY ONE is correct.
[Q. No.1 to Q.No.4 3 marks]
Q.1 A block of mass M is kept in gravity free space and connected to the two springs of spring constant k
and 4k fixed to the walls as shown in the figure. Initially springs are in its natural length. Now, the block
is shifted (l
0
/2) from the given position in such a way it compresses left spring and released. The time
period of oscillation of mass will be
(A)
K
M
2
t
(B*)
K 5
M
2t
(C)
K
M
2
3t
(D)
K 2
M
t
[Sol: k
eq
= k + 4k ; T =
eq
k
m
2t
=
K 5
M
2t
]
Q.2 How many frequencies below 1 KHz of natural oscillations of air column will be produced if a pipe of
length 1 m is closed at one end. [velocity of sound in air is 340 m/s] (neglect end correction)
(A) 5 (B*) 6 (C) 4 (D) 8
[Sol: L = (2n 1)
4

and f =

v
f = (2n 1)
L 4
v
< 1000 n <
2
26 . 12
; n < 6.38 ]
Q.3 A uniform electric field of 400 V/m is directed at 45 above the x-axis as shown in the figure. The
potential difference V
A
V
B
is given by : (Here coordinates of A = (0, 2cm) & B = (3cm, 0))
(A) 0 (B) 4 V (C) 2 6 V (D*)
2 2
V
[Sol.
E

= 200 j 2 200 i 2 +
A
r

= 0.02 j,
B
r

= 0.03i ;

AB
= P.V. of B P.V. of A =
j

02 . 0 i

03 . 0
V
A
V
B
=
E


AB
=
( ) j 2 200 i 2 200 +
. (
j

02 . 0 i

03 . 0
)
=
2 4 2 6
=
2 2
]
Q.4 An organ pipe filled with oxygen gas at 47C resonates in its fundamental mode at a frequency of 300
Hz. If it is now filled with nitrogen gas, at which temperature will it resonate at the same frequency, in the
fundamental mode ?
(A*) 7C (B) 41.1C (C) 280C (D) 92.7C
[Sol. Open pipe or closed pipe fundamental frequence
l
v
) n (
n

v but
M
RT
v

=
PHYSICS
XII (ABC/SMS) RT-1 [Paper-II] Page # 2
n


M
RT 1
l
T

M
2
1
2
1
M
M
T
T
=

28
32
T
47 273
=
+
R =
K 280
32
28 320
=
+
7C ]
[Q. No.5 to Q.No.7; 4 marks]
Q.5 Two identical charged small spheres are suspended by strings of equal length. The strings makes an
angle of 30 with each other. When suspended in a liquid of density 0.8 gm/cc, it was found that angle
between string remains the same. The dielectric constant of the liquid is (density of the material of sphere
is 1.8 gm/cc)
(A*) 2 (B) 4 (C) 2.5 (D) 3.5
[Sol: Initially
T cos u = mg ......(i)
and T sinu = F ......(ii)
from (i) and (ii)
tanu =
mg
F
When suspended in a liquid of density o and dielectric constant K.
F' =
K
F
mg' = mg vog
tanu' =
|
|
.
|

\
|

=
1 kmg
F
' mg
' F
[o and are densities of liquid and sphere respectively]
u' = u ; k =
2
8 . 0 6 . 1
6 . 1
=

=
o

]
Q.6 An o particle (charge +2e) passes rapidly through the exact centre of two fixed point charges each +e
separated by distance 2b, moving on a line perpendicular to the y axis. Where on its path does the o
particle experience the greatest electric force? Neglect other forces except electric force.
(A) x = +
2
b
(B*) x = +
2
b
(C) x = +
2 2
b
(D) none
[Sol: E
P
=
( )
2 / 3
2 2
b x
Kex 2
+
For maximum E
P
0
dx
dE
P
=
x =
2
b
]
PHYSICS
XII (ABC/SMS) RT-1 [Paper-II] Page # 3
Q.7 A spherical shell of radius R
1
with uniform charge on surface q is expanded to radius R
2
due to electric
forces. Then work performed by electric forces is
(A)
0
2
4
q
e t

|
|
.
|

\
|

2 1
R
1
R
1
(B*)
|
|
.
|

\
|

e t
2 1 0
2
R
1
R
1
8
q
(C)
|
|
.
|

\
|

e t
1 2 0
2
R
1
R
1
4
q
(D) Data are insufficient
[Sol. Change in self energy will be equal to work done.
self energy =
R
KQ
2
2
difference = (

2 1 0
2
1 1
8 R R
q

[PARAGRAPH TYPE]
Q.8 to Q.10 has four choices (A), (B), (C), (D) out of which ONLY ONE is correct.
Paragraph for question nos. 8 to 10
In the fig. shown two point charges 2Q & Q are placed at the points A & B seperated by distance L on
x-axis
2Q Q
A B
x
Q.8 The electric field strength
( ) E

can be zero at a point (at finite distance) on x axis. This point will be
(A) Between points A & B (B) Left side of point A
(C*) right side of point B (D) can be on the left side of A as well as on the right side of B
Q.9 As one move from point A to B along x-axis
(A*) electric potential increases (B) electric potential decreases
(C) electric potential first increases & then decreases
(D) electric potential first decreases & then increases
Q.10 The graph of electric potential V vs X an x-axis on the right side of point B will be like
(A)
A B
V
(B*)
A B
V
(C)
A B
V
x (D)
A B
V
x
[Sol.
PHYSICS
XII (ABC/SMS) RT-1 [Paper-II] Page # 4
graph of E.F.
2Q
A
Q
B
graph of Potential
2Q
A
Q
B
by using graph we can answer all question.
[MULTIPLE CORRECT CHOICE TYPE]
Q.11 to Q.13 has four choices (A), (B), (C), (D) out of which ONE OR MORE may be correct.
Q.11 Four identical point charges are placed at the points (1, 0, 0), (0, 1, 0), (1, 0, 0) and (0, 1, 0)
(A) The potential at the origin is zero.
(B*) The electric field at the origin is zero.
(C) The potential at all points on the z-axis, other than the origin, is zero.
(D*) The electric field at all points on the z-axis, other than the origin, acts along the z-axis.
[Sol. As potential is scalar quantity
of electric field is vector
Q
Q Q
Q
(0, 1, 0)
(1, 0, 0)
(0, 1, 0)
( 0, 0) 1,
........at origin
E.F. is zero but potential is non zero
Q.12 A ring with a uniform charge Q and radius R, is placed in the yz plane with its centre at the origin.
(A*) The electric field at the origin is zero (B*) The potential at the origin is k
R
Q
.
(C) The field at the point (x, 0, 0) is k
2
x
Q
(D*) The potential at the point (x, 0, 0) is k
2 2
x R
Q
+
.
PHYSICS
XII (ABC/SMS) RT-1 [Paper-II] Page # 5
[Sol. Electric field at origin is zero.
Potentiol =
R
KQ
x P
Q
R
R + x
2 2
Potentiol at (x, 0, 0)
=
2 2
x R
KQ
+
Q.13 For a sine wave passing through a medium, let y be the displacement of a particle, v be the velocity of
particle and 'a' be its acceleration.
(A) y, v and a are always in the same phase. (B*) y and a are always in opposite phase.
(C*) Phase difference between y and v is
2
t
. (D*) Phase difference between v and a is
2
t
.
Q.14 The stationary waves set up on a string fixed at both ends have the equation y = (2mm) sin[(6.28 m
1
)x]
cos(et). This stationary wave is created by two identical waves, of amplitude A each, moving in opposite
directions along the string. Then (here t = 3.14)
(A) A = 2mm (B*) A = 1mm
(C*) The smallest length of the string is 50 cm (D) The smallest length of the string is 2 m.
[Sol: Comparing with the equation y = 2A sin
( ) t cos
L
x n
e |
.
|

\
| t
,
2A = 2mm, or A = 1mm
L
x nt
= 6.28x = 2tx or L =
2
n
m
For n = 1, L = 0.5 m ]
Q.15 An electron travelling in uniform electric field passes from a region of potential V
1
to a region of higher
potential V
2
. Then
(A*) No change takes place in velocity component parallel to interface of two regions.
(B) Direction of its motion must remains unchanged but speed increases.
(C*) Direction of its motion may change but speed must increase.
(D) Decrease in kinetic energy is proportional to
1 2
V V .
[Sol: Electric field is directed from higher to lower potential, therefore, the component of electric field parallel
to interface of two region will be equal to zero.
When the electron passes from region of potential V
1
to the region of potential V
2
, then it experiences a
force due to the field. It implies that the force is normal to the interface of two regions.
Since, the force has no component parallel to the interface therefore, no change takes place in velocity
component parallel to the interface.
Hence (A) is correct.
Since the direction of electric field is from higher to lower potential and the electron is negatively charges,
therefore, it experiences a force from the region of lower potential to the region of higher potential.
Hence, its velocity component along the direction of field will increase or speed of the electron must
increase.
Since, one compoenent of velocity remains unchanged while the other changes, therefore, direction of
motion may change. Hence (C) is wrong.
Since speed of the electron increases, therefore, kinetic energy also increases. That increase in K.E. will
be equal to the work done by the electric field which is equal to e(V
2
V
1
). Hence (D) is wrong.]
PHYSICS
XII (ABC/SMS) RT-1 [Paper-II] Page # 6
PART-C
[INTEGER TYPE]
Q.1 to Q.5 are "Integer Type" questions. (The answer to each of the questions are upto 4 digits)
[Q. No.1 to Q.No.3; 4 marks]
Q.1 A sound source(s) emits frequency of 180 Hz when moving towards a rigid wall with speed 5 m/s and an
observer (O) is moving away from wall with speed 5 m/s (see figure). Both source and observer moves
on a straight line which is perpendicular to the wall. Find the number of beats per second heard by the
observer. [Speed of sound = 355 m/s] [Ans: 5]
[Sol: Frequency heard by observer directly coming from source =
Hz 175 180
5 355
5 355
=
+

f
2
frequency heard by observer after reflection
=
180
355
05 355
05 355
355

= 180 Hz
f
2
f
1
= 5 Hz ]
Q.2 Linear charge density of a ring of radius R varies as =
0
cos u where
0
is a constant and u is angle
with any radial line as shown (Take
0
=
0
2tc unit; R = 4 unit) . Find the electric potential on the axis
of ring at distance R from its centre: [Ans: 0]
[Sol. Here,
( )
R 2
Rd
4
1
dV
0
u
tc
=
u u
tc

= d . cos
2 4
dV
0
0
Now,
} }
t
= u u
tc

= =
2
0
0
0 d . cos
2 4
dV V
Q.3 A positive charged small sphere of mass m is attached to one end of an ideal spring of
spring constant k whose other end is fixed to a rigid support. The sphere is tied with a
thread so that the spring is in its natural length. Another negatively charged sphere is
fixed with floor, vertically below the positively charged sphere as shown. If initial
separation between the spheres is r
0
and magnitude of charge on each sphere is q. The
maximum elongation of the spring when the thread is burnt is
2
r
0
.Then find the value of
2
3
0
| q |
r K e t
. (Neglect gravity) [Ans: 2]
PHYSICS
XII (ABC/SMS) RT-1 [Paper-II] Page # 7
[Sol: Apply energy conservation principle]
[Q. No.4 to Q.No.5; 5 marks]
Q.4 Two equal point charges (10
3
C) are placed at 1 cm apart in a medium of dielectric constant K = 5.
The electrostatic interaction force between the point charges is given by x 10
7
N. Fill the value of x in
OMR. [Ans: 9]
[Sol: Interaction force between point charges
F =
( )
( )
N 10 9
10
10
10 9
r
q q
4
1
7
2
2
2
3
9
2
B A
0
= =
tc

Remark Net force


F =
( )
( )
N 10 18
10
10
5
10 9
r
q q
K 4
1
6
2
2
2
3 9
2
2 1
0
=

=
tc

Q.5 An organ pipe of 3.9 t m long, open at both ends is drived to third harmonic standing wave. If the
amplitude of pressure oscilaltion is 1% of mean atmospheric pressure [p
0
= 10
5
N/m
2
], the maximum
displacement of particle from mean position is given by
N
10
cm, then fill the value of N in OMR.
[given v = velocity of sound = 200m/s and
0
density of air 1.3 kg/m
3
] [Ans: 9]
[Sol: Pressure amplitude = KA P
0
| = A
A =
K V
P
K
P
2
0
0 0

A
=
|
A
=
t

A
2 K V
P
2
0
0
=
3
L
V
P
2
0
0

A
=
t
A
2
0
0
V
L P
3
2
]
CHEMISTRY
XII (A, A1) RT-1 [Paper-II] Page # 1
PART-A
[SINGLE CORRECT CHOICE TYPE]
Q.1 to Q.7 has four choices (A), (B), (C), (D) out of which ONLY ONE is correct.
[Q. No.1 to Q.No.4 3 marks]
Q.1 Which of the following graph is correct at 273 K for He :
(A)
Z
P
Ideal
He
(B)
Z
P
Ideal
He
(C)
Z
P
Ideal
He
(D*)
Z
P
Ideal
He
Q.2 Which of the following statement is correct about [Fe(H
2
O)
5
Cl]Cl
2
(A) Primary valency of iron is two and are saticefied with chloride ion.
(B*) Three primary & one secondary valency of iron are saticefied with chloride ion.
(C) All primary and secondary valencies both are directional.
(D) Primary valencies are non-directional.
Q.3 A liquid which is confined inside an adiabatic piston is suddenly taken from state 1 to state 2 by a single
stage process. If the piston comes to rest at point 2 as shown. Then the enthalpy change for the process
will be :
(A)
1
V P 2
H
0 0

= A
(B)
1
V P 3
H
0 0

= A
(C*) AH = P
0
V
0
(D) None of these
[Sol. AU = W = P
0
(4V
0
V
0
) = 3P
0
V
0
AH = AU + A(PV)
AH = 3P
0
V
0
+ (P
0
4V
0
2P
0
V
0
)
AH = 3 P
0
V
0
+ 2P
0
V
0
AH = P
0
V
0
]
Q.4 The pressure of 11 gm of an ideal gas which is placed in a 4 litres container at 127C is 2 atm, then the
gas would be : [Given : R = 0.08 atm lit/moleK]
(A*) N
2
O (B) O
3
(C) NO
2
(D) None of these
[Sol.
RT
M
PV
e
= 44 16 28 M
O N
2
= + =
CHEMISTRY
XII (A, A1) RT-1 [Paper-II] Page # 2
400 08 . 0
M
11
4 2 =
3
O
M = 48
46 32 14 M
2
NO
= + =
M = 44 gm Ans. N
2
O gas
[Q. No.5 to Q.No.7; 4 marks]
Q.5 Which of the following is incorrect statement about [Cr(en)
3
]
3+
ion.
(A) Octahedral coordination polyhedron. (B) Species possess three chelating rings.
(C) Coordination sphere is homoleptic. (D*) Coordination number of central ion is three.
Q.6 Given below are some standard heats of reaction :
(i) Heat of formation of water = 68.3 kcal
(ii) Heat of combustion of acetylene = 310.6 kcal
(iii) Heat of combustion of ethylene = 337.2 kcal
Calculate the heat of reaction for the hydrogenation of acetylene at constant pressure at 25C.
(A) 47.1 kcal (B) 52.3 kcal (C*) 41.7 kcal (D) + 52.3 kcal
[Sol. Standard heats of reaction means AH at 1 atm and 25C. Using the data given :
H
2
+
2
1
O
2
H
2
O ; AH = 68.3 kcal .............(i)
C
2
H
2
+
2
5
O
2
2CO
2
+ H
2
O ; AH = 310.6 kcal .............(ii)
C
2
H
4
+ 3O
2
2CO
2
+ H
2
O ; AH = 337.2 kcal .............(iii)
C
2
H
2
+ H
2
C
2
H
4
; AH = ?
Adding equation (i) and (ii) and then subtracting equation (iii)
C
2
H
2
+ H
2
C
2
H
4
; AH = 41.7 kcal
Q.7 Which of the following is correct electronic configuration in 5d orbitals of metal ion w.r.t. their energy in
complex K
2
[PtCl
4
], (
78
Pt[Xe]

4f
14
5d
9
6s
1
) :
(A) (5d
xy
)
2
< (5d
xz
)
2
< (5d
yz
)
2
<
( )
1
y x
2 2
d 5

< ( )
1
z
2
d 5
(B) ( )
2
z
2
d 5 < (5d
xy
)
2
= (5d
xz
)
2
< (5d
yz
)
2
<
( )
2
y x
2 2
d 5

(C)
( )
2
y x
2 2
d 5

< ( )
2
z
2
d 5 < (5d
xy
)
2
= (5d
xz
)
2
< (5d
yz
)
0
(D*) ( )
2
z
2
d 5 < (5d
xz
)
2
= (5d
yz
)
2
< (5d
xy
)
2
<
( )
0
y x
2 2
d 5

[Sol. It is a square planar complex.


CHEMISTRY
XII (A, A1) RT-1 [Paper-II] Page # 3
[PARAGRAPH TYPE]
Q.8 to Q.10 has four choices (A), (B), (C), (D) out of which ONLY ONE is correct.
Paragraph for question nos. 8 to 10
VESPR theory may be summarised as follows :
(1) Each valence shell electron pair of an atom is stereochemically significant and repulsions between
them determine molecular shape.
(2) Repulsions decrease in the sequence lone pairlone pair > lone pairbonding pair > bonding pair
bonding pair.
(3) Repulsions also decrease in the sequence triple bondsinble bond > double bond single bond >
single bond single bond.
(4) Repulsions between the bonding pairs in a species ABn depend upon the difference in electronegativity
between A and B, and decrease as the electronegativity of B increases.
Q.8 Which of the following pair is correct w.r.t. their dipole moment :
(A) H
2
O > H
2
S (B) NF
3
< NH
3
(C) CHCl
3
< CH
2
Cl
2
(D*) All are correct
Q.9 Which of the following is incorrectly match :
(A)
4 H N
+
> NH
3
> H
2
O : bond angle
(B) Ethylene < Cyanogen (CN)
2
< ethane : order of CC bond distance
(C)
2
3
CO < CO
2
< CO : order of CO bond energy..
(D*) H
2
O
2
< O
2
< O
3
: bond order between OO.
Q.10 Which of the following molecule has see-saw type shape :
(A) ClF
3
(B) SiF
4
(C*) XeO
2
F
2
(D) XeO
3
[MULTIPLE CORRECT CHOICE TYPE]
Q.11 to Q.15 has four choices (A), (B), (C), (D) out of which ONE OR MORE may be correct.
Q.11 Which of the following is/are correct statement(s) :
(A*) [Co(en)
2
Cl
2
]
+
has three space isomers.
(B) [Co(H
2
O)
5
(NO
2
)] NO
3
exhibt linkage, ionisation as well as hydrate isomerism.
(C*) [Co(NH
3
)
3
(NO
3
)
3
] has two geometrical isomers and both are optically inactive.
(D) [Zn(gly)
2
] does not show geometrical isomerism and it is optically inactive.
Q.12 Which of the following statement is correct :
(A*) Isobaric heat exchange is path independent.
(B) PV work is always non zero when volume of initial & final states are not same.
(C*) If entropy of system increases during a process occur in isolated system then it must be spontaneous.
(D) If entropy of system increases during a process then it must be spontaneous.
Q.13 Metal (3d seri es) obey 18 el ectrons rul e i n compl ex ; [ M (o C
3
H
5
) (q
3
C
3
H
5
)(CO)
3
] ; which of the
following is/are correct statement about the complex :
(A) Atomic number of metal is 24.
(B*) Species is diamagnetic in nature.
(C) Species is paramagnetic and contains three unpaired electrons.
(D*) o-Allyl-q
3
-allyltricarbonyliron(II) is correct IUPAC name of the compound.
[Sol. Metal is Fe.
EAN = at number - ox. state + 2 CN
CHEMISTRY
XII (A, A1) RT-1 [Paper-II] Page # 4
Q.14 If the rms velocity of nitrogen and oxygen molecule are same at two different temperature and same
pressure then correct statement is/are :
(A*) Average speed of molecules is also same
(B*) Density (gm/lt.) of nitrogen and oxygen is also equal.
(C) Number of moles of each gas must be equal.
(D*) Most probable velocity of molecules is also equal.
[Sol.
( ) ( )
2 2
O rms N rms rms
v v
M
RT 3
v = =
1
28
32
T
T
32
TO
28
T
2
2 2
N
O
2
N
> = =
(A)
same
M
T
as same
M
RT 8
v
avg
= =
t
=
(B)
RT
PM
d =
= same at same presure.
(C)
RT
PV
n =
(as only P = same so no comment on moles)
(D) v
mps
=
M
RT 2
= same
Q.15 Which of the following IUPAC names is/are incorrectly match :
(A) [NiCl
2
{P(CH
3
)
2
C
6
H
5
}
2
] dichloridobis(dimethylphenylphosphine) nickel(II)
(B*) [Fe(H
2
O)
5
(SCN)]
2+
pentaaquathiocyanato-S-ferrate(III) ion.
(C*) (SO
4
)
2
Bis[amidotetraamminedicobalt(III)] sulphate.
(D) Na
3
[Ag(S
2
O
3
)
2
] sodium bis(thiosulphato)argenate(I)
PART-C
[INTEGER TYPE]
Q.1 to Q.5 are "Integer Type" questions. (The answer to each of the questions are upto 4 digits)
[Q. No.1 to Q.No.3; 4 marks]
Q.1 Calculate magnitude of AH (in kcal) for the following homogeneous gaseous reaction
CH
3
COCH
3
+ 2O
2
CH
3
COOH + CO
2
+ H
2
O
from the following data :
Bond energies C H = 99 kcal
C C = 83 kcal
C == O = 173 kcal
O == O = 118 kcal
C O = 84 kcal
O H = 110 kcal [Ans. 0144]
[Sol.
O O
|| ||
OH H O C O H O C CH O 2 CH C CH
3 2 3 3
+ = = + +
CHEMISTRY
XII (A, A1) RT-1 [Paper-II] Page # 5
AH
rxn
= ( ) ( )

A A product H t tan reac H
. D . B . D . B
A
xn
= {3
c
CH
+
c
CC
+ c
C=C
+ c
CO
+ c
OH
+ 2c
C=O
+ 2c
OH
}
+{
c
CH
+
c
C=O
+ 2c
O=O
+ 2c
CC
}
AH
rxn
=
c
CH
+
c
O=O
+ c
CC
+ c
CO
c
OH
2c
C=O
2c
OH
AH
rxn
= 3 99 + 2 118 + 83 84 110 2 173 2 110
AH
rxn
= 144 Kcal
Q.2 Determine the change in Gibb's energy (in Joule) of 24 gm of liquid benzene (d = 0.8 gm/ml) when the
pressure is increased isothermally from 1 bar to 11 bar. (1 lit. bar = 100 J)
[Ans. 0030]
[Sol. dG = Vdp 0
V
liquid
=
lit
1000
30
ml 30
8 . 0
24
d
m
= = =
( )
} }
= = = A
1 2
P P V dp V dG G
=
( ) . lit bar 1 11
1000
30

=
J 30 100 10
1000
30
=
Q.3 How many species among them have bond angle 180?
2
O N
+
, ClF
3,
BrF
5,
XeF
2
, I
3

, [NiCl
4
]
2
, [Ni(CN)
4
]
2
, H
2
S, Graphite [Ans: 0004]
[Ans:
2
O N
+
, XeF
2
, I
3

, [Ni(CN)
4
]
2
]
[Q. No.4 to Q.No.5; 5 marks]
Q.4 Calculate magnitude of AU (in cal/mol) 2 moles of CH
4
(g) undergo combustion in excess of O
2
(g) at
300 K if AH (in cal/mol) for the following reaction is :
CH
4
(g) + 2O
2
(g) CO
2
(g) + 2H
2
O(l), AH = 400 cal/mol
[Ans. 1600]
[Sol. AH = AU + Ang RT
400 = AU 2 2 300
400 = AU 1200
AU = 1200 400 = 800
AU = 2 800 = 1600 ]
Q.5 Consider the following
CoCl
3
6H
2
O, NiCl
2
6H
2
O ; CuSO
4 anhy
, FeCl
3
6H
2
O, ZnCl
2
6H
2
O, K
2
Cr
2
O
7
, K
2
MnO
4
, HgI
2
,
TiCl
4
Coloured species = A
Coloured species due to d-d transition = B
Coloured species due to charge transfer = C
Coloured species due to polarisation = D
Write your answer as 'ABCD'. [Ans: 6411]
[Sol. A : CoCl
3
.6H
2
O, NiCl
2
.6H
2
O, FeCl
3
.6H
2
O,K
2
Cr
2
O
7
, K
2
MnO
4
, HgI
2
= 6
B : CoCl
3
.6H
2
O, NiCl
2
.6H
2
O, FeCl
3
.6H
2
O, K
2
MnO
4
= 4
C : K
2
Cr
2
O
7
=1
D : HgI
2
= 1
MATHEMATICS
XII (ABC/SMS) RT-1 [Paper-II] Page # 1
PART-A
[SINGLE CORRECT CHOICE TYPE]
Q.1 to Q.4 has four choices (A), (B), (C), (D) out of which ONLY ONE is correct. [3 Marks]
Q.1 If
3 1 x
k
x n
k
sec Lim
1
1 x
t
=
|
|
.
|

\
|

l
, then the value of k is equal to
(A) 2 (B) 3 (C*) 4 (D) 6
[Sol.
|
|
.
|

\
|

1 x
k
x n
k
Lim
1 x l
= 2 [ST-8]
Put x = 1 + h
( )
) h 1 ( n h
) h 1 ( n h ( k
Lim
0 h +
+
l
l
= 2
2
2
0 h
h
.......
2
h
h h k
Lim
(
(

|
|
.
|

\
|
+

= 2

2
k
= 2. k = 4]
Q.2 Which one of the following function is discontinuous for atleast one real value of x?
(A*) f(x) = x sgn 1+ (B) g(x) =
3 e
1 e
x
x
+
+
(C) h(x) =
7
5
x 3
x 2
5 2
1 2
|
|
.
|

\
|
+
+
(D) k(x) = x sin 2 3+
[Note : sgn x denotes signum function of x.]
[Sol. k(x) =
x sgn 1+
=

>
=
<
0 x ; 2
0 x ; 1
0 x ; 0
[ST-9]
So, k(x) is discontinuous at x = 0. Ans.]
Q.3 The value of
(cos
4
1 + cos
4
2 + cos
4
3 + + cos
4
179 ) (sin
4
1 + sin
4
2 + sin
4
3 + + sin
4
179)
equals
(A) 2cos 1 (B*) 1 (C) 2sin 1 (D) 0
[Sol. Expression [ST-9]
(cos
4
1 + cos
4
2 + cos
4
3 + + cos
4
179 ) (sin
4
1 + sin
4
2 + sin
4
3 + + sin
4
179)
= cos 2 + cos 4 + cos 6 + ............. + cos (358)
= cos
( )
1 sin
1 179 sin
2
358 2

|
.
|

\
| +
= cos (180) = 1. Ans.]
MATHEMATICS
XII (ABC/SMS) RT-1 [Paper-II] Page # 2
Q.4 Let f(x) = sin
1
(sin x), g(x) = cos
1
(cos x), then which one of the following incorrect?
(A) f(x) = g(x) x e
|
.
|

\
| t
4
, 0
(B) f(x) < g(x) x e
|
.
|

\
| t t
4
3
,
2
(C) f(x) < g(x) x e
|
.
|

\
| t
t
4
5
,
(D*) f(x) > g(x) x e |
.
|

\
|
t
t
2 ,
2
3
[Sol. f (x) = sin
1
(sin x) =

t
s <
t
t
t
s <
t
t
t
s s
t
2
5
x
2
3
, 2 x
2
3
x
2
, x
2
x
2
, x
g (x) = cos
1
(cos x) =

t s < t t
t s s
2 x , x 2
x 0 , x
Now, verify alternatives. ]
Q.5 to Q.7 has four choices (A), (B), (C), (D) out of which ONLY ONE is correct. [4 Marks]
Q.5 If x + sin y = 101 and x + 101 cos y = 100 where 0 s y s
2
t
then the value of [x + y] is
(A) 99 (B) 100 (C*) 101 (D) 102
[Note : [k] denotes the largest integer less than or equal to k.]
[Sol. x + sin y = 101 ......(1) [ST-5]
x + 101 cos y = 100 ......(2)
(1) (2) sin y 101 cos y = 1
sin y = 1 + 101 cos y
y e
(

t
2
, 0
cos y e [0, 1]
possible only if sin y = 1 y =
2
t
and cos y = 0 y =
2
t
sin y = 1 x = 100
[x + y] = 101. Ans.]
Q.6 Let g(x) =

t
=
t
=
|
|
.
|

\
|
+
t
2
x ; 1 p
2
x ;
] x [sin 1
1
2
x 2
2
then the value of p for which f(x) is continuous at x =
2
t
is
[Note: [k] denotes the largest integer less than or equal to k.]
(A*) 2 (B) 1 (C)
2
1
(D) 0
MATHEMATICS
XII (ABC/SMS) RT-1 [Paper-II] Page # 3
[Sol. As g(x) is continuous at x =
2
t
, so [ST-6]
|
.
|

\
| t
2
g = ( )

t
t

|
|
.
|

\
|
+
1
] x [sin 1
1
Lim
x 2
2
2
x
= e
L
, where
t

|
|
.
|

\
|

+
=
t

x 2
2
1
] x [sin 1
1
Lim L
2
x
=
t

x 2
2
] x [sin 1
] x [sin
Lim
2
x
=
quantity zero non some
zero actual

= 0

1 e
2
g
0
= = |
.
|

\
| t
= p
2
1 p
2
= 2 p = 2 . Ans.]
Q.7
|
|
.
|

\
|
|
.
|

\
|
+


x
x 1 x
x
e
1
x Lim equals
(A)
e
1
(B*)
e 2
1
(C)
e 2
1
(D)
e
1
[Sol.
|
|
.
|

\
|
|
.
|

\
|
+


x
x 1 x
x
e
1
x Lim [ST-7]
Let x =
t
1

|
|
.
|

\
|
|
.
|

\
|
+

t 1
0 t t 1
1
e
1
t
1
Lim
=
t 1
t 1
0 t
) t 1 ( t
e ) t 1 (
Lim
e
1
+
+

=
t
e e
Lim
e
1
t
) t 1 ( n
0 t
2

l
= |
.
|

\
|

+
|
.
|

\
|

+

1
t
) t 1 ( n

1
t
) t 1 ( n
1 e
Lim
e
1
1
t
) t 1 ( n
0 t
l
l
l
=
2
0 t
t
t ) t 1 ( n
Lim
e
1 +

l
=
e 2
1
. Ans.]
[PARAGRAPH TYPE]
Q.8 to Q.10 has four choices (A), (B), (C), (D) out of which ONLY ONE is correct.
Paragraph for question nos. 8 to 10
Let f(x) be a polynomial satisfying
1 x
) x ( f x
Lim
8
4
x
+

= 3,
f(2) = 5, f(3) = 10, f(1) = 2, and f (6) = 37.
Q.8 The value of f (0) is equal to
(A) 1 (B) 0 (C*) 109 (D) 119
MATHEMATICS
XII (ABC/SMS) RT-1 [Paper-II] Page # 4
Q.9 The value of
) 6 x ( 3
1 x ) x ( f
Lim
2
6 x
+


, is equal to
(A) 6! (B) 6! (C)
2
! 6
(D*)
2
! 6
Q.10 The number of points of discontinuity of g(x) =
) x ( f 1 x
1
2
+
in
(

2
5
,
2
15
, is equal to
(A) 4 (B*) 3 (C) 1 (D) 0
[Sol. According to given information, we must have f(x) a polynomial of degree 4 with leading coefficient 3.
So, f(x) = 3 (x 2) (x 3) (x + 1) (x + 6) + (x
2
+ 1) [ST-9]
(i) f(0) = 109. Ans.
(ii)
) 6 x ( 3
1 x ) x ( f
Lim
2
6 x +


=
) 6 x ( 3
) 6 x ( ) 1 x ( ) 3 x ( ) 2 x ( 3
Lim
6 x +
+ +

= ( 8) ( 9) ( 5) = 360. Ans.
(iii) We have g(x) =
) x ( f 1 x
1
2
+
=
) 1 x ( ) 6 x ( ) 1 x ( ) 3 x ( ) 2 x ( 3 ) 1 x (
1
2 2
+ + + +
=
) 6 x ( ) 1 x ( ) 3 x ( ) 2 x ( 3
1
+ +

, x = 6, 1, 2, 3
But x e
(

2
5
,
2
15
, so points of discontinuous are three i.e., x = 6, 1, 2. Ans.]
[MULTIPLE CORRECT CHOICE TYPE]
Q.11 to Q.15 has four choices (A), (B), (C), (D) out of which ONE OR MORE may be correct.
Q.11
lcd
Let f(x) = min. ( | e x |, t | x | ). Then which of the following statement(s) is (are) correct?
(A*) f(x) is many one but not even function.
(B) Range of f(x) is
(

\
| t

2
e
,
.
(C*) f(x) is continuous and derivable at all integral points.
(D) f(x) is continuous everywhere but non-derivable at exactly two points.
[Sol. Clearly f(x) is continuous everywhere
but non-derivable at 3 points viz.
2
e
, e ,
2
e
x
+ t t
= .
y=ex
y=x+t y= x t
y=xe
(0, ) t
(0,e)
( ,0) t
( ,0) t (e,0)
x =
e
2
t O
(0,0)
x
y
Graph of y = f (x)
2
e
x
+ t
=
Now verify alternatives from graph.
Also, Range of f(x) is
(

\
| + t

2
e
,
[ST-1] ]
MATHEMATICS
XII (ABC/SMS) RT-1 [Paper-II] Page # 5
Q.12 Which of the following are continuous function?
(A) f(x) =

>
s s
<
1 x if , x 4
1 x 0 if , 0
0 x if , x 2
(B*) g (x) =

> +
<
0 x if , 1 x
0 x if ,
x
x sin
(C*) h (x) = | x | | x + 1 | (D*) k (x) =

=
=
0 x if , 1
0 x if , x cos x sin
[Sol.
(A) f (x) is discontinuous at x = 1, as f (1

) = f (1) = 0, but f (1
+
) = 4.
(B) g (x) is continuous at x = 0, as g(0

) = g (0) = g(0
+
) = 1.
(C) h (x) is continuous x e R as difference of two continuous function is also a continuous function.
(D) k (x) is continuous at x = 0 as k(0
+
) = k(0

) = k(0) = 1. ]
Q.13
62
If
x cos x sin
1
6 6
+
> o x e R, then o can be
(A) 3 (B) 4 (C*) 5 (D*) 6
[Sol. Given, o >
x 2 sin
4
3
1
1
2

x e R
o > 4 x e R. Ans.]
Q.14
76
Which of the following statements is(are) correct ?
[Note: [x] and {x} denote greatest integer less than or equal to x and fractional part of x respectively.]
(A*) f(x) = [ln x] + } x n {l , x > 1 is continuous at x = e.
(B*) If
|
|
.
|

\
|
+
+ + +

2 x x
1 a ax x 3
Lim
2
2
2 x
exists and equals l, then
l
1
a +
= 10.
(C*) f : [ 1, 1] [ 1, 1], f(x)= x
2
sgn(x) is a bijective function, where sgn x denotes signum function
of x.
(D*) If f is continuous on [ 1, 1] , f( 1) = 4 and f(1) = 3, then there exists a number r such that 1 r <
and f(r) = t.
Sol.
(A) f(e) = 1 ; f(e
+
) = 1 ; f(e

) = 1
(B) Here, a = 13, l =
3
1
; so a +
l
1
= 13 +
|
|
|
|
.
|

\
|

3
1
1
= 13 3 = 10.
(C) f(x) = x
2
sgn x =

>
=
<
0 x , x
0 x , 0
0 x , x
2
2
.
y
x
(0,0)
(1,1)
(1,1)
x= 1 x=1
(D) As, f is continuous on [1, 1] and f ( 1) = 4, f (1) = 3
there exists a number r such that | r | < 1 and f (r) = t.]
MATHEMATICS
XII (ABC/SMS) RT-1 [Paper-II] Page # 6
Q.15
66
The value of 'k' for which both roots of the equation 4x
2
2x + k = 0 are completely in ( 1, 1),
then k may be equal to
(A*) 1 (B*) 0 (C) 2 (D) 3
[Sol. Let f(x) = 4x
2
2x + k
1 1
or
1 1
Here D > 0 k s
4
1
........(1)
1
A 2
B
1 <

<

1
4
1
1 < <
........(2)
f( 1) > 0 k > 6 ........(3)
f(1) > 0 k > 2 ........(4)
So, (1) (2) (3) (4)
k e
(

\
|

4
1
, 2 . Ans.]
PART-C
[INTEGER TYPE]
Q.1 to Q.3 are "Integer Type" questions. (The answer to each of the questions are Single digits) [4 Marks]
Q.1 Find number of points where f(x) = 1 x x x
3
2
is not differentiable. [Ans. 0]
[Sol. Given, f (x) =
3 2
| x | x
| x | 1 [12th, 06-05-2012, P-2] [TN, conti] OK
=

> =
< = + = +
0 x , 1 1 x x
0 x , 1 1 x x 1 x x
3 3
Hence, f (x) = 1 x e R
y = 1
x
y
So, f (x) is continuous and differentiable x e R.
Hence, number of points of non-derivability of f (x) is 0. ]
Q.2 If
4
27
x tan
x sin 4 ) b ax (
Lim
0 x
=
+ +

, where a, b e R then find (a 3b). [Ans. 1]


[Sol.
4
27
x tan
x sin 4 ) b ax (
Lim
0 x
=
+ +

As x 0, Dr 0
So, Nr 0 for existence of limit. So
b 2 = 0 b = 2.
Now,
x
x sin 4 ) 2 ax (
Lim
0 x
+ +

=
4
27

|
.
|

\
|
0
0
( ) x sin 4 2 ax x
) x sin 4 ( ) 2 ax (
Lim
2
0 x
+ + +
+ +

=
4
27
MATHEMATICS
XII (ABC/SMS) RT-1 [Paper-II] Page # 7
|
|
.
|

\
|
+
x
x sin ax 4 x a
Lim
2 2
0 x
= 27 4a 1 = 27 a =
4
28
= 7.
Hence, (a 3b) = 7 3(2) = 1. Ans.]
Q.3 Let a = [

=
|
|
.
|

\
|

+
2 n
3
3
1 n
1 n
and b = [

+
+
1 n
1
2 1
n 2 1
) n 1 (
, then find the value of (ab). [Ans. 3]
[Sol. a =
[

=
|
|
.
|

\
|

+
2 n
3
3
1 n
1 n
= M = [

=
+ +
+

+
2 n
2
2
) 1 n n (
) 1 n n (

1 n
1 n
=
|
|
.
|

\
|
+ +
+

|
.
|

\
|

+
1 n n
1 n n
.....
21
3

13
7

7
3
1 n
1 n

2 n
n
.....
4
6

3
5

2
4

1
3
2
2
=
1 n n
3

2
) 1 n ( n
Lim
2
n
+ +
+

=
2
3

2
3
a =
N = [

+
+
1 n
1
2 1
n 2 1
) n 1 (
= [

=
|
.
|

\
|
+
|
.
|

\
| +
1 n
2
2 n
n
n
1 n
= [

=
|
|
.
|

\
|
+
+
1 n
2
) 2 n ( n
) 1 n (
N = [ [

=

=
|
.
|

\
| +
|
.
|

\
|
+
+
1 n 1 n
n
1 n
2 n
1 n
=
n . .......... 3 2 1
) 1 n ( n ..... 4 3 2
) 2 n )( 1 n ......( 5 4
) 1 n ......( .......... 4 3

3
2 +

+ +
+
=
2 n
) 1 n ( 2
+
+
= 2 2 b =
(ab) =
2
3
2 = 3 Ans. ]
Q.4 & Q.5 are "Integer Type" questions. (The answer to each of the questions are Single digits) [5 Marks]
Q.4 Let x and y be real numbers such that
y sin
x sin
= 3 and
y cos
x cos
=
2
1
. The value of
y 2 cos
x 2 cos
y 2 sin
x 2 sin
+
can be expressed in the form
q
p
, where p and q are relatively prime positive integers. Find | p q |.
[Ans. 9]
[Sol. Given
y sin
x sin
= 3 .......(1)
and
y cos
x cos
=
2
1
.....(2)
Now,
y 2 sin
x 2 sin
=
|
|
.
|

\
|
|
|
.
|

\
|
y cos
x cos
y sin
x sin
=
( )
|
.
|

\
|
2
1
3
=
|
.
|

\
|
2
3
Now,
y 2 cos
x 2 cos
=
1 y cos 2
1 x cos 2
2
2

........(3)
MATHEMATICS
XII (ABC/SMS) RT-1 [Paper-II] Page # 8
(1)
2
9 sin
2
y = sin
2
x ........(4)
(2)
2
cos
2
y = 4 cos
2
x 1 sin
2
y = 4 4 sin
2
x sin
2
y = 4 sin
2
x 3
Put the value of sin
2
y in equation (4) 36 sin
2
x 27 = sin
2
x sin
2
x =
35
27
sin
2
y =
35
3
Hence,
y 2 cos
x 2 cos
=
1 y cos 2
1 x cos 2
2
2

=
y sin 2 1
x sin 2 1
2
2

=
|
.
|

\
|

|
.
|

\
|

35
3
2 1
35
27
2 1
=
29
19
Hence,
y 2 cos
x 2 cos
y 2 sin
x 2 sin
+ =
2
3

29
19
=
58
49
=
q
p
| p q | = | 49 58 | = | 9 | = 9. Ans.]
Q.5 Consider the function f defined as f(x) = R x 1 | x | e and another function g(x) such that
g(x) = (fof) (x). Find number of points where g(x) is non-differentiable. [Ans. 5]
[Sol. We have f (x) = 1 | x | =

< <
s s +
< s +
< <
x 1 ; 1 x
1 x 0 ; 1 x
0 x 1 ; 1 x
1 x ; 1 x
( ) ) x ( f f = 1 | ) x ( f | = 1 1 | x | [12th, 06-05-2012, P-2] [TN, conti] OK
=

< s
< < +
s s
< <
s s +
< <
x 2 ; 2 x
2 x 1 ; 2 x
1 x 0 ; x
0 x 1 ; x
1 x 2 ; 2 x
2 x ; 2 x
(0,0)
y
=
x
y
=

x

2
y
=

x
+
2
y
=

x
+
2
y
=

x
y
=

x

2
x=1 x=2 x= 1
(1,1) (1,1)
x= 2
x
y
Graph of y = f f (x) ( )
So, ( ) ) x ( f f , is non-derivable at five points viz. x = 2, 1, 0, 1, 2.]

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