LEVEL 1

DATE : 09/05/2015
TIME : 2 Hours

CHEMISTRY ( CHEMICAL KINETICS )

1) Rate constant of a reaction depends upon

a) Speed (rate) of reaction
b) Concentration of the reactants
b) Pressure of the surroundings
d)Temperature
2)The time taken for the completion of of a first order reaction is
a)(2.303/k) log(3/4 )

b)(2.303/K) Log 4

c)(2.303/0.75)log k

d)(2.303/k)log 1/4

3)Which of the following equation is correct for the reaction

N2 (g) +3H2(g) -------- 2 NH3(g) ?
a)3d[H2]/dt =2d[N2]/dt

b)2d[N2]/dt=1/3d[H2]/dt

c) 2d[NH3]/dt= -3d[H2]/dt

d) 2d[NH3]/dt= -2d[H2]/dt

4)The activation energy for a simple chemical reaction A--B is Ea in forward direction .The
activation energy for the reverse reaction
a)is negative of Ea

b)is always less than Ea

c)can be less or more than Ea

d)is always double of Ea

5)A chemical reaction was carried out at 300k and 280k .The rate constants were found to be K 1
and K2 respectively.Then
a) K2=4 K1 b) K2=2 K1 c) K2=0.25 K1 d) K2=0.5 K1
6)The rate constant is given by the equation K=P.Ze -E/RT. which factor register a decrease for the
reaction to proceed more rapidly ?
a)T

b)Z

c)E

d)P

7)If concentration of reactants is increased by x then rate constant K becomes

a)In K/x b)K/x

c)K+x d)K

8)A large increase in the rate constant with small rise in temperature for a gaseous reaction is
indicative of
a)Large number of collisions at higher temperature
b)High value of activation energy of the reaction
c)High value of the pre exponential factor
d)Increase in the average speed of molecules .
9)Which of the following formulae represents the first order reaction ?
a)k=2.303/t log [A]/[A]0
log(a/a+x)

b) k=2.303/t log( a-x/a )

[A]=[A 0]e-kt

c)

d) k=2.303/t

10) If a is the initial concentration of the reactant ,the time for completion of the reaction, if it is
of zero order,will be
a)a/k

b)a/2k

c)2a/k

d)k/a

11) The second order rate constant is usually expressed as

a) mole litre s-1

b)mole-1 litre-1s-1

c) mole litre-1s-1

d) mole-1 litre s-1

12) Which of the reaction of first order ?

a)2N2O5 -----4NO2 +O2

b)2HI ---H2 +I2

c)2NO2 ----2NO +O2

d) 2NO+O2 ---2NO2

13)What is the order of a reaction which has a rate expression rate =k[A] 3/2[B]-1 ?
a)3/2

b)1/2 c)zero

d)none of these

14)The Arrhenius equation expressing the effect of temperature on the rate constant of the
reaction is
a)k=e-Ea/RT

b)k=Ea/RT

c)k=logeEa/RT d)k=Ae-Ea/RT

15)The rate constant of a reaction is 2.1 x 10-2 mol-2litre

a) zero

b) 1

c) 2

min -1.The order of reaction is

d) 3

16)When concentration of reactant in reaction A--- B is increased by 8 times, the rate increase
only 2 times .The order of the reaction would be
A) 2

b) 1/3

c) 4

d)

17) For the first order reaction half life is 14 s .The time required for the initial concentration to
reduce to 1/8 th of its value is
A)28 s

b)42 s

c)(14) 3s

d) 14)2s

18)The rate constant of n-th order has units

a) litre

1-n

mol1-n s-1

b) mol1-n litre

1-n

c) mol

1-n2

litren2 s-1

d) mol1-n litre

n-1

s-1

19)An endothermic reaction A--B has an activation energy as x kJmol-1 of A. If energy change of
the reaction is y kJ. The activation energy of the reverse reaction is
A) -X

b) x-y

c) x + y

d) y-x

20)The units of rate of reaction are

a) L mol-1 s-1

b) mol L-1 s

-1

c) mol s-1

d) none of these

MATHEMATICS ( VECTOR & RELATIONs &

FUNCTIONs )
1)The value of a unit vector in the direction of vector A=5i-12j is
a)

i^

^
b) j

^
c) ( i

^j
)/13

d)

(5 i1 j)/13

2)Two vectors A and B lie in X-Y plane .The vector B is perpendicular to vector A if A=I + j, then B
may be
a) i j b i+ j c 2i+2 j d an y of the above
3) The two vector A=2i +j +3k

and B= 7i-5j-3k are

A)parallel

c) anti- parallel

b)perpendicular

d)none of these

4) Angle that the vector A=2i+3j makes with y axix is

A)tan-1 3/2

b) tan-1 2/3

c) sin-1 2/3

d) cos-1 3/2

5) A vector A points vertically upward and ,B points toward north The vector product A*B is
a) Along west

b) along east

c) zero

d) vertically downward

6) If A = B + C and the magnitudes A ,B , and C are 5,4 ,and 3 units ,the angle between A and C is
a)cos-1 (3/4)

b)cos-1 (4/5)

c) /2

7) The resultant of A and B makes an angle

a) <

B) < IF A<B

d) sin -1(3/4)

with A and with B then

c) < if A>B

d) < if A =B

8) A unit vector perpendicular to the vector a & a + b Where a =I +j +k

a)-I +j b) j +k

c) i +j -2k

9) The vectors a+ 5b -7 c
a)10

b)-10

c) 0

b=I + j + k

d) j + 3k + i
& -2a b + 14c are collinear ,then the value of is

d) 14

10) The position vectors of the points which divided internally &externally in ratio 3:4,the join of the points a+b , 2a b
respectively are

a)

10 a+b
& 2 a+7 b
7

c)

10 a2 b
4 a+7 b
7

10 ab
12 a+ 4 b
7

b)

d)

2 a+7

b10 a+b
7

11) Find the co ordinates of the terminal point of the vector AB where initial point has co-ordinates (5,6)
and whose components are -7i & 4j along x and y axis respectively
a)(2,10 )
12) If

c) (-2 ,0)

d)(10 ,10)

a=i+2 j+3 k ,b=2 j+ 4 kc =i2 j+k then ( a+ b ) . c

a) 8
13) If

b) (10 ,2)

b) 9

c) 10

d) 14

a=i+2 j3 k b=3i j2 k the angle between 2 a+ba+2 b is

a)cos-1(3/4)

b) cos-1 (13/14)

c)cos-1(3/4)

d)cos-1(14/13)

14) Find the value of a so that the angle between the two vector

a)-4

b)(-4 ,0)

c) (-1 ,4 )

i j+ ak
0
i+k is 60

d) ( 0, 3)

15) What will be the angle between a & b if there is a set of there vectors a , b & c such that a+b+c =0 &|a| = 3 |b|=5
& |c| =7
a) =90

b )=40

c) =60

d) =30

16) find the value of when the scalar projection on

a)6

b)7

d) 8

a=i+ j+4 k on b=2i+6 j+3 k is 4 unit

d)5

17) A unit vector perpendicular to the vector a & b . where

a) 5i -3 j k

5i
3j
k

c) 195 195 j 195

18 ) The two vectors a=
a) Parallel

a=i+2 jk b=2i+3 j+k

5i
3j
k

35 35 35

d)

12 i+ 16 j9 k

3 i+3 jb=4 i4 j+ 2 k are

b) perpendicular c)makes 45o angle d)

19) The area of a parallelogram whose vertices are

none of these

( 3 ,1 , 2 ) , ( 1,1 , 3 ) , ( 4 ,3 ,1 )( 6 ,3 , 0 ) is

a)21 sq unit

b) 14 sq unit

c) 15 sq unit

d) 27 sq unit

20) The vectors a , b ,c ,d are as shown in the figure below

a)

|c +d|=|a+ d| b a+d=a+d

b)

a=c d d=b

21) Let A={1,2,3} then the number of equivalence relations containing (1, 2) is
a) 1

b) 2

c) 3

d) 4

22)R is a relation an the set Z of integers and it is given by (x , y) R | x-y |

a)reflexive and transitive

b)reflexive and symmetric

c)symmetric and transitive

d)an equivalence relation

then R is

23) Let R be the root line .Consider the following subsets of the plane R*R
S=

T=

{( x , y ) : y=x +10< x< 2

{( x , y ) : x y is aninteger }

Which one of the following is true ?

a)T is an equivalence relation on R but S is not

b)Neither S nor T is an equivalence relation on R

c)Both S and T are equivalence relations on R

d)S is an equivalence relation on R but T is not

24)Let W denotes the words in the English dictionary .Define the relation R by
R=

{ ( x , y ) ww : the words x y hav at least one letter common } then R is

a)reflexive , symmetric and not transitive .

b) reflexive ,symmetric and transitive
c)reflexive , not symmetric and transitive
d)not reflexive ,symmetric and transitive
25)Let R1 and R2 be equivalence relations on a set A , then R1U R2 need not be
a) reflexive b) symmetric

c) transitive

d) none of these

26) Which of the following functions from Z into Z are bijections ?

a)

f ( x )=x

b)

f ( x )=x

+2

27) The function f : R -- R defined by

a)one one bt not onto

c)

f ( x )=2 x +1

f ( x )=( x1 ) ( x2 ) ( x 3 ) is

b) nto but not one- one

d)

f ( x )=x

+1

c)both one-one and onto

d)neither one-one nor onto

28)Let A={ x : -1 x 1

} and f: A -A such that

a) a bijection

then

is

then

is

b) injective but not surjective

c)surjective but not injective

29)Let function

f ( x )=x |x| ,

d)neither injective nor surjective

f : R R be difined by f ( x )=2 x+ sinx for xR

a)one-one and onto

b)one-one but not onto

c)onto but not one-one d)neither one-one nor onto

30)

f ( x )=

is rational
{0x,if, ifxxisirrational
}

g ( x ) = 0,if x is rational
x ,if x is irrational

and

a)neither one-one nor onto

b) one-one and onto

c)one-one and into

d) many one and onto

then

f g is

PHYSICS ( ELECTROSTATICS )

1)

Two point charges +4 c and +2 c

repel each other with a force of 8 N . If a

charge of -4 c is added to each of these charges ,the force would be

a)zero

b) 8 N

c) 4 N

d) 12 N

2)
A long string with a charge of per unit length passes through an imaginary cube of edge
a .the maximum flux of the electric field through the cube will be
a) a/ E

b) 2 a/ E

c) 6 a/ E

d) 3 a /E

3)
If charge q is placed at the centre of the line joining two equal charges Q.The system of
three charges will be in equilibrium if q is
a) Q/2

b) Q/4

c) 4Q

d) +Q/2

There are two charges +1 c and +5 c . The ratio of the forces acting on them

4)
will be

a)1 : 1

b)1: 2

c)1 : 3

d)1:4

5)
Two spheres A and B of exactly same mass are given equal positive and negative charges
respectively .Their masses after charging
a)remain unaffected
can be said

b)mass of A > mass of B

c)mass of A < mass of B d) nothing

6)
Two point charges repel each other with a force of 100N .One of the charges is increased by
10 %and other is reduced by 10 % .The new force of repulsion at the same distance would be
a)100N

b)121 N

c)99N

d)none of these

7)
Two electrons are separated by a distance r metre and have coulomb force F .Two alpha
particles separated by 2r metre will have a force equal to
a)2F
8)

b)3F

c)F/2

d)F

In S.I. system , the value of

a)1 C2 N-1m-2

B)9 x 109 C2 N-1m-2

is
C)1/(9 x 109 ) C2 N-1m-2

D) 1/(4

x 9 x 109 ) C2 N-1m-

9)
A positively charged rod is brought near an uncharged conductor .if the rod is then suddenly
withdrawn, the charge left on the conductor will be
a)positive
10)

b)negative

c)zero

d)note sure

Two balls carrying charges +7 c and -5 c attract each other with a force F. if a

charge -2 c is added to both ,the force between them will be

a)F

b)F/2

11)
line

d)zero

What is the angle between electric dipole moment and electric field due to it on the axial

a)00
12)

c)2F

b) 900

c)1800

d)none of the above

An electric dipole is kept in a uniform electric field it experiences

a)a force and a torque

b) a force ,but no torque

c)a torque but no force

d)neither a force nor a torque

13)

Electric intensity due to an electric dipole varies with a distance(r) as E

a) -3

b)- 2

c)- 1

d) 0

where n is

14)
Fig .12.28 given here is plot of lines of force due to two charges q 1 and q2 .The signs of
the two charges are
a)both positive
b)both negative
c)upper positive ,lower negative
d)upper negative ,lower positive
15)

Electric field strength at a point varies as 1/r for

a)a point charge b)an electric dipole

infinite length
16)

c)a plane infinite sheet of charge d)a line charge of

A surface encloses an electric dipole .The flux through the surface is

a)zero
17)

b)positive

c)negative

d)infinite

The electric flux over a sphere of radius 1m is

if the radius of the sphere were doubled

without changing the charge enclosed electric flux would become

a)2
18)

b)

/2

c)

/4

d)

The electric flux from a cube of edge L is

. What will be its value if edge of cube is

made 2L and charge enclosed is halved

a)
19)

/2

b)

c)

Two point charges +2 C

d)

and +6 C

repel each other with a force of 12N .If a charge

of -4 C

is given to each of these charges ,the force now is

a)zero

b)4N attractive

c)4N repulsive

d)12N attractive

20)
A charge particle q is placed at the centre O of a cube length L .Another same charge q is
placed at a distance L from O .The electric flux through the cube is
a) q /4 0L

b) q /

c)2 q /

d)zero

 MECHANICS

1)

A particle is moving so that its displacement s is given as s=t 3 -6t2 +4 metre .Its velocity at
the instant when its acceleration is zero will be
a) 3 m/s
b) -12 m/s
c) 42 m/s
d) -9 m/s

2)
If y denotes the displacement and t denotes the time and displacement is given by y=a sin
wt ,the velocity of the particle is
a)a cos wt

b) a cos wt

c)aw cos wt

d) (a cos wt )/w

3)
The displacement x of a particle moving along a straight line is related to time by the
reaction t=x +3 ,The displacement of the particle when its velocity is zero is given by
a)0

b) -2

c)2

d) 1

4) The variation of velocity of a particle moving along straight line shown in figure .The distance
traversed by the body in 4 sec is
a)70 m
b)60 m
c) 40 m
d) 55 m
5)

which of the following curves do not represent motion in one dimension

a)

b)
6)

b)

d)

The unifom motion in the following acceleration time graph is

a)
b)
c)
d)

AB
BC
CD
DE

7) The adjoining curve represents the velocity- time graph of a particle ,its acceleration values along
OA,AB and BC in metre/sec 2 are respectively
a)1,0,0.5

b)1,0,0.5

c)1,1,0.5

d)1,0.5,0

8)
A particle, after starting from rest ,experiences, constant acceleration for 20 sec .if it
covers a distance of S1 in first 10 sec and distance S2 in next 10 sec ,then
a) S2= S1/2

b) S2= S1

c) S2= 2S1

d) S2= 3S1

9)
The initialvelocity of a particle is 10 m/s and its retardation is 2 m/sec 2 .The distance
covered in the fifth second of the motion will be
a) 1m

b) 19 m

c) 50 m

d) 75 m

10) A moving train is stopped by applying brakes .it stops after travelling 80 m .if the speed of
the train is doubled and retardation remains the same .it will cover a distance
A) Same as earlier
b) double the distance covered earlier
c) Four times the distance covered earlier d) half the distance covered earlier
11) A body starts from rest ,the ratio of distances travelled by the body during 3 rd and 4th
seconds is
a)7/5

b) 5/7

c) 7/3

d) 3

12) Which of the following equations represent the motion of a body with finite constant
acceleration . in these equations y denotes the position of the body at time t and a, b ,and c are
constant of the motion
a)y=a/t =bt

b) y=at

c) y = at +bt 2

d) y = at +bt2 +ct3

13) A rocket is projected vertically upwards and its time-velocity graph is shown in the
figure.the maximum height attained by the rocket is
a)
b)
c)
d)

1 km
10km
100km
60km

14) An object is released from some height .Exactly after one second ,another is release from
the same height The distance between the two objects exactly after 2 seconds of the release of
second object will be
a) 4.9 m

b) 9.8 m

c)19.6 m

d) 24.5m

15) A stone is thrown vertically upwards from the top of a tower with a velocity u an it reaches
the ground with a velocity 3u .the height of the tower is

a) 3u2/g

b)4 u2/g

c) 6u2/g

d)9 u2/g

16) A ball is thrown from the ground with a velocity of 80 ft/sec .Then the ball will be at a height
of 96feet above the ground after time
a)2 and 3 sec

b) only 3 sec

c) only 2 sec

d) 1 and 2 sec

17) A stone is dropped from a bridge and it reaches the ground in 4 seconds .the height of the
bridge is
a) 78.4m

b)64

c)260m

d)2000m

18) A rocket is launched from the earth surface so that it has an acceleration of 19.6 m/s 2 .if its
engine is switched off after 5 seconds of its launch,then the maximum height attained by rocket
will be
a)245m

b) 490

c)980m

d) 735m

19) Two bodies of different masses ma and mb are dropped from two different heights viz a and
b .the ratio of times taken by the two to drop through these distances is
a)a:b

b) ma/ mb

c) a:b

d)a2/b2

20) A body thrown up with a finite speed is caught back after 4 sec .the speed of the body with
which it is thrown up is
a)10 m/s

b) 20 m/s

c) 30 m/s

d) 40 m/s

21)
A ball is dropped from certain height on a glass floor so that it rebounds elastically to the
same height .if the process continues the velocity time graph for such a motion would be

22) In the following velocity-time graph of a body .the distance and displacement travelled by
the body in 5 second in meters will be
a)70,110
b)110,70
c)40,70
d)90,50

23) The following figures show some velocity v versus time t curves but only some of these can
be realized in practice .This are

a)a ,b ,d
b) a ,b ,c
c) b , c
d) all of them

24) a girl walks along an east-wst street and a graph of her displacement from home is as
shown in figure.Her average velocity for the whole time interval is
a)
b)
c)
d)

Zero
6m/min
11m/min
15 m/min

25) If graph of velocity Vs distance is as shown .The graph of acceleration Vs distance is

represented by

a)

b)

B)

D)

26) Adjacent graph shown the variation of velocity of a rocket with time .Find the time of
burning of fuel from the graph
a)10 sec

b)110sec
c)120sec
d) cannot be estimated from the graph
27) A particle moves from the position of rest and attains a velocity of 30m/sec after10 sec
.The acceleration will be
a)9 m/sec2
28)

b)18 m/sec2

c)3 m/sec 2

d)4 m/sec 2

The dimension of acceleration and velocity are respectively

a)[MLT-2] and [M0LT2]

B) [ML 1T1] and [LT-1]

c)[M0LT-2] AND [M0LT-1]

d ) [M 1LT-1] and [M0LT-2]

29) A bal is thrown upwards with a speed V from a height h above the ground .The time taken
by the ball to hit the ground is
a)(2h/g )

b) (gh/g)

c) (V 2 +2gh )/g + V/g

d) V/g +(2h/g)

30)
A car accelerates from rest at a constant rate for some time ,after which is
deaccelerates at a constant rate and comes to rest .IF the tota time elapsed in t ,then the
maximum velocity acquired by the car is
A)(2 + 2 /)/t

b) (2 - 2 /)/t

c) ( + )t /

d)t/+

ALL THE BEST