Exxon Elite Oil MSDS
Exxon Elite Oil MSDS
Exxon Elite Oil MSDS
PRODUCT
Product Name: AVIATION OIL ELITE 20W-50
Product Description: Base Oil and Additives
Product Code: 201050201045, 430405-00, 97U847
Intended Use: Aviation Piston Engine Oil
COMPANY IDENTIFICATION
Supplier:
SECTION 2
HAZARDS IDENTIFICATION
This material is hazardous according to regulatory guidelines (see (M)SDS Section 15).
CLASSIFICATION:
Reproductive toxicant (fertility): Category 2.
LABEL:
Pictogram:
Health:
Health:
1
1*
Flammability: 1
Flammability: 1
Reactivity: 0
Reactivity: 0
NOTE: This material should not be used for any other purpose than the intended use in Section 1 without expert
advice. Health studies have shown that chemical exposure may cause potential human health risks which may vary
from person to person.
SECTION 3
CAS#
Concentration*
TRICRESYL PHOSPHATE
1330-78-5
1 - < 2.5%
* All concentrations are percent by weight unless material is a gas. Gas concentrations are in percent by volume.
As per paragraph (i) of 29 CFR 1910.1200, formulation is considered a trade secret and specific chemical identity and
exact percentage (concentration) of composition may have been withheld. Specific chemical identity and exact
percentage composition will be provided to health professionals, employees, or designated representatives in
accordance with applicable provisions of paragraph (i).
SECTION 4
INHALATION
Remove from further exposure. For those providing assistance, avoid exposure to yourself or others. Use
adequate respiratory protection. If respiratory irritation, dizziness, nausea, or unconsciousness occurs, seek
immediate medical assistance. If breathing has stopped, assist ventilation with a mechanical device or use
mouth-to-mouth resuscitation.
SKIN CONTACT
Wash contact areas with soap and water. Remove contaminated clothing. Launder contaminated clothing
before reuse. If product is injected into or under the skin, or into any part of the body, regardless of the
appearance of the wound or its size, the individual should be evaluated immediately by a physician as a
surgical emergency. Even though initial symptoms from high pressure injection may be minimal or absent, early
surgical treatment within the first few hours may significantly reduce the ultimate extent of injury.
EYE CONTACT
Flush thoroughly with water. If irritation occurs, get medical assistance.
INGESTION
Seek immediate medical attention. If medical attention will be delayed, contact a Regional Poison Center or
emergency medical professional regarding the induction of vomiting or use of activated charcoal/syrup of
ipecac. Do not induce vomiting or give anything by mouth to a groggy or unconscious person.
SECTION 5
EXTINGUISHING MEDIA
Appropriate Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish
flames.
Inappropriate Extinguishing Media: Straight Streams of Water
FIRE FIGHTING
Fire Fighting Instructions: Evacuate area. Prevent runoff from fire control or dilution from entering streams,
sewers, or drinking water supply. Firefighters should use standard protective equipment and in enclosed
spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to
protect personnel.
Unusual Fire Hazards: May generate irritating and harmful gases/vapors/fumes when burning.
Hazardous Combustion Products: Aldehydes, Incomplete combustion products, Oxides of carbon,
Phosphorus oxides, Smoke, Fume
FLAMMABILITY PROPERTIES
Flash Point [Method]: >250C (482F) [ASTM D-92]
Flammable Limits (Approximate volume % in air): LEL: 0.9
Autoignition Temperature: N/D
SECTION 6
UEL: 7.0
NOTIFICATION PROCEDURES
In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable
regulations. US regulations require reporting releases of this material to the environment which exceed the
applicable reportable quantity or oil spills which could reach any waterway including intermittent dry creeks. The
National Response Center can be reached at (800)424-8802.
PROTECTIVE MEASURES
Avoid contact with spilled material. See Section 5 for fire fighting information. See the Hazard Identification
Section for Significant Hazards. See Section 4 for First Aid Advice. See Section 8 for advice on the minimum
requirements for personal protective equipment. Additional protective measures may be necessary, depending
on the specific circumstances and/or the expert judgment of the emergency responders.
For emergency responders: Respiratory protection: respiratory protection will be necessary only in special
cases, e.g., formation of mists. Half-face or full-face respirator with filter(s) for dust/organic vapor or Self
Contained Breathing Apparatus (SCBA) can be used depending on the size of spill and potential level of
exposure. If the exposure cannot be completely characterized or an oxygen deficient atmosphere is possible or
anticipated, SCBA is recommended. Work gloves that are resistant to hydrocarbons are recommended.
Gloves made of polyvinyl acetate (PVA) are not water-resistant and are not suitable for emergency use.
Chemical goggles are recommended if splashes or contact with eyes is possible. Small spills: normal antistatic
work clothes are usually adequate. Large spills: full body suit of chemical resistant, antistatic material is
recommended.
SPILL MANAGEMENT
Land Spill: Stop leak if you can do it without risk. Recover by pumping or with suitable absorbent.
Water Spill: Stop leak if you can do it without risk. Confine the spill immediately with booms. Warn other
shipping. Remove from the surface by skimming or with suitable absorbents. Seek the advice of a specialist
before using dispersants.
Water spill and land spill recommendations are based on the most likely spill scenario for this material; however,
geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction and
speed may greatly influence the appropriate action to be taken. For this reason, local experts should be
consulted. Note: Local regulations may prescribe or limit action to be taken.
ENVIRONMENTAL PRECAUTIONS
Large Spills: Dike far ahead of liquid spill for later recovery and disposal. Prevent entry into waterways,
sewers, basements or confined areas.
SECTION 7
HANDLING
Avoid all personal contact. Avoid contact with used product. Prevent small spills and leakage to avoid slip
hazard. Material can accumulate static charges which may cause an electrical spark (ignition source). When
the material is handled in bulk, an electrical spark could ignite any flammable vapors from liquids or residues
that may be present (e.g., during switch-loading operations). Use proper bonding and/or ground procedures.
However, bonding and grounds may not eliminate the hazard from static accumulation. Consult local applicable
standards for guidance. Additional references include American Petroleum Institute 2003 (Protection Against
Ignitions Arising out of Static, Lightning and Stray Currents) or National Fire Protection Agency 77
(Recommended Practice on Static Electricity) or CENELEC CLC/TR 50404 (Electrostatics - Code of practice for
the avoidance of hazards due to static electricity).
Static Accumulator: This material is a static accumulator.
STORAGE
Keep containers closed when not in use. The container choice, for example storage vessel, may effect static
accumulation and dissipation. Do not store in open or unlabelled containers. Store in a cool, dry place with
adequate ventilation. Keep away from incompatible materials, open flames, and high temperatures.
SECTION 8
Exposure limits/standards for materials that can be formed when handling this product: When mists/aerosols
can occur the following are recommended: 5 mg/m - ACGIH TLV (inhalable fraction), 5 mg/m - OSHA PEL.
NOTE: Limits/standards shown for guidance only. Follow applicable regulations.
No biological limits allocated.
ENGINEERING CONTROLS
The level of protection and types of controls necessary will vary depending upon potential exposure conditions.
Control measures to consider:
Adequate ventilation should be provided whenever the material is heated or mists are generated.
PERSONAL PROTECTION
Personal protective equipment selections vary based on potential exposure conditions such as applications,
handling practices, concentration and ventilation. Information on the selection of protective equipment for use
with this material, as provided below, is based upon intended, normal usage.
Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a
level which is adequate to protect worker health, an approved respirator may be appropriate. Respirator
selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of
respirators to be considered for this material include:
No special requirements under ordinary conditions of use and with adequate ventilation.
For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode.
Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate,
gas/vapor warning properties are poor, or if air purifying filter capacity/rating may be exceeded.
Hand Protection: Any specific glove information provided is based on published literature and glove
manufacturer data. Glove suitability and breakthrough time will differ depending on the specific use conditions.
Contact the glove manufacturer for specific advice on glove selection and breakthrough times for your use
conditions. Inspect and replace worn or damaged gloves. The types of gloves to be considered for this material
include:
Chemical resistant gloves are recommended. If contact with forearms is likely wear gauntlet style
gloves.
Eye Protection: If contact is likely, safety glasses with side shields are recommended.
Skin and Body Protection: Any specific clothing information provided is based on published literature or
manufacturer data. The types of clothing to be considered for this material include:
Chemical/oil resistant clothing is recommended.
Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after
handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective
equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned.
Note: Physical and chemical properties are provided for safety, health and environmental considerations only
and may not fully represent product specifications. Contact the Supplier for additional information.
GENERAL INFORMATION
Physical State: Liquid
Form: Clear
Color: Amber
Odor: Characteristic
Odor Threshold: N/D
IMPORTANT HEALTH, SAFETY, AND ENVIRONMENTAL INFORMATION
Relative Density (at 15 C): 0.88
Flammability (Solid, Gas): N/A
Flash Point [Method]: >250C (482F) [ASTM D-92]
Flammable Limits (Approximate volume % in air): LEL: 0.9 UEL: 7.0
Autoignition Temperature: N/D
Boiling Point / Range: > 158C (316F) [Estimated]
Decomposition Temperature: N/D
Vapor Density (Air = 1): N/D
Vapor Pressure: < 0.013 kPa (0.1 mm Hg) at 20 C [Estimated]
Evaporation Rate (n-butyl acetate = 1): N/D
pH: N/A
Log Pow (n-Octanol/Water Partition Coefficient): > 3.5 [Estimated]
Solubility in Water: Negligible
Viscosity: 182 cSt (182 mm2/sec) at 40 C | 20.3 cSt (20.3 mm2/sec) at 100C
Oxidizing Properties: See Hazards Identification Section.
OTHER INFORMATION
Freezing Point: N/D
Melting Point: N/A
Pour Point:
-33C (-27F)
DMSO Extract (mineral oil only), IP-346:
SECTION 10
< 3 %wt
TOXICOLOGICAL INFORMATION
Conclusion / Remarks
Inhalation
Acute Toxicity: No end point data for material.Minimally Toxic. Based on assessment of the components.
Irritation: No end point data for material.
Ingestion
Acute Toxicity: No end point data for material. Minimally Toxic. Based on assessment of the components.
Skin
Acute Toxicity: No end point data for material. Minimally Toxic. Based on assessment of the components.
Skin Corrosion/Irritation: No end point data for Negligible irritation to skin at ambient temperatures. Based on
material.
assessment of the components.
Eye
Serious Eye Damage/Irritation: No end point May cause mild, short-lasting discomfort to eyes. Based on
data for material.
assessment of the components.
Sensitization
Respiratory Sensitization: No end point data Not expected to be a respiratory sensitizer.
for material.
Skin Sensitization: No end point data for
material.
Germ Cell Mutagenicity: No end point data Not expected to be a germ cell mutagen. Based on assessment of
for material.
the components.
Carcinogenicity: No end point data for
material.
Reproductive Toxicity: No end point data for Contains a substance that may be a reproductive toxicant. Based on
material.
assessment of the components.
Lactation: No end point data for material.
OTHER INFORMATION
For the product itself:
Oils that are used in gasoline engines may become hazardous and display the following properties: Carcinogenic in
animal tests. Caused mutations in vitro. Possible allergen and photoallergen. Contains polycyclic aromatic compounds
(PAC) from combustion products of gasoline and/or thermal degradation products.
Contains:
Technical grade TCP (tricresylphosphate) may contain various aryl ortho-phosphate esters which after ingestion of high
doses has been reported to cause cholinesterase inhibition and delayed neurotoxic effects, in both animals and
humans, as well as reproductive effects in animals. These effects are predominately attributed to certain isomeric forms
(ie. ortho isomers) and current grades of TCP in this ExxonMobil product have very low levels of the ortho-isomers.
Neurotoxicity testing in hens, and reproductive toxicity tests in rodents of products with up to 3% TCP were without
effect. Tricresyl phosphate (TCP). TCP (<9% ortho isomer) administered to rats by oral gavage in a one-generation
reproduction/developmental toxicology study adversely affected both males and females. TCP-treated male rats had
decreased sperm concentration and motility, abnormal sperm morphology and adverse histologic changes in the testes
and epididymides. Adverse histologic changes were also observed in the ovaries of TCP-treated female rats. The
percent of sperm-positive females littering was significantly reduced in the TCP-treatment groups with only one of
twenty females in the high dose group delivering young . Developmental parameters were unaffected by TCP exposure.
Impaired fertility and decreased sperm motility following TCP treatment have also been reported in a reproduction
toxicity study in mice.
1 = NTP CARC
2 = NTP SUS
SECTION 12
ECOLOGICAL INFORMATION
The information given is based on data available for the material, the components of the material, and similar materials.
ECOTOXICITY
Material -- Not expected to be harmful to aquatic organisms.
MOBILITY
Base oil component -- Low solubility and floats and is expected to migrate from water to the land. Expected to
partition to sediment and wastewater solids.
PERSISTENCE AND DEGRADABILITY
Biodegradation:
Base oil component -- Expected to be inherently biodegradable
ECOLOGICAL DATA
Ecotoxicity
Test
Duration
Organism Type
Test Results
21 day(s)
Daphnia magna
SECTION 13
DISPOSAL CONSIDERATIONS
Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable
laws and regulations, and material characteristics at time of disposal.
DISPOSAL RECOMMENDATIONS
Dispose of waste at an appropriate treatment & disposal facility in accordance with applicable laws and
regulations, and product characteristics at time of disposal. Protect the environment. Dispose of used oil at
designated sites. Minimize skin contact. Do not mix used oils with solvents, brake fluids or coolants. Product is
suitable for burning in an enclosed, controlled burner for fuel value or disposal by supervised incineration.
REGULATORY DISPOSAL INFORMATION
RCRA Information: The unused product, in our opinion, is not specifically listed by the EPA as a hazardous
waste (40 CFR, Part 261D), nor is it formulated to contain materials which are listed as hazardous wastes. It
does not exhibit the hazardous characteristics of ignitability, corrositivity or reactivity and is not formulated with
contaminants as determined by the Toxicity Characteristic Leaching Procedure (TCLP). However, used product
may be regulated.
Empty Container Warning Empty Container Warning (where applicable): Empty containers may contain residue and
can be dangerous. Do not attempt to refill or clean containers without proper instructions. Empty drums should be
completely drained and safely stored until appropriately reconditioned or disposed. Empty containers should be taken
for recycling, recovery, or disposal through suitably qualified or licensed contractor and in accordance with
governmental regulations. DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE
SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION.
THEY MAY EXPLODE AND CAUSE INJURY OR DEATH.
SECTION 14
TRANSPORT INFORMATION
SECTION 15
REGULATORY INFORMATION
OSHA HAZARD COMMUNICATION STANDARD: This material is considered hazardous in accordance with OSHA
HazCom 2012, 29 CFR 1910.1200.
Listed or exempt from listing/notification on the following chemical inventories: AICS, DSL, ENCS, IECSC,
KECI, PICCS, TSCA
EPCRA SECTION 302: This material contains no extremely hazardous substances.
CAS Number
List Citations
DIPHENYLAMINE
122-39-4
18
TRICRESYL PHOSPHATE
1330-78-5
17
1 = ACGIH ALL
2 = ACGIH A1
3 = ACGIH A2
4 = OSHA Z
5 = TSCA 4
16 = MN RTK
17 = NJ RTK
18 = PA RTK
19 = RI RTK
OTHER INFORMATION
Revision Changes:
Section 01: Company Mailing Address information was modified.
Section 05: Hazardous Combustion Products information was modified.
Section 14: Marine Pollutant information was modified.
Section 12: Environmental tox table header information was added.
Section 12: Test - Column Header information was added.
Section 12: Organism Type - Column Header information was added.
Section 12: Duration - Column Header information was added.
Section 12: Test Results - Column Header information was added.
Section 12: Environmental tox table in section 12 information was added.
Section 12: Ecological data - Header information was added.
Section 15: Product Registration Status - Header information was deleted.
Section 15: Product Registration Status List information was deleted.
Section 16: Revision Information - Implementation of GHS requirements phrase. information was deleted.
----------------------------------------------------------------------------------------------------------------------------------------------------The information and recommendations contained herein are, to the best of ExxonMobil's knowledge and belief, accurate
and reliable as of the date issued. You can contact ExxonMobil to insure that this document is the most current
available from ExxonMobil. The information and recommendations are offered for the user's consideration and
examination. It is the user's responsibility to satisfy itself that the product is suitable for the intended use. If buyer
repackages this product, it is the user's responsibility to insure proper health, safety and other necessary information is
included with and/or on the container. Appropriate warnings and safe-handling procedures should be provided to
handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, republication or retransmission of this document, in whole or in part, is not permitted. The term, "ExxonMobil" is used for
convenience, and may include any one or more of ExxonMobil Chemical Company, Exxon Mobil Corporation, or any
affiliates in which they directly or indirectly hold any interest.
----------------------------------------------------------------------------------------------------------------------------------------------------Internal Use Only
MHC: 0, 0, 0, 0, 0, 0
PPEC: C