MATERIAL SAFETY DATA SHEET- EXXSOL D95

SECTION 1 PRODUCT AND COMPANY IDENTIFICATION

PRODUCT
Product Name : EXXSOL D95 FLUID
Product Description : Dearomatised Hydrocarbons
Recommended Use : Solvent

COMPANY IDENTIFICATION
Supplier : PON PURE CHEMICALS GROUP
CHENNAI, TAMILNADU, INDIA
24 Hour Health Emergency (91) 8939878447
(91) 9444038694
Transportation Emergency (91) 9444038517
Phone

Company Name Place EMERGENCY TELEPHONE NUMBER

Pon Pure Chemicals Group CHENNAI Day Emergency – 044-26161803-26161809
This (M)SDS is a generic document with no country specific information included.

SECTION 2 HAZARDS IDENTIFICATION

This material is hazardous according to regulatory guidelines (see (M)SDS Section 15).

CLASSIFICATION:
Aspiration toxicant: Category 1.

LABEL:
Symbol:

Signal Word: Danger

Hazard Statements:

Health: H304: May be fatal if swallowed and enters airways.

Precautionary Statements:

Prevention: P210: Keep away from flames and hot surfaces. -- No smoking. P280: Wear protective
gloves and eye / face protection.
Response: P301 + P310: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P331: Do NOT induce vomiting. P370 + P378: In case of fire: Use water fog, foam, dry chemical or
carbon dioxide (CO2) for extinction.
Storage: P403 + P235: Store in a well-ventilated place. Keep cool. P405: Store locked up.
Disposal: P501: Dispose of contents and container in accordance with local regulations.
Contains: DISTILLATES (PETROLEUM), HYDROTREATED LIGHT

Other hazard information:

PHYSICAL / CHEMICAL HAZARDS
Material can accumulate static charges which may cause an ignition. Material can release vapours that
readily form flammable mixtures. Vapour accumulation could flash and/or explode if ignited.
Combustible.

HEALTH HAZARDS
May be irritating to the eyes, nose, throat, and lungs. Repeated exposure may cause skin dryness or
cracking.

ENVIRONMENTAL HAZARDS
No significant hazards.

NOTE: This material should not be used for any other purpose than the intended use in Section 1
without expert advice. Health studies have shown that chemical exposure may cause potential human
health risks which may vary from person to person.

SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS

This material is defined as a substance.

Hazardous Substance(s) or Complex Substance(s) required for disclosure

Name CAS# oncentration* GHS Hazard
Codes
DISTILLATES (PETROLEUM), HYDROTREATED 64742-47-8 100 % H227, H304
LIGHT

* All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are in percent
by volume.

SECTION 4 FIRST AID MEASURES

INHALATION
Remove from further exposure. For those providing assistance, avoid exposure to yourself or
others. Use adequate respiratory protection. If respiratory irritation, dizziness, nausea, or
unconsciousness occurs, seek immediate medical assistance. If breathing has stopped, assist
ventilation with a mechanical device or use mouth-to-mouth resuscitation.

SKIN CONTACT
Wash contact areas with soap and water. Remove contaminated clothing. Launder contaminated
clothing before reuse.

EYE CONTACT
Flush thoroughly with water. If irritation occurs, get medical assistance.
INGESTION
Seek immediate medical attention. Do not induce vomiting.

NOTE TO PHYSICIAN
If ingested, material may be aspirated into the lungs and cause chemical pneumonitis. Treat
appropriately.

SECTION 5 FIRE FIGHTING MEASURES

EXTINGUISHING MEDIA
Appropriate Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2)
to extinguish flames.
Inappropriate Extinguishing Media: Straight streams of water

FIRE FIGHTING
Fire Fighting Instructions: Evacuate area. Prevent run-off from fire control or dilution from
entering streams, sewers or drinking water supply. Fire-fighters should use standard protective
equipment and in enclosed spaces, self-contained breathing apparatus (SCBA). Use water spray
to cool fire exposed surfaces and to protect personnel.

Unusual Fire Hazards: Combustible. Hazardous material. Firefighters should consider

protective equipment indicated in Section 8.

Hazardous Combustion Products: Smoke, Fume, Incomplete combustion products, Oxides of

carbon

FLAMMABILITY PROPERTIES
Flash Point [Method] : 88°C (190°F) [ASTM D-93]
Flammable Limits (Approximate volume % in air): LEL: 0.6 UEL: 7 [Approximate]
Auto ignition Temperature : >200°C (392°F)

SECTION 6 ACCIDENTAL RELEASE MEASURES

NOTIFICATION PROCEDURES
In the event of a spill or accidental release, notify relevant authorities in accordance with all
applicable regulations.

PROTECTIVE MEASURES
Avoid contact with spilled material. Warn or evacuate occupants in surrounding and downwind
areas if required, due to toxicity or flammability of the material. See Section 5 for fire fighting
information. See the Hazard Identification Section for Significant Hazards. See Section 4 for
First Aid Advice. See Section 8 for advice on the minimum requirements for personal protective
equipment. Additional protective measures may be necessary, depending on the specific
circumstances and/or the expert judgment of the emergency responders. For emergency
responders: Respiratory protection: half-face or full-face respirator with filter(s) for organic
vapor and, when applicable, H2S, or Self Contained Breathing Apparatus (SCBA) can be used
depending on the size of spill and potential level of exposure. If the exposure cannot be
completely characterized or an oxygen deficient atmosphere is possible or anticipated, SCBA is
recommended. Work gloves that are resistant to aromatic hydrocarbons are recommended.
Note: gloves made of polyvinyl acetate (PVA) are not water-resistant and are not suitable for
emergency use. Chemical goggles are recommended if splashes or contact with eyes is possible.
 Small spills: normal antistatic work clothes are usually adequate. Large spills: full body suit of
chemical resistant, antistatic material is recommended.

SPILL MANAGEMENT
Land Spill: Stop leak if you can do so without risk. Recover by pumping or with suitable
absorbent.

Water Spill: Stop leak if you can do so without risk. Warn other shipping. Remove from the
surface by skimming or with suitable absorbents. Seek the advice of a specialist before using
dispersants.

Water spill and land spill recommendations are based on the most likely spill scenario for this
material; however, geographic conditions, wind, temperature, (and in the case of a water spill)
wave and current direction and speed may greatly influence the appropriate action to be taken.
For this reason, local experts should be consulted. Note: Local regulations may prescribe or limit
action to be taken.

ENVIRONMENTAL PRECAUTIONS
Large Spills: Dyke far ahead of liquid spill for later recovery and disposal. Prevent entry into
waterways, sewers, basements or confined areas.

SECTION 7 HANDLING AND STORAGE

HANDLING
Avoid contact with skin. Prevent small spills and leakage to avoid slip hazard. Material can
accumulate static charges which may cause an electrical spark (ignition source). When the
material is handled in bulk, an electrical spark could ignite any flammable vapors from liquids or
residues that may be present (e.g., during switch-loading operations). Use proper bonding
and/or earthing procedures. However, bonding and earthing may not eliminate the hazard from
static accumulation. Consult local applicable standards for guidance. Additional references
include American Petroleum Institute 2003 (Protection against Ignitions Arising out of Static,
Lightning and Stray Currents) or National Fire Protection Agency 77 (Recommended Practice on
Static Electricity) or CENELEC CLC/TR 50404 (Electrostatics - Code of practice for the avoidance
of hazards due to static electricity).

Transport Temperature: [Ambient]

Static Accumulator: This material is a static accumulator. A liquid is typically considered a
nonconductive, static accumulator if its conductivity is below 100 pS/m (100x10E-12 Siemens
per meter) and is considered a semi conductive, static accumulator if its conductivity is below
10,000 pS/m. Whether a liquid is nonconductive or semi conductive, the precautions are the
same. A number of factors, for example liquid temperature, presence of contaminants, anti-
static additives and filtration can greatly influence the conductivity of a liquid.

STORAGE
The container choice, for example storage vessel, may effect static accumulation and dissipation.
Keep container closed. Handle containers with care. Open slowly in order to control possible
pressure release. Store in a cool, well-ventilated area. Storage containers should be earthed
and bonded. Fixed storage containers, transfer containers and associated equipment should be
earthed and bonded to prevent accumulation of static charge.
Storage Temperature : [Ambient]
Storage Pressure : [Ambient]
 Suitable Containers/Packing: Barges; Drums; Tank Trucks; Railcars
Suitable Materials and Coatings (Chemical Compatibility): Carbon Steel; Stainless Steel;
Polyester; Polyethylene; Polypropylene; Teflon
Unsuitable Materials and Coatings: Natural Rubber; Butyl Rubber; Ethylene-proplyene-diene
monomer (EPDM); Polystyrene

SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION

EXPOSURE LIMIT VALUES

Exposure limits/standards (Note: Exposure limits are not additive)

Substance Name Form Limit/Standard Note Source Year

DISTILLATES (PETROLEUM), Vapour RCP - 1200 164 ppm Total ExxonMobi 2009
HYDROTREATED LIGHT TWA mg/m3 Hydrocar l
bons

NOTE: Limits/standards shown for guidance only. Follow applicable regulations.

ENGINEERING CONTROLS

The level of protection and types of controls necessary will vary depending upon potential exposure
conditions. Control measures to consider:
Adequate ventilation should be provided so that exposure limits are not exceeded. Use explosion-proof
ventilation equipment.

PERSONAL PROTECTION

Personal protective equipment selections vary based on potential exposure conditions such as
applications, handling practices, concentration and ventilation. Information on the selection of
protective equipment for use with this material, as provided below, is based upon intended,
normal usage.

Respiratory Protection: If engineering controls do not maintain airborne contaminant

concentrations at a level which is adequate to protect worker health, an approved respirator may
be appropriate. Respirator selection, use, and maintenance must be in accordance with
regulatory requirements, if applicable. Types of respirators to be considered for this material
include:
Half-face filter respirator Type A filter material.

For high airborne concentrations, use an approved supplied-air respirator, operated in positive
pressure mode. Supplied air respirators with an escape bottle may be appropriate when oxygen
levels are inadequate, gas/vapour warning properties are poor, or if air purifying filter
capacity/rating may be exceeded.

Hand Protection: Any specific glove information provided is based on published literature and
glove manufacturer data. Glove suitability and breakthrough time will differ depending on the
specific use conditions. Contact the glove manufacturer for specific advice on glove selection and
breakthrough times for your use conditions. Inspect and replace worn or damaged gloves. The
types of gloves to be considered for this material include:
 If prolonged or repeated contact is likely, chemical-resistant gloves are recommended. If
contact with forearms is likely, wear gauntlet-style gloves. Nitrile

Eye Protection: If contact is likely, safety glasses with side shields are recommended.

Skin and Body Protection: Any specific clothing information provided is based on published
literature or manufacturer data. The types of clothing to be considered for this material include:
If prolonged or repeated contact is likely, chemical, and oil resistant clothing is recommended.
Specific Hygiene Measures: Always observe good personal hygiene measures, such as
washing after handling the material and before eating, drinking, and/or smoking. Routinely wash
work clothing and protective equipment to remove contaminants. Discard contaminated clothing
and footwear that cannot be cleaned. Practice good housekeeping.

ENVIRONMENTAL CONTROLS
Comply with applicable environmental regulations limiting discharge to air, water and
soil. Protect the environment by applying appropriate control measures to prevent or limit
emissions.

SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES

Note: Physical and chemical properties are provided for safety, health and environmental
considerations only and may not fully represent product specifications. Contact the Supplier
for additional information.

GENERAL INFORMATION
Physical State : Liquid
Form : Clear
Colour : Colourless
Odour : Mild Petroleum/Solvent
Odour Threshold : N/D

IMPORTANT HEALTH, SAFETY, AND ENVIRONMENTAL INFORMATION

Relative Density (at 15 °C):0.808
Density (at 15 ºC) : 807 kg/m³ (6.73 lbs/gal, 0.81 kg/dm³)
Flammability (Solid, Gas) : N/A
Flash Point [Method] : 88°C (190°F) [ASTM D-93]
Flammable Limits (Approximate volume % in air): LEL: 0.6 UEL: 7 [Approximate]
Autoignition Temperature: >200°C (392°F)
Boiling Point / Range : 220°C (428°F) - 236°C (457°F)
Decomposition Temperature: N/D
Vapour Density (Air = 1) : > 1 at 101 kPa
Vapour Pressure : 0.011 kPa (0.08 mm Hg) at 20 °C | 0.03 kPa (0.23 mm Hg) at
38C | 0.06 kPa (0.45 mm Hg) at 50C
Evaporation Rate (n-butyl acetate = 1): < 0.01
pH : N/A
Log Pow (n-Octanol/Water Partition Coefficient): N/D
Solubility in Water : Negligible
Viscosity : 1.83 CST (1.83 mm2/sec) at 40ºC | 2.44 cSt (2.44 mm2/sec) at
25C
Oxidizing Properties : See Hazards Identification Section.
OTHER INFORMATION
Freezing Point : <-20°C (-4°F)
Melting Point : N/D
Molecular Weight : 179 [Calculated]
Hygroscopic : No
Coefficient of Thermal Expansion: 0.00092 V/V/DEG C

SECTION 10 STABILITY AND REACTIVITY

STABILITY : Material is stable under normal conditions.

CONDITIONS TO AVOID : Avoid heat, sparks, open flames and other ignition sources.
MATERIALS TO AVOID : Strong oxidisers
HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures.
POSSIBILITY OF HAZARDOUS REACTIONS: Hazardous polymerization will not occur.

SECTION 11 TOXICOLOGICAL INFORMATION

ACUTE TOXICITY
Route of Exposure Conclusion / Remarks
Inhalation
Toxicity: Data available. Minimally Toxic. Based on test data for structurally similar
materials.
Irritation: Data available. Negligible hazard at ambient/normal handling
temperatures. Based on test data for structurally similar
materials.

Ingestion
Toxicity: LD50 > 15000 mg/kg Minimally Toxic. Based on test data for structurally similar
materials.

Skin
Toxicity: LD50 > 3160 mg/kg Minimally Toxic. Based on test data for structurally similar
materials.
Irritation: Data available. May dry the skin leading to discomfort and dermatitis.
Based on test data for structurally similar materials.

Eye
Irritation: Data available. May cause mild, short-lasting discomfort to eyes. Based
on test data for structurally similar materials.
OTHER HEALTH EFFECTS FROM SHORT AND LONG TERM EXPOSURE
Anticipated health effects from sub-chronic, chronic, respiratory or skin sensitization, mutagenicity,
reproductive toxicity, carcinogenicity, target organ toxicity (single exposure or repeated exposure),
aspiration toxicity and other effects based on human experience and/or experimental data.

For the product itself:

Vapour concentrations above recommended exposure levels are irritating to the eyes and the respiratory
tract, may cause headaches and dizziness, are anesthetic and may have other central nervous system
effects. Prolonged and/or repeated skin contact with low viscosity materials may defat the skin resulting
in possible irritation and dermatitis. Small amounts of liquid aspirated into the lungs during ingestion or
from vomiting may cause chemical pneumonitis or pulmonary edema.
Additional information is available by request.

IARC Classification:
The following ingredients are cited on the lists below: None.

--REGULATORY LISTS SEARCHED--

1 = IARC 1 2 = IARC 2A 3 = IARC 2B

SECTION 12 ECOLOGICAL INFORMATION

The information given is based on data available for the material, the components of the material, and
similar materials.

ECOTOXICITY
Material -- Not expected to be harmful to aquatic organisms.
Material -- Not expected to demonstrate chronic toxicity to aquatic organisms

PERSISTENCE AND DEGRADABILITY

Biodegradation:
Material -- Expected to be readily biodegradable.
Hydrolysis:
Material -- Transformation due to hydrolysis not expected to be significant.
Photolysis:
Material -- Transformation due to photolysis not expected to be significant.
Atmospheric Oxidation:
Material -- Expected to degrade rapidly in air
OTHER ECOLOGICAL INFORMATION
VOC: Yes

SECTION 13 DISPOSAL CONSIDERATIONS

Disposal recommendations based on material as supplied. Disposal must be in accordance with current
applicable laws and regulations, and material characteristics at time of disposal.

DISPOSAL RECOMMENDATIONS
Product is suitable for burning in an enclosed controlled burner for fuel value or disposal by supervised
incineration at very high temperatures to prevent formation of undesirable combustion products.

Empty Container Warning Empty Container Warning (where applicable): Empty containers may
contain residue and can be dangerous. Do not attempt to refill or clean containers without proper
instructions. Empty drums should be completely drained and safely stored until appropriately
reconditioned or disposed. Empty containers should be taken for recycling, recovery, or disposal
through suitably qualified or licensed contractor and in accordance with governmental regulations. DO
NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO
HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION. THEY MAY EXPLODE
AND CAUSE INJURY OR DEATH.

SECTION 14 TRANSPORT INFORMATION

LAND : Not Regulated for Land Transport

SEA (IMDG): Not Regulated for Sea Transport according to IMDG-Code
Marine Pollutant: No

SEA (MARPOL 73/78 Convention - Annex II)

Product Name : NOXIOUS LIQUID, N.F.,(9) N.O.S., (Exxsol D95, contains Iso-and
cycloalkanes (C12+))
Ship type : 3
Pollution category : Z

AIR (IATA): Not Regulated for Air Transport

SECTION 15 REGULATORY INFORMATION

Material is hazardous as defined by Specification for Hazardous communication for hazardous
chemicals and dangerous goods (Singapore Standard SS586) Part 2:2008 - Globally
harmonised system of classification and labelling of chemicals - Singapore's adaptation.

REGULATORY STATUS AND APPLICABLE LAWS AND REGULATIONS

Complies with the following national/regional chemical inventory requirements: AICS, TSCA,
IECSC, KECI, PICCS, ENCS, DSL
Workplace Safety and Health Act & Workplace Safety and Health (General Provisions) Regulations

SECTION 16 OTHER INFORMATION

N/D = Not determined, N/A = Not applicable

KEY TO THE H-CODES CONTAINED IN SECTION 3 OF THIS DOCUMENT (for information only):
H227: Combustible liquid; Flammable Liquid, Cat 4
H304: May be fatal if swallowed and enters airways; Aspiration, Cat 1

THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS:

Updates made in accordance with implementation of GHS requirements.

The information and recommendations contained herein are, to the best of Pon Pure Chemicals Group
knowledge and belief, accurate and reliable as of the date issued. You can contact Pon Pure
Chemicals Group to insure that this document is the most current available from Pon Pure Chemicals
Group. The information and recommendations are offered for the user's consideration and examination.
It is the user's responsibility to satisfy itself that the product is suitable for the intended use. If buyer
repackages this product, it is the user's responsibility to insure proper health, safety and other
necessary information is included with and/or on the container. Appropriate warnings and safe-handling
procedures should be provided to handlers and users. Alteration of this document is strictly prohibited.
Except to the extent required by law, re-publication or retransmission of this document, in whole or in
part, is not permitted.