1

SOLUTIONS OF JEE MAIN 2016 (CODE H)

PHYSICS
1.

(2) We know that V =

Initially

V=

Finally

w A2

3v =

A2 - x 2

2A
-

w A' 2

2A
-

2A
A' 2 -

3
2A
A2 -

(2, 4)We know that a =

a V
a
V

X
a
R
2
In none of the cases, the perpendicular

2A
, velocity
3

- a
distance r^ is

6.

2 4A 2
4A 2
9 A - 9 = A'2

9
2.

to trebled)

3
=
1

a
A

R/ 2

Where A'= final amplitude (Given at x =

On dividing we get

V
a

(3) In amplitude modulation, the amplitude of the high

frequency carrier wave made to vary in proportional to
the amplitude of audio signal.

Audio signal

7A
\ A' =
3

Carrier wave

Ic
Ic
and b =
Ib
Ie

Amplitude modulated wave

Also Ie = Ib + Ic
Ic
Ib
Ic
b
\ a=
=
=
I
I b + Ic
1+ b
1+ c
Ib

7.

Option (2) and (4) are therefore correct.

3.

(3)

5.

4
1
hn 0 - hn 0 = mv ' 2
3
2

4
n - n0
3
\
=
n - n0
v2

4.

1
mv2
2

v '2

| DT1 | + | DT2 | + | DT3 | + | DT4 |

DT =
4

2 +1+ 3 + 0
= 1.5
4
As the resolution of measuring clock is 1.5 therefore
the mean time should be 92 1.5
(1) In case of an 'OR' gate the input is zero when all inputs
are zero. If any one input is ' 1', then the output is '1'.

(3) hn02 hn0 =

\ v' >

8.

4
n - n0
\ v' = v 3
n - n0

4
3

(2) Case (a) :

(1) We know that L = mvr^

bA =
=

0 I

I
2p = 0
2p
4p R
4p l / 2p

0 I
(2p) 2
4p l

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(2pR = l)

2
Case (b) :

11.

a/2

= 4
9.

0
I
I
2

= 0 32 2
4p l / 8
2 4p l

(b)

v
u
f ' = 4(l / 2) = 2l = f

Q a
b
\ E 4pr2 =

Gaussiam
surface

Q + 4par 2 - 4pAa 2
0

dr
dv

1
4p 0

[Q R =

V 80
=
= 8]
I 10

dr =4pA [r2 a2]

Q - 4pAa 2

+ 4pA

2
r

For E to be independent of 'r'

Q 4pAa2 = 0

Q
4pa 2

q
Vo

2Vo

- P0
P = V V + 3P
0
-P0
, c = 3P0]
V0

PV0 + P0V = 3P0V0

pv = nRT
nRT
v

...(i)

...(ii)

nRT
V0 + P0V = 3P0V0
v
\ nRT V0 + P0V2 = 3P0V0
...(iii)

From (i) & (ii)

dT
=0
dv
Differentiating e.q. (iii) by 'v' we get

For temperature to be maximum

nRV0

\ A=

Po

Vo

\p=

Q = r4pr2

E=

R + 4 p2 v 2 L2

But

r dr

R +w L

e
2

S E. ds = 0

r 4pr

2 2

[4a = l]

[slope =

(3) Applying Gauss's law

Q=

e
2

64 + 4p (50) L

Po

v
The fundamental frequency in case (a) is f =
2l
The fundamental frequency in case (b) is

2Po

(a)

r=

220

uur uur

+ X 2L

3Po

10.

12.

On solving we get
L = 0.065 H
(3) The equation for the line is

(2)

10 =

0 I
[sin 45 + sin 45]
4p a / 2

BB = 4

i=

45
BB

(2) Here

dT
+ P0(2v) = 3P0V0
dv

\ nRV0

dT
= 3P0V0 2 P0V
dv

dT 3P0 V0 - 2P0 V
=0
=
nRV0
dv

V=

3V0
2

\ Tmax =

\ p=

3P0
2

9Po Vo
[From (iii)]
4nR

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[From (i)]

3
13. (2) n =

W
mgh 1000 10 9.8 1 1000
=
=
input
input
input

Input =

98000
= 49 104J
0.2
49 10 4

Fat used =

3.8 107

= N0 -

--- (i)

2
]
PQ

[sin 30 =

Also work done P Q = work done Q R

\Required ratio =

15. (1)

22

1
16 15 4 5
=
1 =
16 3 4
14

1-

C1 = 4F

9F

1
= 0.29
2 1.732

24
No =

3F

20. (1) 4F

12F = CP

2F

From (i) 2 = 2 3 m + 2 3 m = 4 3 m

4 3

No -

No

19. (3) Graph (a) is for a simple diode.

Graph (b) is showing the V Break down used for zener
diode.
Graph (c) is for solar cell which shows cut-off voltage
and open circuit current.
Graph (d) shows the variation of resistance h and
hence current with intensity of light.

\ 2 3 m = mx
\ x 3.5m

m=

. Therefore nuclei decayed

22
No -

2
3

+ mx
sin 30
2

2 = 2 3 m + mx

22

No

= 12.89 103kg.

14. (1) Loss in P.E. = Work done against friction from p Q

+ work done against friction from Q R
mgh = m(mgcosq) PQ + mmg (QR)
h = m cos q PQ + m(QR)
2= m

No

\ Nuclei remaining =

8v

8v

12

Charge on C1 is q1 =
8 4 = 24mc

4 + 12

4
8 = 2v
4 + 12
\ Voltage across 9mF is also 2V
\ Charge on 9mF capacitor = 9 2 = 18mC
\ Total charge on 4 mF and 9mF = 42mc

The voltage across CP is VP =

T
T
Sami conductor
Metal (for limited
Eg
K T
range of temperature)
B

E, Z Decreases

16. (3)

g-rays X-rays uv-rays Visible rays IR rays

Radio
VIBGYOR Microwaves waves

Radio wave < yellow light < blue light < X-rays
(Increasing order of energy)
17. (3) Ig G = ( I Ig)s
\ 103 100 = (10 103) S
\ S 0.01 W
18. (2) For At = 20 min, t = 80 min, number of half lifes n = 4
\ Nuclei remaining =
= N0 -

No
24

. Therefore nuclei decayed

No

24
For Bt = 40 min., t = 80 min, number of half lifes n = 2

\E =

KQ
r2

= 9 109

42 10-6
= 420 Nc1
30 30

21. (2) For h << R, the orbital velocity is

Escape velocity =

gR

2gR

\ The minimum increase in its orbital velocity

=

2gR

gR =

gR ( 2 1)

0.5
= 0.01 mm
50
Zero error = 5 0.01 = 0.05 mm (Negative)
Reading = (0.5 + 25 0.01) + 0.05 = 0.80 mm

22. (4) L.C. =

23. (3) As shown in the diagram, the normal reaction of AB on

roller will shift towards O.
This will lead to tending of the system of cones to turn
left.

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\ n=

C - Cv - R C - C v - Cp + Cv
=
C - Cv
C - Cv

24.

25.

C
(2) Graph [A] is for material used for making permanent
magnets (high coercivity)
Graph [B] is for making electromagnets and
transformers.
(1) Given geometrical spread = a

(2) A telescope magnifies by making the object appearing

closer.

29.

(3) We know that i + e - A = d

35 + 79 A = 40
\ A = 74
A + dm
74 + d m
sin
sin

2
2

But m =
74
sinA / 2
sin
2
d
5
= sin 37 + m
3
2

lL
The sum b = a +
a
d
lL
a +
=0
da
a

db
=0
For b to be minimum
da

m max can be

b min =

lL + lL = 2 lL = 4lL
(1) We know that velocity in string is given by

T
v=
m

...(I)

m<

30.

m
xg
l

From (1) and (2)

x -1/2 dx = g dt

\ 1- n =

R
1- n
R
C - Cv

.... (i)

1
4 = a (q 20) 86400
2

....(ii)

MATHEMATICS

\ x -1/2dx - g dt

l
20
=2
=2 2
g
10

\ C - Cv =
\ 1-

40 q
q 20

3q 60 = 40 q
4q = 100 q = 25C

(4) For a polytropic process

C = Cv +

1
Dq 86400 second
2

1
12 = a (40 q) 86400
2

On dividing we get, 3 =
T

2 l = gt \ t = 2
27.

..(II)

dx
= gx
dt

5
5
sin 57 < sin 60 m = 1.45
3
3

(3) Time lost/gained per day =

m mass of string
where m = =
l length of string
The tension T =

5
5
. That is m max is less than = 1.67
3
3

But dm will be less than 40 so

a = lL
26.

(Q C p - Cv = R )

C - Cv

28.

l
lL
L=
a
a

Diffraction spread =

C - Cp

R
1- n

R
=n
C - Cv

A (2, 2)

31.

(4)

(2, 2)

Points of intersection of the two curves are (0, 0), (2, 2)

and (2, 2)
Area = Area (OAB) area under parabola (0 to 2)

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5
2

p (2) 2
- 2 x dx
4

8
3

=p-

32. (1)

1
f (x) + 2f = 3x
x
1
3
f ( ) + 2f (x) =
x
x

.......(1)
.......(2)

1
1
Adding (1) and (2) f (x) + f = x +
x
x

1 3
Substracting (1) from (2) f (x) - f = - 3x
x x
On adding the above equations
2
f (x) = - x
x

33. (4)

x10
2( x5 +x3 +1) 2

(x 5 + x3 + 1)3

35

+C

(2)

2
-2
2
-x=
+xx =
x
x
x

6
k
P(h, k)
k

dx

X'

Dividing by x15 in

numerator and denominator

For the given circle,
centre : (4, 4)
radius = 6

+ 6 dx
1 x 1 3
1 + 2 + 5
x
x
x3

6+ k =

2 5

dx = dt

x 3 x 6
2 5

3+ 6
dx = - dt
x
x

This gives,
2

5
+ 6 dx
dt
x 1 x 1 3 = t3

1 + 2 + 5
x
x
3

1
2t 2

+C

(h - 4)

+ (k - 4) 2

(h 4)2 = 20k + 20
\ locus of (h, k) is
(x 4)2 = 20(y + 1),
which is a parabola.

1
1
Substitute 1+ 2 + 5 = t
x
x

+C

34. (4) g (x) = f (f (x))

In the neighbourhood of x = 0,
f(x) = | log2 sin x| = (log 2 sin x)
\ g (x) = |log 2 sin| log 2 sin x ||
= (log 2 sin(log 2 sin x))
\ g (x) is differentiable
and g'(x) = cos(log 2 sin x) ( cos x)
g'(0) = cos (log 2)

or x = 2, - 2 .

2x12 + 5x9

1 1 2
2 1+ +
x 2 x5

C(4, 4)

f (x) = f (- x)
x2 = 2

36. (3)

(x 2 - 5x + 5) x

+ 4x - 60

=1

Case I
x2 5x + 5 = 1 and x2 + 4x 60 can be any real number
x = 1, 4
Case II
x2 5x + 5 = 1 and x2 + 4x 60 has to be an even
number
x = 2, 3
where 3 is rejected because for x = 3, x2 + 4x 60 is odd.
Case III
x2 5x + 5 can be any real number and x2 + 4x 60 = 0
x = 10, 6
Sum of all values of x = 10 + 6 + 2 + 1 + 4 = 3

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6
37.

(4) Let the GP be a, ar and ar 2 then a = A + d; ar = A + 4d;

ar2 = A + 8d

r=

38.

(1)

Slope of normal =

ar 2 - ar (A + 8d)-(A + 4d)
=
ar - a (A + 4d)-(A + d)

p p p
At , +
6 4 12

4
3

2b 2
=8
a

and 2b =

p
p p

y + = 2 x
4 12

1
(2ae)
2

4p
2p
= 2 x +
12
6

p
p
= 2 x +
3
3

4b2 = a 2 e2 4a 2 (e 2 - 1) = a 2e 2

3e2 = 4 e =
39.

(2)

2
3

y = 2 x +

Total number of terms = n+2C2 = 28

(n + 2) (n + 1) = 56
x= 6
Sum of coefficients = (1 2 + 4)n = 36 = 729
40.

(1)

42.

{(p q) T} (: p q)

(n + 1)(n + 2)...3n n

(4) y = lim

n
n 2n

1 1 2 2n
ln
1 +
1 + n
....
1 +

n n n
n

(p q) (: p q)

ln y = lim

{(p q) : p} (p q q)
T (p q)

41.

(4)

2p
3

2p
This equation is satisfied only by the point 0,
3

(p : q) q (: p q)
{(p q) (: q q)} (: p q)

1
= 2
dy

dx

2
2n
1 1
ln 1 + + ln 1 + + .... + ln 1 +
n
n n
n
n

pq

ln y = lim

1 + sin x
f ( x) = tan 1
1 sin x

= lim

1 2n r
ln 1 + n
n n r =1
2

1
= tan

=0 ln(1+ x)dx

2
x
x

sin + cos
2
2
2
x
x

sin cos
2
x

Let 1 + x = t dx = dt
when x = 0, t = 1
x = 2, t = 3
33
27
3
3
ln y =1 ln t d t = [t ln t t]1 = ln = ln
e2
e2

1 + tan

2
= tan 1
x
1 tan

y=

p x
= tan 1 tan +
4 2

y=

p x
+
4 2

dy 1

=
dx 2

27
e2
(3, 2)

43.

(4) B

5 2

A
(2, 3)

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7
Centre of S : O (3, 2) centre of given circle A(2, 3)
OA = 5 2
Also AB = 5 ( Q AB = r of the given circle)
Using pythagoras theorem in DOAB

49. (2) ALLMS

No. of words starting with

4!
= 12
2!
_ _ _ _ _ 4! = 24
L : L

_____
A: A

r=5 3
44. (2) P(E1) =

1
1
1
; P(E 2 ) = ; P(E 3 ) =
6
6
2

_____
M: M

1
1
1
, P(E2 E3 ) = , P(E1 E3 ) =
36
12
12
And P(E1 E2 E 3) = 0 P (E1) . P(E2) . P(E3)
E1, E2, E3 are not independent.
45. (2) Rationalizing the given expression

_A
_____
S : S

P(E1 E 2 ) =

(2 + 3isin q)(1 + 2isin q)

1 + 4sin 2 q
For the given expression to be purely imaginary, real
part of the above expression should be equal to zero.

2 - 6 sin 2 q
2

1 + 4 sin q

sin q =

46. (4)

=0

sin 2 q =

16 11(11 + 1)(22 + 1)

- 1

25
6

16
16
m = 101
5
5

m = 101.
47. (2) For trivial solution,

1 l -1
l - 1 -1 = 0
1

2 + 3 + a + 11 a
= +4
4
4

x=

x i2
n-x

()

s=

3.5=

16
16
= 505 = 101
25
5

50. (4)

SMALL 58th word

16 2 2 2
S=
2 + 3 + 4 + ... + 112
25

-l

51.

48. (2) Line lies in the plane (3, 2, 4) lie in the plane
3l 2m + 4 = 9 or 3l 2m = 5 ..... (1)
Also, l, m,1 are dr's of line perpendicular to plane and
2, 1, 3 are dr's of line lying in the plane
2l m 3 = 0 or 2l m = 3 .....(2)
Solving (1) and (2) we get l = 1 and m = 1
l2 + m2 = 2.

2
4 + 9 + a 2 +121 a

-
+
4

4
4

49 4(134 + a 2 ) - (a 2 + 256 + 32a)

=
4
16

3a 2 - 32a + 84 = 0
(1) 4x + 2pr = 2 2x + pr = 1
S = x2 + pr2
2

1 - pr
2
S =
+ pr
2
dS
1 - pr -p
= 2
+ 2pr
dr
2 2

-p p2 r
+
+ 2pr = 0
2
2

x=

2
p+ 4

52. (1) ln P = lim+

x 0

r=

1
p+ 4

x = 2r

1
ln (1 + tan 2 x )
2x

1
ln sec x
x 0 x
Applying L hospital's rule :
lim

-ll+
( 1)(l- 1) = 0
l= 0, +1, 1

3!
=3
2!

: S_ L_ _ _ _ 3! = 6

1
3

8 2 12 2 16 2 20 2
44 2

+

+ + ... +

5 5 5 5
5

4!
= 12
2!

= lim

x 0+

= lim

x 0+

sec x tan x
sec x 2 x
tan x
2 x

1
2

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8
53.

(3) Minimum distance perpendicular distance

Eqn of normal at p(2t2, 4t)
y = tx + 4t + 2t3
It passes through C(0, 6)
t3 + 2t + 3 = 0
t =1

57.

(2)

h
x+a
1
h

=
3h = x + a
3 x +a
h
h
tan 60 = 3 =
a
a

...(1)

h = 3a

...(2)

tan 30 =

From (1) and (2)

3a = x + a x = 2a

30
x

60
a

Here, the speed is uniform

2

P (2t , 4t)

So, time taken to cover x = 2 (time taken to cover a)

\ Time taken to cover a =

58.

(4)

P(1, 5, 9)

x=y=z

Q
O

On comparing both sides

r r
3
3
a b = cosq= 2
2
r
r
[Q a and b are unit vectors]

eqn of PO :

(4) A(adj A) = A AT

distance OP = = 10 3.

adj A = AT
2 b 5a 3
=

-3 5a - b 2
2
a = and b = 3
5
5a + b = 5

59.

(1)

x y +1= 0

5=0

A1A (adj A) = A1A AT

O (1,2)

7x y

56.

5p
6

q=

x -1 y + 5 z - 9
=
=
=l
1
1
1

x =l+ 1; y =l- 5;z =l+ 9.

Putting these in eqn of plane :l+ 1 -l+ 5 +l+ 9 = 5
l= -10
O is (9, 15, 1)

r
r
where q is the angle between a and b

+m=

55.

(2) y (1 + xy)dx = xdy

xdy - ydx
= xdx
y2
x

- d
y =xdx

x x2
- =
+ C as y(1) = 1 C = 1
y 2
2

-2x
-1
4
f =
Hence, y = 2
2
5

x +1
r r r
3 r r
(b + c)
(2) a (b c) =
2
r rr r r r
3r
3r
(a c)b - (a b)c =
b+
c
2
2

7x y

54.

10
minutes = 5 minutes
2

xy +l=0

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Let other two sides of rhombus are

x y+ l=0
and 7x y + m = 0
then O is equidistant from AB and DC and from AD and BC

\ -1 + 2 + 1 = -1 + 2 +l l= 3
and -7 + 2 - 5 = -7 + 2 +m m= 15
\ Other two sides are x y 3 = 0 and 7x y + 15 = 0
On solving the eqns of sides pairwise, we get

1 -8
-7 -4
, , (1, 2), , , (-3, -6)
the vertices as
3 3
3 3

9
65. (1) The maximum limit of nitrate in drinking water is 50
ppm. Excess nitrate in drinking water can cause disease
such as methemoglobinemia ('blue baby' syndrome).
66. (2) Given
C(s) + O2(g) CO2(g); DH = 393.5 kJ mol1
(i)
1
O CO2(g); DH = 283.5 kJ mol1 (ii)
2 2(g)
\ Heat of formation of CO = eqn(i) eqn(ii)
= 393.5 (283.5)
= 110 kJ
67. (1) Given,

CO(g) +

C + D
A + B

60. (1) cos x + cos 2x + cos 3x + cos 4x = 0

2 cos 2x cos x + 2 cos 3x cos x = 0

No. of moles initially 1

At equilibrium
1a

5x
x
2 cos cos = 0
2cos x
2
2

cos x = 0, cos

Pi V Pi V Pf V Pf V
+
=
+
RT1 RT1 RT1 RT2
2

Pi Pf Pf
= +
T1 T1 T2

2 Pi T2
T1 + T2
62. (1) There is extensive intermolecular hydrogen bonding
in the condensed phase instead of intramolecular
H-bonding.
63. (2) 4 moles of NaOH and one mole of Br2 is required during
production of one mole of amine during Hoffmann's
bromamide degradation reaction.
O
||
RCNH2 + Br2 + 4NaOH RNH2 + K2CO3 + 2NaBr + 2H2O
64. (2) Alkali metals have the lowest ionization energy in each
period on the other hand Sc is a d - block element.
Transition metals have smaller atomic radii and higher
nuclear charge leading to high ionisation energy.

1+ a
= 10
1- a
On solving
a = 0.81
[D]At eq = 1 + a = 1 + 0.81 = 1.81
1COOH
(2)

p 3p p 3p 7p 9p
x =p, , , , , ,
2 2 5 5 5 5

61. (1) For a given mass of an ideal gas, the volume and amount
(moles) of the gas are directly proportional if the
temperature and pressure are constant. i.e
Vn
Hence in the given case.
Initial moles and final moles are equal (nT)i = (n T)f

1
1+a

1+ a
\ Kc =
= 100
1- a

5x
x
= 0 , cos = 0
2
2

CHEMISTRY

1
1a

68.

H
H

2
3

OH
Cl

4
CH3
For second carbon
c

Pf =

b
The priority order a > b > c > d
a = OH
b = CHCH3
|
Cl
c = COOH
d = H
For third carbon
The priority order a > b > c > d
a = Cl
b = CHCOOH
|
OH
c = CH3
d = H

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1
1+a

10
69.

(1) According to Freundlich adsorption isotherm

x
1
= log K + log P
m
n
Thus if a graph is plotted between log(x/m) and log P,
a straight line will be obtained
n
1/
=
e
p
slo

74.

log x/m

log

75.

76.
Intercept = log K

70.

71.

72.

log P
The slope of the line is equal to 1/n and the intercept
on log x/m axis will correspond to log K.
(2) Spent-lye and glycerol are separated by distillation
under reduced pressure.
Under the reduced pressure the liquid boil at low
temperature and the temperature of decomposition will
not reach. e.g. glycerol boils at 290C with
decomposition but at reduced pressure it boils at
180 C without decomposition.
(4) Sodium lauryl sulphate (C11H23CH2OSO3 Na+) is an
anionic detergent. Glyceryl oleate is a glyceryl ester of
oleic acid. Sodium stearate (C17H35COONa+) is a soap.
Cetyltrimethyl ammonium bromide

77.

CH3 (CH 2 )15 N(CH3 )3 Br is a cationic detergent.

79.

1
[5 + 0 + 0 - 1] = 2 i.e. sp hybridisation
2

NO2 =

1
[5 + 0 + 1 - 0] = 3 i.e. sp2 hybridisation
2

1
[5 + 0 + 1 - 0] = 3 i.e. sp2 hybridisation
2
The lewis structure of NO2 shows a bent molecular
geometry with trigonal planar electron pair geometry
hence the hybridization will be sp2

Br

NBS/hv

Br

Br

78.

H2O/K2CO3

(4) Region 2 will be the hottest region of Bunsen flame

shown in given figure

4x + y
y
(4) CxHy(g) +
O2(g) xCO2(g) + H2O(l)
2
4

20
= 75 ml
100
From the reaction of combustion

1 ml CxHy requires =

4x + y
ml O 2
4

4x + y
15 ml = 15
= 75
4
So, 4x + y = 20
x= 3
y= 8

NO3 =

C3H8
80.

(3)
Acid

Formula

Oxidation state of
Phosphorous

Pyrophosphorous
acid
Pyrophosphoric
acid
Orthophosphorous
acid
Hypophosphoric
acid

H4P2O5

+3

H4P2O7

+5

H3PO3

+3

H4P2O6

+4

73.

O
O
(1) Among 20 naturally occuring amino acids "Cysteine"
has ' SH' or thiol functional group.
General formula of amino acid RCHCOOH
|
NH2
Value of R = CH2SH in Cysteine.

OH

Volume of O2 used = 375

1
(3) Hybridization (H) = [no. of valence electrons of
2
central atom + no. of Monovalent atoms attached to it
+ (ve charge if any) (+ve charge if any)]

NO2+ =

(1) Froth floatation method is mainly applicable for

sulphide ores.
(1) Malachite ore : Cu(OH)2 . CuCO3
(2) Magnetite ore : Fe3O4
(3) Siderite ore : FeCO3
(4) Galena ore : PbS (Sulphide Ore)
(2) High density polythene is used in the manufacture of
housewares like buckets, dustbins, bottles, pipes etc.
Low density polythene is used for insulating electric
wires and in the manufacture of flexible pipes, toys,
coats, bottles etc.
(4) Out of all the four given metallic oxides CrO2 is attracted
by magnetic field very strongly. The effect persists
even when the magnetic field is removed. Thus CrO2 is
metallic and ferromagnetic in nature
(4) N bromosuccinimide results into bromination at allylic
and benzylic positions

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11
81. (4)
d

H
CH3 C = CH2

d+

HO Cl

OH

+
OH
CH3 C CH2Cl
CH3 C = CH2Cl
H

82. (1) When tert -alkyl halides are used in Williamson

synthesis elimination occurs rather than substitution
resulting into formation of alkene. Here alkoxide ion
abstract one of the b-hydrogen atom along with acting
as a nucleophile.
CH3
CH3

CH2

CH2

CH3 + Na OCH3

On solving (ii) we get

Ps = 752.4 torr
86. (3) Reaction of Zn with dil. HNO3
4Zn + 10HNO3(dil)
4Zn(NO3)2 + 5H2O + N2O
(Zn reacts differently with
very dilute HNO3)
Reaction of Zn with conc. HNO3
Zn + 4HNO3(conc.)
Zn(NO3)2 + 2H2O + 2NO2
87. (4) H2O2(aq) H2O(aq) +
For a first order reaction

CH3OH

2.303
a
log
t
(a - x)
Given a = 0.5, (a x) = 0.125, t = 50 min

k=

Cl
2-Chloro-2-methylpentane

2.303
0.5
log
50
0.125
= 2.78 102 min1
r = k[H2O2] = 2.78 102 0.05
= 1.386 103 mol min1
Now

H CH3
CH OH

CH3CH2

CH3 + CH3OH + NaBr

2-Methyl-pent-2-ene

83. (3) Optical isomerism occurs when a molecule is non

super imposable with its mirror image hence the complex
cis [Co(en)2Cl2]Cl is optically active.

k=

d [ H 2 O2 ]

dt
2d [O2 ]

dt
d [ O2 ]
dt
=

84. (2) On heating with excess of air Li, Na and K forms

following oxides
4 Li + O2
2Li2O

1
O (g)
2 2

d [H2 O]

=-

dt

2d [O2 ]
dt

d [ H 2 O2 ]
dt

1 d[H 2 O2 ]

2
dt

1.386 10-3
= 6.93 104 mol min1
2

88. (4)
Complex

Metal ion Configuration Magnetic moment

m=

Lithium monoxide

2Na + O2
K + O2

575 K

Na2O2

Sodium peroxide

KO2

Potassium superoxide

85. (1) According to Raoult's Law

P - Ps WB M A
=
(i)
Ps
M B WA
Here P = Vapour pressure of pure solvent, Ps = Vapour
pressure of solution
WB = Mass of solute, WA = Mass of solvent
MB = Molar mass of solute, MA = Molar Mass of
solvent
Vapour pressure of pure water at 100 C (by assumption
= 760 torr)
By substituting values in equation (i) we get,
760 - Ps
18 18
=
Ps
180 178.2

[Cr(H2O)6]2+

Cr+2

d4

24

]2+

Fe2+

d6

24

Co2+

d7

15

Mn 2+

d5

[Fe(H2O)6
[CoCl4]2

]2+

[Mn(H2O)6
35
89. (2) Galvanization is the process by which zinc is coated
over corrosive (easily rusted) metals to prevent them
from corrosion.
90. (2) As electron of charge 'e' is passed through 'V' volt,
kinetic energy of electron will be eV
Wavelength of electron wave (l) =
l=

(ii)

n(n + 2)

h
2meV

h
=
l

h
2m.K .E

2meV

Solutions prepared by authors of Disha's 38 yrs Topic-wise Solved Papers for

JEE Main & Advanced: Er.Sunil Batra, Deepak Agarwal and Mrs. Mamta Batra
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