Quad Era
Quad Era
Table Of Contents
QUADERA Help ........................................................................................................ 1
II Agreement .......................................................................................................... 3
3. Copyright ...................................................................................................... 4
Copyrights................................................................................................................. 7
QUADERA ................................................................................................................ 15
Introduction .......................................................................................................... 15
iii
QUADERA HTML Help
Calling Help..................................................................................................... 20
Further Information.......................................................................................... 23
Installing ........................................................................................................... 26
Setting Up ......................................................................................................... 27
Updating ........................................................................................................... 33
Uninstalling ........................................................................................................ 34
Options........................................................................................................... 46
iv
Table Of Contents
Toolbox .......................................................................................................... 47
Introduction .................................................................................................... 73
v
QUADERA HTML Help
vi
Table Of Contents
vii
QUADERA HTML Help
Recipes......................................................................................................... 164
Average........................................................................................................... 183
viii
Table Of Contents
Scripting.......................................................................................................... 189
ix
QUADERA HTML Help
Glossary................................................................................................................ 217
Index.................................................................................................................... 221
x
QUADERA Help
Program version 4.50, July 2012
Resources to access the online Help: The online Help contains all the information
required for operating QUADERA.
Please read the "Setting Up" section to easily configure QUADERA and the devices.
NOTE:
Read the QUADERA Release Notes. They list new features, bugfixes, known
problems and limitations of QUADERA. In addition, the Release Notes give
important information on installing and configuring QUADERA, on the
operating system, and on the network settings.
Via the Windows start menu: Program Files > QUADERA > Readme
Open the file "Readme.html" in the directory for programs and settings.
1
License Agreement
Please be sure to read the conditions of this Software License Agreement.
USA:
INFICON Inc.
Two Technology Place
E. Syracuse NY 13057
USA
INFICON Aktiengesellschaft
Abteilung KA
LI-9496 Balzers
Liechtenstein
I Preliminary Remarks
3. This contract defines the conditions under which INFICON grants the LICENSEE
the right to use the SOFTWARE required for computer control of the HARDWARE.
II Agreement
2. License Fees
The license fees for the use of the SOFTWARE under discussion in this agreement
are contained in the basic price of the HARDWARE. If this SOFTWARE is supplied
separately, the license fees are included in the price of the SOFTWARE.
3
QUADERA HTML Help
Upon payment of the basic price, the LICENSEE is granted the right to the use of
this SOFTWARE for an unlimited period of time on the HARDWARE according to the
following conditions.
3. Copyright
INFICON has the exclusive copyright on the SOFTWARE (including the source
code) under discussion in this agreement. The contract partners agree that the
licensed SOFTWARE may only be used within the framework of the permission
outlined in this agreement. Any other use not expressly stated in the agreement is
a breach of both, the copyright and the agreement and will lead to an immediate
termination of the license by INFICON with INFICON being entitled to full
compensation from the LICENSEE.
The LICENSEE recognizes that the codes for the SOFTWARE are a INFICON trade
secret. Any use of these codes by the LICENSEE not expressly permitted in the
agreement constitutes a disclosure of this trade secret making the LICENSEE fully
responsible to INFICON for damages in the declared amount of the investment and
development costs for the SOFTWARE. INFICON rights as declared in Section II,
Paragraph 1 also apply in this case.
The LICENSEE is obligated to undertake any and all measures required to prevent
his employees from causing any of the above described breaches of contract,
either during or after the period of their employment in the LICENSEE's company.
4. User Rights
Each licensed SOFTWARE under discussion in this contract has been developed by
INFICON for use on the previously defined HARDWARE, its peripherals and its
operating system. The conditions of use required by INFICON are specified in this
agreement and in the accompanying SOFTWARE description.
The LICENSEE may make as many copies of the SOFTWARE description as needed.
However, all descriptions, documentation, and one backup copy of the software
remain the property of INFICON.
INFICON warrants that the SOFTWARE under discussion in this agreement will
function according to the SOFTWARE specification laid down in the agreement and
the conditions of use specified.
4
License Agreement
Both parties recognize that software errors can occur even when extreme care is
taken.
If the object of the agreement does not meet the guaranteed specifications given
with it, the LICENSEE only has the right to a correction by INFICON, and this only
within the period of the warranty for the HARDWARE. If the SOFTWARE is supplied
separately from the HARDWARE, the warranty time shall be 90 days from the date
of delivery.
INFICON excludes any right to warranty service and liability claims if the
LICENSEE or any third party makes any modification in the license product and/or
the HARDWARE for which it was intended.
Any further warranty claims are expressly excluded. This exclusion includes in
particular any liability for damage to the HARDWARE and/or SOFTWARE itself as
well as any damage that may occur as a result of the use of this SOFTWARE.
6. Additional Software
INFICON will supply additional SOFTWARE at the cost of an additional license fee.
The conditions of this contract as described above also apply to any additionally
supplied SOFTWARE.
8. Gouverning Law
The LICENSEE states that he has read this agreement and understands its
contents. In opening the sleeve the LICENSEE indicates that he accepts this
agreement as the only valid agreement between the two parties concerning the
SOFTWARE under discussion therein. Any earlier oral or written agreements are
nullified by this agreement. Changes must be made in writing.
INFICON
Two Technology Place
E. Syracuse NY USA
Tel +1 315 434 1100
Fax +1 315 437 3803
5
QUADERA HTML Help
INFICON
LI-9496 Balzers
Furstentum Liechtenstein
Tel +423 / 388 3111
Fax +423 / 388 3700
www.inficon.com
6
Copyrights
COPYRIGHTS
Copyright 2004 - 2012 INFICON All rights reserved.
No part of this software and the accompanying material may be reproduced in any way
nor may it be manipulated with electronic systems, duplicated or distributed without
written permission from INFICON. Offenses against these regulations will result in
compensation claims.
The original software delivered may not be used for purposes other than those intended
nor is it permitted to make copies of the software. In particular, it is strictly forbidden to
give copies of the software to other people.
The use of trade names, brand names, trademarks, etc. in this document does not
entitle third parties to consider these names to be unprotected and to use them freely.
This is in accordance with the meaning of the laws and acts covering brand names and
trademarks.
TRADEMARKS
QUADERA is a registered trademark of INFICON.
7
Cross-References from Manuals
In this topic you find cross-references from manuals that refer to the QUADERA
Online-Help. Click on the corresponding link below to display the required topic:
9
Migrating from Quadstar to QUADERA
Migrating from Quadstar to QUADERA
Quadstar is an application software for the QMS 422/421 and QMS 200 Prisma
quadrupole mass spectrometers. QUADERA and Quadstar share some basic
capabilities. However, they sometimes differ in the used terminology, and especially in
the functionality and the tools. Once you know these differences you will be able to
migrate to QUADERA easily.
11
QUADERA HTML Help
The terms and concepts of Quadstar and QUADERA differ in some ways. Many terms
have a similar meaning, but they are named differently. The table below contains the
terms used in Quadstar and the equivalent terms used in QUADERA.
12
Migrating from Quadstar to QUADERA
The following table lists several functions and shows how to call them up in Quadstar
and in QUADERA.
Notation: xxx > yyy > zzz means "In the main menu, select the item xxx. In the
following submenu, select the item yyy. Then select the item zzz".
13
QUADERA HTML Help
14
QUADERA
Introduction
Product Description
Product Description
QUADERA is a powerful operation and analysis software for the following quadrupole
mass spectrometers:
QMG220
QMG700
QUADERA allows you to save and to document measuring data, to reload these data
and to display the reloaded data in various ways (table, bar graph, trend etc.).
15
QUADERA HTML Help
Main Features
Service functions
16
QUADERA
Scope of Delivery
Software
CD-ROM with QUADERA. The supplied installation program will create the
required folders and copy various files into these folders.
Directories created during installation under Windows XP with the default settings
Notes:
[User] represents your registered profile,
[Version] indicates the currently installed version of QUADERA,
[QMG] specifies the mass spectrometer, i.e. QMG220, QMG700.
Directories created during installation under Windows Vista with the default
settings
Notes:
[User] represents your registered profile,
[Version] indicates the currently installed version of QUADERA,
17
QUADERA HTML Help
Ethernet cable with crossed wires for direct connection of the mass spectrometer
to a PC
18
QUADERA
System Requirements
Free space on the harddisk: 100 MB to install the program, additional space for
the measurement data
Graphics card: Resolution 1024 x 768 pixels or higher, at least 256 colors
CD-ROM drive
Color monitor
Software
19
QUADERA HTML Help
Getting Help
Calling Help
If you need help during your work, you may utilize the following resources:
2. If the Contents, Index and Search tabs are not displayed in the Help window,
click Show .
You can control the number of the found topics by adding key words to the search string
or by removing them from the string. This way you can restrict the search result in the
list to the relevant topics and key words.
In addition, you can use the Windows start menu to open the online help:
20
QUADERA
The Help window uses the same settings for fonts, font colors and background colors as
the browser installed on your computer. These settings and other options depend on the
type and version of the installed browser. You can change the appearance of the help
topics in the Help window by changing the settings for fonts and colors.
3. In the General tab, click Accessibility and then select Ignore colors specified
on Web pages.
4. Click OK.
5. Perform one of the following actions in the Internet Options dialog box:
Changing the background or text color in the help:
In the General tab, click Colors... and then select the required options.
Changing the font in the help:
In the General tab, click Fonts... and then select the required options.
NOTE:
Any change in the font and background color of the help topics in the Help
window will also affect the font and background color of websites displayed by
Microsoft Internet Explorer.
Further information on the settings and options available in your browser can be found
in the help file for your browser.
21
QUADERA HTML Help
22
QUADERA
Further Information
You can check which version of QUADERA is installed on your computer and determine
the product ID and the license key of your program. In addition, you can call up system
information.
23
QUADERA HTML Help
Reporting Errors
QUADERA allows you to create an error report which also contains additional
comments from you. These reports are helpful to our support staff when solving
problems.
In the Help menu, click Report an Error. You are directly connected to
an error report form on the website of QUADERA (http://www.quadera.net).
Please fill out this form carefully.
Your error report will be automatically acknowledged if you quote a valid email
address. You receive an email and a reference number for further queries on the
status of your issue.
24
QUADERA
QUADERA comes as a compressed file on a CD-ROM. SETUP copies and unpacks the
QUADERA program files and creates the required directories on the selected drive (pay
attention to the system requirements).
NOTE:
If required you can change the locations of the special subdirectories after the
installation has been completed (menu Tools>Options).
Installing QUADERA,
Updating QUADERA,
Upgrading QUADERA.
NOTES:
Uninstalling QUADERA prior to installing a new version will most often result in
the best installation.
25
QUADERA HTML Help
Installing
NOTE:
Unrestricted use of QUADERA requires a valid license key.
NOTE:
In order to install QUADERA, a user account with administrator access rights
is required.
2. Start Windows and close all other applications. Pay attention to the instruction
manual for your operating system.
4. Follow the instructions of the installation program and enter all required parameters
or accept the respective default settings.
NOTE:
After installing QUADERA, you have to set up the following:
26
QUADERA
Setting Up
1. Start QUADERA.
2. In the Device menu, click Device Setup. The "Device Setup" dialog opens.
Click Search.
3. The search scans the network for running QMG mass spectrometers. Click Search
again, if all mass spectrometers are not found, to start another search.
4. In the "Device Search" dialog select a device (or devices) and click Add. Close the
dialog.
5. Click Apply in the 'Device Setup' dialog to acknowledge the input. QUADERA will now
connect to each device, acquire the Device Name, and disconnect from each device.
8. QUADERA is now configured for the connection with the mass spectrometer(s).
QUADERA now allows more than one device to be connected and acquiring data
simultaneously if properly licensed ('Multiplexing' license). This multiple device design,
known as Multisensor, can run for an extended period of time but it is recommended to
limit duration and/or quantity of data collected in any one session.
NOTE: Multisensor can be enabled through the Options menu and must be
enabled to use the Multiplexing add-in.
27
QUADERA HTML Help
NOTE:
Normally most device settings have already been performed in the factory. The
Device Name is one setting that can be customized.
2. In the device status view, click on the "Device Configuration View" icon. The
"Device Configuration" window opens.
3. Adjust the parameters to the device settings. The following table list the available
parameters.
NOTE:
Select only components that are actually installed in your device.
Device Name Edit box The Device Name used to label the
device.
28
QUADERA
source,
Grid: Grid ion source,
SPM: Sputter Process Monitor,
High sensitivity (only QMG220),
SpecPos (only QMG700),
SpecNeg (only QMG700).
Protection Dropdown list Monitoring of filament and SEM.
If a pressure gauge is installed:
InternalOff: use QUADERA to
switch filament and SEM manually
on and off,
ExternalOnOff: an external system,
such as a pressure gauge, protects
filament and SEM. They are
automatically switched on and off
as determined by the parameters
"Total Pressure Level On/Off".
ExternalOff: an external system,
such as a pressure gauge, protects
filament and SEM. They are
automatically switched off as
determined by the parameter
"Total Pressure Level Off". Use
QUADERA to switch filament and
SEM manually on.
If no pressure gauge is installed: the
protection input of the device is used.
QMA For QMG220: Indicates the installed QMA.
Automatically
detected
For QMG700: Selection of the QMA.
Dropdown list
QMH For QMG220: Indicates the installed RF device,
Automatically which defines the mass range.
detected
For QMG700: Selection of the QMH, depends on the
Dropdown list installed QMA.
Mass Range Automatically Indicates the mass range in [amu],
detected depends on the installed QMA and
QMH.
Simulation Dropdown list Defines the simulation mode of the
Mode device:
Off,
29
QUADERA HTML Help
Internal,
External.
NOTE:
The software simulation (local
simulation on the PC) requires no
real device.
IO220, or Automatically Indicates whether an Input/Output-
IO700 detected module (IO220 or IO700) has been
detected or not.
Total Number > 0 Only valid when a total pressure gauge
Pressure is installed.
Level Off
Monitoring the QMG via total pressure
measurement: pressure threshold
when filament and SEM switch
automatically off (pressure rise).
The parameters "Total Pressure Level
Off" and "Total Pressure Level On"
should form a hysteresis to avoid
repeated switching when minor
pressure fluctuations occur.
Total Number > 0 Only valid when a total pressure gauge
Pressure is installed.
Level On
Monitoring the QMG via total pressure
measurement: pressure threshold
when filament and SEM switch
automatically on (decrease of
pressure).
Total Valid address Only valid when a total pressure gauge
Pressure RS is installed.
485 Address
Total pressure measurement: address
of the installed digital pressure gauge.
Note that the pressure gauge is only
recognized when the device is turned
on (no "hot-plug").
Total Automatically Only valid when a total pressure gauge
Pressure Type detected is installed.
Total pressure measurement: type of
the installed analog/digital pressure
gauge.
Note that the pressure gauge is only
recognized when the device is turned
on (no "hot-plug").
30
QUADERA
NOTE: Buttons are available to degas the Filament Ion Source and Total
Pressure Gauge filament (if present). Degas of the Filament Ion Source can be
started and stopped manually or run for a duration of time. The Degas function
can also be accessed from the All Device Status View.
31
QUADERA HTML Help
Version Number
In the Help>About menu you find the version number of your software and further
information, as well as product extensions.
Update
A software update is a maintenance release of the software within the same major
version. The minor version has been increased (e.g. from 1.12 to 1.13). Updates contain
new features and additional functions or they fix software bugs that have been
discovered.
Upgrade
A software upgrade represents an extensive revision of the software and is marked as a
new major version (e.g. from version 1 to 2). Upgrades contain extensive revisions and
they offer an extended and improved range of functions for the software.
32
QUADERA
Updating
The version number allows you to find out if an update or upgrade for QUADERA is
available.
2. Insert the CD with the latest product release into the CD-ROM drive.
3. Follow the instructions of the installation program and enter all required
parameters or accept the respective default settings.
33
QUADERA HTML Help
Uninstalling
NOTE:
In order to uninstall QUADERA, a user account with administrator access
rights is required.
1. Exit QUADERA.
2. In the Windows Start menu, select Control Panel > Add or Remove
Programs.
In Windows Vista: Start menu Control Panel > Programs > Uninstall a
program
3. Select QUADERA.
4. Click [Remove] or Uninstall (Vista). You are asked to confirm the action.
NOTE:
Files which have been created automatically by the software and user files
remain on the harddisk. If you want to remove these files you may do so
manually. In this case, adhere to the QUADERA Release Notes.
34
QUADERA
Operating Concept
Object Description
35
QUADERA HTML Help
Example for the relation between measurement task and data display
In order to observe the change of several gases with time, the MID (Multiple Ion
Detection) type of measurement is especially suitable. In this example, one
measurement task relates to a mass whose intensity is to be measured, and it defines
the parameters required for the measurement. The recipe unites all measurement tasks,
i.e. the masses to be observed. During a measurement, the measurement tasks are
performed one after the other, the readings are collected and stored in the related
measurement project. The repeated execution of a measurement task results in a
sequence of data which show the course of the related mass signals as a function of the
time. The measuring data which are obtained in a measurement task can be displayed
graphically in a chart in the section (e.g. as a curve or a bar chart). As a result, they
represent a chart element.
36
QUADERA
Operating Elements
User Interface
The QUADERA window is divided into several areas. For each area, a tooltip displays
brief information. For this, move the mouse pointer to the required area in the figure
below. For more detailed information, click the respective area.
37
QUADERA HTML Help
Screen Elements
38
QUADERA
Mouse Actions
Click Position the mouse pointer on the required object (file, text, figure
etc.). Then press the left mouse button.
Double- Position the mouse pointer on the required object. Then press the
click left mouse button twice in rapid succession.
Drag & Position the mouse pointer on the required object. Press the left
drop mouse button and keep it pressed. Drag the object to the new
position (destination) and then release the mouse button. The
object will be put down at the destination.
Right Position the mouse pointer on the required object. Then press the
mouse right mouse button. In general, this will open a context menu
button offering some object related functions to you.
39
QUADERA HTML Help
Keyboard Shortcuts
NOTE:
The following table describes the default settings for the keyboard shortcuts.
You can customize the keyboard shortcuts to suit your needs.
Key Action
F1 Call up help
CTRL+O Open a measurement project
ALT+F4 Exit the application
ALT+F8 Call up the Macros dialog
40
QUADERA
2. Click Customize...
3. Click Keyboard...
5. Click a command in the command list. The Specify a Shortcut field displays the
keyboard shortcut that is currently assigned to the selected command.
If the selected keyboard shortcut has already been assigned to another command, the
latest assignment will replace the previous one.
Click Reset All to reset all keyboard shortcuts to the default assignments.
2. Click Customize...
3. Click Keyboard...
5. Click a command in the command list. The Specify a Shortcut field displays the
keyboard shortcut that is currently assigned to the selected command.
6. Click Remove. The assignment between the keyboard shortcut and the
command is removed.
41
QUADERA HTML Help
Click Reset All to reset all keyboard shortcuts to the default assignments.
42
QUADERA
User Interface
Title Bar
Program symbol: Click this symbol to call up the title bar menu.
Program name
43
QUADERA HTML Help
Menu Bar
Each menu contains a list of commands. The menu bar allows you to call up all functions
of QUADERA. The following main menus are available:
File menu
The File menu contains the following functions:
Open
Export
ASCII
Save as Template...
Close
Recent Files
Exit
View menu
The View menu contains the following functions:
Event View
Device Status
Toolbox
Tools menu
The Tools menu contains the following functions:
Programming
44
QUADERA
Macros
Create Add-in...
Add-in Manager...
Options
Spectra Library
Device menu
The Device menu contains the following functions:
Connect
Run
Device Setup...
Window menu
The Window menu contains the following functions:
Arrange Icons
Cascade
Tile Horizontally
Tile Vertically
Window List
Help menu
The Help menu contains the following functions:
Contents
Index
Report an Error...
About...
45
QUADERA HTML Help
Options
Specifying the path (file location) for various file types used by Quadera ("File
Locations" tab)
Enabling Multisensor, the ability to connect to and collect from more than one
device. As of QUADERA version 4.20 this must be enabled (and licensed) to use
either Multisensor or Multiplexing (from VSTA).
46
QUADERA
Toolbox
Toolbox
The toolbox is used to customize the working area of a measurement project. The main
task is to create new objects. The toolbox is subdivided into different groups according
to the subject. One tool can be used in several groups. Click the respective button to
open the required toolbox.
NOTE:
Toolboxes may contain varying tools depending on the configuration of
QUADERA.
Refer to the alphabetical list of tools if you search for a specific tool.
47
QUADERA HTML Help
Applying Tools
2. Use the buttons and if necessary. The toolbox is scrolled up and down,
respectively, to display the desired tool.
48
QUADERA
List of Tools
49
QUADERA HTML Help
50
QUADERA
51
QUADERA HTML Help
The measurement window is used to display a measurement project and contains the
following areas:
Recipe selection,
Working area,
52
QUADERA
Recipe Selection
The recipe selection tab allows you to switch to a recipe within a measurement project.
53
QUADERA HTML Help
Working Area
The working area is used for displaying measuring data and for editing the currently
selected recipe. The recipe editor is present in every recipe and cannot be removed by
the user. Additional display areas serve as containers for the related measuring data
displays. The user can add several display areas to a recipe.
54
QUADERA
Several working areas are available for each recipe. The working area selection tabs
allow you to switch between the displays.
55
QUADERA HTML Help
The device status view shows the most important device parameters and states. At a
glance, you can see all the important information on the status of the connected device,
the measurement and the recipe. The displayed icons and parameters are
predetermined and cannot be hidden. Use the icons to easily access the basic functions
of the software and the device:
Icon Description
Device disconnected.
Click on the icon to connect the device.
Device connected.
Click on the icon to disconnect the device.
Basic device settings.
Click on the icon to view the basic device settings in the
"Device Configuration" window, and edit as appropriate.
Measurement stopped.
Click on the icon to start the measurement.
Measurement running.
Click on the icon to stop the measurement.
Filament off.
Click on the icon to switch the filament on.
Filament on.
Click on the icon to switch the filament off.
SEM off.
Click on the icon to switch the SEM on.
SEM on.
Click on the icon to switch the SEM off.
NOTE:
The "Common SEM Voltage" parameter is not available when the Faraday-Cup
has been selected in the basic device settings (Symbol "Device Configuration
View").
56
QUADERA
The All Device Status View is a subarea of the QUADERA user interface.
The All Device Status View shows a collection of the most important device parameters
and states for all devices connected to QUADERA. At a glance, you can see all the
important information on the status of the connected device, the measurement and the
recipe. The displayed icons and parameters are predetermined and cannot be hidden.
Use the icons, described on the Device Status View page, to easily access the basic
functions of the software and the device.
The All Device Status View allows for selection of multiple devices (using CTRL or Shift
key) and provides a context menu for selection of functions. The All Device Status View
is most useful for viewing status when operating QUADERA in the Multiplexing mode.
Please note that the All Device Status View does not replace the Start Page as
the main control. You must still use the Start Page and its Device icons to
access Projects and Templates for a Device.
57
QUADERA HTML Help
Event View
The event view informs you of events that have occurred for each device (the selected
device on the Start page). Warnings, informations and errors are displayed in a compact
way.
Events related to measurement, device and system are listed. The presentation follows
the event view used by the Windows operating system. Refer to the list of events for a
detailed description.
58
QUADERA
Context Menus
Context Menus
A context menu is a special menu that opens up when pressing the right mouse button.
It is context sensitive and always contains commands which are related to the currently
used screen area.
In QUADERA, you may call up context menus in the following screen areas:
59
QUADERA HTML Help
60
QUADERA
Click with the right mouse button into the title bar of a window. The context menu "title
bar" appears. It contains the following functions:
61
QUADERA HTML Help
Click with the right mouse button into the menu bar. The context menu "Menu bar"
appears. It contains the following functions:
62
QUADERA
Click with the right mouse button into the recipe selection area. The context menu
"Recipe Selection" appears. It contains the following functions:
63
QUADERA HTML Help
Click with the right mouse button into the frame of the section. The context menu
"Frame of the section" appears. It contains the following functions:
64
QUADERA
Click with the right mouse button into a chart located in the working area. Various
context menus are available, depending on the selected mouse pointer position:
Click on the measuring data display. Context menu "Chart" appears. It contains
the following functions:
Zoom Out
Reset Zoom
Hold
Legend
Print
Enable Background Subtraction
Enable Reference Subtraction
View as Partial Pressure
Marker (only in MID/MCD recipes)
Display (only in MID/MCD recipes)
Analog I/O Characteristics
Only when the legend is shown: Click on the chart legend. Context menu
"Legend" appears.
Only for trending charts in MID/MCD recipes: Click on the right y-axis. Context
menu "Axis Y2" appears.
65
QUADERA HTML Help
66
QUADERA
67
QUADERA HTML Help
Color...
Opens the "Color" dialog to select the color for
the chart display of the measurement task
(curve color).
68
QUADERA
NOTE:
This context menu is only available for the docker windows (Toolbox, Device
Status View, All Device Status View, Event View), but not for the measurement
project window and the start page.
Click with the right mouse button into the docker window title. The context menu
"Docker Window" appears. It contains the following functions:
69
QUADERA HTML Help
As a written documentation for your measurement projects you can capture and print
out screens of the QUADERA user interface. Proceed as follows:
1. Capture the screen. The screenshot is copied into the Windows clipboard:
Full screen capture: press the key combination "CTRL+Print",
Active window capture: press the key combination "CTRL+ALT+Print".
2. Open a suited image editor, e.g. Microsoft Paint (Windows start menu > Programs >
Accessories > Paint).
3. Paste the screenshot from the Windows clipboard into the image editor, e.g. press
the key combination "CTRL+V".
NOTE:
Various screen capture tools are available as freeware, shareware, and by
purchasing. In general, these tools provide enhanced screen capture features
compared to the procedure described above.
70
QUADERA
Getting Started
Starting QUADERA
You can start QUADERA from the Windows Start menu or from the desktop.
1. Click the Windows Start button and select the All Programs entry.
2. Select the QUADERA program group and click the QUADERA entry.
Desktop
You can start QUADERA from the desktop if a shortcut has been created for the
desktop during installation.
71
QUADERA HTML Help
Start Page
The Start Page selection (File or a Device) determines what is displayed within the views
of QUADERA (e.g. Measurement Projects, Event View, Device Status View, title bars,
etc.). For example, select a device on the start page to see its Event View.
After starting QUADERA, the start page is displayed. Here you can perform one of the
following actions:
Open existing measurement projects (*.qmp files) and work with them:
Click on the File icon. All measurement projects that have been worked on
recently are shown in a list. Select the required project and open it with OK
or by double-clicking it.
Click the More... button to open a measurement project that is not present in
the list.
In the View menu, click Show Start Page. The start page is displayed.
Only if the start page is already open: In the Window menu, click the respective
item in the list of open windows.
NOTE:
Continuing the measurement using an existing measurement project is not
possible.
72
QUADERA
Example of a Measurement
Introduction
The goal of this sample measurement is to analyze the composition of air. For this, we
do not perform a real measurement in vacuum. Instead, we are going to use the
simulation mode of QUADERA and the stored simulation data which represent a typical
measurement of air with a Faraday detector. Except for small details, the course of a
measurement is the same for all mass spectrometers.
73
QUADERA HTML Help
NOTE:
For software training and in order to practice the measurement runs we
recommend that QUADERA be used in the simulation mode.
The scan measurement type (ion current as a function of m/e) is suitable for obtaining
an overview of all present gases.
1. Open the start page: In the View menu, click Show Start Page.
4. The new measurement project window appears. The working area displays the
scan project.
Edit the recipe (if necessary): Click the Edit tab.
Display the measuring data: Click the Measure tab.
NOTE:
You can start the measurement regardless whether the recipe editor or the
working area has been selected.
5. Start the measurement: In the device status view, click on the "Start" icon.
The connection to the device is automatically established. The device now
receives the parameters for the current measurement task. You can adjust the
chart layout while the measurement is running.
6. Stop the measurement: In the device status view, click on the "Stop" icon.
7. Close and save the measurement project. In the File menu, click Close. You are
requested if you want to save the measurement project. QUADERA suggests an
automatically generated file name that is based on date/time of the measurement and
the used template.
Yes: the "Save As" window used for saving measuring data opens up. Select a
suitable name and path and then click Save. The measurement project will be
saved and closed.
Please note: The file extension for measurement projects is *.qmp
No: the measurement project will be closed without saving the data.
Cancel: the action is cancelled. You will return to the measurement project
without saving the data.
74
QUADERA
NOTE:
For software training and in order to practice the measurement runs we
recommend that QUADERA be used in the simulation mode.
The MID measurement type (Multiple Ion Detection) is suitable for observing changes of
several gases with time.
1. Open the start page: In the View menu, click Show Start Page.
4. The new measurement project window appears. The working area displays the
MID project.
Edit the recipe (if necessary): Click the Edit tab.
Display the measuring data: Click the Measure tab.
NOTE:
You can start the measurement regardless whether the recipe editor or the
working area has been selected.
5. Start the measurement: In the device status view, click on the "Start" icon. The
connection to the device is automatically established. The device now receives the
parameters for the current measurement task. You can adjust the chart layout while the
measurement is running.
6. Stop the measurement: In the device status view, click on the "Stop" icon.
7. Close and save the measurement project. In the File menu, click Close. You
are requested if you want to save the measurement project. QUADERA
suggests an automatically generated file name that is based on date/time of the
measurement and the used template.
Yes: the "Save As" window used for saving measuring data opens up. Select a
suitable name and path and then click Save. The measurement project will be
closed and saved.
Please note: The file extension for measurement projects is *.qmp
No: the measurement project will be closed without saving the data.
Cancel: the action is cancelled. You will return to the measurement project
without saving the data.
75
QUADERA HTML Help
Chart Display
In the working area selection, click the Measure tab (or the tab which corresponds to
the required working area). The measuring data of the project are displayed in the
section (chart display):
You can navigate in the measuring data by means of the data navigator or by
pulling the cursor (mouse pointer is displayed as a double arrow).
The context menus for the chart gives you access to additional functions.
Use the tools "Add Chart Element" and "Remove Chart Element" to add and
delete existing measurement tasks to and from the chart, respectively.
76
QUADERA
Data Navigator
Data Navigator
You can show and hide the data navigator by means of the context menu "frame of the
section".
The data navigator is located below the measurement display. It allows you to scroll
through the measuring data along the time axis. This is possible while a measurement is
running and also for stored measuring data. If a measurement is running, this will
automatically freeze the display (hold mode). You can exit the hold mode with the Hold
Off function, e.g. by clicking on the "Hold Mode" icon.
Data navigator
The lower navigator bar comprises the entire measurement period. Use the
dropdown list to the right of the bar to select the required period. This period will
be represented by a green scroll bar.
Time period ("1 min""4 weeks"): The measuring values of the selected time
period can be displayed.
All: All measuring values can be displayed.
The upper navigator bar comprises the time period that has been selected in the
lower navigator bar (green bar). The range limits are displayed at the left and
right end of the bar.
The red scroll bar inside of the upper navigator bar comprises a time period
whose range limits are displayed at the upper left and lower right end of the bar
(it covers 1 minute in the above example "Data navigator").
The cursor in the upper navigator bar (vertical line) is used to determine which
point of time is to be displayed in the chart. This point of time is displayed next
to the cursor.
77
QUADERA HTML Help
78
QUADERA
Scan measurements
In a scan measurement, the data navigator refers to the chronological order of the
individual scans (measuring cycles). This is useful when navigating between the
individual measuring cycles. The zoom function applies to the scan displayed in the chart
(intensity as a function of the mass) and is independent of the data navigator.
The selected magnification is maintained if you select another measurement cycle or
change the time period with the data navigator.
79
QUADERA HTML Help
The chart displays a scan (intensity as a function of the mass) at a point in time which is
specified by the cursor position in the data navigator (item 3 in the above figure). It is
only possible to display the scans in the time period specified by the red scroll bar in the
upper navigator bar.
The measuring values displayed in the chart are determined by the cursor positions in
the data navigator and in the chart. The following rules apply:
The cursor in the upper navigator bar (item 3) determines which scan is to be
displayed in the chart, i.e. the point in time of a scan within the entire
measurement period (measurement cycle).
The cursor in the chart (item 1) determines the mass (x-axis) in the displayed
scan for which the measuring values are listed (item 2).
80
QUADERA
Select the required chart view using the "Diagram" context menu.
"Trend" view
The measurement data (item 1 in the above figure) are displayed as a function of the
time. The chart covers the period of time which is specified by the red scroll bar in the
upper navigator bar. The displayed measuring values (item 3) are specified by the
cursor position. Please note that the cursor in the red scroll bar (item 4) and the one in
the chart (item 2) are synchronized.
"Bar" view
The measuring data are displayed as a bar graph for the point in time specified by the
cursor position in the data navigator. The measuring data can only be displayed within
the period of time specified by the red scroll bar in the upper navigator bar.
"Table" view
The measuring data are listed as a table for the point in time specified by the cursor
position in the data navigator. The measuring data can only be displayed within the
period of time specified by the red scroll bar in the upper navigator bar. Please note that
the average and the maximum values are still based on the entire time of the
measurement.
81
QUADERA HTML Help
82
QUADERA
Exiting QUADERA
Press ALT+F4 (standard method for exiting the currently active Windows
application).
Click the Close symbol in the upper right corner of the QUADERA window.
Call up the context menu for the title bar of the QUADERA window and click
Close.
83
QUADERA HTML Help
2. Select the directory, the file name and the file type for the required measurement
project.
3. Click Open.
You may also open an existing measurement project via the Start page.
NOTE:
Continuing the measurement in an existing measurement project that is
already saved is not possible. The relevant icons and menu commands are not
available.
84
QUADERA
1. The most recently used files are listed in the lower part of the File menu. Click
the More... button to open a measurement project that is not present in the list.
You may also open a recently used file via the Start page.
85
QUADERA HTML Help
NOTE:
If you have not selected a section of a Measurement Project then the Export
submenu item is disabled.
Exporting
Proceed as follows to export the data of an open measurement project:
4. The "Export Options" window used for selecting measuring data opens up.
5. Click OK. The "ASCII-Export data as" window used for exporting measuring data
opens up. Select a suitable name and path and then click Save. The measurement
project will be exported.
Delimiters, the date and time format, and decimal separators (period and comma) are
country specific. These settings can be adjusted in the operating system: Windows Start
menu > Control Panel > Date, Time, Language, and Regional Options. The settings for
the operating system will also be used by QUADERA.
86
QUADERA
or
2. Click the Close symbol in the upper right corner of the measurement
project window.
Yes: the "Save As" window used for saving measuring data opens up. Select a
suitable name and path and then click Save. The measurement project will be
closed and saved.
Please note: The file extension for measurement projects is *.qmp
No: the measurement project will be closed without saving the data.
Cancel: the action is cancelled. You will return to the measurement project
without saving the data.
87
QUADERA HTML Help
In QUADERA, you can specify the path (file location) for various file types created by
the user:
1. In the Tools menu, click Options. The "Options" window opens up.
4. Click Modify.
5. The "Browse For Folder" window opens up. Select the desired path and then click
OK.
NOTE:
Click "Default" to reset the paths for all file types to the default settings.
88
QUADERA
You can adjust the display of measuring data in the section, even while a measurement
is running. Proceed as follows:
1. Click the section with the right mouse button. The related context menu opens
up.
89
QUADERA HTML Help
Zooming in Charts
3. Move the cursor to the opposite corner of the rectangle. The zoom area is
indicated by a dashed rectangle.
4. Release the left mouse button. The marked area is zoomed in.
NOTE:
For sample measurements, the data navigator displays the time period of the
zoomed area of the x-axis (time axis).
90
QUADERA
Proceed as follows:
1. Click with the right mouse button into the measuring data legend of the section.
The corresponding context menu opens.
For a more detailed description of the "Color" dialog box, please refer to the Windows
operating system help.
91
QUADERA HTML Help
Proceed as follows:
3. Enable the "Smooth Chart Lines" checkbox to smooth the displayed lines in
charts.
4. Use the spin buttons to increase and decrease the line thickness.
The settings are applied to the charts for all measurement projects.
92
QUADERA
You can split up the working area into several sections, i.e. you can add new sections.
Toolbox
Proceed as follows:
3. Drag the required tool ("Split") onto the working area (drag&drop). The section is
split up according to the selected tool.
93
QUADERA HTML Help
Deleting a Section
NOTE:
Measurement data remain stored when a section is deleted.
You can remove sections of the working area, i.e. you can delete a section.
Toolbox
Proceed as follows:
2. Drag the Remove Section tool onto the required section (drag&drop).
3. You are asked to confirm the deletion of the section. Click OK.
94
QUADERA
You can create a new working area in a measurement project. This allows you to display
the measurement tasks of a measurement project in different ways according to your
requirements (e.g. different combinations of measurement tasks, or the representation
as a curve and a bar graph).
Toolbox
Proceed as follows:
3. Drag the Add Working Area tool onto the working area (drag&drop). A new tab
labeled "New WorkingArea" appears in the working area selection, and the new
working area is displayed.
4. Use the context menu "Frame of the section" to rename the new working area as
desired.
95
QUADERA HTML Help
NOTE:
Measurement data remain stored when a working area is deleted.
Toolbox
Proceed as follows:
3. Drag the Remove Working Area tool onto the working area (drag&drop).
4. You are asked to confirm the deletion of the working area. Click OK.
96
QUADERA
You can freeze the display while a measurement is running. This will allow you e.g. to
scroll through a measurement or to zoom an area.
Proceed as follows:
1. Click on the measuring data display in the section with the right mouse button.
The related context menu opens up.
2. Click Hold:
The checkmark indicates that the function is enabled, i.e. the display is now
frozen.
The function is disabled if the checkmark is not shown.
or
1. Click on the "Hold mode" icon in the data navigator. Note that the icon is only
displayed when the data navigator is shown.
NOTE:
If you are zooming an area or moving the cursor, the "Hold" function will be
switched on automatically, i.e. the display will freeze.
97
QUADERA HTML Help
Displaying Windows
QUADERA can manage several windows at a time. Individual windows can be handled
as usual under the Windows operating system (close, move, resize, etc.). You may also
use the title bar context menu for the respective window. In addition, the following
options are available:
Arrange icons
In the Window menu, click Cascade. This will arrange all open windows in an
overlapping manner.
In the Window menu, click Tile Horizontally. This will arrange all open
windows as horizontal tiles (one below the other).
In the Window menu, click Tile Vertically. This will arrange all open windows
as vertical tiles (side by side).
In the Window menu, click Minimize All Windows. This will minimize all open
windows.
In the Window menu, click Close All Windows. This will close all open
windows.
1. Open the Window menu. A list of all open measurement projects is displayed at
the bottom of the pulldown menu.
2. Click the required measurement project in order to move the related window to
the front.
98
QUADERA
When switching to another measurement project, the device status display is always
updated. This means that the status of the device belonging to the current measurement
project is displayed.
Arranging icons:
In the Window menu, click Arrange Icons. This will arrange all icons.
99
QUADERA HTML Help
You can show and hide docker windows in the View menu.
Event view
In the View menu, click the Event View element to show and hide the event view.
Device status
In the View menu, click the Device Status element to show and hide the device status.
Toolbox
In the View menu, click the Toolbox element to show and hide the toolbox.
100
QUADERA
The device connection is automatically configured. One simulator per Device type is
present (if licensed); other mass spectrometers can be added using 'Search' in
'Device>>Device Setup'.
101
QUADERA HTML Help
NOTE:
New or modified parameters for the measurement task are accepted from the
device only after the measurement has been restarted. Ion source parameters
affect the device immediately, i.e. as soon as the device is connected with
QUADERA.
1. In the device status view, check that the filament and SEM are on. The
corresponding icons and tooltips indicate the current status. If required, switch
the filament and the SEM on.
When the filament and the SEM are switched off and you want to start the
measurement a requester appears automatically. It queries if the corresponding
component is to be switched on or not.
2. In the Device menu, click Run. The connection to the device is automatically
established and then the current recipe is started. The checkbox indicates that
the measurement is running (checkmark).
or
2. In the device status view, click the "Start" icon . The connection to the
device is automatically established and then the current recipe is started. The
"Start" icon appears in gray thus indicating a running measurement. The "Stop"
icon becomes available.
1. In the Device menu, click Run. The measurement is being stopped. The
checkbox indicates that the measurement has been stopped (no checkmark).
or
1. In the device status view, click the "Stop" icon . The measurement is being
stopped. The "Stop" icon appears in gray thus indicating that the measurement is
stopped. The "Start" icon becomes available.
102
QUADERA
Disconnecting
1. In the Device menu, click Connect. The checkbox indicates that the device is no
longer connected (no checkmark).
or
1. In the device status view, click the "Connected" icon . After the connection
NOTE:
A requester appears if you disconnect the device while the measurement is
running:
Click "Yes" if you want to disconnect the device. The measurement will
be stopped.
Click "No", if you want to continue the measurement. The device will not
be disconnected.
103
QUADERA HTML Help
NOTE:
New or modified parameters for the measurement task are accepted from the
device only after the measurement has been restarted. Ion source parameters
affect the device immediately, i.e. as soon as the device is connected with
QUADERA.
Start Page
Select the desired device. You can choose between a real device and a simulator.
Connecting
In the Device menu, click Connect. The checkbox indicates that the device is
connected (checkmark), or
In the device status view, click the "Disconnected" icon . After the
connection has been established the icon toggles to the "Connected" icon .
104
QUADERA
Simulation Mode
QUADERA allows you to simulate the operation of a mass spectrometer. This doesn't
mean that a simulation is being performed in the real device; instead, a simulation
software is used. By default, the simulation software is installed together with
QUADERA. The simulator is running on the same PC as QUADERA. The local
simulation mode is e.g. helpful for getting familiar with the software.
To use the simulator, select it on the 'Start Page' and use it as you would a real device.
NOTE:
The simulation in the real device is defined via the basic device settings of the
device status view ("Device Configuration View" icon). In contrast, using the
simulation software (local simulation on the PC) does not require a real device.
105
QUADERA HTML Help
Calibration
Calibration Projects
In QUADERA, devices are calibrated by using calibration projects, which are based on
normal measurement projects. Calibration projects are called via the start page.
One recipe,
You can modify recipe parameters directly in the recipe. The parameters that are
relevant for the calibration project are linked to editing fields in the working area. Thus,
you can change these parameters directly in the working area.
QUADERA provides basic templates for each calibration project, such as gas specific
calibration and background determination. These templates are intended to create user
specific calibration project templates, for ab initio calibration projects.
NOTE:
For a written documentation of your calibration projects you can capture
screens of the QUADERA user interface.
106
QUADERA
Consider one or two peaks of a scan-analog measurement to tune the ion source (ion
source optimization). Use the recipe editor to change the recipe parameters defined in
the calibration project for the ion source. Typically, one or more masses are scanned.
The calibration project allows you to optimize the performance of the ion source. The
scans will be recorded when you start the calibration project. The currently set ion
source parameters are used. They are displayed in the working area. Tune the ion
source while the measurement is running; optimize the peak shape and intensity by
changing the ion source parameters. Changed parameters are forwarded from the
calibration project to the device and accepted instantly.
107
QUADERA HTML Help
1. Open the start page: In the View menu, click Show Start Page.
3. Create a new calibration project: In the "Calibration and Tuning" list, double-click
Ion Source Tuning.qmt. This way you create a new calibration project based
on the selected template.
4. The new measurement project window appears. The working area displays the
calibration project.
Edit the recipe according to your needs (if necessary): Click the corresponding
tab in the working area selection.
Display the measuring data: Click the corresponding tab in the working area
selection.
NOTE:
You can start the measurement regardless whether the recipe editor or the
working area has been selected.
5. Start the measurement: In the device status view, click on the "Start" icon.
The connection to the device is automatically established. The device now
receives the parameters for the current measurement task. You can adjust the
chart layout while the measurement is running.
6. Optimize the peak shape and intensity: Change the ion source parameters in the
section of the calibration project during the measurement ("Ion Source" editor).
Changed parameters are accepted by the device instantly.
You will find the procedures to optimize the ion source potentials for the QMG700 with
QMA400/410/430 in the operating instructions BG 805983 BD/E.
Procedures to optimize the specific ion source types for the QMG220:
Crossbeam Ion Source
Grid Ion Source
SPM Ion Source
Open High Sensitivity Ion Source
Gastight High Sensitivity Ion Source
7. Stop the measurement: In the device status view, click on the "Stop" icon.
8. Close and save the measurement project. In the File menu, click Close. You are
requested if you want to save the measurement project. QUADERA suggests an
automatically generated file name that is based on date/time of the measurement and
the used template.
Yes: the "Save As" window used for saving measuring data opens up. Select a
suitable name and path and then click Save. The measurement project will be
saved and closed.
Please note: The file extension for measurement projects is *.qmp
No (recommended option): the measurement project will be closed without
saving the data.
Cancel: the action is cancelled. You will return to the measurement project
without saving the data.
108
QUADERA
NOTE: The filament Ion Source can be degassed from the Device Configuration
window.
109
QUADERA HTML Help
The "Ion Source" editor in the calibration project displays the parameters for tuning the
ion source. Modify the parameters directly in this editor. The device applies modified
parameters instantly.
A separate parameter set is stored for each ion source type and filament. The QMG220
additionally provides 4 parameter sets per ion source type, containing ion source
voltages ("Active Set").
110
QUADERA
111
QUADERA HTML Help
112
QUADERA
113
QUADERA HTML Help
1. Select the filament and operate it with 1 mA emission current for approximately
half an hour. The message "Emission Error" appears repeatedly: start with
reduced emission current and increase it slowly.
Default settings:
Emission 1
Current: mA
Protection 4.0
Current: A
RF-Polarity: pos
Ion Reference: 150
V
Cathode: -70
V
Focus: -5
V
Field Axis: -10
V
Extract: -50
V
3. Wait until the pressure reaches < 10-7 mbar and the residual gas spectrum remains
stable.
4. Introduce a test gas, such as air, into the recipient for a pressure of 10-6 mbar.
Otherwise, use the residual gas to perform the optimization procedure.
5. Repeatedly record spectra of the relevant peaks (e.g. 2534 m/e). Observe
intensity, resolution, and peak shape.
a. Check which "RF-Polarity" ("pos" or "neg") results in the better peak shape
and select this polarity.
114
QUADERA
115
QUADERA HTML Help
1. Select the filament and operate it with 2 mA emission current for approximately
half an hour. The message "Emission Error" appears repeatedly: start with
reduced emission current and increase it slowly.
Default settings:
Emission 2
Current: mA
Protection 4.0
Current: A
RF-Polarity: pos
Ion Reference: 150
V
Cathode: -90
V
Field Axis: -12
V
Vary the "Field Axis" potential to optimize sensitivity, peak shape, and resolution.
3. Wait until the pressure reaches < 10-8 mbar and the residual gas spectrum remains
stable.
4. Repeatedly record spectra of the relevant peaks (e.g. 2534 m/e). Observe
intensity, resolution, and peak shape.
116
QUADERA
1. Select the filament and operate it with 1 mA emission current for approximately
half an hour. The message "Emission Error" appears repeatedly: start with
reduced emission current and increase it slowly.
2. Introduce a process gas, such as argon, into the process chamber for a pressure
of 10-310-2 mbar.
3. Repeatedly record spectra of the relevant peaks (e.g. argon 3241 m/e).
Observe intensity, resolution, and peak shape.
Default settings:
Emission 1
Current: mA
Protection 3.5
Current: mA
Ion Reference: 105
V
Cathode: -
40.0
V
Focus: -2.0
V
Field Axis: -2.0
V
Extract: -60
V
117
QUADERA HTML Help
1. Select the filament and operate it with 2 mA emission current for approximately
half an hour ("Protection Current" at 3.5 A). The message "Emission Error"
appears repeatedly: start with reduced emission current and increase it slowly.
Default settings:
Emission 2
Current: mA
Protection 3.5
Current: A
RF-Polarity: pos
Ion Reference: 150
V
Cathode: -75
V
Focus: -5
V
Field Axis: -7
V
Extract: -50
V
3. Wait until the pressure reaches < 10-7 mbar and the residual gas spectrum remains
stable.
4. Introduce a test gas, such as air, into the recipient for a pressure of 10-6 mbar.
Otherwise, use the residual gas to perform the optimization procedure.
5. Repeatedly record spectra of the relevant peaks (e.g. 2534 m/e). Observe
intensity, resolution, and peak shape.
a. Check which "RF-Polarity" ("pos" or "neg") results in the better peak shape
and select this polarity.
118
QUADERA
119
QUADERA HTML Help
1. Select the filament and operate it with 1 mA emission current for approximately
half an hour ("Protection Current" at 3.5 A). The message "Emission Error"
appears repeatedly: start with reduced emission current and increase it slowly.
Emission 1 mA
Current:
Protection 3.5 A
Current:
RF-Polarity: pos
Ion 150 V
Reference:
Cathode: -60 V
Focus: -5 V
Field Axis: -7 V
Extract: -50 V
2. Repeatedly record spectra of the relevant peaks (e.g. 2534 m/e). Observe
intensity, resolution, and peak shape.
120
QUADERA
1. Select the filament and operate it with 1 mA emission current for approximately
half an hour ("Protection Current" at 3.5 A). When the message "Emission Error"
appears repeatedly start with reduced emission current and increase it slowly.
Emission 1 mA
Current:
Protection 3.5 A
Current:
RF-Polarity: pos
Ion 105 V
Reference:
Cathode: -40 V
Focus: -5 V
Field Axis: -6 V
Extract: -50 V
2. Repeatedly record spectra of the relevant peaks (e.g. 3542 m/e). Observe
intensity, resolution, and peak shape.
a. Check which "RF-Polarity" ("pos" or "neg") results in the better peak shape
and select this polarity.
121
QUADERA HTML Help
Basics
Gas components are represented by integer mass numbers. Typically, the measuring
apparatus causes small deviations between the nominal mass number and the actual
position of the peak maximum. The correct position of the peak maxima is usually close
to theoretical value, e.g. at 13.95 instead of 14.00. However, an exact measurement
requires measuring the peak maximum. To achieve best accuracy in measurements, the
exact position of the peak maxima has to be determined by calibrating the mass scale.
Procedure
QUADERA uses two steps to calibrate the mass scale:
Coarse tuning:
Two parameters are used to shift and to shrink or stretch the mass scale. This
coarse tuning will be applied to all measurements.
Fine tuning:
The fine tuning is based on the coarse tuning and compensates nonlinearity of
the mass scale by manually entering corrected mass values. This fine tuning is
applied to sample measurements and scan-stair measurements, and also to scan-
analog measurements with the QMG700.
Update Mass List Adds new masses from the Recipe into the Mass Adjust list. In
order to update the Mass Adjust list, masses must first be entered into the Recipe
as Measurement Tasks.
Remove Mass Removes a selected Mass from the Mass Adjust list. This action
has no effect on the Masses (Measurement Tasks) in the Recipe.
Apply to Mass Scale Table Downloads the changes made in Mass Scale Adjust to
the device Mass Scale Table. This action commits and saves the changes
determined by QUADERA (and the device) into the device.
Reset Mass Scale Table Resets all Actual Masses in the Mass Adjust list to their
respective Reference Mass.
State column The following states can occur when running Mass Scale Adjust:
Ok: The calibration has been successfully performed; the exact mass
numbers are shown in the column Actual Mass.
122
QUADERA
Mass number too low: The entered mass number is too far to the left of the
peak (i.e. too low in AMU).
Mass number too high: The entered mass number is too far to the right of the
peak (i.e. too high in AMU).
Peak Intensity below threshold: Intensity lower than the level defined by the
Threshold parameter.
Peak Intensity too high: Intensity equal to or higher than full scale range.
Peak width too narrow: The peak is too narrow to determine a maximum.
Mass number too low; intensity tail too high: Intensity is too constant to
determine a maximum.
Two scan analog measurements in various mass ranges are used for tuning of the mass
scale. The recipe parameters are defined in the calibration project for the mass scale.
Use the recipe editor to change the parameters. Normally, scanned masses range from
one up to many masses.
NOTE:
It is preferred that the two scans cover a mass range as wide as possible. One
peak should appear at a very low mass number, another one at a very high
mass number.
Scan recording begins when the calibration project is started. The currently set mass
scale parameters are applied and displayed in the working area. Perform the tuning
procedure during the course of the measurement: Modify the parameters to adjust the
peak positions to the nominal mass numbers. You can observe the effect of modified
parameters during the next cycle and iteratively tune the mass scale.
123
QUADERA HTML Help
1. Feed a suitable calibration gas into the vacuum chamber. Use air if special
calibration gases are not available.
2. Open the start page: In the View menu, click Show Start Page.
4. Only for QMG700: Reset the fine tuning data points before starting the coarse
tuning procedure of the mass scale. Fine tuning is applied to scan analog
measurements and will affect the coarse tuning.
5. Create a new calibration project: In the "Calibration and Tuning" list, double-click
e.g. Mass Scale Tuning (Coarse).qmt. This way you create a new calibration
project based on the selected template. You can modify it according to your
needs.
6. The new measurement project window appears. The working area displays the
calibration project.
Edit the recipe according to your needs (if necessary): Click the corresponding
tab in the working area selection,
Display the measuring data: Click the corresponding tab in the working area
selection.
NOTE:
You can start the measurement regardless whether the recipe editor or the
working area has been selected.
7. Start the measurement: In the device status view, click on the "Start" icon. The
connection to the device is automatically established. The device now receives the
parameters for the current measurement task. You can adjust the chart layout while the
measurement is running.
8. Adjust the actual peak positions to the nominal mass numbers: change the
parameters in the section of the calibration project ("Mass Scale Tuning" editor)
while the measurement is running. You can observe the effect of modified
parameters during the next measurement task and iteratively tune the mass
scale.
"Mass Scale Offset" shifts the mass scale,
"Mass Scale Slope" shrinks and stretches the mass scale.
8. Perform a fine tuning of the mass scale (if required). Otherwise, reset the fine tuning
values to the default values.
9. Stop the measurement: In the device status view, click on the "Stop" icon.
10. Close and save the measurement project. In the File menu, click Close. You
are requested if you want to save the measurement project. QUADERA
suggests an automatically generated file name that is based on date/time of the
measurement and the used template.
Yes: the "Save As" window used for saving measuring data opens up. Select a
suitable name and path and then click Save. The measurement project will be
124
QUADERA
NOTE:
The coarse tuning of the mass scale will be applied to all measurements.
125
QUADERA HTML Help
NOTE:
Perform the fine tuning of the mass scale exclusively within a coarse tuning
procedure.
1. Feed a suitable calibration gas into the vacuum chamber. Use air if special
calibration gases are not available.
2. Open the start page: In the View menu, click Show Start Page.
4. Create a new calibration project: In the "Calibration and Tuning" list, double-click
e.g. Mass Scale Tuning (Fine).qmt. This way you create a new calibration
project based on the selected template. You can modify it according to your
needs.
5. The new measurement project window appears. The working area displays the
calibration project.
Edit the recipe according to your needs (if necessary): Click the corresponding
tab in the working area selection.
Display the measuring data: Click the corresponding tab in the working area
selection.
NOTE:
You can start the measurement regardless whether the recipe editor or the
working area has been selected.
6. Start the measurement: In the device status view, click on the "Start" icon. The
connection to the device is automatically established. The device now receives the
parameters for the current measurement task. You can adjust the chart layout while the
measurement is running.
7. Define the data points for the linear interpolation of the mass scale ("Mass
Scale Tune Fine" editor):
b. Enter the measured mass number in the "Actual Mass" fields (use the cursor
to locate peak maximum).
9. Stop the measurement: In the device status view, click on the "Stop" icon.
126
QUADERA
10. Close and save the measurement project. In the File menu, click Close. You
are requested if you want to save the measurement project. QUADERA
suggests an automatically generated file name that is based on date/time of the
measurement and the used template.
Yes: the "Save As" window used for saving measuring data opens up. Select a
suitable name and path and then click Save. The measurement project will be
saved and closed.
Please note: The file extension for measurement projects is *.qmp
No (recommended option): the measurement project will be closed without
saving the data.
Cancel: the action is cancelled. You will return to the measurement project
without saving the data.
NOTE:
The fine tuning of the mass scale will be applied to MID/MCD measurements
and to scan-stair measurements, and also to scan-analog measurements with
the QMG700.
127
QUADERA HTML Help
Two parameters are used for coarse tuning, to shift and to shrink or stretch the mass
scale. This way you can match the actual peaks with the nominal mass numbers.
The "Mass Scale Tune Coarse" editor in the calibration project displays the parameters
for coarse tuning of the mass scale. Modified parameters are forwarded to the device
and take effect in the next measurement cycle.
Mass Scale -0.12 < Offset Shift the mass scale to the left and
Offset < 0.12 right for negative and positive values,
respectively.
Mass Scale 0.985 < Slope < Shrink and stretch the mass scale for
Slope 1.015 values < 1.000 and > 1.000,
respectively.
128
QUADERA
129
QUADERA HTML Help
The fine tuning is based on the coarse tuning and compensates nonlinearity of the mass
scale. You have to perform the fine tuning when the coarse tuning has been changed.
Modified parameters are forwarded to the device and take effect in the next
measurement cycle.
Data points on the mass scale have to be input for the fine tuning. These points are
used for linear interpolation of mass numbers located in between. The "Mass Scale Tune
Fine" editor lists the data points in a table. Use the context menu of this editor to delete
data points.
Delete selected rows: Delete the selected rows, i.e. remove the data points.
130
QUADERA
131
QUADERA HTML Help
Offset
Offset
Basics
The offset is caused by a drift of the measuring amplifier and can be compensated by a
correction measurement. The measured intensity will be applied to future measurement
projects by subtracting it from the results of the corresponding measurement tasks. You
cannot switch on and off the offset values for saved data.
Procedure
The measurement of the offset is performed by the device automatically. However, there
is no real measurement. Instead, the offset of the electronic circuit of the measuring
amplifier is determined for each measuring range at a defined mass number. The values
are automatically stored in the device and will remain after the power has been cut.
132
QUADERA
NOTE:
Determine the offset for the electrometer preamplifier and detector, which you
intend to use in the subsequent measurement:
QMG220: one electrometer preamplifier is used with both detectors (if
installed), i.e. there is only one set of offset values,
QMG700: individual electrometer preamplifiers are used with both
detectors (if installed), i.e. there are two different sets of offset values.
1. Open the start page: In the View menu, click Show Start Page.
3. Create a new calibration project: In the "Calibration and Tuning" list, double-click
e.g. Offset Calibration.qmt. This way you create a new calibration project
based on the selected template. You can modify it according to your needs.
4. The new measurement project window appears. The working area displays the
calibration project.
5. Only QMG700:
Select the detector corresponding to the measuring amplifier ("Electrometer
Preamplifier") whose offset is to be determined:
Faraday,
SEM.
7. Start the measurement: In the device status view, click on the "Start" icon. The
connection to the device is automatically established. The device now receives the
parameters for the current measurement task. The measurement runs automatically and
should take about 1015 s.
8. QUADERA calculates the necessary offset values. The values are automatically
stored for the individual measuring ranges of the amplifier and applied to future
measurement projects.
9. Close and save the measurement project. In the File menu, click Close. You
are requested if you want to save the measurement project. QUADERA
suggests an automatically generated file name that is based on date/time of the
measurement and the used template.
Yes: the "Save As" window used for saving measuring data opens up. Select a
suitable name and path and then click Save. The measurement project will be
saved and closed.
Please note: The file extension for measurement projects is *.qmp
No (recommended option): the measurement project will be closed without
saving the data.
Cancel: the action is cancelled. You will return to the measurement project
without saving the data.
133
QUADERA HTML Help
Offset Parameters
The calibration project displays the parameters required to determine the offset.
Modified parameters are forwarded to the device and take effect in the next
measurement task.
134
QUADERA
Basics
The high frequency voltage of the RF generator (QMH, or RF22x for QMG220, see device
settings) is applied to the rod pairs of the QMG to separate ions. The output resonant
circuit of the generator has to be matched to the QMG rod system in the following cases:
problems appear when masses near the upper mass scale limit are measured.
Procedure
Tuning the RF generator requires to turn the tuning screw. The calibration project in
QUADERA is used to display and check the tuning voltage.
NOTE:
Use the device specific instructions (OEM manual) when tuning the RF
generator.
135
QUADERA HTML Help
NOTE:
Use the device specific instructions (OEM manual) when tuning the RF
generator.
1. Open the start page: In the View menu, click Show Start Page.
3. Create a new calibration project: In the "Calibration and Tuning" list, double-click
RF Tuning.qmt or Tune Data.qmt. This way you create a new calibration
project based on the selected template.
1. The new measurement project window appears. The working area displays the
calibration project. Note:
No recipe is assigned to this calibration project (RF Tuning.qmt). Thus, no
user specific adaptation is available.
An actual measurement is not performed, i.e. you can not start and stop the
measurement.
NOTE:
Do not damage the tuning screw of the generator. Never tighten or remove the
tuning screw.
6. Close and save the measurement project. In the File menu, click Close. You
are requested if you want to save the measurement project. QUADERA
suggests an automatically generated file name that is based on date/time of the
measurement and the used template.
Yes: the "Save As" window used for saving measuring data opens up. Select a
suitable name and path and then click Save. The measurement project will be
saved and closed.
Please note: The file extension for measurement projects is *.qmp
No (recommended option): the measurement project will be closed without
saving the data.
Cancel: the action is cancelled. You will return to the measurement project
without saving the data.
136
QUADERA
137
QUADERA HTML Help
NOTE:
Use the device specific instructions (OEM manual) when tuning the RF
generator.
1. Open the start page: In the View menu, click Show Start Page.
3. Create a new calibration project: In the "Calibration and Tuning" list, double-click RF
Tuning.qmt or Tune Data.qmt. This way you create a new calibration project based on
the selected template.
4. The new measurement project window appears. The working area displays the
calibration project. Note:
No recipe is assigned to this calibration project. Thus, no user specific
adaptation is available.
An actual measurement is not performed, i.e. you can not start and stop the
measurement.
5. The QMH is set to the maximum mass number in RF Tuning.qmt. Tune the
output resonant circuit as described in the instructions of the RF generator.
NOTE:
Do not damage the tuning screw of the generator. Never tighten or remove the
tuning screw.
6. Close and save the measurement project. In the File menu, click Close. You are
requested if you want to save the measurement project. QUADERA suggests an
automatically generated file name that is based on date/time of the measurement and
the used template.
Yes: the "Save As" window used for saving measuring data opens up. Select a
suitable name and path and then click Save. The measurement project will be
saved and closed.
Please note: The file extension for measurement projects is *.qmp
No (recommended option): the measurement project will be closed without
saving the data.
Cancel: the action is cancelled. You will return to the measurement project
without saving the data.
138
QUADERA
Background Determination
Background Determination
Basics
The mass spectrometer background is caused by residual gases. These gases are
present in every analysis chamber and do not originate from the measuring sample. The
background is mainly constant if the measuring apparatus is well conditioned. However,
measurement results may be distorted if the background is not considered properly. The
background determination identifies the existing residual gases. The detected ion
currents are subtracted from subsequent measurement projects. The result will show the
true composition of the measuring gas.
Procedure
Residual gases are measured either with the gas inlet closed or by using a zero gas, i.e.
a pure gas that is fed into the analysis chamber to reach the same pressure as expected
for future measurements. Using a zero gas takes account of adsorption and desorption
effects better than pumping down the chamber to final vacuum.
An MID measurement is used to determine the background. The recipe parameters are
defined in the corresponding calibration project. Use the recipe editor to change the
parameters. You can determine the mass spectrometer background for each detector
type separately and store the results in the Background Library. The stored values will
be used in future MID and MCD measurement projects where they are subtracted from
the measured signals.
NOTE:
Always pump down the chamber to final vacuum before performing the
background determination, or let in a suitable zero gas. Otherwise, serious
measurement errors may result.
139
QUADERA HTML Help
NOTE:
Before starting the measurement, check the correct calibration of the mass
spectrometer components. If a calibration is necessary, perform the following
preparatory measurements:
Calibrate the mass scale,
Determine the offset.
1. Feed a suitable zero gas into the vacuum chamber, or pump the chamber down
to final vacuum.
2. Open the start page: In the View menu, click Show Start Page.
5. The new measurement project window appears. The working area displays the
calibration project.
Edit the recipe according to your needs (if necessary): Click the corresponding
tab in the working area selection.
The measurement tasks must not contain mass numbers where peaks of the
zero gas appear.
Display the measuring data: Click the corresponding tab in the working area
selection.
NOTE:
You can start the measurement regardless whether the recipe editor or the
working area has been selected.
6. Start the measurement: In the device status view, click on the "Start" icon.
The connection to the device is automatically established. The device now
receives the parameters for the current measurement task. The measurement is
running automatically.
7. Check the measured values, e.g. display the measuring data in a table.
9. Close and save the measurement project. In the File menu, click Close. You are
requested if you want to save the measurement project. QUADERA suggests an
automatically generated file name that is based on date/time of the measurement and
the used template.
Yes: the "Save As" window used for saving measuring data opens up. Select a
suitable name and path and then click Save. The measurement project will be
140
QUADERA
NOTE:
The data sets in the Background Library will be subtracted in MID and MCD
measurements. If you wish to skip this subtraction then reset the data sets in
the Background Library ("Delete Background Library" button). Background
Subtraction can also be disabled, without resetting the Background Library,
from the context menu when running a Measurement Project.
141
QUADERA HTML Help
Background Library
The Background Library in the section of the calibration project displays the parameters
required to determine the background. Changed parameters take effect in the next
measurement task.
The Background Library contains the corresponding background data for all measured
mass numbers in tabular form. You can use various zero gases and perform consecutive
background determinations. The results can be combined in the Background Library
(function "Apply to Background Library"). Note that an individual Background Library is
created for each installed detector.
142
QUADERA
Library
NOTE:
"Delete Background Library"
deletes the data sets of the
Background Library irretrievably.
In this case, a new background
determination is required for new
data sets.
143
QUADERA HTML Help
144
QUADERA
NOTE:
Perform the following preparatory measurements before the gas specific
calibration:
Calibrate the mass scale,
Determine the offset,
Determine the background.
Basics
An MCD measurement project uses a matrix of calibration factors (analysis matrix) to
convert ion currents into gas concentrations. The calibration factors are not universally
valid. They have to be quantified by a separate calibration measurement using known
gases (calibration gases). Calibration gases are selected according to the components in
the measurement project whose concentrations are to be measured.
NOTE:
Gas mixtures that contain components with overlapping masses are not suited
for use as calibration gas. The same mass number must not be assigned to
several components.
Procedure
One MID measurement project is created per calibration gas. The recipe parameters
include the mass numbers of the calibration gas components and can be modified in
the recipe editor. The "GSC Matrix" editor specifies the concentration of each calibration
gas component and its contribution on the related mass number. The gas specific
calibration factors are required for the actual MCD measurement project. They are
determined in the calibration project (GSC Result View) and saved in the MCD
Calibration Factor Library.
145
QUADERA HTML Help
NOTE:
Before starting the measurement, check the correct calibration of the mass
spectrometer components. If calibration is necessary, perform the following
preparatory measurements:
Calibrate the mass scale,
Determine the offset.
Determine the background.
NOTE:
Gas mixtures that contain components with overlapping masses are not suited
for use as calibration gas. The same mass number must not be assigned to
several components.
2. Open the start page: In the View menu, click Show Start Page.
4. Create a new calibration project: In the "Templates" list, double-click e.g. Gas
Specific Calibration.qmt. This way you create a new calibration project based
on the selected template. You can modify it according to your needs.
5. The new measurement project window appears. The working area displays the
calibration project.
Edit the recipe according to your needs (if necessary): Click the corresponding
tab in the working area selection.
Display the measuring data: Click the corresponding tab in the working area
selection.
6. Input the parameters which define the calibration gas in the "GSC Matrix" editor.
Use the commands of the related context menu to edit the measurement
tasks and masses.
Note: Use an identical name for the gas component in an MCD project.
Otherwise, QUADERA cannot refer to this component. As an example,
QUADERA does not equate "O2" and "Oxygen".
NOTE:
You can start the measurement regardless whether the recipe editor or the
working area has been selected.
7. Start the measurement: In the device status view, click on the "Start" icon.
The connection to the device is automatically established. The device now
receives the parameters for the current measurement task. The measurement is
running automatically.
8. In the GSC Result View, check the measured values and the calculated calibration
factors.
9. Click Apply to MCD Calibration Factor Library to save the calibration factors in
the MCD calibration factor library. Note:
146
QUADERA
New calibration factors are added to the MCD Calibration Factor Library,
Current values replace existing data sets in the MCD Calibration Factor
Library.
10. When required for future applications: save the calibration project as template
(menu File > Save as Template).
11. Close and save the measurement project. In the File menu, click Close. You are
requested if you want to save the measurement project. QUADERA suggests an
automatically generated file name that is based on date/time of the measurement and
the used template.
Yes: the "Save As" window used for saving measuring data opens up. Select a
suitable name and path and then click Save. The measurement project will be
saved and closed.
Please note: The file extension for measurement projects is *.qmp
No (recommended option): the measurement project will be closed without
saving the data.
Cancel: the action is cancelled. You will return to the measurement project
without saving the data.
147
QUADERA HTML Help
The parameters that define the calibration gas are displayed in the "GSC Matrix" editor
of the calibration project. Each calibration gas component is defined by its name,
concentration, and the measurement task(s). Use the "Add MCD Task" tool to add a new
component (measurement task).
148
QUADERA
Delete selected Component: delete the marked measurement task (table row)
from the "GSC Matrix" editor.
Delete selected Mass: delete the marked mass (table column) from the "GSC
Matrix" editor.
Set as internal standard: set the internal standard for the calibration factors.
Proceed as follows to set the internal standard for the calibration factors:
1. Open the context menu in the table element related to the mass/component pair
you want to set as internal standard.
2. Click Set as internal standard. The table element for the internal standard
appears with a red background color.
149
QUADERA HTML Help
150
QUADERA
The parameters required to determine the calibration factors are displayed in the "GSC
Result View" of the calibration project.
The "GSC Result View" displays the calibration factors in a tabular form. They are
calculated for all measurement tasks of the MID recipe, using the corresponding
measured data. In the course of time you can extend and complete the MCD Calibration
Factor Library (function "Apply to MCD Calibration Factor Library") by using various
calibration gases to determine the calibration factors.
NOTE:
New calibration factors are added
to the MCD Calibration Factor
Library,
Current values replace existing
data sets in the MCD Calibration
Factor Library.
151
QUADERA HTML Help
152
QUADERA
Measuring the concentration of the components of a gas mixture requires that the
corresponding calibration factors are known. These are stored in the MCD Calibration
Factor Library, in tabular form. Each calibration factor is defined in the related
calibration project by the mass number and the name of the corresponding component.
The calibration factors are quantified relatively. This requires to set one calibration factor
as the internal standard. Normally, the calibration factor for N 2 (m/e = 28) is used and
set to 1 (standard setting). The other calibration factors relate to the standard. This
approach allows you to create a consistent MCD Calibration Factor Library. Use the
context menu of the "GSC Matrix" editor to set the internal standard.
2. Apply the new calibration factors to the MCD Calibration Factor Library:
In the section of the calibration project, click Apply to MCD Calibration Factor
Library.
1. Click Delete MCD Calibration Factor Library to remove all data sets from the
MCD calibration factor library.
NOTE:
"Delete MCD Calibration Factor Library" deletes the data sets of the MCD
Calibration Factor Library irretrievably. In this case, a new gas specific
calibration is required for new data sets.
153
QUADERA HTML Help
154
QUADERA
The Device Sensitivity must be determined for the device to display Partial Pressure.
155
QUADERA HTML Help
An Offset Calibration must have been executed at some point. QUADERA will
check to see if this has been done.
A SEM Amplification Calibration must have been executed at some point. This
determines the gain of the SEM.
The Sensitivity must be determined for the device using the Sensitivity
Determination measurement project. A default Sensitivity is available but is not
as accurate as a Sensitivity determined by QUADERA for the specific device.
156
QUADERA
Measurement projects
A measurement project contains the measuring data as well as an image of the device
required for displaying the measuring data correctly.
157
QUADERA HTML Help
In scan-analog measurement projects you can also add analog input tasks (e.g. via
quadrupole controller QC, "EXT IN").
Scan-analog also allows for capturing and comparing a reference scan if using a
reference-based measurement project.
A separate measurement project - Bargraph Cycles - can be used to plot analog scans
against time.
NOTE:
A precise measurement requires the correct calibration of the components of
the mass spectrometer.
NOTE:
For a written documentation of your measurement projects you can capture
screens of the QUADERA user interface. Reports can also be printed from a
selection on the context menu.
158
QUADERA
In an MID measurement (Multiple Ion Detection) you specify distinct m/e values for
which the ion current is to be measured. Only the specified mass numbers are scanned
in this case. Each of these mass numbers is represented by a separate measurement
task for which all parameters can be set.
Changes in the gas composition with time can be recorded and displayed easily. An
additional analysis of the measuring data allows you to convert the results into
concentrations given in %, ppm, etc (MCD measurement).
The Sensitivity of the instrument is the ratio of the ion current measured for a
given mass to the partial pressure of a gas.
Partial Pressure also uses a Calibration Factor, which is the ratio of the total ion
current (at all masses) produced from a given partial pressure of that substance,
to the total ion current produced from nitrogen at the same partial pressure. The
Calibration Factor(s) depends strongly on the energy of the ionizing electrons. If
the correct values of the Calibration Factors are not known for the exact
conditions of the particular analyzer being used, they can be approximated using
published relative ion gauge sensitivities for various gases.
If the SEM voltage is changed after SEM Amplification and Sensitivity have been
determined then Partial Pressure calculations will be less accurate. If changing
the SEM voltage, it is best to calibrate the SEM Amplification and determine the
Sensitivity again before using Partial Pressure.
NOTE: Setting or changing the partial pressure units requires one full scan
through the MID measurement tasks to correctly update the chart.
NOTE:
A precise measurement requires the correct calibration of the components of
the mass spectrometer.
NOTE:
For a written documentation of your measurement projects you can capture
screens of the QUADERA user interface. Reports can also be printed from a
selection on the context menu.
159
QUADERA HTML Help
NOTE:
A precise measurement requires the correct calibration of the mass
spectrometer components.
2. Open the start page: In the View menu, click Show Start Page.
4. Create a new MCD measurement project: In the "Templates" list, double-click the
desired measurement project template. This way you create a new measurement project
based on the selected template.
5. The new measurement project window appears. The working area displays
the MCD project.
Edit the MCD recipe if necessary: click the corresponding tab in the working
area selection,
Display the measuring data: click the corresponding tab in the working area
selection.
NOTE:
You can start the measurement regardless whether the recipe editor or the
working area has been selected.
6. Start the measurement: In the device status view, click on the "Start" icon. The
connection to the device is automatically established. The device now receives the
parameters for the current measurement task. You can adjust the chart layout while the
measurement is running.
7. Stop the measurement: In the device status view, click on the "Stop" icon.
8. Close and save the measurement project. In the File menu, click Close. You
are requested if you want to save the measurement project. QUADERA
suggests an automatically generated file name that is based on date/time of the
measurement and the used template.
160
QUADERA
Yes: the "Save As" window used for saving measuring data opens up. Select a
suitable name and path and then click Save. The measurement project will be
saved and closed.
Please note: The file extension for measurement projects is *.qmp
No: the measurement project will be closed without saving the data.
Cancel: the action is cancelled. You will return to the measurement project
without saving the data.
NOTE:
For a written documentation of your measurement projects you can capture
screens of the QUADERA user interface. Reports can also be printed from a
selection on the context menu.
161
QUADERA HTML Help
Use the recipe editor to add the measurement task "Total Pressure" to the measurement
project. The measured data (total pressure in the vacuum system) are displayed and
saved. Besides, the course of a measurement corresponds to the selected measurement
project.
Further notes
Pay attention to the following items when measuring the total pressure:
The pressure gauge is not permanently switched on because the plasma in the
gauge influences the gas composition in the recipient. Exception: monitoring the
QMG.
Note that igniting the pressure gauge and displaying the correct pressure will
take some time (refer to the operating instructions for the pressure gauge).
NOTE:
For a written documentation of your measurement projects you can capture
screens of the QUADERA user interface. Reports can also be printed from a
selection on the context menu.
162
QUADERA
1. Use e.g. the start page to open an existing measurement project template, or an
existing measurement project.
2. Use the recipe editor to modify the recipe parameters according to your needs.
3. Use the toolbox to change the working area according to your needs.
4. In the File menu, click Save As Template.... Select the path for the
measurement project template, and input the file name.
Note:
By default, the path set in the options is used for new measurement project
template,
163
QUADERA HTML Help
Recipes
Recipes
A recipe contains a sequence of measurement tasks. Use the recipe editor to change the
recipe parameters.
In an MID measurement (Multiple Ion Detection) you specify distinct m/e values
for which the ion current is to be measured. Only the specified mass numbers are
scanned in this case. Each of these mass numbers is represented by a separate
measurement task for which all parameters can be set.
Changes in the gas composition with time can be recorded and displayed easily.
An additional analysis of the measuring data allows you to convert the results
into concentrations given in %, ppm, etc. (MCD measurement).
In MID measurement projects you can also add total pressure measurement
tasks (for the QMG220, if a pressure gauge is installed) and analog input tasks
(AI).
NOTE:
New or modified parameters for the measurement tasks are accepted by the
device only after the measurement has been restarted.
164
QUADERA
Recipe Editor
In the working area selection, click the corresponding tab. The recipe parameters for the
active recipe are displayed in the section in tabular form (recipe editor). The columns
represent the measurement tasks and the rows represent the recipe parameters.
Editing parameters
Proceed as follows to edit a parameter:
2. Drag&Drop the measurement task to the required position. A red arrow indicates
the insert position.
2. On the keyboard, click the Del key (delete), or use the context menu. When the
measurement task contains data a requester appears and queries you to approve
deleting.
165
QUADERA HTML Help
NOTE:
New or modified parameters for the measurement tasks are accepted by the
device only after the measurement has been restarted.
166
QUADERA
NOTE:
New or modified parameters for the measurement tasks are accepted by the
device only after the measurement has been restarted.
Task Name
First Mass
Width
Speed
Dwell
Mass Mode
Detector Type
AI Channel
Gain (only QMG700)
SEM Voltage
CP-Level (only QMG700)
Autorange Mode
Detector Range
Range Limit
Analog Signal Filter (only QMG700)
Resolution
Pause Calibrate
AO Channel
AO Mode (only QMG220)
AO Range (only QMG220)
Trip Type
Level A
DO# A
Level B
DO# B
State
167
QUADERA HTML Help
168
QUADERA
Type
AI Channel Dropdown list Number of the analog input for
measuring data (only relevant for
detector type AI in analog input
measurement tasks).
Gain Dropdown list Parameter valid only for QMG700
Measuring range for the analog input
of the QC (only relevant for detector
type EXT_IN_# in analog input
measurement tasks).
SEM Voltage Number > 0 Operating voltage for the SEM.
Enter the required value or use the
spin buttons.
The value "0" means that the common
SEM voltage is applied. It is displayed
and set in the device status view.
CP-Level Number > 0 Parameter valid only for QMG700
Response threshold of the ion counter
preamplifier.
Autorange Dropdown list In QUADERA, the amplifier
Mode measuring range can be fixed or
adjusted automatically.
FIX:
You can select the measuring range
under Amplifier Range.
AUTO:
The measuring range is selected
automatically from all possible
ranges.
AUTO-DOWN:
The measuring range is selected
automatically from all ranges
located between the largest (least
sensitive) range and the Range
Limit.
Detector Dropdown list Measuring range for the ion current
Range (only relevant for Autorange
Mode=FIX)
Range Limit Dropdown list Most sensitive measuring range for the
ion current (only relevant for
Autorange Mode=AUTO-DOWN)
Analog Signal Dropdown list Parameter valid only for QMG700
Filter
Time constant of analog filter.
169
QUADERA HTML Help
170
QUADERA
171
QUADERA HTML Help
NOTE:
New or modified parameters for the measurement tasks are accepted by the
device only after the measurement has been restarted.
Task Name
Mass
Dwell
Detector Type
AI Channel
Gain (only QMG700)
SEM Voltage
CP-Level (only QMG700)
Autorange Mode
Detector Range
Range Limit
Analog Signal Filter (only QMG700)
Resolution
Pause Calibrate
AO Channel
AO Mode (only QMG220)
AO Range (only QMG220)
Trip Type
Level A
DO# A
Level B
DO# B
State
172
QUADERA
173
QUADERA HTML Help
Mode=FIX)
Range Limit Dropdown list Most sensitive measuring range for the
ion current (only relevant for
Autorange Mode=AUTO-DOWN)
Analog Signal Dropdown list Parameter valid only for QMG700
Filter
Time constant of analog filter.
Resolution Integer number Mass resolution (small number = clear
>0 separation of peaks). Typical values
are approx. 25 for QMG700, and
approx. 50 for QMG220.
Enter the required value or use the
spin buttons.
Pause Number > 0 A factor used to multiply the pause
Calibrate time determined in the device. In
order to wait for transient effects, no
measurements are performed during
the pause time between two
measurement tasks.
Enter the required value or use the
spin buttons.
AO Channel Dropdown list Number of the analog output.
Measured values are output to this AO.
AO Mode Dropdown list Parameter valid only for QMG220
Scales the measurement signal output
(010 V). Parameter valid only for
specified AO Channel.
AO Range Dropdown list Parameter valid only for QMG220
Adjusts the measurement range to the
maximum measured signal output.
Parameter valid only for specified AO
Channel.
Trip Type Dropdown list The trip function can monitor
measurement values of MID- and MCD
measurements, total pressure
measurements, and analog input
measurements (AI). Each
measurement task provides two trip
functions, A and B, and the related
threshold values, Level A and Level B.
The trip function results are sent to the
output Bits DO# A and DO# B.
OFF:
The trip function is switched off.
ABS:
174
QUADERA
175
QUADERA HTML Help
NOTE:
New or modified parameters for the measurement tasks are accepted by the
device only after the measurement has been restarted.
The rows of the analysis matrix are defined by the name of the gas components
for the quantitative analysis.
Use the "Add MCD Task" tool to add a row (gas component) to the matrix.
NOTE:
In the MCD project, use identical names for the gas components as used in the
gas specific calibration. Otherwise, QUADERA cannot refer to the components.
As an example, QUADERA does not equate "O2" and "Oxygen".
The columns of the analysis matrix are defined by the measurement recipe, and
correspond to the mass numbers in the measurement tasks.
The individual matrix elements represent the gas specific calibration factors for
the quantitative gas analysis. The calibration factors are determined in the gas
specific calibration and stored in the MCD Calibration Factor Library.
176
QUADERA
NOTE:
New or modified parameters for the measurement tasks are accepted by the
device only after the measurement has been restarted.
Task Name
Dwell
Detector Type
Trip Type
Level A
DO# A
Level B
DO# B
State
177
QUADERA HTML Help
HYST:
Use the trip function "HYST" to
prevent permanent switching for
fluttering signals. Read further
information.
Level A Number Threshold value A (available only for
trip types ABS and HYST).
DO# A Integer number Digital output Bit. The result of the trip
>0 function is output to this DO (available
only for trip types ABS and HYST).
Level B Number Threshold value B (available only for
trip types ABS and HYST).
DO# B Integer number Digital output Bit. The result of the trip
>0 function is output to this DO (available
only for trip type ABS).
State Dropdown list Status of the measurement task.
ENABLE:
The measurement task is being
measured and the parameters are
being saved.
SKIP:
The measurement task is not being
measured, but the parameters are
preserved.
178
QUADERA
Vacuum monitoring,
Windows comparator.
Vacuum monitoring
Requires just the trip function Trip A. Proceed as follows to use the trip function for
vacuum monitoring in MID and MCD measurement projects:
3. Set the digital output Bit "DO# A". The result of the trip function is output to
DO# A.
The trip function ABS-Trip A switches on when the signal falls below Level A.
3. Set the digital output Bit "DO# B". The result of the trip function is output to
DO# B.
The trip function ABS-Trip B switches on when the signal exceeds Level B.
179
QUADERA HTML Help
Windows Comparator
Requires the two trip function Trip A and Trip B. Proceed as follows to use the trip
functions as comparator in MID and MCD measurement projects:
4. Set identical values to the digital output Bits "DO# A" and "DO# B", i.e. DO#
A:xx and DO# B:xx. The two trip functions are conjoined (logical operator AND).
The trip function ABS switches on when the signal is in the range between the threshold
values Level B and Level A.
180
QUADERA
Use the trip function "HYST" (hysteresis) to prevent permanent switching for fluttering
signals.
This requires just the trip function Trip A. Proceed as follows to use the hysteresis trip
function "HYST" in MID and MCD measurement projects:
4. Set the digital output Bit "DO# A". The result of the trip function is output to
DO# A.
The trip function HYST switches on when the signal falls below Level A, and it switches
off when the signal exceeds Level B.
181
QUADERA HTML Help
Minimum
Action
Return the smallest measuring value found in the selected part of the measuring curve:
182
QUADERA
Average
Action
Calculate the average value for all measuring values located in the selected part of the
measuring curve:
183
QUADERA HTML Help
Maximum
Action
Return the largest measuring value found in the selected part of the measuring curve:
184
QUADERA
Action
Calculate the absolute standard deviation for all measuring values located in the selected
part of the measuring curve:
185
QUADERA HTML Help
Automating Tasks
The purpose of the Triggered Run Add-in (installed with QUADERA 4.40) is to provide a
QUADERA Add-in that automates the execution of multiple QUADERA operations. These
operations include loading a Template, running the associated Measurement Project,
saving its data, and then exporting that data into an ASCII file. These operations are
combined into what is referred to as a Triggered Run Task. The Add-in has the ability to
create and configure a list of these tasks prior to run time. The Add-in also manages
configuration of the execution of this task list by means of digital input triggering.
Allows multiple Triggered Run Tasks, where each task can be configured so that:
A Template can be selected.
The Save Files can be defined. (Save file is of type .qmp, and the exported
ASCII file will have the same name, with the .asc extension.)
The Filament can be turned on or off.
The SEM can be turned on or off.
Allows the user to select the Digital Input to be used as the Trigger.
Allows the user to select the how the Digital Input should be used:
The QMG can run when the Digital Input switches on and then stop when it
switches off.
The QMG can run when the Digital Input switches off and then stop when it
switches on.
Allows automatic preparation of the system, so that all Measurement Files have
been opened and the QMG is ready to run.
This sequence of steps should be followed to run the Triggered Run Add-in:
Select QMG In the list labeled Select QMG choose the QMG to be used for the
run. Only one QMG can be selected for a run.
Configure the Task List A Task is an operation that uses a given template to
open a Measurement File, configures the QMG Filament and SEM, runs that QMG
and then finally saves and exports the associated data.
186
QUADERA
Add New Using the text boxes under the list view, define the parameters of
a new Task.
Template Enter the name of an existing template stored in the
default template directory, including .qmt extension, or use the browse
button to navigate to the desired template.
Save As Enter in the name to give the saved Measurement File,
including extension .qmp. This entered File name will also be used to
save the exported ASCII file, but it will use the .asc extension instead.
Filament Check Filament if it is desired for this task to be run with
the filament turned on.
SEM Check SEM if it is desired to run this task with the SEM turned
on.
Click Add Task and a new row will be added to the table with the
parameters as defined above.
Update Task When a task is selected in the table, the fields for editing
are automatically filled. The user can modify any or all of the fields and
then click the Update Task button. The selected row will be updated
with the new values.
Delete Task When one or more rows are selected in the table, and the
Delete task button is clicked, those rows will be removed.
Configure the Run The Run (i.e. how all tasks will be executed) can be
configured by the controls in the group labeled Manage Running of Tasks.
Connect Connect executes the task of making a connection between
QUADERA and the QMG device. You must connect prior to configuring the
Run. Certain information is only available after connection. If the Button
says Connect then you must connect to the selected QMG. If the button
says Disconnect then the QMG is already connected and you are ready to
configure.
Run while DI On indicates that the user wants each task to start and run
when the Digital Input indicated changes state to On (if checked) or Off (if
not checked).
If Run while DI On is checked, then when the Digital Input changes
to On, the next task will begin running. When that Digital Input
changes to Off, it will stop the task from running.
If Run while DI On is not checked, then when the Digital Input
changes to Off, the next task will begin running. When that Digital
Input changes to On, it will stop the task from running.
Run while DI On is used for immediately starting the run if the start
condition is true. After clicking the Start button, the run will begin with out
waiting for a change in the Digital Input.
Digital Input to watch is a list ranging from 1 to the number of Digital
Inputs in the QMG device This indicates which Digital Input will be used as
the trigger for the run.
Reload when Finished indicates that the scheduled run will be reloaded after
completing the previous run. The next run is loaded, but it will not start
watching for triggers until the Start button has been clicked. The next set
187
QUADERA HTML Help
of files will have their name appended with an index (#). This will
increment and the runs will continue reloading until the Add-in has been
dismissed.
Restart after Reload will be enabled if Reload when Finished has been
checked. Using Restart after Reload skips the need for the user to click on
Start after each run. The Add-in will immediately begin watching for
triggers as soon as it has completed reloading.
Start Click Start after both the tasks and the Run have been
configured. This will tell the Add-in to begin loading Measurement Files and to
prepare for the Run. The Add-in will begin watching for value changes on the
selected Digital Input. When that Digital Input changes value it triggers the Add-
in to take action by either starting or stopping the current Task. By using these
Triggers, the Add-in starts and stops each Task, iterating through the list until
they have all been executed.
Stop Once the Start button has been clicked, the button text will change to
Stop. Clicking the button at this point will manually stop the run.
Completion of the run When the run has been completed, the Add-in will
automatically save the data file and export the data.
188
QUADERA
Scripting
Scripting
Scripting has been integrated into the host application, enabling the user to adapt the
functions of the application to his or her needs. Scripting always requires the host
application in order to be executed.
The Visual Studio Tools for Applications (VSTA) development system is suited to
customize applications by using the .NET framework. VSTA replaces Visual Basic for
Applications (VBA) and uses Visual Studio as the IDE.
With scripting, you can develop your own solutions to problems and in this way
automate and extend the functions of the application. You can develop solutions that
extend the functions of your application and that may be used again and again. By
integrating VSTA, QUADERA provides the user with a widely used and supported
programming environment.
NOTE:
For further information on scripting and the programming environment, please
refer to the help file for Microsoft Visual Studio Tools for Applications. Use
the Help menu of the VSTA editor.
NOTE:
The help system for the scripting functions within QUADERA explains the
extended instruction set and the corresponding syntax.
NOTE:
The QUADERA Release Notes ("Readme.html" file) provide a description of
"Saving VBA code for reprogramming in VSTA" to support users who have been
working with VBA up to now.
189
QUADERA HTML Help
File types
A scripting add-in contains the following file types:
Add-in DLL:
.Net assembly which contains the compiled add-in code (*.dll),
Source code:
These are the files which allow the user to view, edit and compile the add-in. The
main file is a "Visual Basic .Net" project (*.vbproj) which then contains links to
other files such as VB.Net code (*.vb).
Directories
Scripting add-ins are stored by default in the directory "My Documents\My
Quadera\Scripting":
The sub-directory "Code" contains the source code files. Each add-in is stored in
a separate directory.
Example
The following table shows an example file structure for an add-in with the name
"Sample":
(directories appear in normal type, files in italics)
Scripting
MeasureProjectAddIns Sample.dll
Code
Sample Sample.vbproj
ThisMeasureProject.vb
Note that you can change the file location of the scripting directory.
190
QUADERA
Copying Add-ins
a. Create a new directory under "Code" with the name of the add-in
(without the DLL extension!).
191
QUADERA HTML Help
Deleting Add-ins
NOTE:
Add-ins can be used by more than one measurement project. Care should be
taken when deleting an add-in.
2. If source code is also available: Remove the directory with the add-in name from
the "Code" directory.
192
QUADERA
Using Macros
In VSTA, an add-in can include more than one function. Each function can be considered
as a macro and an add-in as "macro collection". Thus, you have two options to create a
new macro:
Edit an existing add-in to include a new function that can be used as macro,
Create a new add-in and program a function that can be used as macro.
3. In the submenu, select Create Add-in. The "Create Add-in" window opens up.
5. Click [OK]. The VSTA editor opens up. Now you can create the new add-in:
VSTA automatically creates the basic structure of the add-in that is
executable without any functions,
Then you can program your own functions to expand the add-in.
QUADERA stores each add-in in a main scripting directory. When required the add-ins
are available for all measurement project templates.
NOTE:
For further information on scripting and the programming environment, please
refer to the help file for Microsoft Visual Studio Tools for Applications. Use
the Help menu of the VSTA editor.
193
QUADERA HTML Help
Activating Add-ins
3. In the submenu, select Add-in Manager. The "Add-in Manager" window opens
up.
4. In the displayed "Available Add-ins" list, enable the checkbox next to the name of
the required add-in.
5. Click [OK].
194
QUADERA
Running Macros
Automatic run
QUADERA automatically executes macros in the following cases:
Manual run
You have to activate the relevant add-in before you can manually execute the macro.
3. In the displayed macro list, click the name of the macro to be executed (not the
checkbox).
4. Click Run.
NOTE:
You can call up the "Macros" window with the keyboard shortcut ALT+F8.
195
QUADERA HTML Help
In VSTA, an add-in can include more than one function. Each function can be considered
as a macro and an add-in as "macro collection". Proceed as follows to edit an add-in or
an included macro:
3. In the submenu, select Add-in Manager. The "Add-in Manager" window opens
up.
4. In the displayed "Available Add-ins" list, click the name of the add-in to be
edited, or browse for the required add-in.
5. Click [Edit]. The source code will then be opened in the VSTA editor for editing.
QUADERA stores each add-in in a main scripting directory. When required, the add-ins
are available for all measurement project templates.
NOTE:
For further information on scripting and the programming environment, please
refer to the help file for Microsoft Visual Studio Tools for Applications. Use
the Help menu of the VSTA editor.
196
QUADERA
3. In the submenu, select Add-in Manager. The "Add-in Manager" window opens
up.
4. In the displayed "Available Add-ins" list, click the name (not the checkbox) of the
add-in to be edited, or browse for the required add-in.
5. Click [Edit]. The source code is being opened in the VSTA editor for editing.
QUADERA stores each add-in in a main scripting directory. When required the add-ins
are available for all measurement project templates.
NOTE:
For further information on scripting and the programming environment, please
refer to the help file for Microsoft Visual Studio Tools for Applications. Use
the Help menu of the VSTA editor.
197
QUADERA HTML Help
or
NOTE:
The VSTA Help includes the help for the specific QUADERA scripting
functionality.
198
QUADERA
Spectra Library
Spectra Library
The Spectra Library is accessed via the Tools>>Spectra Library menu selection or from
any Bargraph Cycles measurement project.
The Spectra Library view and contents can be customized and saved.
199
QUADERA HTML Help
Use the relevant measurement project as a user interface for testing and servicing the
input/output module (if existing). For this, connect the device with QUADERA.
Digital Inputs: display the states of the digital input (DI) channels:
Number: identification of the DI channel,
Value: value of the DI channel (On/Off),
Digital Outputs: switch on and off the digital output channels (DO) manually:
Number: identification of the DO channel,
Value: value of the DO channel (On/Off),
Add a measurement task "Add Analog Input Task" to Scan and MID measurement
projects to measure the voltage at a analog input.
200
QUADERA
Creating IO Characteristics
Characteristics can be created for Analog Inputs and Outputs. Characteristics can be
assigned to one or all devices. Analog I/O Characteristics work with the following
devices:
The Characteristics Editor can be accessed from the context-menu of the All Device
Status View or from the Device Configuration.
The function of AI/AO Characteristics allows definition of a characteristic set of data that
can be applied to an Analog Input or Analog Output. Once defined, these characteristics
are then available for use on any Analog Input or Output. For example, a set of data can
be defined that produces a charted temperature for an Analog Input.
Example: X*1.8 + 32
The AI/AO Characteristics dialog can be accessed from the Tools>> AI/AO
Characteristics menu selection. From this dialog new Characteristics can be created and
edited. Characteristics can also be copied (to create a new Characteristic from a
standard Characteristic) or deleted. The Characteristic Definition Editor provides a table,
graph and formula interface for easy creation of the Characteristic. The Definition Editor
is also where the Characteristic type is defined Analog Input, Analog Output or Analog
Input to Analog Output. A name and unit must also be entered in this editor.
The formula interface describes the Y value as a function of X. The formula can use the
operators of + - * / ^ as well as the following functions:
201
QUADERA HTML Help
logarithm, base e
Expressions in ( ) ( )
parentheses
Pi Pi Pi
The formula parser will indicate when a formula is constructed incorrectly. Note that the
parser may indicate Operator Input Error as the formula is being entered. Disregard
that message unless it appears when the formula is finalized.
AI/AO Characteristics are then assigned to Analog Inputs and Analog Outputs via the
context menu item AI/AO Characteristics in any MID chart. Once a Characteristic is
assigned to an Analog Input it is used for that Analog Input in any MID Measurement
Project that uses that Analog Input. For example, if Analog Input 1 is wired to a
temperature sensor, and a Characteristic is assigned to Analog Input 1, then all MID
Measurement Projects that use Analog Input 1 will automatically use that Characteristic.
202
QUADERA
List of Events
"Source" displays the source that caused the event, e.g. measurement or device,
"Description" displays a brief message text on the event, and specifies warnings
and errors. This three-part specification contains:
the device specification,
the code letter of the event type ("E" means error, "W" means warning),
the three-digit identification number of the event.
203
QUADERA HTML Help
Message text:
"emission current out of tolerance"
Description:
The emission current deviates from the set value.
The emission current deviates 10% and more than 40 A from the specified
value.
Reasons
Consequences
Solutions
Replace the IS220 when the message occurs repeatedly with stable pressure
conditions.
204
QUADERA
Message text:
"emission current wide out of tolerance"
Description:
The emission current essentially deviates from the set value.
The emission current deviates more than 20% and more than 40 A from the
specified value.
Reasons
Consequences
Solutions
Replace the IS220 when the message occurs repeatedly with stable pressure
conditions.
205
QUADERA HTML Help
Message text:
"RF-stage temperature is high"
Description:
The temperature of the RF stage has exceeded 65C.
Reasons
Cooling of the RF stage is not sufficient because the fan filter pad is blocked,
Consequences
Solutions
206
QUADERA
Message text:
"external protection triggered"
Description:
The protection for SEM and filament has triggered.
The total pressure gauge is not properly connected, or the protection input is not
properly connected.
Reasons
Connected total pressure gauge: the pressure has exceeded the specified
threshold,
Consequences
Filament and SEM are switched on and off depending on the selected protection
mode.
Solutions
207
QUADERA HTML Help
Message text:
"emission error"
Description:
An emission error occurred.
Reasons
Consequences
Ionization is impossible,
Solutions
Replace the filament. Refer to the device specific instructions of the QMG (OEM
manual) for further information,
208
QUADERA
Message text:
"filament 1 defect"
Description:
The filament 1 is broken.
Reasons
Consequences
Ionization is impossible,
Solutions
Replace the filament. Refer to the device specific instructions of the QMG (OEM
manual) for further information.
209
QUADERA HTML Help
Message text:
"filament 2 defect"
Description:
The filament 2 is broken.
Reasons
Consequences
Ionization is impossible,
Solutions
Replace the filament. Refer to the device specific instructions of the QMG (OEM
manual) for further information.
210
QUADERA
Message text:
"RF-stage switched off because of excessive temperature"
Description:
The RF stage was switched off because the temperature has exceeded 80C.
Reasons
Cooling of the RF stage is not sufficient because the fan filter pad is blocked,
Consequences
Solutions
Switch the device off, and wait until the RF stage has cooled down. Then switch
the device on again.
211
QUADERA HTML Help
Message text:
"ionsource error"
Description:
An error occurred in the power supply of the ion source.
Reasons
The specified protection current limit for degas mode is too low.
Consequences
Solutions
Check and correct contacts and cable of the IS220 power supply,
212
QUADERA
Message text:
"SEM error"
Description:
An error occurred in the control of the SEM voltage.
The SEM voltage deviates 10% and more than 30 V from the specified value,
Reasons
Consequences
Solutions
Check the SEM. Refer to the device specific instructions of the SEM (OEM manual)
for further information.
213
Scripting in QUADERA
NOTE:
You first have to activate the QUADERA VSTA functionality through an
appropriate license key in order to use 'scripting'. Adhere to the notes given in
the Release Notes and to the "About" dialog.
You can use the VSTA functions provided by QUADERA to automate tasks and to tailor
them according to your needs. The available instructions, how to use them, and the
syntax is integrated into the Help of the VSTA editor:
The bottom right part of the window displays the available information on the
component. Press the F1 key to invoke the general VSTA Help.
NOTE: VSTA Add-ins can be started from the QUADERA command line if
desired. There is a command line option [/addin] that can be used with the
Add-in name. As an example (XP English shown), the following command line
can be used to automatically load and start the [GSD320] Add-in:
To modify the command line, create a program shortcut in Windows and edit
the shortcuts Properties>>Target field.
215
Glossary
A
AI: Analog Input: Analog (continuous) input of the mass spectrometer.
amu: atomic mass unit.
Analog Input: Analog (continuous) input of the mass spectrometer.
Analog Output: Analog (continuous) output of the mass spectrometer.
AO: Analog Output: Analog (continuous) output of the mass spectrometer.
B
Background: See Mass spectrometer background.
Bar graph: Display of measuring data on a category axis.
Button: Graphical representation of a binary switch.
C
C-SEM: Secondary electron multiplier with channeltron (also known as channel electron
multiplier).
Category: In QUADERA: A non-continuous division of a measuring data axis.
Context menu: A context menu can be called up by clicking certain spots in the graphical
user interface with the right mouse button. It contains only menu items that make
sense in the clicked area (object specific functions).
D
Data navigator: Operating element for navigation within the measuring data. The data
navigator is especially useful when handling large amounts of data.
Degassing: For a specified time, the filament receives a current that is higher than usual.
This heats out the measuring head and cleans it from contamination.
DI: Digital Input: Digital (binary) input of the mass spectrometer.
Digital Input: Digital (binary) input of the mass spectrometer.
Digital Output: Digital (binary) output of the mass spectrometer.
Dimension: Relation between a quantity of physics and the basic quantities.
DO: Digital Output: Digital (binary) output of the mass spectrometer.
E
Emission current: Electron current required for ionizing the analysis gas.
Event display: Display for events: Warnings, informations, errors.
217
QUADERA HTML Help
F
Filament: Glowing wire which emits the electrons required for ionizing the gas molecules.
FIR: Finite Impulse Response (digital filter).
G
Gas specific calibration factors: Correction factors, used for calculating partial pressures
from ion currents.
Graphics: Display with a graphical representation of the measuring values (line graph, bar
graph, ...).
GSC: Gas Specific Calibration.
H
Hold: Used if data are being analyzed while a measurement is running. The command
freezes the section it its current state (the latest measuring data are not being
displayed). However, the measurement continues in the background.
I
Ion source optimization: Calibration process during which the ion source is adjusted in
order to optimize the ion current with respect to the intensity and/or the peak shape.
M
Mass scale calibration: Correction between nominal mass number and actual peak
maximum.
Mass spectrometer background: Background determination by the software. Mostly, a
zero gas is used for this.
MCD: Multiple Concentration Determination. In this measuring mode, the concentration of
the individual gas components is calculated from measured ion currents.
Measurement project: Contains all instruments required to perform a specific
measurement task. One device is assigned to each measurement project. It is
possible that several measurement projects relate to the same device.
Measurement project template: See Template.
Measurement task: Constitutes the basic component of a recipe and contains the
measuring mode and all parameters required to specify this mode. Measurement
tasks can be configured.
Measuring mode: The different types of measurement that are supported by the device.
MID: Multiple Ion Detection. In this measuring mode, the intensity for specified masses is
measured as a partial pressure or ion current.
MS: Mass spectrometer.
218
Glossary
O
Object: General term for elements that are being used in the software in any way, e.g.
chart, task.
Offset: Offset of a real measuring amplifier from zero.
P
Parameter set: Group of parameters that are related or belong together otherwise
(settings).
Partial pressure: Pressure that is being created by an individual component in a gas
mixture.
Peak: A scan-analog spectrum consists of a number of peaks. These represent fractions of
the individual gas components at the respective masses.
PGA: Process gas analysis.
ppb: Parts per billion (1 : 1,000,000,000).
ppm: Parts per million (1 : 1,000,000).
Process gas analysis: Analysis of gas mixtures that are being expected in a process.
Property dialog field: Dialog window, generally containing several tabs.
Q
QC: Quadrupole Controller. See operating instructions QMG.
QMG220: High-end mass spectrometer.
QMG700: High-end mass spectrometer.
QUADERA: Operation and analysis software for the QMG mass spectrometers.
R
Recipe: A recipe is a sequence of measurement tasks.
RF: Radio Frequency.
RGA: Residual Gas Analyzer.
S
Scan: See Scan Analog.
Scan Analog: Ion current as a function of m/e.
Scan speed: Sampling rate for scan-analog measurements. In most cases the time/mass.
Scan-F filter: FIR filter, used for smoothing a scan-analog signal.
219
QUADERA HTML Help
T
Template: Predefined settings which help the user to create a measurement project
(configuration of the measurement without measuring data).
Toolbox: Graphical operating element which depicts functions with small pictograms. The
functions are activated or executed by dragging & dropping the related pictograms.
Trend: Course of a value with time.
Trend display: Graphical display for the course of a measured quantity with time.
Tune Mode: Procedure for tuning a device such as the ion source and optimizing the signal
shape.
U
Unit: Quantity of physics = Numerical value * unit.
V
VBA: Visual Basic for Applications. Scripting language by Microsoft which is used for
programming in applications. Followed by VSTA.
VSTA: Visual Studio Tools for Applications. Development system to customize applications
by using the .NET framework. Replaces VBA.
W
Working area: Part of the measurement project window or recipe. The working area is
used to display measuring data or to specify parameters for the currently selected
recipe.
Workspace: See Working area
WYSIWYG: "What You See Is What You Get": The displayed screen is being output at the
printer as faithfully as possible.
220
Index
A Axis Y ............................................... 65
Axis Y1 ............................................. 65
About ............................................... 23 Axis Y2 ............................................. 65
Active Set ....................................... 111
Actual Mass ..................................... 130 B
Add Analog Input Editor ...................... 49
Add Analog Input Task ........................ 49 Background .............................. 139, 140
Add Analog Output Editor .................... 49 Background library .................... 140, 142
Add Chart Element ............................. 49 Bar ............................................. 65, 82
Add Digital Input Editor....................... 49
Add Digital Output Editor .................... 49 C
Add MCD Chart .................................. 49
Add MCD Task ................................... 49 Calibration and Tuning ........................ 72
Add MID Chart ................................... 49 Calibration factor ...................... 146, 153
Add MID Task .................................... 49 Calibration gas ................................. 145
Add Peak Task ................................... 49 Calibration project .......................72, 107
Add Scan Chart .................................. 49 Background ........................... 139, 140
Add Scan Task ................................... 49 Calibration factor .................... 146, 153
Add Total Pressure Task ...................... 49 File location .................................... 89
Add Working Area ........................ 49, 96 Gas specific calibration ............ 145, 146
Add-in ............................................ 190 Ion source ............................. 108, 109
Activating ..................................... 194 Mass scale ......................122, 124, 126
Copying ....................................... 191 Offset ................................... 132, 133
Creating ....................................... 193 RF tuning ..................................... 135
Deleting ....................................... 192 Calibration recipe ............................. 176
Editing ......................................... 196 Calling up
Manager ................................ 194, 196 Context menu ................................. 60
AI Channel ............................... 167, 172 Help............................................... 20
Amplifier offset ................................ 133 Macro .......................................... 195
Analog filter .............................. 167, 172 VSTA editor .................................. 197
Analog input editor ........................... 200 VSTA help ............................. 198, 215
Analog Inputs .................................. 201 Calling up context menus .............. 59, 60
Analog output editor ......................... 200 Capturing screens .............................. 70
Analog Signal Filter ................... 167, 172 Cascade ............................................ 99
Analyser Detector Type ....................... 28 Cathode .......................................... 111
Analysis matrix ................................ 176 Characteristics ................................. 201
AO Channel .............................. 167, 172 Characteristics Editor ........................ 201
AO Mode ......................................... 167 Chart display .......................... 76, 81, 82
AO Range ........................................ 167 Chart element .................................... 35
Apply to Background Library .............. 142 Checkbox .......................................... 38
Apply to MCD Calibration Factor Library Click ................................................. 39
................................................... 151 Close ..................................... 61, 84, 88
Arrange Icons .................................... 99 Close All Windows .............................. 99
Auto Hide .......................................... 69 Closing
Automating ..................................... 189 Application ..................................... 61
Autorange Mode ........................ 167, 172 Measurement project ....................... 88
Available Add-ins ...................... 194, 196 Quadera ......................................... 84
Average .......................................... 183 Window .................................... 61, 99
Axial ............................................... 111 Color .......................................... 65, 92
Axis X ............................................... 65 Common SEM voltage .......... 56, 167, 172
221
QUADERA HTML Help
222
Index
223
QUADERA HTML Help
Closing ........................................... 88 Q
Displaying ................................ 65, 90
Exporting ....................................... 87 QMP ............................................... 157
Maximum ..................................... 184 QMT ............................................... 157
Minimum ...................................... 182 Quadera ............................................ 15
Opening ................................... 72, 85 Exiting ........................................... 84
Saving ........................................... 88 Installing .................................. 25, 26
Standard deviation ........................ 185 License key..................................... 26
Measuring mode .............................. 105 Main features .................................. 16
Measuring range ....................... 167, 172 Migrating from Quadstar .................. 11
Menu bar .................................... 44, 62 Product description .......................... 15
Menu commands ................................ 44 Release Notes ................................... 1
Menus............................................... 44 Scope of delivery ............................. 17
MID measurement project ................. 159 Screenshot ..................................... 70
Minimize ........................................... 61 Setting up ...................................... 27
Minimize all windows .......................... 99 Start page ...................................... 72
Minimum ......................................... 182 Starting.......................................... 71
Move ................................................ 61 Uninstalling .................................... 34
Multiplexing ....................................... 46 Update ..................................... 32, 33
Multisensor .................................. 27, 46 Upgrade ................................... 32, 33
User interface ................................. 37
N Version .......................................... 23
VSTA reference ............................. 215
Network settings .................................. 1 Quadrupole controller ....................... 172
New section ....................................... 94 Quadstar ................................ 11, 12, 13
New working area .............................. 96
Nominal Mass .................................. 130 R
224
Index
225
QUADERA HTML Help
226