Met Al Aqueous Ion Limited Naoh Limited NH Excess Naoh Excess NH Na Co HCL

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Met Aqueous Limited Excess Excess Na2CO3 HCl

al Ion NaOH NaOH NH3


Limited NH3
Fe2+ [Fe(H2O)6]2+ Fe(H2O)4(OH) FeCO3
Green 2 Green
Solution Green Precipitate
Precipitate
Cu2+ [Cu(H2O)6]2+ Cu(H2O)4(OH [Cu(NH3)4(H2O CuCO3 [CuCl4]2-
Blue )2 )2]2+ Blue-Green Yellow-
Solution Blue Deep Blue Precipitate Green
Precipitate Solution Solution
Co2+ [Co(H2O)6]2+ Co(H2O)4(OH [Co(NH3)6]2+ CoCO3 [CoCl4]2-
Pink )2 Yellow-Brown Pink Blue
Solution Blue Solution Precipitate Solution
Precipitate
Fe3+ [Fe(H2O)6]3+ Fe(H2O)3(OH) Fe(H2O)3(OH)3
Purple 3 Brown
Solution Brown Precipitate CO2
Precipitate Effervescence
Al3+ [Al(H2O)6]3+ Al(H2O)3(OH) [Al(OH)4] -
Al(H2O)3(OH)3
Colourless 3 Colourles White
Solution White s Precipitate
Precipitate Solution CO2
Effervescence
Cr3+ [Cr(H2O)6]3+ Cr(H2O)3(OH) [Cr(OH)6] [Cr(NH3)6] 3+
Cr(H2O)3(OH)3
Violet 3
3-
Violet Solution Green
Solution Green Green Precipitate
Precipitate Solution* CO2
Effervescence

Goes brown in air or H2O2: Fe2+ is oxidised to Fe3+
Goes brown in air or H2O2: Co2+ is oxidised to Co3+
*Goes yellow in H2O2: Cr3+ oxidised to CrO42- (then the dichromate equilibrium is established)

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