Sulfur Sticks SDS 05-2016 IRPLLC Rev3

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The document provides safety information about ammonia leak detectors including their physical properties, health hazards, safe handling and use, and disposal.

The ammonia leak detectors, also known as sulfur tapers, are used to detect leaks of ammonia gas. They are yellow sticks impregnated with sulfur that produce sulfur dioxide gas when ignited, acting as visual indicators of ammonia leaks.

Potential health hazards from the ammonia leak detectors include irritation of the eyes, nose, throat and lungs from the sulfur dioxide gas produced when ignited. Repeated skin contact may also cause irritation.

SAFETY DATA SHEET

Xo66e 2032 ELK KNOB ROAD LAUREL SPRINGS, NC 28644


MCCAWLEY, LLC PHONE 336-359-2594 FAX 336-359-2595

SECTION I - PRODUCT IDENTIFICATION


PRODUCT NAME: Ammonia Leak Detectors Rev. Date 10-07-2015

COMMON NAME: Sulphur Taper (stick) CAS Number: 7704-34-9

PHYSICAL DESCRIPTION: Taper no longer than 8" x 1/8" yellow to buff cellulose
cordage impregnated with sulphur.

SECTION II - PHYSICAL PROPERTIES


Exposure Limits (TWAs) in Air
Chemical Name CAS Number Ofo ACGIH TLV OSHA PEL STEL
Sulfur 7704-34-9 100 N/A N/A N/A

SECTION Ill - HAZARD IDENTIFICATION


ROUTES OF EXPOSURE:
SUMMARY OF ACUTE HEALTH HAZARDS
INGESTION: Sulfur has a low order of toxicity
INHALATION: Avoid inhaling fumes. Lighted detector generates Sulphur dioxide which can cause severe
irritation to nose, throat and lungs. Use of detector is local and temporary.
SKIN: Repeated contact may cause irritation of the skin. Avoid flame contacting body tissue.
EYES: Sulphur dioxide gas can cause severe irritation.
SUMMARY OF CHRONIC HEALTH HAZARDS: N/A
SIGNS AND SYMPTOMS OF EXPOSURE: N/A
EFFECTS OF OVEREXPOSURE: Burning of a detector can be temporarily irritating to the eyes if held to
~lose.
MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE: N/A
NOTE TO PHYSICIANS: N/A

SECTION IV- FIRST AID MEASURES

INGESTION: If large amounts are swallowed, call a physician.


INHALATION: Move to fresh air, should irritation or symptoms persist consult a physician.
SKIN: Wash with soap and water. Consult a physician if symptoms persist.
EYES: Flush eyes with clean water thoroughly. Consult a physician if irritation persist.

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SECTION V- FIRE FIGHTING MEASURES
6 6
FLASH POINT: 405 F; 20rc AUTOIGNITION TEMPERATURE: 450 F; 232C
3
LOWER EXPLOSIVE LIMIT: 35g/m UPPER EXPLOSIVE LIMIT: 1400g/m3
UNUSUAL FIRE AND EXPLOSION HAZARDS: Fire may restart after it has been extinguished.
EXTINGUISHING MEDIA: Water, sand or dirt that excludes oxygen.
SPECIAL FIREFIGHTING PROCEDURES: Wear self-contained breathing apparatus.

SECTION VI - ACCIDENTIAL RELEASE MEASURES

N/A

SECTION VII - HANDLING AND STORAGE

N/A

SECTION VIII - EXPOSURE CONTROLS/PERSONAL PROTECTION

RESPIRATORY PROTECTION: Avoid inhaling fumes of lighted detector.


VENTILATION: General Ventilation
PROTECTIVE CLOTHING: Don't allow flame to contact body tissue or combustible material.
EYE PROTECTION: Safety Glasses
OTHER PROTECTIVE CLOTHING OR EQUIPMENT: N/A
WORK /HYGIENIC PRACTICES: Wash thoroughly with soap and water after using Taper.

SECTION IX- PHYSICAL AND CHEMICAL PROPERTIES

PHYSICAL STATE: Solid until ignited thus becoming a gas. pH: N/A
MELTING POINT/RANGE: 234.5-246.2F; 112.5-119C BOILING POINT/RANGE: 832F; 444.6C
APPEARANCE/COLOR/ODOR: Yellow to buff strip, approximately 8" long by 1/8"
SOLUBILITY IN WATER: Insoluble VAPOR PRESSURE (mmHg): N/A
SPECIFIC GRAVITY (WATER=1): 2.07 MOLECULAR WEIGHT: N/A
VAPOR DENSITY (AIR-1): N/A %VOLATILES: 100
HOWTO DETECTTHIS COMPOUND: N/A

SECTION X- STABILITY AND REACTIVITY

STABILITY: Stable
CONDITIONS TO AVOID: Potentially explosive mixtures are formed when in contact with oxidizing
materials. DO NO USE if ammonia concentration in air is in range of 15% to 28%.
MATERIALS TO AVOID: Potential explosive mixtures are formed when in contact with oxidizing materials.
Separate from chlorates, nitrates, charcoal, metals, carbides, halogens and other oxidizers.
HAZARDOUS DECOMPOSITION PRODUCTS: Upon oxidation will form oxides of sulfur including sulfur
dioxide and sulfur trioxide. Formation of hydrogen sulphide may occur.

SECTION XI -TOXICOLOGICAL INFORMATION


N/A

SECTION XII - ECOLOGICAL INFORMATION

N/A Page 2 of 3
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SECTION XIII - DISPOSAL CONSIDERATIONS
Waste should be handled in accordance with local, state, and federal regulations.

SECTION XIV- TRANSPORT INFORMATION

DOT PROPER SHIPPING NAME: Sulfur


DOT HAZARD CLASS/I.D. NO.: 9, NA1350,111
For International Shipments Only:
DOT PROPER SHIPPING NAME: Sulfur
DOT HAZARD CLASS/I.D. NO.: 4.1, UN1350,111

SECTION XV- REGULATORY INFORMATION

REPORTABLE QUANTITY: N/A


NFPA RATING: HEALTH- 2; FLAMMABILITY- 1; INSTABILITY- 0
0 = Insignificant 1 = Slight 2 = Moderate 3 = High 4 = Extreme
CARCINOGENICITY LISTS: None NTP: No IARC MONOGRAPH: No OSHA REGULATED: No

SECTION XVI - OTHER INFORMATION


SYNONYMS/COMMON NAMES: Sulfur Tapers
CHEMICAL FAMILY/TYPE: Sulfur, Sulphur
This MSDS information is based on sources believed to be reliable. However the conditions of handling
and use are beyond our control; Kobbe'-McCawley, LLC makes no warranty, expressed or implied. It is the
user's responsibility to determine the suitability of this product and to consider risks prior to use.

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