A264 Msds
A264 Msds
A264 Msds
A264
Version 11
Revision date 11/Dec/2015
Supersedes date 09/Dec/2015
1. Identification
1.1 Product identifier
1.2 Relevant identified uses of the substance or mixture and uses advised against
Supplier
Schlumberger Technology Corporation
110 Schlumberger Drive
Sugar Land, Texas 77478, USA
Telephone: 1-281-285-7873
Prepared by
Global Regulatory Compliance - Chemicals (GRC - Chemicals) , Gulan Sun
Emergency telephone (24 Hour) Australia +61 2801 44558, Asia Pacific +65 3158 1074, China +86 10 5100 3039, Europe +44
(0) 1235 239 670, Middle East and Africa +44 (0) 1235 239 671, New Zealand +64 9929 1483, USA 001 281 595 3518, Canada
001 613 996 6666
2. Hazards identification
2.1 Classification of the substance or mixture
GHS - Classification
Health hazards
Acute oral toxicity Category 3
Acute dermal toxicity Category 3
Acute inhalation toxicity - vapor Category 3
Skin corrosion/irritation Category 1 Subcategory 1B
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Corrosion Inhibitor A264 SDS no. A264
Revision date 11/Dec/2015
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Environmental hazards
Chronic aquatic toxicity Category 3
Physical Hazards
Flammable Liquids Category 2
Signal word
DANGER
Hazard statements
H301 - Toxic if swallowed
H311 - Toxic in contact with skin
H314 - Causes severe skin burns and eye damage
H331 - Toxic if inhaled
H370 - Causes damage to organs
H412 - Harmful to aquatic life with long lasting effects
H225 - Highly flammable liquid and vapor
Precautionary statements
P210 - Keep away from heat/sparks/open flames/hot surfaces. - No smoking
P260 - Do not breathe dust/fume/gas/mist/vapors/spray
P280 - Wear protective gloves/ protective clothing/ eye protection/ face protection
P301 + P310 - IF SWALLOWED: Immediately call a POISON CENTER or doctor/ physician
P303 + P361 + P353 - IF ON SKIN (or hair): Remove/ Take off immediately all contaminated clothing. Rinse skin with water/
shower
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing
P370 + P378 - In case of fire: Use dry sand, dry chemical or alcohol-resistant foam for extinction
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3. Composition/information on Ingredients
3.1 Substances
Not Applicable
3.2 Mixtures
Comments
The product contains other ingredients which do not contribute to the overall classification. The specific chemical identity and/or
exact percentage (concentration) of composition has been withheld as a trade secret
Inhalation Move to fresh air. If breathing is difficult, (trained personnel should) give oxygen. If not
breathing, give artificial respiration. Get medical attention immediately if symptoms occur.
Ingestion Do not induce vomiting. If conscious, give 2 glasses of water. Get immediate medical
attention.
Skin contact Wash off immediately with soap and plenty of water. Remove contaminated clothing and
shoes. Get medical attention if irritation persists.
Eye contact Rinse immediately with plenty of water, also under the eyelids. Remove contact lenses.
Continue to rinse for at least 15 minutes. Get medical attention if any discomfort continues.
4.2 Most important symptoms and effects, both acute and delayed
Main symptoms
Inhalation Please see Section 11. Toxicological Information for further information.
Ingestion Please see Section 11. Toxicological Information for further information.
Skin contact Please see Section 11. Toxicological Information for further information.
Eye contact Please see Section 11. Toxicological Information for further information.
4.3 Indication of any immediate medical attention and special treatment needed
Corrosion Inhibitor A264 SDS no. A264
Revision date 11/Dec/2015
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Notes to physician Ethanol may be administered in an IV solution to counteract the adverse effects of
methanol ingestion. Fomepizole (Antizol) may also be used for treatment of methanol
poisoning.
5. Fire-fighting measures
5.1 Extinguishing media
Extinguish all ignition sources. Avoid sparks, flames, heat and smoking. Evacuate personnel to safe areas. Use personal
protective equipment. If spilled, take caution, as material can cause surfaces to become very slippery.
Do not allow spilled material to enter sewers, storm drains or surface waters.
No information available.
Handling
Keep away from heat, sparks and open flame. No smoking. Avoid breathing vapors or mists. Avoid contact with skin, eyes and
clothing.
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Storage precautions Keep away from open flames, hot surfaces and sources of ignition. Keep container/package
tightly closed and in a well-ventilated place. Follow safe warehousing practices regarding
palletizing, banding, shrink-wrapping and/or stacking. To avoid ignition of vapors by static
electricity discharge, all metal parts of the equipment must be grounded
Packaging material Uncoated phosphatized steel drum; high density polyethylene (HDPE) can for short term
storage only.
All chemical Personal Protective Equipment (PPE) should be selected based on an assessment of both the chemical hazard
present and the risk of exposure to those hazards. The PPE recommendations below are based on an assessment of the chemical
hazards associated with this product. Where this product is used in a mixture with other products or fluids, additional hazards may
be created and as such further assessment of risk may be required. The risk of exposure and need of respiratory protection will
vary from workplace to workplace and should be assessed by the user in each situation.
Hygiene measures Wash hands before breaks and immediately after handling the product, Remove and wash
contaminated clothing before re-use.
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Hazardous polymerization
Hazardous polymerization does not occur.
Aldehydes. Ketones. When heated strongly or burned, oxides of carbon, nitrogen oxides, ammonia and harmful organic chemical
fumes are released.
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Acute toxicity
Product information Methanol is more toxic to humans and primates than to most experimental animals, due to
differences in how it is metabolized. Non-primates do not appear to experience the acidosis
or vision effects observed in humans and primates.
Inhalation Toxic by inhalation. May cause irritation of respiratory tract. Vapors inhaled in high
concentration have a narcotic effect on the central nervous system. Symptoms of
overexposure are dizziness, headache, tiredness, nausea, unconsciousness, cessation of
breathing.
Eye contact Corrosive to the eyes and may cause severe damage including blindness.
Skin contact Causes severe skin irritation. Toxic in contact with skin. May be absorbed through the skin
in harmful amounts. Harmful: danger of serious damage to health by prolonged exposure in
contact with skin.
Ingestion Toxic if swallowed. Ingestion may cause gastrointestinal irritation, nausea, vomiting and
diarrhea. May cause adverse cardiac effects, blood disturbances, and metabolic acidosis.
Intoxication can lead to a coma with metabolic acidosis that may be fatal.
Sensitization This product does not contain any components suspected to be sensitizing.
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Target organ effects Eyes. Optic nerve (nervus opticus). Central nervous system. Respiratory system. Liver.
Kidney.
Toxicity to algae
See component information below.
Toxicity to fish
See component information below.
No information available.
This preparation contains no substance considered to be persistent, bioaccumulating nor toxic (PBT)
This preparation contains no substance considered to be very persistent nor very bioaccumulating (vPvB)
None known.
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Disposal Method Disposal should be made in accordance with federal, state and local regulations.
Contaminated packaging Do not re-use empty containers. Empty containers should be taken for local recycling,
recovery or waste disposal. Dispose of in accordance with local regulations.
14.1 UN Number
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State Comments
Proposition 65: This product contains chemical(s) considered by the State of California's Safe Drinking Water and Toxic
Enforcement Act of 1986 to cause cancer and/or reproductive toxicity.
Methanol
developmental toxicity
Formaldehyde
carcinogen
Canadian Classification
This Safety Data Sheet has been prepared in compliance with the Hazardous Products Regulations.
Version 11
HMIS classification
Health 3*
Flammability 3
Physical hazard 0
PPE J
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Disclaimer
The information contained herein is considered in good faith as reliable of the date issued and is based upon on
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of purpose; any express or implied warranty; or non-infringement of intellectual property rights; and supplier assumes no
responsibility for any direct, special or consequential damages, results obtained, or the activities of others. To the
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