Termo 1 6.20 6.21
Termo 1 6.20 6.21
Termo 1 6.20 6.21
Very pure liquid water can be subcooled at atmospheric pressure to temperatures well below
273.15 K (0C). Assume that 1 kg has been cooled as liquid to 267.15 K (-6C). A small ice crystal
(of negligible mass) is added to seed the subcooled liquid. If the subsequent change occurs
adiabatically at atmospheric pressure, what fraction of the system freezes and what is the final
temperature? What is Stotal for the process, and what is its irreversible feature? The latent
heat of fusion of water at 273.15 K (0C) is 333.4 J g-1, and the specific heat of subcooled liquid
water is 4.226 J g-1 C-1.
Penyelesaian :
Diketahui :
T1 = -6oC
m = 1 kg
H = 333.4 J/g
Cp = 4.226 J/goC
Isenthalpic Htotal = 0
Maka :
a. Fraksi massa
Cp. T + x. H = 0
.T
= H
4.226 .6
= 333.4
= 0.076
b. Enthropy
T2 = 0oC = 273.5 K
T x .H
S = Cp ln (T2 ) +
1 T2
273.15 0.076(333.4)
S = 4.226 ln (266.15) + 266.15
J
S = 1.03x103 gmK
20. The state of 1 kg of steam is changerd from saturated vapor at 1.38 bar to superheated vapor at
15 bar and 811.15 K (538C). What are the enthalpy and entropy changes of the steam? What
would the enthalpy and entropy changes be if steam were an ideal gas?
Penyelesaian :
Diketahui :
Ditanyakan :
H & S
Mencari nilai entalpi dan entropi masing-masing kondisi dari Tabel F.3 & F.4 :
T1 = 228 oF
H1 = 1156 H2 = 1534.3
S1 = 1.732 S2 = 2
H = H2-H1
= 1534.3-1156
= 378.3
S = S2-S1
= 2 - 1.732
= 0.268
T1 = 385.55 K
T2 = 814.44 K
H =
= .
= (1 , 2 , , , , )
= 4.36
= 0.1986 4.36
= 0.865896
( ( 2 ) ( 2 ))
1 1
S =
= .
= (1 , 2 , , , , )
= 4.32
814.44 50
1.986(4.32 ( ) ( ))
388.55 20
S = 18
=0.251 .