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● INCH-POUND

‘ivfIL-F-24385F
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7 January ”1992
SUPERSEDING
MI L-F-0024385 E(SH)
30 November 1990
MI L-F-24385D
260ctober 1989

MILITARY SPECIFICATION
✌
FIRE EXTINGUISHING AGENT, AQUEOUS FILM-FORMING FOAM (AFFF)
.“ LIQUID CONCENTRATE FOR FRESH AND SEA WATER

This specification is approved [or use by all departments and agencies of the
Department of Defense.
L SCOPE

1.1 Scope. This specification covers Lhe requirements for aqueous film-forming foam (AFFF)
liquid concentrate fire extinguishing agents consisting of fluorocarbon surfactants and other
compounds, as required, to conform to this specification. At the time of use they shall be diluted

● with fresh or sea water to form a fire-extinguishing solution. Certain proportioning equipment may
produce AFFF solutions of extreme concentrations; requirements for such concentrations are
specified herein.

1.2 Classification. Concentrates shall be of the following types, as specified (see 6.2):

Type 3 – To be used as three parls concentrate to ninety-seven parts water by volume

solution
Type 6 – To be used as six parts concentrate to ninety-four parts water by volume solution.

/-
-, /
/’ Beneficial mmmenrs (recnnrmendatiorrs, additions, deletions) and any pertinent data which may bc of usc in improving
this document should be addressd [o Commander, Naval Sea SPtorrs Command, SEA 5523, Deparrmcnl of the
Nay, Wastriaglm, DC 20362-5101 by using lhe self-addressedStandmdmtion Documem Improvement Propaal (DD
Form t426) appearing at the end of this dceument or by letter.

AMSC NIA FSC 4210

DISTRIBUTION STATEMENT A. Approved for public release; distribution is unlimited.

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2. APPLICABLE DOCUMENrS
I -. .”.-

LL. 1 specnicmlons
. . . . .

ona standards.
. .

1 Ire
. .

Iollowmg specmca(ions, and slandards [orm a parl of

this document to the exlent specified herein. Unless olhmwise specified, the issues of these
documents are those listed in the issue of the Department of Defense Index of Specifications and
Standards (DODISS) and supplement lhereto, cited in the solicitation (see 6.2).

SPECIFfCATIONS

FEDERAL
NN-P-71 Pallets, Material Handling, Wood, Slringcr Construction, 2-Way and
4-Way (Partial)
O-D-1407 Dry Chemical, Fire Extinguishing, Potassium Bicarbonate
PPP-C-1337 Containers, Metal, With Polye~hylenc Insert
QQ-S-781 Terminal; Wire Rope Swaying Military Standard
RR-S-%6 Sieve, Test
IT-E-489 Enamel, Alkyd, Gloss, Low VOC Conten{

MILITARY

MIL-I-17214 Indicator, Permcabilit~ Low-Mu (GO-NO-GO)

STANDARDS

FEDERAL

1 FED-STD-595 Colors Used in Government Procuremcrrt

MILITARY

MIL-STD- 129 Marking for Shipment and Storage

MIL-STD-130 Identification Marking 0[ U.S. Military Property
MIL-STD-147 Palletizcd Unit Loads
MIL-STD-731 Quality of Wood Members for Containers and Pallets
I
(Unless otherwise indicated, copies of federal and military specifications, standards and handbooks

2 @

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MIL-F-24385F

are available from the Standardization Documents Order Desk, Building 4D, 7MI Robbins Avenue,
Philadelphia, PA 19111-5094.)

2.1.2 Other Government publications. The following other Government publications form a part
of this document to the extent specified herein. Unless otherwise specified, the is-suesare those cited
in the solicitation.

PUBLICATIONS

DEPARTMENT OF TRANSPORTATfON

Code of Federal Regulations, Thle 49

.
(Application for copies should be addressed to the Superintendent of Documents, U.S. Government
Prirding Oflice, Washington, DC 20402.)

MILITARY

DAVID W. TAYLOR NAVAL SHIP RESEARCH AND DEVELOPMENT CENTER

(DTNSRDC)

●
Standard Marine Bioassay Procedure for Shipboard Chemicals.

(Application for copies should be addressed to Commander, David W. Taylor Naval Ship Research
and Development Center, (Code 2865), Annapolis, MD 21402.)

2.2 Non-Government prsblicutions. The following documents form a part of this document to
the extent ssrecified herein. Unless otherwise specified, the issues of the documents which are DOD
adopted are”those listed in the issue of DODISS cited in the solicitation. Unless otherwise specified,
the issues of documents not listed in the DODISS are tbe issues of the documents cited in the
solicitation (see 6.2).

AMERICAN SOCIETY FOR TESTING AND MATERIALS (ASTM)

D96 Standard Tesl Methods for Water and Sediment in

Crude Oils (DoD adopted)
D439 Standard Specification for Automotive Gasoline
(DoD adopted)
D445 Standard Test Method for Kinema!ic Viscosity of Transparent and
Opaque Liquids (and (he Calculation of Dynamic Viscnsity) (DoD
adopted)
D1141 Standard Specification for Substitute Ocean Water
D1331 Standard Test Melhods for Surface and Interracial

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Tension of Solutions of Surface-Active Agenta

D1821 Standard Test Method for Inorganic
Chlorides in Askarels
E527 Standard Practice for Numbering Metals and Alloys
(UNS)
E729 Standard Practice for Clmrducdng Acute Toxicity Tests with Fish,
Macroinvertebrales and Amphibians

(Application for copies should be addressed to (be American Society for Testing and Materials, 1916 ‘
Race Street, Philadelphia, PA 19103.)
.
AMERICAN PUBLIC HEALTH ASSOCIATION
I
Standard Methods for tbe Examination of Water and Waste Water

(Application for copies should be addressed to the American Public Health Association, 1015 15tb
Street NW, Suite 300, Washington, DC 20005.)

NATIONAL FIRE PROTIXXTON ASSOCIATION (NFPA)

NFPA No. 412 Evaluating Foam Fire Fighting Equipment on Aircraft Rescue and Fire
Fighting Vehicles

(Application for copies should be addressed to the National Fire Protection Association,
●
Batterymarch Park, Quincy, Massachusetts 02269.)

UNIFORM CLASSIFICATfON COMMITTEE, AGENT

Uniform Freight Classification Ratings, Ruk.s, and Regulations

(Application for copies should be addressed to the Uniform Classification Committee Agent, Tariff
Publication Officer, Room 1106, 222 South Riverside Plaza, Chicago, IL rXttW6.)

(Non-Government standards and other publications are normally available from the organizations that
prepare or distribute the documents. These documents also maybe available in or through libraries
or other informational services.)

23 Order of precedence. In the event of a conflict between the text of this document and the
references cited berein (except for related associated detail specifications, specification sheets, or MS
standards), the text of this document takes precedence. Nothing in this document, however,
supersedes applicable laws and regulations unless a specific exemption bas been obtained.

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3. REQUIREMENTS
I
3.1 Qrscdificatiosr. Liquid concentrate fire extinguishing agents furnished under this specification
shall be products which are qualified for listing on the applicable Qualitied Products List at tbe time
set for opening of bids (see 4.3 and 6.4).

3.2 Materials. Concentrates shall consist of fluorocarbon surfactants plus other compounds as
required to conform to the requirements specified hereinatler. The material shall have no adverse
effect on the health of personnel when used for its intended purpose.

3.3 Concentrate chtrmcteristics. Concentrates shall conform to the chemical and physical
requirements shown in table I.
1“
3.3.1 Film fnrmntion nnd sealability. The foam produced film shall spread over the fuel surface
and seal off vapor production to prevent substained ignition (see 4.7.6).

3.3.2 Stability. The concentrate (Type 3 or Type 6) and a 3 percent premix solution of Type
3 or a 6 percent premis solution of Type 6 as applicable shall conform to the following requirements
after 10 days storage at 65 Celsius CC) ~ 2.0 “C (see 4.7.10):

a. Spreading coefficient: (See table 1)

b. Formability (See table I)

c. Film formation and sealability As specified in 3.3.1

d. Fire performance, 2S square feet (ft2) fire, 1.5 and 3 percent of Type 3 and 3 and 6 percent
of Type 6 fresh and sea water solutions: As specified in 3.4

e. Stratification: No visible evidence following test (see 4.7.14)

f. Precipitation: 0.05 percent by volume (see 4.7.15).

333 Compatibility. The concentrates of one manufacturer shall be compatible in all proportions
with concentrate furnished by other manufacturers listed on the quaIiIied products list. The material
shall afso be compatible with materials in inventory which were acquired under previous issues of this
specification and known to be still in use in significant quantities. Information regarding tbc.se
materials may be obtained from NAVSEA. The concentrate shall conform to the following
requirements after 10 days storage at 65 “C * 2.0 “C (see 4.7.11):

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a. Formability (See table 1)

b. Film formation and sealability As specified in 3.3.1
c. Fire performance 23 ftz, 3 percent of Type 3 and 6 percent of Type 6 fresh and sea water
solution: As specified in 3.4
d. Stratification: No visible evidence following test (see 4.7.14)
e. Precipitation: 0.05 pcrccr-h by volume (SCC4.7.15).

TABLE I. Chemical rrnd .nhvsicol

. requirements .for concentrates or solutions.

values
Applicable Tesl
Requirement
publication paragraph
Tyfx 3 Type 6

Refractive index, minimum 1.3630 1.3ss0 4.7. I

Viscmily, cemistokes ASTM D445-74 4.7.2
Minimum m 5 “C 20 10
Minimumat 2S ‘C 2 2
Hydrogenion concentration (PI{) 7.0 to 8,5 7.0108.5 4.7,3
Spreading coefticiem, minimum 3 3 4.7.4
Formability
Foam expansion, minimum 5.0 S.o NFTA STD 412 4.7.5
Faam 25% drainage time, minums, minimum 2.5 2.5 NFPA STD 412 4.7.5
Corrosion ram
General
Cold rolled, low cmkm SICCI(UNS G 101OO),
milti intyr, maximum I .5 1.5 ASTM E527 4.7.7
Copfxr.nickel (90-10) (UNS C70600),
mini injyr, maximum I .0 1.0 ASTM S?S27 4.7.7
N,ckel~ppcr (70-30) (UNS N04400),
mini inlyr, maximum I .0 I .0 ASTM E-527 4.7,7
Bronze (UNS C90500), milligrams, maximum 100 100 ASTM ES27 4.7,7
Loratiied, mrmsion-msismm (CRES) sled,
(UNS S304fXJ) No pits No pim 4.7.7
Total halide-s,p/m, maximum son 210 ASTM D1821 4.7.8
Dry chemical mmpmibility, bum.txmk,
resistance time, seconds, minimum 360 360 4.7.9
Environmental impac[:

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Tmxicity, LC50 m#L, minimum SW moo 4.1.12.1
COD, mg/L, maximum 1000K 500K 4.7.12.2
~20 minimum .65 .65 4,7.123
COD

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● 3.3.4 Total fluorine content. The total fluorine content of the AFFF shall be determined and
I shall not deviate more than 15 percent of the value determined and reported at time of
qualification report (see 4.7.16.1).

3.4 Fire perfnrrrmrce. The foam shall conform to the fire performance requirements shown
in table II.

✎
‘-~b . . . .,,. w,Jur#r,,,**-

AFFF snlutions, percent

1.5% of TYPC 3 3% of TyPC 3 15% of TyfE 3

3% of Tyfx 6 6% of Type 6 30% of ~ 6

(Fresh and sea) (Fresh and sea) (s03)

38 Jii [i (see 4.7.13.1):
Fnam application time to extingukh,
secmnds,maximum 45 30 55
Bumhack time of resulting foam cover,
seconds, minimum 300 360 200

● 50 f2 Jii (see 4.Z 13.2):

Fusm applirmion time to extinguish,
seconds, maximum 50(Sea only)
Burnhack time of resulting fcam cover,
I rcomds, minimum 3m
40-scmnd summation, minimum 320
L

3.5 Marking.

---- . .. ,., ,, ,. .. . . . . . “— ..” . . . . . . .,

3.s.1 luermttcat{on marKme . snail ne m accoromrce wm Ml L-s 1 U-1.w. m aaamors. tne

marking on the containers (see 5.3) shall be in while characters against a green background for
Type 3, a blue background for the Type 6.

3.5.2 Two identical markings conforming to figures 1 and 2 shall be applied to containers so
that the markings are located diametrically opposite. The markings shall be applied on the
I
containers in such a manner that water immersion contact with the contents of the containers, or
normal handling will not impair the legibility of the marking. Paper labels shall not be used.
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4. QUAf-lTV ASSURANCE PROVISIONS

4.1 Responsibility for inspection. Unless otherwise specified in the contract, the contractor
is rcspoosihle for the performance of ail inspection requirements as specified herein. Except as
otherwise specilicd in the contract, the contractor may use his own or any other facilities suilable
for the performance of the inspection requirements specified herein, unless disapproved by (be
Government. The Government reserves the right to perform any of the inspections SCLforth in
the specification where such inspections arc deemed nccessacy to ensure supplies and services
conform to prescribed requirements.

4.2 Classification of inspections. The inspection requirements specified herein are classified
as follows

a. Qualification inspection (see 4.3)

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b. Quality conformance inspection (see 4.5)
(1) Examination of filled containers
(2) Quality conformance inspection.

4.3 Qualification inspection. Qualiticaiion inspection shall be conducted al a laboratory

●
satisfactory to (he Naval Sea Systems Command. Qualification inspection shall consist of the
inspections and Ies(s shown in table 111.

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TABLE III. L l[i/ication and qualisy con. nance inspections.

Referents mtgmph Quatity
Examination or 1ss[ Qualification
mnforraanre
Requirement Test

Refractive index 3.3 4.7.1 x x

Viity 3.3 4.7.2 x x
PH vatue 3.3 4.7.3 x x
Spreading cmlTcienl 33 4.7.4 x x
Foamabitity 3.3 4.7.5 x x
Film formalion and seatabildy 3.3, I 4.1.6 x x
,
General corrosion 3.3 4.7.7 x
Lmaliid mrrce.ion 3.3 4.7.7 x
Total halides 3.3 4.7,8 x x
Fluorine mntem 3.3.4 4.7.16 x x
Dry chemical mmpatibility 3.3 4.7.9 x
Stability 3.3.2 4.7.10 x
Compatibility 3.3.3 4.7.11 x
Environmental impact 3.3 4.7.12 x
2E ftz tire 1ss1 3.4 4.7.13 x
50 ft2 fire [=1 ?..4 4.7,13 x x
Examination of filled mmaincrs 4,6 x
Torque to remave CaP1 S.1.l.l.l(q 4,7.17.2 x x
I
lTorque ~e~t,0 ~ ~rformcd a minimum of 48 hours after initial cl~ure.
I

4.3.1 Samples for quttlifkrtion inspection. One hundred gallons of Type 3 and 200
gallons of Type 6 are required for the qualification inspection.

4.4 Sampling for quality conformance inspection.

4.4.1 Inspecting lot. A lot shall consist of all foam manufactured

as one unchanged
process batch and transferred from one mixing tank to the shipping container.

4.4.2 Sampling for examimrtinn nf filled cnntitiners. ,% a minimum, the contractor shall
I randomly select a sample quantity from each lot of filled containers in accordance with Table
IV and examine them in accordance with 4.6, 5.1.1.1, and 5.1.1.2. The sample size depends on
I lot size. if one or more defects are found in any sample, the entire lot shall be rejected. The
contractor has the option of screening 100 percent of the rejected lot for the defective
characteristics, or providing a new lot, which shall be examined in accordance with the
sampling plan contained herein. The contractor shall maintain for a period of three years after
contract completion, records of inspections, tests, and any resulting rejections.

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TABLE fv. Sample size for rwrmina(ion of filled containers.

1 Lntsize Samo[e size

2-5 All
6-5o 5
51-90 7
91-150 11
151-2ao 13
281-500 16
501-1200 19
1201-3200 23

4.43 Sampling for quality conformmrce inspection. Three filled 5-gallon containers shall
be selected at random from each lot and used as one composite sample for the tests specified
in 4.6, or three 5-gallon containers of the product shall be withdrawn from an agitated mixing
tank prior to packaging. The results of the tests required by 4.5 shall be submitted to
NAVSEA or the designated laboratory.

4.5 Quality conformance inspection. The samples selected in accordance with 4.4.3 shall
be subjected to the quality conformance inspection of table 111. If the sample tested is found
I
to be not in conformance with any of the quality conformance tests, the lot represented by the
sample shall be rejected (see 6.3).

4.6 Examination of filled containers. Each sample tilled container shall be examined for
0!
defects of construction of the container and tbe closure, for evidence of leakage, and for
unsatisfactory markings. Each tilled container shall also be weighed 10 delermine the amount
of contents

4.7 Test procedure. ‘Test procedures shall be as follows.:

4.7.1 Refmctive index. The refractive index shall be determined at 25 “C ~ 0.1 ‘C, using I
sodium vapor source lamp illumination. I
I
4.7.2 Vkcosity. The viscosity shall be determined at temperatures of 5 “C * 0.1 “C and
25 ‘C & 0.1 “C in accordance wilh ASTM D445-74, using capillary viseosimeters in the
appropriate size.

4.7S pH vcdue. The pH value shall be determined potentiometrically, using a pH meter

with a glass electrode and a reference electrode, at 25 ‘C ~ 1.0 “C.

4.7.4 Spreading eoeftlcient. The spreading coefficient shall be determined with reference
to cyclohexane in accordance with the following relationship:

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where: uf!yj=)f-~-~
= Spreading coefficient
&
I = Surface tension of cyclohexane as determined in 4.7.4.1
%
XL = Surface tension of AFFF solution as determined in 4.7.4.1
,
= Interracial tension between liquids as determined in 4.7.4.2.
fi
4.7.4.1 Surface tension. The surface tension of 3 * 0.05 percent of type 3 or 6 * 0.1
percent of type 6 by volume in distilled water, as appropriate, and of reagent grade eyclohexane
shall be determined with a DuNoy tensiometer, or equal, at 23 “C * 2.0 “C in accordance with
ASTM D1331.

] Where sea waleris required for Icsm, synthetic sca waler in accordance with ASTM D 1t 4 I shall bs used. A sea
1
sail mkturc cunlorming m ths standard may bc purcha=d from bke Products Company, Inc., P.0, Buc 2248, St.
I Louis, Mi.wuri 63W3.
I
4.7.4.2 [nterfncial tensinn. The interracial tension between 3 ~ 0.05 percent of type 3 or
6 & 0.1 percent of type 6 by volume in distilled water, as appropriate, and reagent grade
cyclohexane shall be determined with a DuNoy tensiometer, or equal, at 23 “C * 2.0 “C until
the readings come to equilibrium and in accordance with ASTM D1331.

4.7.5 Formability. The foam shall be generated by means of a special 2 gallons per minute
I (gaI/min) test nozzle. The basic nozzle, as made by National Foam S~tem, Inc., Lionville,
Pennsylvania, (or equal) shall be modified by shortening the length of the foam barrel from 2-
I 1/2 to 1-1/4 inches, and by adding a “wing-tip” spreader on the outlet. The spreader shall have
a US inch wide, circular orifice, 1-7/%inches long. (It may be made by slightly compressing a
I Bernz-o-matic TX-1527, or equal, flame spreader). A print of the nozzle cmstruction is
I
available from the Naval Research Laboratory, Code 6180, Washington. DC 20375. During
I foam sample collection, the nozzle inlet pressure shall be maintained at a 8auge pressure of 100
I pounds per square inch ([b/inz), and tbe solution temperature at 23 ‘C * 5.0 ‘C. The nozzle
shall be held at hip height and directed onto the backboard from a distance of 4 to 6 feel. The
method and procedure shall be in accordance with NFPA 412. Formability shall be run on 6
I percent fresh and sea water solutions of the type 6 enncentrate and 3 percent fresh and sea
water solutions of the type 3 concentrate.

4.7.6 Film fnrmntion and sealability.

4.7.6.1 Test equipment. A CRES graduated measure of 1,000 milliliter (mL) capacity (4-
1I2 inches in diameter, 5 inches deep; Cole-Parmer Co., Chicago, Illinois, or equal) shall be
fitted with two retaining clips at the top edge. The clips serve to restrain a cone 5 inches in

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height and 4-3/4 inches in diameter, made of SO-mesh perforated CRES, in an inverted position
inside the measure. The 2 gal/rein nozzle specified in 4.7.5 shall be used for foam production.

4.7.6.2 Test procedure. After placing 400 mL of water and 200 mI. of 98-percent
cyclohexane in the measure, 200 mL of freshly-made foam shall be poured onto the fuel. The
inverted cone shall be pushed down into the measure, thereby pushing most of the foam aside
but allowing the film-producing liquid to creep in through the mesh openings. A foam-free
surface shall be created by manually scooping out most of the residual foam from the center
of the cone. After a l-minute waiting period, a pilot flame shall be passed over the fuel
surface at a height of about 112inch. A small flash is permitted, but no sustained ignition shall
result, if an effective vapor seal is present. A 1-inch long pilot flame shall be provided with a
hand-held propane cylinder fitted with a capillary tubing outlet.

4.7.7 Corrosion. The liquid for immersion of the metal specimens for general corrosion
and locafized corrosion tests shall consist of the concentrate diluted by 10 percent by volume
with sea water.

4.7.7.1 General corrosion.

4.7.7,1.1 Test specimens. The test specimens shall consist of the following metals, in
accordance with UNS designations (see ASTM E.527): GIO1OO steel, C70600 copper-nickel
alloy, N04400 nickel-copper and C90500 bronze. Afl specimens, except the bronze, shall be
milied to finished dimensions of approximately 1/16 inch thick, lr2 inch wide, and 3 inches long.
The bronze shall have sand cast faces and be approximately 3/16 inch thick, lr2 inch wide, and
3 inches long. Aft specimens shall be degreased io acetone, rinsed with distilled water, and air
dried before exposure. (Prepared metal specimerp may be obtained from the Metaspec
Company, Box 27707, San Antonio, Texas 27227-0707.)

4.7.7.1.2 Test procedures. Five weighed specimens of each metal shall be fully immersed
in the test medium in a separate 600 mL beaker and held at room temperature for a period
of 60 days. A watch-glass cover shall be used to retard evaporation. At the end of the
exposure period, Lhe weight-loss shall be determined and the corrosion rate calculated as
required.

4.7.7.2 Locsdized corrosion.

4.7.7.2.1 Test specimens. The test specimens shall consist of UNS S30400 CRES milled
to finished dimensions of approximately 1/16 inch thick, 1/2 inch wide, and 3 inches long. After
decreasing with acetone, rinsing with distilled water, and air drying before exposure, the
specimens shall be pretreated by immersion in a 1:9 concentrated nitric acid-water solution for
a period of 5 minutes.

I 4.7.7.2.2 Pswcedure. Ten specimens shall be girdled lengthwise with a clean 1/16 to 1/8
inch wide band of a good grade of gum rubber of a size such that the band is taut during the
test. Because of tbe poor quality of most commercial rubber bands, it is recommended that the

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bands for this test be cut from 1-3/4 inch flat width pure gum amber tubing (Preiser Scientific
Rubber tubing, Pure Gum, Gooch type, 1/32-inch thin wall, pure gum amber tubing, very
elastic, especially made for Gooch crucibles, or equal). This tubing is most easily cut into
uniform strips with a blade-type papercutter, but can also be cut with sharp shears. The
specimens girdled with the robber bands shall be placed in a 600 mL beaker so that no contact
is made between individual specimens. A l/4-inch layer of glass beads shall be introduced into
the beaker to aid in stabilizing specimen position. Enough liquid shall be added to completely
immerse the specimens, and a watch-glass shall be placed over the beaker to retard evaporation
(but allow air a-) and act as a dust cover, and the assemblies allowed to stand at mom
, temperature for 60 days.

4.7.7.23 Results. The specimens shall be monitored daily over the 60-day period to
ascertain the presence or absence of pitling. These daily examinations shall be made without
disturbing the test (olher than removing the cover). Corrosion is customarily signaled by the
appearance of a dark spot which, if removed after suftlcient exposure, discloses a corrosion pit.
If the suspected area cannot be positively identified by the naked eye, it can be at a
magnification of 10X. At the end of the test, each specimen shall be inspected carefully with
particular attention being given to the edges of the specimens and those areas of the specimens
under or adjacent to the rubber bands. IOX magnification shall be used, if necessary.

4.7.S Totrd halides. The halide content shall be determined to be in accordance with
ASTM D1821, except for the following moditicationx
● a. Procedure
(1) Weight 4 * 0.1 g or add 4 * 0.1 mL of concentrate into a 250 mL beaker
(2) Add 75 mL of acetone. Add 2 mL of dilute nitric acid (one vohrrne of
concentrated acid to 60 volumes of water).
b. The calculation shall be modified as follows:
Halide content, p/m = 44.4(A-B).
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4.7.9 Dry chemical compatibility. The foam’s compatibility with potassium bicarbonate
I
dry chemical extinguishing agent shall be determined by measuring the burnback time in the
I
presence of dry chemical.
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4.7.9.1 Test mnterials. The fuel shall be unleaded gasoline conforming to ASTM D439.
The dry chemical agent shall conform to O-D-1407. The sieve shall be an 8-inch diameter, 40
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mesh sieve conforming to type I, style A of RR-S-366.

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4.7.9.2 Test procedure. A 28-square-foot fire test shall be conducted in accordance with
4.7.13.1 using type 3 or 6 AFFF sea water solution, as required. Before placing the burning
pan, one pound of d~ chemical agent shall be evenly distributed over the foam blanket with
the aid of a sieve on a long handle. This shall be accomplished within a 30-secortd period so
that the total time from end of foam application to placement of the burning pan will be not

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longer than 90 seconds. The burnback time shall be determined as in 4.7,13.1.4.

4.7.10 Stability.

4.7.10.1 Sample prepamtion. %mplcs of concentrate, and type 3 and type 6 AFFF frcsb
water and sea water solution, as appropriate, shall be prepared in sufficient quantity to perform
the required tests. One liter (L) of each shall be placed in lightly stoppcred glass cylinders.
AO samples shall then be stored at 65 “C & 2.0 “C for a period of 10 days. The samples shall
then be subjected to the following tests:

a. Spreading coefficient 4.7.4

b. Foamabilily 4.7.5
c. Film formation and sczrlabilily 4.7.6
d. Fire performance (28 t“(z) 4.7.13.1
e. Stratification 4.7.14
f. Precipitation 4.7.15’

I,n the ~re~ratinn of ,he ~mpk..,0 ~ “scd for lhc prccipim[inn IesI, the synthetic sea WIICr shall ~ filtered PriOr
10 use.

4.7.11 Comptitibility.

4.7.11.1 Sample prepamtion. Tbc Government

will provide samples of appropriate ●
qualified product(s) to manufacturers officially authorized to submit candidate material for
qualification (see 3.3.3). Mixtures, of the type 3 and type 6 concentrates, to be tested shall
be prepared in sufficient quantities to perform the required tests. (For qualification testing,
the testing activity will determine the number of product mixtures to be evaluated and the ratio
of produc[ comprising these mixtures.) Additionally, 3 percent of type 3 or 6 percent of type
6 AFFF fresh water and sea water solutions shall be prepared from cacb concentrate mixture.
Onc L of each shall be placed in lightly stoppered glass cylinders. Tbc samples shall be stored
at 65 ‘C & 2.0 “C for a period of 10 days. The samples shall then bc subjected to tbe following
tests:

a. Formability 4.7.5
b. Film formation and sealability 4.7.6
c. Fire performance (28 flz) 4.7.13.1
d. Stratification 4.7.14
e. Precipitation 4.7.15

4.7.12 Envimnmenttd impact.

4.7.12.1 Toxicity. Toxicity test shall be performed on tbe KiOicfish (Fundultis herteroc[itus)
in accordance with ASTM E729, using dynamic procedures. The minimum acceptable dissolved
Owgen content of water used in this procedure shall bc 5 p/m.

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MIL-F-24385F

I 4.7.12.2 Chemical oxygen demmsd (COD). COD shall be determined in accordance with
procedures in Standard Method for the Examination of Water and Waste Water (latest
applicable edition).

4.7.12S Biodegsndability. Biodegradability shall be determined by dividing tbe value

expressed in m@ for tbe 2fJ-day biOlOgical Oxygen demand (BC3D20) determined frOm 5-day
BOD test in aceordarree with the procedure specified in Standard Methods for the Examination
of Water and Waste Water (latest applicable edition) by the value expressed in mg/L for
chemical oxygen demand (COD) determined as specified in 4.7.12.2.
4.7.13 Firt test.l No tire test shall be conducted when the wind speed is above 10 miles
per hour (mi/lsr).

4.7.13.1 Twenty-eight-sqsmm-foot fire test.

1~~ tc.q.rare “omal~ conducted indeors 10 mmid adverse weathermndiliOnS.

4.7.13.1.1 Test equipment. The fire test shall be conduc!ed in a level, circular pan 6 feet
in diameter, fabricated from l/4-inch thick steel with a 4-inch high side. A shallow water layer
shall be used to protect tbe pan bottom and to ensure complete coverage of the area with fuel.
The nozzle used for foam application shall be the 2 gal/rein device specified in 4.7.5.

● 4.7.13.1.2 Test materials. Foam shall be generated at 23 ‘C & 5.0 “C from AFFF solutions
made with fresh or sea water, as required, at ‘mrrcentration values shown in table V. The fuel
shall be 10 gallons of unleaded gasoline conforming to ASTM D439.

TABLE V. AFFF lest concentration values.

t
1 Solutions Tyfx 3 TW 6
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t.eanl 1.5 * 0.03 3 ? O.1
Normal slrenglh 3 t 0.05 6 t O.1
Rich2 15 t 0.2 30 * 0.2

Ion= ,=! M,h fresh water imd one with sea Wter.
‘One tesr with sea water.

4.7.13.13. Test proeedrsre. The fuel shall be dumped within a 30-seeorrd period. The fuel
shall be ignited within 30 seconds of fueling and allowed to burn freely for 10 seconds. After
the preburn period, the fire shall be attacked and extinguished as expeditiously as possible and
tbe fire extinguishing time shall be reeorded at the exact cessation of all flame, but foam
application shall continue for a total of 90 seecmds.
4.7.13.1.4 Burnbnck prsseedrrre. Within 60 seconds of the completion of foam application,
a burning pan (1-foot in diameter with 2-irrch side) containing one gallon of unleaded gasoline

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MIL-F-24385F

shall be placed in the center of the 28-square-foot pan and a limer started. When it appears
that the fire has spread outside the pan so that burning will continue after pan removal, the
pan shall be removed. The burnback time is that time at which it is estimated that 7 square
feet (25 percent) of the total area is involved in flames.

NOTE

Intermillenl “ffash-overs” may occur. They are characterized by

creeping faint blue or invisible flames over the foam surface which
usually self-extinguish. They arc not considered a part of the
burnback area unless sustained burning occurs. AfI isolated, sustained
burning areas shall be included in arriving a! the 7-square-foot total
area.

4.7.13.2 Fifty-squure-foot fire test.

4.7.13.2.1 Test site. The fire test shall be conducted on a level, circular area 8 feet in
diameter. ‘fire base and surrounding wall shall be suitable for containment of the fuel on a
substrate of water. The water depth shall be the minimum required to ensure complele
coverage of the area wi[h the fuel.

4.7.13.2.2 Test equipment. The nozzle used for foam application shall be the 2 gal/rein
device specified in 4.7.5, operated at a gauge pressure or 100 lb/in2.

4.7.13.2.3 Test materiuls. The foam shall bc generated at 23 “C & 5.0 “C from 3 ~ 0.05
percent of type 3 or 6 t 0.1 percent of type 6 AFFF solutions made with sea water. The fuel
shall be 15 gallons of urdcaded gasoline conforming to ASTMD439.

4.7.13.2.4 Test procedure. The fuel shall be dumped into the area in less than 60 seconds
and ignited in less than 30 seconds after fuel dumping is completed. After allowing a preburn
period of 10 seconds the fire shall be attacked and extinguished in an expeditious manner. At
10-second intervals after the start of foam application, obsewers shall estimate the percentage
of fire area extinguished. The percentages at 10, 20, 30, and 40 seconds shall be totaled to give
the “40-second summation” value. The exact exlinguisbing time shall also be recorded at the
cessation of all flame, but foam application shall conlinuc for a total of W seconds.

4.7.13.2.5 Brrrnback procedure. Within 60 seconds of the completion of foam application,

a burnback test shall be conducted as specified in 4.7.13.1.4, except (bat the burnback area shall
be 12.5 square feet (25 percent).

4.7.14 StruIificntion. The presence of stratification shall be determined by visual

examination of the samples contained in the glass cylinders.

16

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4.7.15 Precipitation. The amount of precipitation shall be determined by centrifuging the
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100 mL sample withdrmvn from the 1-L sample after thorough agitation in accnrdancc with the
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primary method of ASTM D96
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4.7.16 Ffrmrirre cnntent.
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4.7.16.1 Qrmliffcution. The total fluorine content shall be determined. The total fluorine
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content and the test procedure used to determine the content shall be furnished as part of the
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qualification inspection report.
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4.7.16.2 Quulity corsforsrsnnce inspection. ‘fIre total fluorine content shall be determined
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in accordance with the test procedure furnished with the qualification inspection report (see
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4.7.16.1). The total fluorine content shall be included in tbe quality conformance inspection
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report.

4.7.17 Pnckuging inspection. Sample packages and packs and the inspection of
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presewation, packaging, packing, and marking for shipment and storage shall be in accordance
with the requirements of 4.6, section 5 and the documents specified therein. The magnetic
permeability test (for metal handles of 5-galIon containers) of 4.7.17.1 and the torque test (for
the pour cap of 5-gallon containers) of 4.7.17.2 shall be included.

4.7.17.1 Mugnetic permeability (metsd handles of 5-gullon corstuirsers). The metal handles
● of the 5-gallon containers shall be checked to determine conformance with the magnetic
requirements of 5.1.l.l.l.d using a permeability indicator, low-mu (GO-NO-GO) in acmrdance
with MfL-I-17214.

4.7.17.2 Torque test (pour cap of S-gsrllon corstniner). The pour cap of the 5-gallon
container shall be subjected to a torque test to determine conformance with 5.1.1.1.1 .f.

5. PACKAGING

(The packaging requirements specified herein apply only for direct Government acquisitions.
For the extent of applicability of the packaging requirements of referenced documents listed
in section 2, see 6.5).

5.1 Preservntinn-packugirrg. Preservation-packaging for level A shall be as specified

hereinafter.

5.1.1 The AFFF liquid concentrate shall be furnished in a 5-gallon plastic container or in
a 55-gallon composite container as specified (see 6.2.d).

5.1.1.1 Five-gallnn plustic corstniner. The container shall be molded polyethylene as

specified herein. The mntainer shall be as follows:

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MIL-F-24385F

a. Capacity S-gallon (min.)

b. Height, bndy (overall) 15-inches (max.)
c. Diameter, body (overall) 11-3/4 inches (max.)
d. Pour opening (inside dia.) 1-1/.2 inchex (min.)

5.1.1.1.1 The container shall meet the requirements of Department of Transportation

Specification Number 34 as specified in the Cnde of Federal Regulations, Tide 49, Part 178.19,
and as follow

a. Shall be stackable and self-supporting.

b. Shall be provided with a threaded-type plastic cap fitted with a gasket for the pour
opening.

c. May be provided with a vent opening having an easily punctured membrane.

When furnished, vcnl opening shall be provided with a threaded type plastic cap.

d. Shall be provided with an integrally molded or recessible plastic or metal handle.

Metal handles shall not exceed a magnetic permeability of 2.0.

e. Shall have colors conforming to 5.1.1.3, type 3 green, type 6 blue.

f. The torque required to remove the pour opening cap shall not exceed 50 inch
pounds. ●
5.1.1.2 Fifty-five gallon container. The 55-gallon container shall be a composite comprised
of a plastic insert and a steel drum overpack. The composite container shall conform to the
requirements of type II, class 4 of PPP-C-1337, and the following

a. Insert. The insert shall contain two protruding openings in the top head –
one 3/4-inch and one 2-inch. Openings shall be so designed that when positioned
in the steel drum cover there will be no strain on the protruding openings. The
protruding plastic openings shall be secured to the drum cover by means of lock
or retaining rings and gaskets. Openings shall be closed by use of NPT threaded
plastic plugs.

b. c o v e rs. Th e steel drum cover shall be provided with two openings to

accommodate the protruding insert openings. Covers shall be fully removable.
Cover gaskets are not required. Covers shall be secured to tbe steel drum with
minimum 16-gauge bolt or lever lock type locking rings.

5.1.13 Exterior color nnd crmting. The green color (see 3.5) shall be an approximate
match to color number 14187 of FED-STD-595. The blue color (see 3.5) shall be an
approximate match to color number 15123 of FE D-STD-595. Exterior coating for steel drum
overpacks shall cnnform to lT-E-489.

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5.2 Pocking. For level A no further packing is required.

5.2.1 Method of shipment shall comply with Uniform Freight Classification Ratings, Rules,
and Regulations or other carrier rules as applicable to the mode of transportation.
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5.2.2 Palletimtion.
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a. Thirty-six S-gallon plastic containers shall be palletized in accordance with the
requirements of MIL-STD- 147, load type XVII. Pallets conforming to NN-P-71,
type V, class I, wood group optional, size 2, are acceptable. Containem shall be
properly and firmly nested and arranged to ensure a snug, non-shifting load. Pallet
dimensions may be adjusted to ensure a snug, non-shifting load, but shall not
1.
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exceed 43 x 52 inches.

b. Invetied caps. The inverted cap shall be the open sheathing type, wood group
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optional.
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c. Top wood cap. The top wood cap shall be the closed sheathing (plywood) wood
cap, wood group optional for slats. In addition, each corner of the plywood cap
shall be secured to the end and side slats with strapping. Strapping shall be
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3/4 inch by 0.035 inch and shall extend a minimum of 3 inches into the plywood

‘o d.
top and slats. Nails used to secure the strapping shall be clinched.

Strapping. Afl primary, secondary, auxiliary, and horizontal strapping shall not be
less than 1-1/4 inches by 0.035 inches. Strapping shall conform to QQ-S-781, class
1, type I or IV, finish B. Cross ties shall be applied in accordance with
MIL-STD-147.

e. Skfe fmmes. Minimum size of side frame members shall be a nominal 1 X 6 inches
conforming to group I, II, 111,or IV of MIL-STD-731. Nails used to secure flat
surfaces of side frames shall be clinched not Icss than 1/4 inch.

I 53 Marking. In addition to the marking specified in 3.5 and any special marking required
(see 6.2.), containers and palletized unit loads shall be marked in accordance with
MIL-STD-129.
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6. NOTES

(This sec[ion contains information of a general or explanato~ nature that may be helpful, but
is not mandato~.)

6.1 Intended use. The concentrate is intended for use in mechanical foam generating
equipment such as fire-lighting trucks or foam sprinkler systems for extinguishing fires in
flammable liquids such as gasoline or fuel oils. Type 6 is intended for use in pmportioners
designed to dispense only the 6 percent solu[ion (usually shipboard fire protection systems).

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MIL-F-243S5F

Type 3 maybe used in any equipment capable of proportioning at variable rates or at tlxed 3
percent solution.

6.2 Acquisition requirements. Acquisition document should specifj the following

a. Title, number, and date of this specification

b. Issue of DODISS to be cited in the solicitation, and if required the specific issue
of individual documents referenced (see 2.1.1 and 2.2)
c. Type of concentrate required (see 1.2)
d. Size of container required (see 5.1.1)
e. Special marking, if required (see 5.3).

63 Considerrrtion of data requirements. The following data requirements should be

considered when this specification is applied irr a contract. The applicable Data Item
Description (DID’s) should be reviewed in conjunction with’ the specific acquisition to ensure
that only essential data are requested/provided and that the DID’s are tailored to reflect the
requirements of the specific acquisition. To ensure correct contractual application of the data
requirements, a Contract Data Requirements Lk.t (DD Form 1423) must be prepared to obtain
the data, except where DOD FAR Supplement 27.475-1 exempts the requirements for a
DD F orm 1423.

Reference psrmgmph DID number DID title Suggested tailoring

●
4.5 DI-T-2072 Test Report —

The above DIDwas cleared as of the date of this specification. The current issue of DOD
501O.12-L, Acquisition Management Systems and Data Requirements Control List (AMSDL),
must be researched to ensure that only current, cleared DID’s are cited on the DD Form 1423.

6.4 Qrmlifieution. Whh respect to products requiring qualification, awards will be made
only for products which are at the time set for opening of bids, qualified for inclusion in the
applicable QualifiedproductsList QPL 24385 whether or not such products have actually been
so listed by that date. The attention of the contractors is called to these requirements, and
manufacturers are urged to arrange to have the products that they propose to offer to the
Federal Government tested for qualification in order that they may be eligible to be awarded
contracts or orders for the products covered by this specilicalion. The activity responsible for
the Qualified Products L~t is Naval Sea Systems Command, SEA 51222, Department of the
Navy, Washington, DC 20362-5101, and information pertaining to qualification of products may
be obtained from that activity. Application for Qualification tests shall be made in accordance
with Provisions Governing Qualification SD-6 (see 6.4. 1).

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I 6.4.1 Copies of Provisions Governing Qualification SD-6 maybe obtained upon application
I to Standardization Document Order Desk, Building 4D, 700 Robbins Avenue, Philadelphia, PA
I 19120-5099.

6.5 Sub-euntmcted muterial and parts. The packaging requirements of referenced

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documents listed in section 2 do not apply when material is acquired by the contractor for
incorporation into the concentrate and lose separate identity when tbe euncentrate is shipped.

6.6 Chunges frum previuus issue. Marginal notations are not used in this revision to
identify changes with respect to the previous issue, due to the extensiveness of the changes.

Preparing activity
Navy – SH
(Project 4210-0445)

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MIL-F-24385F

“IHIS END UP

U.S.

AQUEOUS FILM FORMING FOAM (AFI:F) LIQUID CONCENTRATE

in accordance with

MILITARY SPECIFICATION MI L-F-24385F

TYPl? 3 (3%]

TuIs FIRE EXTINCiUISNING CONCENTRATE Is FOR usE BY DILUTION WITU WATER IN HXED OR

MOBILE SYSTEMS. IT MAY BE USED ALONE OR IN cOMBINATION WITN ‘TWINNED” DRY ?

CIIEMICAL EQUIPMENT. TNE CONCENTRATE MAY 13E DILUTED FOR USE IN FLOW

PROPORTIONING EQUIPMENT WITR SEA WATER OR FRESIi WATER AT VOLUME PROPORTIONS

OF TUREE GALLONS CONCENTRATE TO 97 GALLONS WAll?R. IT MAY ALSO BE DILUTED FOR

READY-USE STORAGE AT A THREE PllRCUNr PREM [X SOLUTION WIT}{ FRESN WATER.

FOR READY USE DO NOT STORE BELOW 32 “F. AVOID PROLONGED STORAGE AROVE 120 “F. DO

NOT MIX WITH OTUER THAN LIQU1O CONCENTRATE IN ACCORDANCE WI’111 MIL-F-24.3S5E(SH)
●
(AND PREVIOUS ISSUES) AND WATER.

MANUFACI’LSRERS NAME
ADDRESS
BATC1 I NO.
DATE OF MANUFACTURE

FIGURE 1. Type 3 container mnrkings.

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MIL-F-24385F

THIS END UP

Us.

AQUEOUS FILM FORMING FOAM (AFFP) LIQUID CONCENTRATE

In accordance wi~h

MILITARY SPECIFICATION MIL-F-24.W5F

TYPE 6 (6%)
*
THIS FIRE EXTINGUISHING CONCENTRATE IS FOR USE BY DILUTION WITN WATER IN FIXED OR

MOBILE SYSTEMS. IT MAY BE USED ALONE OR IN COMBINATION wnm -FWINNEIY DRY CHEMICAL
,

EQUIPMENT. THE CONCENTRATE MAY BE DILUTED FOR USE IN FLOW PROPORTIONING EOUIPMENT

WITH SEA WATER OR FRESH WATER AT VOLUME PROPORTIONS OF SIX GALLONS CONCENTRATE TO

94 GALLONS WA?ER. IT MAY ALSO BE DILUTED FOR READY-USE sTORAGE AS A SIX-PERCENT PREMIX

SOLUTION WITH FRESH WATER. FOR READY USE DO NOT STORE BELOW 32 “F. AVOID PROLONGED

flORAGE ABOVE 120 “F. DO NOT MIX WITH OTHER THAN L1OUID CONCENTRATE IN ACCORDANCE

● WSTH MIL.F-243S5~SH) (AND PREVIOUS ISSUES) AND WATER.

MANAUFACSURERS NAME
ADDRESS
BATCH NO.
DATE OF MANUFACTURE

FIGURE 2. Type 6 cormsiner mnrkings.

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STANDARDIZATION DOCUMENT IMPROVEMENT PROPOSAL

lNSTRUCllONS

1. The preparing astivity must complete blocks 1, 2, 3, and 8. In block 1, both the document number and revision
letter should be given.
2. The submitter of this form must complete blocks 4, S, 6, and 7.
3. The preparing activity must provide a reply within 30 days from receipt of the form.
I
NOTE: This form may not be used to request copies of documents, nor to request waivers, or clarification of
requirements on current contracts. Comments submitted on this form do not constitute or imply authorization to
I
waive any portion of the referenced document(s) or to amend contradual requirements.
I
2. D O C UMENT D ATE (WMMDDJ
I ~*”~~’~~=@~~~GE:
,., .+.,<..,.,.
.!.*@4,..:,.w,,*...,,.~.:,,,,,,,1+. ,.:.< I ;,~.;;;~,”’” 1 JANUARY 1992
) 1. WMENT TITLE
I FIRS EXTINGUISHING AGENT, AQUEOUS FILM- FORMING FOAM (AFFF) LIOUID CONCE~TE
I L NAIURE OF CHANGE (Idmsify pwagrap+i numbw ●nd indd proposed rewrite, if podble. At’rach ●tir. sheen ●s needed.)
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. REASON FOR RECOMMENDATION
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& O R G A NIZAT@N
.,,:,:..:. m:~ <.
.,~, :,,,;,,:, ,.:: .: :,:
d. TELEWON5 @xA@e ,lrea Coda)

. ~PAAMG AKTIVITY
NAME b. TELEPH O NE (ln d u d E Ar e a C o d e)
(1)
Commercial (2) AUTOVON
COKf4ANDER
(703) 602-5545 (AV) 332-5545
A C I O RESS (In c lu d e Zip C -d e ) 1$ Y O U D O N O T RE C EWE A REPLY WITHIN 45 OAYS, CONTA~
WASHINGTON, DC 20362-5101 Defense Quality ●nd Sszndardizatlon Office
5203 Leesbwg Pike, Suite 1003. Falls Church. VA .?2041.3466
Telephone (703) 756+300 AUTOVON 289.2300
I ,. ..——
w mrm
. .. .
8.La,
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03 F1-eVmn ealncln ●m OasOiere.
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