LAMPIRAN II

PERHITUNGAN

Masa NaOH 0,5 N

Volume 100 ml → 0,1 L
N x BM x %
gr = V
Val.Purity
40 100
= 0,5 x x x 0,1
1 99

= 2,02 gr
Dik :
Pichnometer = 12,45 gr
Pichnometer + Air = 17,2604 gr
Pichnometer +etil asetat = 17,1965 gr
Pichnometer + etanol = 16,1990 gr
Pichnometer + HCl 3N =17,2604 gr
Pichnometer + Asam Asetat = 5,09 gr

Mencari density
Berat akhir (isi)−Berat awal (kosong)
etanol = volume pichnometer
16,1990−12,45
= 5
0,749
=
5

= 0,7498 gr/ml

Berat akhir (isi)−Berat awal (kosong)

etil asetat = volume pichnometer
17,1965−12,45
= 5

= 0,9493 gr/ml
 Berat akhir (isi)−Berat awal (kosong)
HCl = volume pichnometer
17,4650−12,45
= 5

= 1,003 gr/ml

Berat akhir (isi)−Berat awal (kosong)

Air = volume pichnometer
17,2604−12,45
= 5

= 0,96208 gr/ml

Berat akhir (isi)−Berat awal (kosong)

Asam asetat = volume pichnometer
17,51−12,45
= 5

= 1,018 gr/ml

a. 5 ml HCl + 5 ml H2O
Massa H2O = v H2O X ρ H2O
= 5 X 0,96208 = 4,8104 gr
4,8104 gram
Mol H2O = = 0,2672 mol
18 gram/mol
Massa HCl = 5 X 1,003 = 5,015
5,015gram
Mol HCl = = 0,139
36 gram/mol

b. 5 ml HCl 3N + 5 ml CH3COOC2H5
Massa CH3COOC2H5 = 5 x 0,9493 gr
= 4,7465 gr
4,7465 gram
mol CH3COOC2H5=
88 gram/mol
= 0,05393 mol
Massa CH3COOC2H5 = 5 X 0,949
= 4,745
4,745gram
Mol CH3COOC2H5 =
88 gram/mol
 = 0,053 mol
0,5 gred
CH3COOC2H5 yang terbentuk = (2,0 – 0,33) ml x
1000 ml
= 1,67 x 0,0005
= 0,000835mol

Derajat persamaan :
HCl + CH3COOC2H5 ↔ C2H5Cl + CH3COOH
Mula-mula : 0,139 0,053 - -
Reaksi : -0,0521 -0,0521 -0,0521 - 0,0521

Setimbang : 0,1911 0,000835 -0,0521 -0,0521

(C2H5Cl)(CH3COOH)
K=
(CH3COOC2H5)(HCl)
[−0,0521][−0,0521 ]
=
[0,000835][0,1911]
0,00271
=
0,000159
= 17,071
c. 5 ml HCl 3 N +4 ml CH3COOC2H5 + 1 ml H2O
Massa CH3COOC2H5 = 4 ml x 0,9493 = 3,796 gr
3,796 gram
mol CH3COOC2H5 = = 0,043 mol
88 gram/mol
Massa H2O = 1x 0,962 gr/ mol = 0,962 gr
0,962 gram
Mol H2O = = 0,05344 mol
18 gram/mol

Massa NaOH yang terpakai 1,9 ml

0,5 gred
CH3COOC2H5 yang terbentuk = (1,9 – 0,33) ml x
1000 ml
= 1,57 x 0,0005
= 0,000785mol
 Derajat persamaan :
CH3COOC2H5 + H2O ↔CH3COOH+ C2H5OH
Mula-mula : 0,043 0,05344 - -
Reaksi : - 0,0422 -0,0422 -0,0422 -0,0422

Setimbang : 0,000785 0,0956 -0,0422 -0,0422

(CH3COOH)(C2H5OH)
K=
(CH3COOC2H5)(H2O)
[−0,0422][−0,0422]
=
[0,000785][0,0956]
0,00178
=
0,0000750
= 23,73

d. 5 ml HCl 3 N + 2 ml CH3COOC2H5 + 3 ml H2O

Massa CH3COOC2H5 = 2 x 0,9493 = 1,898 gr
1,898 gram
mol etil asetat = = 0,021 mol
88 gram/mol
Volume NaOH yang terpakai = 1,7 ml
0,5 gred
CH3COOC2H5 yang terbentuk = (1,7 – 0,33) ml x
1000 ml
= 1,37 x 0,0005
= 0,000685mol

Derajat persamaan :
CH3COOC2H5 + H2O ↔ C2H5OH + CH3COOH
Mula-mula : 0,021 0,160 - -
Reaksi : 0,0203 0,0203 0,0203 0,0203

Setimbang : 0,000685 0,1397 0,0203 0,0203

(C2H5OH)(CH3COOH)
K=
(CH3COOC2H5)(H2O)
 [0,0203][0,0203]
=
[0,000685][0,1397]
0,000412
=
0,0000956
= 4,3096

e. 5 ml HCl 3 N + 4 ml CH3COOC2H5 + 1 ml C2H5OH

Massa CH3COOC2H5 = 4 x 0,9493 = 3,79 gr
3,79 gram
mol etil asetat = = 0,043 mol
88 gram/mol
Massa C2H5OH = 1 x 0,749 = 0,749
0,749 gram
Mol C2H5OH = = 0,016
46 gram/mol

Volume NaOH yang terpakai = 1,5 ml

0,5 gred
CH3COOH yang terbentuk = (1,5 – 0,33) ml x
1000 ml
= 1,17 x 0,0005
= 0,000585 mol

Derajat persamaan :
CH3COOC2H5 + C2H5OH ↔ CH3COOH + C4H8OH
Mula-mula : 0,043 0,286 - -
Reaksi : -0,042 -0,042 -0,042 -0,042

Setimbang : 0,000585 0,328 -0,042 -0,042

(C4H8OH)(CH3COOH)
K=
(CH3COOC2H5)(C2H5OH)
[−0,042 ][−0,042]
= [0,000585][0,328]
0,00176
=
0,000191
= 9,214
f. 5 ml HCl 3N + 4 ml CH3COOC2H5 + 1 ml CH3COOH
Massa CH3COOC2H5 = 4 x 0,9493 = 3,796 gram
3,79 gram
mol CH3COOC2H = = 0,043 mol
88 gram/mol
Massa CH3COOH = 1 x 1,018 = 1,018 gram
1,018 gram
Mol CH3COOH = = 0,016
60 gram/mol

Volume NaOH yang terpakai = 1,8 ml

0,5 gred
CH3COOC2H5 yang terbentuk = (1,8 – 0,33) ml x
1000 ml
= 1,47 x 0,0005
= 0,00073 mol

Derajat persamaan :
CH3COOC2H5 + CH3COOH ↔ C2H5OH + C4H8OH
Mula-mula : 0,043 0,016 - -
Setimbang : -0,042 -0,042 -0,042 -0,042

Setimbang : 0,00073 0,058 -0,042 -0,042

(C2H5OH)(C4H8OH)
K=
(CH3COOC2H5)(CH3COOH)
[−0,042][−0,042]
= [0,00073 ][0,058]
0,00176
=
0,0000423
= 41,702

g. 5 ml HCl 3N + 4 ml C2H5OH + 1 ml CH3COOH

Massa C2H5OH = 4 x 0,749 = 2,996 gr
2,996 gram
mol C2H5OH = = 0,065 mol
46 gram/mol
Massa CH3COOH = 1 ml x 1,018 = 1,018
 1,018 gram
Mol CH3COOH = = 0,016
60 gram/mol

Volume NaOH yang terpakai = 1,2 ml

0,5 gred
CH3COOC2H5 yang terbentuk = (1,2 – 0,33) ml x
1000 ml
= 0,87 x 0,0005
= 0,00043 mol

Derajat persamaan :
C2H5OH + CH3COOH ↔ CH3COOC2H5 + H2O
Mula-mula : 0,065 0,286 - -
Setimbang : 0,00043 0,016 0,00043 0,00043

Setimbang : 0,06457 0,27 0,00043 0,00043

(CH3COOC2H5)(H20)
K=
(C2H5OH)(CH3COOH)
[0,00043][0,00043]
= [0,06457][0,27]
0,00000018
=
0,0174
= 0,0000106