Astm C876-15
Astm C876-15
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This standard is issued under the fixed designation C876; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
5. Apparatus
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This test method is under the jurisdiction of ASTM Committee G01 on 5.1 The testing apparatus consists of the following:
Corrosion of Metalsand is the direct responsibility of Subcommittee G01.14 on
Corrosion of Metals in Construction Materials. 5.1.1 Reference Electrode:
Current edition approved Nov. 1, 2015. Published April 2016. Originally 5.1.1.1 The reference electrode selected shall provide a
approved in 1977. Last previous edition approved in 2009 as C876–09. DOI: stable and reproducible potential for the measurement of the
10.1520/C0876-15.
2
For referenced ASTM standards, visit the ASTM website, www.astm.org, or
contact ASTM Customer Service at [email protected]. For Annual Book of ASTM
3
Standards volume information, refer to the standard’s Document Summary page on The last approved version of this historical standard is referenced on
the ASTM website. www.astm.org.
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States
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FIG. 1 Reference Electrode Circuitry
4
FIG. 2 Sectional View of a Copper-Copper Sulfate Reference
Hampel, C. A., The Encyclopedia of Electrochemistry, Reinhold Publishing
Electrode
Co., New York, 1964, p. 433.
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the two methods described in 7.4.3 or 7.4.4 with the solution and that no electrically conductive part other than the porous
described in 5.1.3 to decrease the electrical resistance of the tip of the copper-copper sulfate electrode reference electrode
circuit. comes in contact with water including use of cable connectors
7.4.2 A test to determine the need for pre-wetting shall be specifically designed for use with submerged reference elec-
made as follows: trodes.
7.4.2.1 Place the reference electrode on the concrete surface
7.5.2 Perform horizontal and vertically upward measure-
and do not move.
ments exactly as vertically downward measurements.
7.4.2.2 Observe the voltmeter for one of the following
However, additionally ensure that when using a copper/copper
conditions:
sulfate electrode that the solution in the reference electrode
(1) The measured value of the corrosion potential does not
makes simultaneous electrical contact with the porous plug and
change or fluctuate with time.
the copper rod at all times.
(2) The measured value of the corrosion potential changes
or fluctuates with time.
8. Recording Corrosion Potential Values
7.4.2.3 If condition (1) is observed, pre-wetting the concrete
surface is not necessary. However, if condition (2) is observed, 8.1 Record the electrical corrosion potentials to the nearest
pre-wetting is required for an amount of time such that the 0.01 V. Report all corrosion potential values in volts and
voltage reading is stable (60.02 V) when observed for at least correct for temperature if the reference electrode temperature is
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preted as indicative of corrosion rate, or even as indicative of
a corrosion reaction.
11. Report
11.1 Report the following information:
11.1.1 Type of cell, used including calibration details and
KCl solution concentration for Ag/AgCl/KCl reference
electrodes,
11.1.2 The estimated average temperature of the reference
electrode during the test,
11.1.3 The method for pre-wetting the concrete member and
the method of attaching the voltmeter lead to the reinforcing
steel,
11.1.4 An equipotential contour map, showing the location
of reinforcing steel contact, or a plot of the cumulative
frequency distribution of the corrosion potentials, or both,
11.1.5 The percentage of the total corrosion potentials that
are more negative than −0.35 V or other suitable lower
threshold, and
11.1.6 The percentage of the total corrosion potentials that
are less negative than −0.20 V or other suitable lower thresh-
FIG. 3 Equipotential Contour Map old.
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grid patter. Six laboratories collected data using the saturated calculated as 2.8 sR, 57 mV.
copper/copper sulfate reference electrode. In addition, four NOTE 2—The saturated KCl silver/silver chloride reference electrode
laboratories also used the saturated KCl silver/silver chloride has a standard potential of +196 mV versus the SHE while the saturated
reference electrode with the same procedure. The results of this copper/copper sulfate electrode has a standard potential of +300 mV
(Practice G3, Table X2.1). The average potential difference between the
program were analyzed according to the Practice E691 proce- copper/copper sulfate reference electrode and silver/silver chloride refer-
dure. ence electrode was 128 mV in this study rather than 104 mV as predicted
12.1.2 Repeatability—The repeatability standard deviations by Practice G3. The reason for this difference was not determined.
for each slab using the copper/copper sulfate reference elec- 12.2 Bias—There is no bias in the potentials measured by
trode are shown in Table 1. The repeatability standard devia- this method because the potentials measurements are defined
tions for these slabs using the KCl saturated silver/silver only in terms of this method.
13. Keywords
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Supporting data have been filed at ASTM International Headquarters and may
be obtained by requesting Research Report RR:G01-1027. Contact ASTM Customer
13.1 concrete-corrosion activity; concrete-corrosion of rein-
Service at [email protected]. forcing steel; corrosion; corrosion activity; corrosion potentials
TABLE 1 Electrode Potentials and Standard Deviations of Steel Rods in Concrete Slabs Versus Saturated Copper/Copper Sulfate
Reference Electrode
NOTE 1—All values in mV.
Slab No. Ave. Electrode Potential Repeatability SD Reproducibility SD
sr sR
1 -520.3 19.3 20.8
2 -173.5 11.8 14.7
3 -461.0 15.6 26.1
4 -557.5 11.3 12.0
5 -535.0 21.7 21.7
APPENDIX
(Nonmandatory Information)
X1.1 Numeric Magnitude Technique—Laboratory testing X1.1.4.1 To evaluate reinforcing steel in concrete that has
(partial immersion in chloride solutions) and outdoor exposure carbonated to the level of the embedded steel,
(including chloride exposure) of various reinforced concretes X1.1.4.2 To evaluate indoor concrete that has not been
aboveground in an area in which the precipitation rate ex- subjected to frequent wetting unless it has been protected from
ceeded the evaporation rate, indicate the following regarding drying after casting,
the significance of the numerical value of the potentials
measured. Voltages listed are referenced to the copper-copper X1.1.4.3 To compare corrosion activity in outdoor rein-
sulfate reference electrode. Other criteria may apply in other forced concretes of highly variable moisture or oxygen content,
situations (see, for instance, 10.2). or both, at the embedded steel, and
X1.1.1 If potentials over an area are more positive than X1.1.4.4 To formulate conclusions concerning changes in
−0.20 V CSE, there is a greater than 90 % probability that no corrosion activity with time on a rehabilitated structure in
reinforcing steel corrosion is occurring in that area at the time which the rehabilitation caused the moisture or oxygen content,
of measurement. or both, at the embedded steel to change with time (for
example, installation of a low permeability overlay or water-
X1.1.2 If potentials over an area are in the range of −0.20 to
proof membrane on a chloride-contaminated bridge or parking
−0.35 V CSE, corrosion activity of the reinforcing steel in that
deck).
area is uncertain.
X1.1.3 If potentials over an area are more negative than X1.2 Potential Difference Technique—Where large areas of
−0.35 V CSE, there is a greater than 90 % probability that electrically interconnected, embedded steel exist, for example,
reinforcing steel corrosion is occurring in that area at the time in bridge decks, reinforced columns, or beams, careful mea-
of measurement. surement of potentials in a closely spaced grid pattern and the
X1.1.4 These criteria should not normally be utilized under subsequent plotting of equipotential contour maps may allow
the following conditions unless either experience or destructive identification of high versus low corrosion rate areas (see Refs
examination of some areas, or both, suggest their applicability: 1-8).
REFERENCES
(1) Spellman, D. L., and Stratfull, R. F., “Concrete Variables and Administration, Washington, DC, 1981.
Corrosion Testing,” Highway Research Record 423, 1973. (5) Virmani, Y. P., Clear, K. C., and Pasko, T. J., Jr., “Time-to-Corrosion
(2) Stratfull, R. F., “Half-Cell Potentials and the Corrosion of Steel in of Reinforcing Steel in Concrete Slabs,” Vol. 5, Federal Highway
Concrete,” Highway Research Record 433, 1973. Administration Report FHWA/RD-83/012, Washington, DC, Septem-
(3) Clear, K. C., and Hay, R. E.,“ Time to Corrosion of Reinforcing Steel ber 1983.
in Concrete Slabs,” Vol. 1, Federal Highway Administration Report (6) ACI Committee 222, “Corrosion of Metals in Concrete,” ACI 222R-
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FHWA-RD-73-32, Washington, DC, April 1973. 85, American Concrete Institute, Detroit, MI, 1985.
(4) Clear, K.C., “FCP Annual Progress Report-Year Ending September (7) “Durability of Concrete Bridge Decks,” NCHRP Synthesis of High-
30, 1981, Project 4K: Cost Effective Rigid Concrete Construction and way Practice 57, Transportation Research Board, Washington, DC,
Rehabilitation in Adverse Environments,” Federal Highway May 1979.
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