Tag 4 Tag Flash Point Tester: Instruction Manual
Tag 4 Tag Flash Point Tester: Instruction Manual
Tag 4 Tag Flash Point Tester: Instruction Manual
what is measurable,
and make measurable
that which is not.
Galileo Galilei (1564 – 1642)
TAG 4
Instruction Manual
TAG 4
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Anton Paar GmbH assumes no liability for technical or printing errors or omissions in this document.
Nor is any liability assumed for damages resulting from information contained in the document.
Anton Paar GmbH reserves the right to content changes. This also extends to changes to delivery
volumes or any features of delivered parts.
All rights reserved (including translation). This document, or any part of it, may not be reproduced,
changed, copied, or distributed by means of electronic systems in any form (print, photocopy,
microfilm or any other process) without prior written permission by Anton Paar GmbH.
Trademarks, registered trademarks, trade names, etc. may be used in this document without being
marked as such. They are the property of their respective owner.
Published by Anton Paar
Printed: Anton Paar, Austria
Copyright © 2010 Anton Paar GmbH, Graz, Austria
E-Mail: [email protected]
Web: www.anton-paar.com
Date: 14.09.2015
Document number: H09IB001EN-A
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INHALTSVERZEICHNIS
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4.3. Program tables ................................................................................................................... 47
4.3.1. Program table °C ......................................................................................................... 47
4.3.2. Program table °F .......................................................................................................... 48
4.3.3. Program parameter in °C ............................................................................................. 49
4.3.4. Program parameter in °F .............................................................................................. 51
4.4. Barometric correction ......................................................................................................... 53
4.5. Printed protocol of a test run ............................................................................................... 54
5. Parameters .............................................................................................................................. 55
5.1. Program parameters........................................................................................................... 55
5.2. Device parameters ............................................................................................................. 63
5.3. Changing of parameters ..................................................................................................... 66
5.3.1. Changing the program parameters............................................................................... 66
5.3.2. Changing of device parameters ................................................................................... 67
5.4. Printing the parameters ...................................................................................................... 68
5.4.1. Printing the program parameters .................................................................................. 68
5.4.2. Printing the device parameters ..................................................................................... 68
6. Functions DISPLAY HISTORY and PRINT HISTORY ............................................................ 70
7. Flash point determination acc. to ISO 1516/ASTM D 3934 and ISO 1523/ASTM D 3941..... 71
7.1. Test conduct according to ISO 1516/ASTM D 3934............................................................ 72
7.2. Test conduct according to ISO 1523/ASTM D 3941............................................................ 75
8. Rapidflash simulation programs............................................................................................ 76
8.1. Rapidflash-Simulation for flash points<ambient RT1<ambient ............................................ 76
8.2. Rapidflash-Simulation for flash points>ambient RT2>ambient ............................................ 78
9. Safety Mode: Dip-in tests every 10°C .................................................................................... 79
10. Maintenance .......................................................................................................................... 80
11. Trouble shooting ................................................................................................................... 81
11.1. Calibration ........................................................................................................................ 81
11.1.1. Calibration of the Pt100 sensor .................................................................................. 81
11.1.2. Calibration of the device with flash point reference materials ..................................... 84
11.2. Trouble shooting ............................................................................................................... 84
11.2.1. Display does not work when switched on ................................................................... 84
11.2.2. Gas ignition does not work ......................................................................................... 84
11.2.3. Gas flame is unstable ................................................................................................. 85
11.2.4. Electric ignition does not work .................................................................................... 85
11.2.5. No indication of sample temperature .......................................................................... 85
11.2.6. Device does not start after pressing RUN-key ............................................................ 85
11.2.7. Flashpoints of reference materials do not comply with the certificate ......................... 85
11.2.8. Indication FP no GAS................................................................................................. 86
11.2.9. Permanent audible alarm ........................................................................................... 86
11.3. Replacing the electric ignition ........................................................................................... 87
12. Spare Parts ............................................................................................................................ 88
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1. IMPORTANT NOTES
WARNING
TAG 4 107101 (with water cooling) must never be operated without circulating cooling
liquid. (damage of cooling assembly)
Thank you for purchasing the new TAG 4 which by its patented construction offers easy handling in
sample changes.
Conventional devices require ignition, moving of the lid and indication as separate operation steps
while changing the samples, whereas the TAG 4 does all this for you in one go by gently pushing
the multifunction head.
The advantages are obvious: In most cases more than one test insert can be filled ready for
change at the same time, covered with lids and multifunction detectors- all set for change.
The actual sample change after a completed test thus is not only faster but also requires less of
the users attention since this is all done practically as the device goes along. This of course means
less errors (Ignition connected? Sensor inserted? etc.) because the user can direct all his or her
attention to the important tasks.
With the new electric ignition system the TAG 4 offers another important improvement. Despite the
compact size of the device it contains an intelligent ignition control. You will be reminded if the
ignition needs changing. The ignition itself is operated at its optimum and therefore lasts much
longer. Especially the voltage fluctuations common to the industry in 24-hour-operation are now
perfectly absorbed.
Of course you can run your TAG 4 with a gas ignition as well. The electric ignition then is used as
an aid to ignition. This comes in handy when doing reference tests and for general assumptions.
The electric ignition controls and ignites the gas flame at start of test or reignites it automatically in
case of extinction. Please ensure a low pressure gas supply to avoid problems at setting.
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1.1. Liability
The device is an electrically operated appliance. It may not be operated unattended or in
areas at risk of explosion or damp locations. Whenever the device is used, a thorough
knowledge of the Instructions for Use and compliance with same is assumed. In all cases the
operator is liable for the safe operation of the device if it is not used according to instructions.
Repair of the device must be carried out only by Anton Paar ProveTec GmbH. Only original
Anton Paar ProveTec parts and replacement parts must be used to operate the device.
The use of a standard may involve hazardous materials, operations and equipment. A
standard does not purport to address all of the safety problems associated with its use. It is
the responsibility of the user of this standard to take appropriate measures for protection of
the safety and health of the personnel prior to application of this standard, to check whether
statutory requirements exist for this purpose and to fulfill these requirements.
Anton Paar ProveTec is not responsible for damage or malfunctions caused by the operator
using the device improperly or contrary to the instructions. We reserve the right to make
technical changes.
DANGER
This device is not to be used in explosive atmospheres!
1.2. Warranty
1. Anton Paar ProveTec products are warranted against defects in material and
workmanship for a period of one year from the date of purchase.
2. Anton Paar ProveTec will replace or repair products - free of any charge - that fail as a
result of defective materials or workmanship within the warranty period.
3. None of the obligations of Anton Paar ProveTec shall apply to any products which have
been subjected to misuse, neglect, accident or any extreme environmental condition or
improper handling.
4. If defective products are returned to Anton Paar ProveTec, the costs of such return will
be borne by the customer, and those of delivering the repaired or replacement products
to the customer will be borne by Anton Paar ProveTec.
Anton Paar ProveTec’s sole liability shall be to repair or replace any product which proves to
be defective. In no event shall Anton Paar ProveTec be liable for any special incidental,
consequential, indirect or other similar damages arising from failure of its products.
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1.3. Service
Should you require service, please contact our Anton Paar service department.
For EU countries:
Directive 2002/96/EC: Directive 2002/96 of the European Parliament and of
the Council of 27 January 2003 on waste electrical and electronic
equipment.
(Anton Paar ProveTec Registration Number WEEE 80418806).
The directive describes the obligation to not dispose of electrical and
electronic devices as unsorted municipal waste and to collect this WEEE
separately. Contact us for an authorized waste disposal company in your
country.
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1.5. Device Specific Safety Information
Please take into account that handling with flammable material always is dangerous. The
instrument should only be used by trained staff or those who have been instructed
accordingly.
The TAG 4 was constructed for use according to the named applications. For use apart from
the named applications we cannot make any kind of confirmations about safety and
functioning.
Please take care to pay attention to the safety regulations referring to the handling of gas.
This refers as well to regularly inspections of the gas supplies and tubes.
If the possibility of health injuries by evaporating gases exists insert the TAG 4 into a drain.
Please take care to keep adequate distance between the device and flammable materials.
It can never be totally excluded that a sample might be burning longer than expected and
therefore can cause damages. Please make sure only to use the device without watching
when handling known samples and when there is absolutely no risk for the surroundings.
DANGER
To prevent injuries never touch the test insert or other components of the device which might
be hot during test.
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1.6. Summary of all Warnings in this Document
10. When setting up the device select a location away from heat, smoke, electrical or
magnetic interference and avoid excessive electrostatic discharges (ESD) to the device.
The bench top must be a level surface and free of vibration.
11. The device is tested to comply with the limits of the European Electromagnetic
Compatibility (EMC) Directive 2004/108/EC. However this device generates radio
frequency energy. If the device is not installed or used in accordance with the instruction
manual it may cause interference to radio communications.
12. Ensure the heater of the device is not exposed to flammable liquids or other combustible
material including the packaging material. Clean the surface before starting a heater test.
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2. DESCRIPTION OF THE DEVICE
Fig. 1
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2.1. Device properties and connection values
Conditions of transport:
Temperature: -50°C up to +50°C
Relative air humidity: max. 90%
Vibrations: 8 to 120Hz at 30m/s2 max.
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2.3. Components
Fig. 2
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Front side
1 Multifunction head
2 Multi detector for flashpoint and temperature
3 Indicator for gas flame
4 Ignition system
5 Test insert with lid (107205)
6 Ignition (gas or electric ignition)
7 Display
8 Cursor-keys
9 STOP-key
10 RUN (START)-key
11 ENTER-key
Rear side
12 ON/OFF-switch
13 Gas connection (for external gas supply)
14 Connecting cable for sensor
15 Control cable for stepping motor
16 Printer interface (RS 232)
17 PC interface (RS 232)
18 Connection for external cooling (only 107098)
19 Alternating switch 115V/230V and fuse holding device
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3. PUTTING INTO OPERATION
3.1. Location
Because of heat emission please make sure the TAG 4 stands freely.
Please take care the device is not exposed to draft. Draft might falsify the measured
flashpoint and influence the gas flame's function control.
If you place more than one TAG 4 next to each other you should separate them with an
appropriate screen since their ventilation can influence their performance in temperature
increase and flashpoint.
3.2.1. Installation
On the bottom part a column has to be mounted (acc. to drawing 4) which holds the
multifunction head later on.
The column is screwed onto the bottom part as shown in drawing 4 with the partition pointing
to the left.
Mount the multifunction head on the bottom part by inserting the bolt into the guide of the
column. Make sure that the pin clicks into place.
Turn the multifunction head to the right and click it into place.
Connect plug for step motor control and the multi detector at the back of the device.
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Fig. 3
At mounting the multifunction head please make sure the column at the head's front side
exactly hits the pin of the crucible.
Normally this is done before delivery.
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Therefore please release the metal casing by loosening the screws.
At the rear you find the adjusting screw (refer to graph 5). By loosening this screw the head
can be brought in the required position.
Afterwards please tighten the screw again and mount the casing.
Fig. 4
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3.2.1.2. Mounting of the test cup holder (109319)
The test cup holder is mounted on the left of ABA 4 rear side. The 2 screws at the left of the
rear panel are loosened and fixed again together with the holder.
At devices using external cooling a cryostat has to be connected with the two pipe unions at
the rear side of the device. It is not important which pipe is connected with the coolant supply
and which one with the coolant outlet.
WARNING
Never use silicon oil as coolant!
We recommend to use a mixture of water and glycol as coolant.
Cooling circuit
Recommended medium: a) Water to +2°C
b) 67Vol.% Water+ 33Vol.% Glycol - mixture below +2°C
Permissable flow rate: 1 l/min...2 l/min
Maximum permissable pressure: 1 bar
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The following flashpoints can be achieved by different coolant's temperatures:
Please be aware that the mounted Peltier-elements can only realize a temperature difference
of about 60°C. Therefore to achieve the auto start temperature at low flashpoints the cryostat
temperature has to be pre-set low.
At higher flashpoints the cryostat temperature has to be pre-set accordingly higher (see
table).
In relation to the material used (high viscose/ low viscose) the given flashpoint range can
vary slightly.
Please bear in mind that according to the standard the empty sample insert has to be
precooled to a temperature of 10°C below the expected flashpoint.
Therefore the parameter for auto start has been set to 11°C below the expected flashpoint in
the reference programs.
3.2.3. Switching on
Before connecting the device to the mains please ensure that the stated voltage on the back
matches the mains or - if necessary - adjust accordingly.
Connect printer (if existent) to the printer interface at the back of the device.
Printer must be switched on prior to switching on the TAG 4 to ensure that the head line will
properly be printed with actual date.
When using a gas ignition connect the external gas supply to the back of the device.
Please fix the electric ignition in its holding or when using the gas ignition in the holding for
the ignition's aid.
In the TAG 4-crucible you will find a circular mark indicating the filling amount of 50 ml.
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After inserting the sample TAG 4 lid and crucible will be connected by a bayonet joint.
Fig. 5
Insert the multi detector into the test insert (cup and lid). Position test insert into the TAG 4
and turn the multifunction head towards you so that the connection between multi detector
and stirrer is made.
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After a brief self test the device gives a quadruple signal to indicate readiness.
The introduction menu displayed is the following:
Sample temperature
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3.3. Menu Guidance
Pressing <ENTER> will position the blinking cursor on the display at the decimal digit of the
flashpoint preselection.
With the keys < Arrow right> and <Arrow left> you can get from one menu point to the other.
With the keys <Arrow up> and <Arrow down> within the respective menu you select your
choice and confirm with <Enter>.
If you move the cursor keys to a menu point and confirm with <ENTER> without having
made a selection yet the display will explain the respective menu points.
If within 10 sec you don’t put anything in while being in a submenu the device will
automatically return to the initial position.
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3.3.1. Status display
The respective explanation is given on display when moving the cursor keys to the menu
point status indication and once again pressed <ENTER>.
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STOPgas Safety feature
If the magnetic valve for gas ignition is opened and the indicator for ignition
flame control is not given a signal for an ignition flame after 50 sec the
magnetic valve automatically turns off again and the program is at STOP.
STOPgrad The expected flashpoint temperature cannot be achieved because the pre-
set cryostat temperature is too low.
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WARNING
The functions STOPgas, STOPhead, STOPsen, STOPign, STOPgrad will be
printed out. On the display you can just see STOP. By moving the cursor to
STOP and <ENTER> you can call up the explanations.
The test has to be started all over again with a lower flashpoint preselection.
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FPok The device detected a flashpoint.
The detected flashpoint corresponds to the standard preselected for
flashpoint preselection and test range.
FPinval A flashpoint being detected during the ignition's first immersion or during
safety mode is not valid.
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FPnoP02 The flashpoint was detected by a
non-standard test.
The pre-set cryostat temperature
was too high so the auto start
temperature could not be
achieved or using devices with air
conditioning the auto start
temperature cannot be achieved
because the ambient temperature
is too high.
noFP No Flashpoint was found in equilibrium program EQ1 according to ISO 1516
or in Rapidflash-Simulation programs RT1 and RT2.
OVERFLO 10°C above the pre-set temperature of the expected flashpoint the program
automatically is aborted for safety reasons.
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3.3.2. Programs
D56-LoVisco Program acc. to ASTM D 56 for low viscous samples, auto start at EFLP-
11°C then rise of temperature 1°/min, 1. ignition test 5°C below expected
flashpoint.
D56-HiVisco Program acc. to ASTM D 56 for high viscous samples, auto start at EFLP-
11°C then rise of temperature 1°/min, 1. ignition test 5°C below expected
flashpoint.
RAPID-LoVisc RAPID-Program for low viscous samples, auto start at EFLP-11°C. First
rise of temperature 3°/min, then 1°/min or. 5°C/min, then 3°C/min , 1.
ignition test 5°C below expected flashpoint.
RAPID-HiVisc RAPID-Program for high viscous samples, auto start at EFLP-11°C then
rise of temperature 3°/min, then 1°/min resp. 5°C/min, then 3°C/min, 1.
ignition test 5°C below expected flashpoint.
SEARCH-LoVis Search program for low viscous samples, cooling of the sample to -35°C,
then rise of temperature 5°/min, ignition test immediately every 2°C
SEARCH-HiVis Search program for high viscous samples, cooling of the sample to -35°C,
then rise of temperature 5°/min, ignition test immediately every 2°C
EQ1-ISO_1516 Equilibrium method acc to ASTM D 3934, 10min tempering of the sample
at preselected flash point then flash point test
EQ2-ISO_1523 Equilibrium method acc ISO 1523, tempering at expected flash point-5°C
and 1. flash point test, then temperature rise 0,5°C/1,5min until flash point
or overflow
RT1<ambient Rapidflash simulation program for flash points < ambient temperature
(only possible with Rapidflash-Set 107240)
RT2>ambient Rapidflash simulation program for flash points > ambient temperature
(only possible with Rapidflash-Set 107240)
UserProgram1 User program 1, free programmable, pre-set with program ASL
UserProgram2 User program 2, free programmable, pre-set with program ASH
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By scrolling with the cursor keys the bottom line shows the following:
DISPLAY HISTORY the results of the last 99 tests conducted can be called-up on
the display
PRINT HISTORY the last 99 test results are printed
PRINT PARAMETER prints the current program parameters
CHANGE PARAMETER jumps to the SETUP-Menu for the program parameters
PRINT MANUAL a brief manual is printed
3.3.3. Sample ID
For sample- and user-ID you are given 7 digits which can be used for alphabetical (A to Z) or
numerical (0 to 9) signs.
If a new user name is put in the header is automatically printed out anew.
The four latest used sample names are saved together with all parameters (used program,
expected flashpoint) and can be called up again by scrolling with the cursor keys.
If the last 3 digits of the sample name are numeric, the sample number is automatically
counted up. To activate this function however the device parameter 29 has to be set at 0001
(chapter 5.2 and 5.3.2).
Example:
• OEL0001 at 1. test
• OEL0002 at 2. test and so on
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3.3.4. Choice of the ignition system to be used
Beim TAG 4 ist es möglich, sowohl eine Elektro- als auch eine Gaszündung zu verwenden.
Fig. 6
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For selection of the ignition please move the
cursor to the ignition symbol.
The selection can be checked by means of the symbol appearing on the display:
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Electric ignition
The electric ignition is put into the ignition holder and fixed with a knurled head screw. Both
ignition plugs are connected into the sockets at the upper surface of the device.
WARNING
Before plugging in the ignition make sure that the knurled head screw is nearly loose
since otherwise the ignition coils could be damaged.
Menu point ELECTRIC IGNITOR contains a submenu for the exchange of the electric
ignition after ageing or short circuit.
See 11.3 Re-placing the electric ignition
Gas ignition
Using the gas ignition the electric ignition has to be used as auxiliary ignitor fixed in a special
support.
WARNING
Make sure that the igniter cables are not bended and don't interfere with the gas
supply, e.g. when moving the multifunction head.
WARNING
For safety reasons the gas valve is switched off during delivery!
Before starting a test please conduct a manual immersion test to put the gas ignition into
operation.
Therefore press <arrow up> and keep it pressed until the escaping gas is ignited by the
electric ignition. (The opening of the magnetic valve is indicated by a faint cracking sound.)
This ensures that the gas has been in all hoses before the test.
Simultaneously the gas valve can be set in that manner, that the ignition flame reaches an
average of 4mm according to standard.
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To shorten the initial ignition process the valve can be CAREFULLY opened a tiny bit for a
very short period of time.
Safety function
If the flame indicator registers no ignition flame within 50 sec the magnetic valve
automatically switches off.
WARNING
For the gas-connection use tubes which are admitted for gas-operation only!
WARNING
If after a program was started the device realizes that there is no electric ignition
connected the program automatically returns to STOP and the following malfunction
message is given.
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3.3.5. Expected flashpoint
To change the preselection move the cursor to the flashpoint preselection, set the requested
value with the arrow keys and confirm with <ENTER>.
The expected flashpoint can be altered even while the program is running.
Just press the <ENTER>-key during the running program and the cursor will flash at the ten
digit of the flashpoint preselection. You can now alter your preselection and confirm with
<ENTER>.
However, if the program has already proceeded to the test range (ignition started) and you
increase the preselection that high, that the program is out of test range again, the ignition is
turned off again.
The temperature of the heating block is expressed on the display by the following symbols:
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Program has been started. Block is heating.
(One bar means approx. 1 min until reaching the
test phase.)
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3.3.8. Setting barometric pressure correction
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4. TEST CONDUCT
The programs D56-LoVisco and D56-HiVisco are standard programs according to ASTM D
56 for low as well as high viscous samples. If the viscosity of the sample can't definitely be
identified as low or high always the program for low viscous samples should be used.
The auto start temperature is about 11°C below the expected flashpoint.
The first flashpoint test has to be carried out at 5°C below the expected flashpoint and then
every 0,5°C (EFLP under 60°C) and every 1°C (EFLP above 60°C).
According to standards the rise of temperature is preset with 1°C/min for flashpoints
expected below 60°C and with 3°C/min for flashpoints expected above 60°C.
The programs RAPID-LoVisc and RAPID-HiVisc are programs appropriate for high
flashpoints (above 70°C).
The auto start temperature is about 11°C below the expected flashpoint.
The temperature gradient at beginning is 3°C/min or 5°C/min. At 25°C below the expected
flashpoint the gradient is slowed down to the normal rise of 1°C/min or 3°C/min.
The first flashpoint test will be conducted at 5°C below the expected flashpoint - and then
every 0,5°C resp. every 1°C.
H09IB001EN-A - 39 -
4.1.3. Programs SEARCH-LoVis and SEARCH-HiVis
These programs are search programs for unknown samples. The auto start temperature is
145°C below the expected flashpoint which has to be set to 110°C.
Using devices with external cooling the cryostat temperature has to be set to a low value
(e.g. -15°C). The sample has to be cooled down to -35°C and then be put into the precooled
crucible (see test conduct).
The temperature gradient will be 5°C/min the ignition immediately dips every 2°C.
Because the cooling of the Peltier elements can only realize a temperature difference of
about 60°C between cryostat temperature and sample temperature, the program will be
stopped at approx. 50°C because of missing sample gradient.
If up to then the device didn't detect a flashpoint the test has to be repeated at a higher
cryostat temperature.
Before starting a new test (after setting the cryostat temperature to a higher value) program
parameter 02 for autostart temperature should be set to a lower value to make an autostart
at 50°C then. For achieving this, program parameter 02 must be set to 0600 (60°C) with an
expected flash point of 110°C.
Programs EQ1-ISO_1516 and EQ2-ISO_1523 are programs for equilibrium methods acc to
ASTM D3934/ISO 1516 (EQ1) und ASTM D 3941/ISO 1523 (EQ2).
Depending on the indication of a flash point as a result either FP (flash point detected) or
noFP (no flash point detected) are documented.
EQ1 is preset to a test conduct acc to ASTM D 3934 and can be set to a test conduct acc to
ISO 1516 by setting program parameter 30 to 0002.
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According to ASTM D 3941/ISO 1523 the sample is temperated at 5°C below test
temperature. As soon as the sample has attained the bath temperature a flash point test is
performed. If a flash point is indicated the test has to be repeated at a 5°C lower test
temperature. If no flash point was found the sample is heated at 0,3°C/min and flash point
tests are performed each 0,5°C until a flash point is found or the overflow is attained.
Programs RT1<ambient and RT2>ambient are simulation programs for rapid test methods
according to ISO 3679, 3680, EN 456, DIN 55680, ASTM D 3828.
As this is only a simulation of rapid flash tests deviations to the flash points from the original
device are possible.
The USER programs are free programmable user programs. At delivery the parameters of
the programs D56-LoVisco (UserProgram1) and D56-HiVisco (UserProgram2) are
programmed.
After programming new parameters these are stored even after switching the device off and
on again.
In all other programs except UserProgram1 and UserProgram2 parameters can be changed
but are only stored until the next switching off of the device. Switching on again reinstalls the
pre-set parameters.
H09IB001EN-A - 41 -
4.2. Program start
4.2.1. Precooling
The TAG 4 allows precooling of the heating block as well as the empty sample insert by
using the function "Precooling". It is activated by <arrow left>.
The heating block will be cooled down to a temperature about 17°C below the expected
flashpoint and kept there for 5 minutes. If during that time no program start took place the
block will be heated up to 25°C (at EFLP<60°C) resp. 35°C (at EFLP>60°C) to prevent icing-
up.
If the cooling gradient becomes as low as 0.1°/min, the cooling will be stopped even without
achieving the temperature. After an acoustic signal this block temperature will be kept for 5
minutes. By this function icing-up of the cooling block can be prevented at extremely low
temperatures.
CAUTION
Is the block temperature not sufficient, a lower cryostat temperature has to be chosen.
Using devices cooling by air the precooling depends highly upon the ambient temperature. If
the required temperature can't be achieved the ambient temperature might be too high
The block will be cooled down to auto start temperature (in the standards 11°C below
expected flashpoint). This temperature will be kept for 5 min.
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At achieving this temperature you can hear a
short acoustic signal. The display shows:
flashing
This test conduct is possible with pure materials. Working with mixed compounds the sample
should always be cooled down to the temperature recommended by standards.
H09IB001EN-A - 43 -
4.2.2. Working with gas ignition
Before using the gas ignition for the first time it is recommended to conduct a manual test to
make sure that the gas has already reached the tip of the ignition jet. Therefore press the key
<arrow up> in the <STOP>-Status and keep it pressed until gas is escaping and ignited by
the electric ignition. Release key then and let the device conduct an immersion test.
Before using the gas ignition for the first time the gas supply to the TAG 4 is filled with air
instead of gas. Therefore it will take some time till the gas is set free from the jet. To increase
the speed you can accelerate the outflow speed (Attention: Take care because the flame will
be larger now).
Press the key <arrow up> till gas escapes from the jet and is ignited by the electric ignition.
WARNING
If the speed of outlet is too high the gas stream will cool down the glowing electric
ignition: No flame can emerge!.
After selecting the requested program, the flashpoint preselection and the ignition the
<START>-key can be pressed.
You can go ahead even if shortly after pushing the multifunction head the sample
temperature is not yet displayed.
- 44 - H09IB001EN-A
Once the program is started you will have
following display:
Independent from the flashpoint preselection it is possible (until 5°C/9°F before test range) to
initiate a flashpoint test with the key <arrow up> at any time.
H09IB001EN-A - 45 -
If a flashpoint was detected depending on the compliance with the standards the display
shows the following:
FPok: The detected flashpoint was found in accordance with the relevant standard.
On the left (main) display always the barometric corrected rounded flash point is displayed.
You can switch to the right (sub) display by pressing <ENTER>, moving the cursor to "FPok"
and pressing <ENTER> again. On this display the values for the uncorrected and corrected
not rounded flash point are shown additionally.
The test has to be repeated with a new sample and a flashpoint preselection at least 10°C
lower than before.
- 46 - H09IB001EN-A
If no flashpoint was detected the device automatically stops at a sample temperature of 10°C
above expected flashpoint:
H09IB001EN-A - 47 -
4.3.2. Program table °F
- 48 - H09IB001EN-A
4.3.3. Program parameter in °C
H09IB001EN-A - 49 -
Programm/Parameter EQ1- EQ2- RT1 RT2 User User
ISO_1516 ISO_1523 <ambient >ambient Prog1 Prog2
01: Test function 0000 0000 0000 0000 0000 0000
02: Autostart 0100 0100 0040 0030 0110 0110
03: init heat.diff 1/10°C a 0000 0000 0000 0000 0000 0070
04: init heat diff 1/10°C b 0000 0000 0000 0000 0070 0120
05: start diff 1/10°C a 0000 0000 0000 0000 0000 0070
06: start diff 1/10°C b 0000 0000 0000 0000 0070 0120
07: 1. sample grad 1/10°C a 0000 0000 0000 0000 0010 0010
08: 1.samplegrd 1/10°C b 0000 0000 0000 0000 0030 0030
09: 2. samplegrd 1/10°Ca 0000 0003 0000 0000 0010 0010
10: 2. samplegrd 1/10°Cb 0000 0003 0000 0000 0030 0030
11: grad1->grad2 1/10°C a 0000 0050 0030 0000 0000 0000
12: grad1->grad2 1/10°C b 0000 0050 0030 0000 0000 0000
13: block nomvalue 1/10°Ca 0000 0000 0000 0000 0000 0000
14: block nom value 1/10°Cb 0000 0000 0000 0000 0000 0000
15: overflow 1/10°C 0100 0100 0100 0100 0100 0100
16: stirrer speed (rpm) 0000 0000 0000 0000 0000 0000
17: precooling time sec 0300 0300 0300 0300 0300 0300
18: block temp at stop 1/10°Ca 0250 0250 0250 0250 0250 0250
19: block temp atstop1/10°Cb 0350 0350 0350 0350 0350 0350
20: Stop after flashp1/0 0001 0001 0001 0001 0001 0001
21: Testcycle 1/10°C a 9999 0005 9999 9999 0005 0005
22: Testcycle 1/10°C b 9999 0005 9999 9999 0010 0010
23: sampletempcontr on/off a 0001 0001 0001 0001 0001 0001
24: sampletempcontr on/off b 0001 0001 0001 0001 0001 0001
25: start testcycle a 0000 0050 0000 0000 0050 0050
26: start testcycle b 0000 0050 0000 0000 0050 0050
27: a logic -> b logic 0600 0600 0600 0600 0600 0600
28: No Gradient logic 0001 0001 0001 0001 0001 0001
29: (0/1/2) calprog 0000 0000 0000 0000 0000 0000
30: (0/1/2/3/4/5) standard 0001 0003 0004 0005 0000 0000
31: (0) Reserved 0000 0000 0000 0000 0000 0000
32: (0) Reserved 0000 0000 0000 0000 0000 0000
33: (0) Reserved 0000 0000 0000 0000 0000 0000
34: (0) Reserved 0000 0000 0000 0000 0000 0000
35: (sec) Printcycle 0060 0060 0060 0060 0060 0060
- 50 - H09IB001EN-A
4.3.4. Program parameter in °F
H09IB001EN-A - 51 -
Programm/Parameter EQ1- EQ2- RT1 RT2 User User
ISO_1516 ISO_1523 <ambient >ambient Prog1 Prog2
01: Test function 0000 0000 0000 0000 0000 0000
02: Autostart 0180 0180 0070 0050 0200 0200
03: initheat. diff 1/10°F a 0000 0000 0000 0000 0030 0130
04: init heat diff 1/10°F b 0000 0000 0000 0000 0130 0220
05: start diff 1/10°F a 0000 0000 0000 0000 0030 0130
06: start diff 1/10°F b 0000 0000 0000 0000 0130 0220
07: 1.samplegrd 1/10°F a 0000 0000 0000 0000 0020 0020
08: 1.samplegrd 1/10°F b 0000 0000 0000 0000 0050 0050
09: 2.samplegrd 1/10°F a 0000 0005 0000 0000 0020 0020
10: 2.samplegrd 1/10°F b 0000 0005 0050 0000 0050 0050
11: grd1->grd2 1/10°F a 0000 0090 0050 0000 0000 0000
12: grd1->grd2 1/10°F b 0000 0090 0000 0000 0000 0000
13: blocknomval 1/10°F a 0000 0000 0000 0000 0000 0000
14: blocknomval 1/10°F b 0000 0000 0000 0000 0000 0000
15: overflow 1/10°F 0180 0180 0180 0180 0180 0180
16: stirrer speed rpm 0000 0000 0000 0000 0000 0000
17: precooling time sec 0300 0300 0300 0300 0300 0300
18: block temp atstop1/10°Fa 0770 0770 0770 0770 0770 0770
19: block temp at stop1/10°F b 0950 0950 0950 0950 0950 0950
20: Stop after flashpoint 1/0 0001 0001 0001 0001 0001 0001
21: Testcycle 1/10°F a 9999 0010 9999 9999 0010 0010
22: Testcycle 1/10°F b 9999 0010 9999 9999 0020 0020
23: sampletempcontr on/off a 0001 0001 0001 0001 0001 0001
24: sampletempcontr on/off b 0001 0001 0001 0001 0001 0001
25: start testcycle a 0000 0090 0000 0000 0100 0100
26: start testcycle b 0000 0090 0000 0000 0100 0100
27: a logic -> b logic 1400 1400 1400 1400 1400 1400
28: No Gradient logic 0002 0002 0002 0002 0000 0000
29: (0/1/2) calprog 0000 0000 0000 0000 0000 0000
30: (0/1/2/3/4/5)standard 0001 0003 0004 0005 0000 0000
31: (0) Reserved 0000 0000 0000 0000 0000 0000
32: (0) Reserved 0000 0000 0000 0000 0000 0000
33: (0) Reserved 0000 0000 0000 0000 0000 0000
34: (0) Reserved for test 0000 0000 0000 0000 0000 0000
35: (sec) Printcycle 0060 0060 0060 0060 0060 0060
- 52 - H09IB001EN-A
4.4. Barometric correction
The integrated barometric pressure sensor enables automatic barometric correction of the
test result. The corrected flashpoint will be printed.
On main display (standard setting) the barometric pressure corrected rounded flash point is
displayed. By setting of device parameter 10 it is also possible to show on main display the
uncorrected flash point or the not rounded flash point.
H09IB001EN-A - 53 -
4.5. Printed protocol of a test run
ANTON PAAR PROVETEC BLANKENFELDE-MAHLOW Tel:033708-56300
TAG 4-Version 13.05.2006 Device No 00000001 Date 14.05.2006
OPERATOR XXXXXXX
SAMPLE PROG EFP SAMPLE FPcor FPcrd BAP GRAD IGN STATUS TIME
NAME NAME °C °C °C °C kPa °C/min G/E (HH:MM)
DODECAN D56-LowVisc 0800 081.0 80,6 80,5 102.7 001.0 E FPok 06:14
The head line will only once be printed when the instrument is switched on.
If the operator is changed, the headline will be printed again.
- 54 - H09IB001EN-A
5. PARAMETERS
The parameters of the TAG 4 are divided in program parameters and device parameters.
Program parameters of all programs except the user programs User1and USER 2 are initiated at
switch-on. Any change undergone in the programs are lost after turn-off.
The device parameters are exclusively for service purposes and should at no means be changed.
Select a program with the cursor in the opening menu and confirm with
<ENTER>.
Then move the cursor to the program and change with <ENTER> to the
sub menu.
DISPLAY HISTORY
PRINT HISTORY
PRINT PARAMETER
CHANGE PARAMETER
PRINT MANUAL
For test/special function set parameter value and then press <ENTER> to
execute
H09IB001EN-A - 55 -
Test/special functions:
0001 Flash programming
1011 Safety mode on
1234 Jump to device setup menu
2000 Print device parameter
4010 Initialize device parameter
4020 Initialize userprogramparameter, samplelabels & operatorname
9990 Ignition lifetime test
9991 Barometer pressure test
9992 Indicator test
9993 Setup date/time
9994 Pt100 amplifier adjustment (excl software offset)
9997 Ignition dip test
9998 Pt100 software offset adjustment
0998 testprint after start, every P35 value & display block / sample
temperature
0997 Display ignition current on test cycle
0996 Display gas flame indicator
0990 Display NTC value
0950 Display inspection counter
Parameter 1: will be set to the a.m. value and confirmed with <ENTER>.
- 56 - H09IB001EN-A
0001 A software upgrade
can be entered into
the device from a
computer.
The display shows:
H09IB001EN-A - 57 -
B behind the
temperature
display designates
the block
temperature.
- 58 - H09IB001EN-A
Parameter 2: 1/10°C
Auto start, when sample temperature <= EFLP-P02
Is the program started at a temperature higher than EFLP-P02, first the
device cools down to the required start temperature. Having achieved the
right temperature it starts automatically.
Parameter 3: 1/10°C
Initial temperature difference (a)
Initial heating parameter. After starting the device heats up to the sample
temperature + difference to initial temperature. Then it switches to normal
heater control according to starting temperature difference (Parameter 5
and 6).
This parameter helps to achieve the standard gradient very quickly.
Parameter 4: 1/10°C
Initial temperature difference (b)
Parameter 5: 1/10 °C
Start temperature difference (a)
After achieving the initial temperature difference the device switches to
start temperature difference (Sample temperature + Parameter 5) and
starts the heat control.
Parameter 6: 1/10 °C
Start temperature difference (b)
Parameter 7: 1/10°C
1. Sample Gradient (a)
Rise 1 of sample temperature per minute
Parameter 8: 1/10°C
1. Sample Gradient (b)
Parameter 9: 1/10°C
2. Sample Gradient (a)
Rise 2 of sample temperature per minute
H09IB001EN-A - 59 -
Parameter 13: 1/10°C
Block nominal value - P13 when gradient 1 --> gradient 2 (a)
Block nominal value - P13 when switching from gradient 1 to gradient 2
Because in the RAPID programs the second gradient is smaller than the
first one, to achieve a quick result the temperature of the heating block
has to be reduced.
CAUTION
Parameter 27 divides the flashpoint tests in 2 temperature areas - flashpoints higher or
lower than given in parameter 27.
During test procedure it is possible to define 2 different speeds of temperature rise e.g.
like in the RAPID programs.
These different gradients can be determined differently for both temperature areas a
and b referring to parameter 27.
Example:
A USER program has to be prepared in which at flashpoints below 50°C the rise of
temperature at the beginning is 1°C/min. Afterwards starting at 20°C below expected
flashpoint the rise is decreased to 0,5°C/min. At flashpoints above 50°C the rise of
temperature is given with 3°C/min, then decreased to 1°C/min. Parameters have to be
set like following:
If a very high gradient has to be decreased to a very low one in parameters 13 and 14
reductions of the heater block's temperature have to be noted. If necessary the respective
suitable value has to be determined by testing several times.
- 60 - H09IB001EN-A
Parameter 15: 1/10°C
Overflow = EFLP+P15
If no flashpoint is detected the device automatically switches to STOP at
10°C above expected flashpoint (safety function)
H09IB001EN-A - 61 -
Parameter 23 1/0
sample temperature controlling on/off (a)
For normal tests this parameter is set to 1, that means the temperature
rise is controlled in the sample.
For high viscous samples this parameter can be set to 0. Now the
temperature is controlled only in the heating block. The block temperature
is increased only by the required temperature rise of the sample. So it is
possible to prevent local overheating in the sample because the
temperature rise in the sample is slower.
- 62 - H09IB001EN-A
Parameter 31: Reserved
Parameter 32:
Parameter 33:
Parameter 34:
Parameter 5: Unused
H09IB001EN-A - 63 -
Parameter 11: Flash point registration at theoretical test temperature off on (0/1)
Flash point is registrated in PMA4 at the temperature when it happens.
Depending on the sample gradient this may also be at a temperature
value other than full numbers (e.g. 60,2°C).
When this parameter is set to 0001 flash point is always registrated at
theoretical test temperature (e.g. 60,0°C; 61,0°C or 62,0°C).
The parameter is preset to 0000.
Parameter 15: Switching from gas to electric ignition by setting parameters to 0000 or
0001. (The option gas or electric ignition is usually set directly in the
menu)
Parameter 22: Threshold value for gas flame indication (relative temperature in digit)
According to this threshold values it will be detected if the gas ignition
flame is on or off.
- 64 - H09IB001EN-A
Parameter 24: Unused
Parameter 25:
Parameter 26:
Parameter 27:
Parameter 28:
Parameter 29: If the last 3 digits of the sample name are numerical, the sample number
is increased by one after each flashpoint test.
After switch-on or off it the counting starts from the last number counted.
This function is switched on/off by setting the parameter to 0000/0001.
Parameter 33:
H09IB001EN-A - 65 -
5.3. Changing of parameters
Only the programs UserProgram1 and UserProgram2 can be changed permanently (User
programs).
In all other programs modifications are accepted, but will be deleted after switching off.
With each new switching on of the TAG 4 all program-parameters are newly initialized.
To change parameters move the cursor to the relevant program and press <ENTER>.
DISPLAY HISTORY
PRINT HISTORY
PRINT PARAMETER
CHANGE PARAMETER
PRINT MANUAL
On the left the number of the parameter is shown (here: program parameter 1), on the right
the parameter's value.
With the cursor by the left you can select the number of the parameter to change.
With the cursor you can as well select the new value of the parameter and confirm with
<ENTER>.
If the parameter was changed, but not confirmed with <ENTER> and only left with <STOP>,
the former value of the parameter will be kept.
- 66 - H09IB001EN-A
5.3.2. Changing of device parameters
The device parameters are set by the manufacturer and should not be changed by the user
except device parameter 1 (Offset Pt100), 4 (Barometric correction) and device parameter 29
for counting numerically set sample names.
To change a device parameter in any given program change to the program parameter set.
For parameter 1 put in value 1234 and confirm with <ENTER>.
Display:
As with the program parameters the number of the parameter will be displayed left and the
value on the right. Changes are made with the cursor keys and confirmed with <ENTER>.
The changes will remain permanent even after switching off the device.
H09IB001EN-A - 67 -
5.4. Printing the parameters
In any program after calling up function CHANGE PARAMETER set parameter 1 to test code
2000 and confirm with <ENTER>.
- 68 - H09IB001EN-A
20=2000 (trel) E-IGN: Threshold overdrive indicator
21=0000 (0) Unused
22=1500 (trel) Threshold gas flame indicator
23=0300 (trel) GAS-IGN: Threshold overdrive indicator
24=0000 (0) Unused
25=0000 (0) Unused
26=0000 (0) Unused
27=0000 (0) Unused
28=0000 (0) Unused
29=0000 (0/1) Increment sample label
30=0000 (0/1) Cooling system (air/liquid)
31=3700 (dgt) NTC threshold
32=0000 (0) Unused
33=0000 (0) Unused
H09IB001EN-A - 69 -
6. FUNCTIONS DISPLAY HISTORY AND PRINT HISTORY
Not used memory space (number of tests conducted <99) will be shown as "INVALID".
OPERATOR XXXXXXX
SAMPLE PROG EFP SAMPLE FPcor FPcrd BAP GRAD IGN STATUS TIME
NAME NAME °C °C °C °C kPa °C/min G/E (HH:MM)
- 70 - H09IB001EN-A
7. FLASH POINT DETERMINATION ACC. TO ISO 1516/ASTM D 3934 AND
ISO 1523/ASTM D 3941
ISO1516/ASTM D 3934 and ISO1523/ASTM D 3941 are equilibrium methods for flash point
determination, the sample to be tested and the air/vapor mixture in the cup are in thermal
equilibrium.
For these programs a special test procedure is necessary.
In these programs it is not possible to change the expected flash point in a running test. A manual
test is also not possible. In the small cup the difference between sample and heater block is much
greater than 2°C according to standard, it is also not possible to use a small cup for the equilibrium
tests.
When tests are performed in the air-cooled device the user must pay attention that the preselected
test temperature is in the working range of the device (+10°C to +110°C).
The sample Pt100 must be aligned against the block temperature sensor and a calibrated
thermometer. This procedure should be done with a calibration lid (107197), best when the device
has not been working over a longer period because in the air-cooled device there would be an
influence from the cooling elements to the heater block and therefore to the temperature sensor.
In the water cooled device the cryostat should be switched off.
An offset for the sample Pt100 must be entered into device parameter 1 and an offset for the block
Pt100 is entered into device parameter 23.
If the adjustment is not done correctly the regulation to the equilibrium temperature will last for a
longer time.
Some requirements of the standards are inaccurate and had to be modified for the test run. The
sample has to reach the same temperature like the heater bath. For this temperatures above and
below room temperature were not considered in the standards because for both the sample will not
reach the bath temperature as it is additionally influenced by the ambient temperature (e.g. through
the cover). That is why we introduced an internal heater block correction that guarantees that the
sample will attain the test temperature.
H09IB001EN-A - 71 -
7.1. Test conduct according to ISO 1516/ASTM D 3934
Program EQ1-ISO_1516 has to be selected.
The test temperature has to be corrected for barometric pressure and then it is entered in the
menu as expected flash point. After introducing the (if necessary precooled to 10°C below
test temperature) sample the test is started with RUN.
After the sample has attained the test
temperature it is held at this temperature for
10min. On the display this is shown by counting
the time down from 600 seconds to 0:
- 72 - H09IB001EN-A
If a flash point is found the test is terminated and
the following display is shown:
If no flash point is found the test is stopped according to ASTM D 3934 with the following
message:
H09IB001EN-A - 73 -
After time expiration a second flash point test is performed.
Test is terminated after the second test is finished:
To switch between test conduct according to ASTM D 3934 and ISO 1516 program
parameter 30 is set to 0001 (ASTM D 3934, preset as standard setting) or 0002 (ISO 1516).
- 74 - H09IB001EN-A
7.2. Test conduct according to ISO 1523/ASTM D 3941
Program EQ2-ISO_1523 has to be selected.
According to ISO 1523 the (precooled) sample is introduced into the device. Then the
sample is temperated to 5°C below test temperature (expected flash point).
As soon as the sample has attained the bath temperature a flash point test is performed.
When a flash point is found the test must be repeated at a test temperature that is 5°C lower.
Display:
If no flash point is detected the sample is heated with 0,3°C/min and flash point tests are
performed each 0,5°C.
Test runs until a flash point is found or the overflow at 10°C above the expected flash point is
attained. According to ISO 1523 a test duration of 1 hour should not be exceeded.
As a result the barometric pressure corrected, to 0.5°C rounded flash point is displayed.
H09IB001EN-A - 75 -
8. RAPIDFLASH SIMULATION PROGRAMS
Programs RT1<ambient and RT2>ambient are for test simulation acc to ISO 3679, ISO 3680, EN
456, DIN 55680
It is ONLY possible to work in these programs with Rapidflash-set 107240.
This set consists of a special cup with a similar volume like in the rapid tester, a special lid, a
multisensor for flash point detection, a sample syringe and a stopper for closing the opening in the
lid.
In RT1<ambient and RT2>ambient instead of the sample temperature detected with the
multisensor a corrected block temperature based on the real block temperature is displayed. That
is why also a sample temperature will be shown on the display although the head is off and the
multisensor is not connected.
In RT1<ambient and RT2>ambient the multi detector is only used for flash point detection.
As this is a simulation of tests with the rapid tester, the flash point values found can deviate from
values that were found with the original equipment.
When the filling temperature is reached there will be an acoustic sound for filling the
precooled sample with the syringe into the test cup. When the sample was inserted this is
confirmed with <ENTER>.
After this the device heats up to the test temperature (expected flash point).
The igniter is switched on and one dip-in test is carried out:
- 76 - H09IB001EN-A
Depending on a flash point was found or not the test is finished and on the display appears:
no flash point:
flash point:
FPinval (Flash point invalid) shows that a flash point was found at first dip-in (this is always
the case in the RT programs).
According to standard now the flash point preselection has to be changed and the test
repeated with fresh sample.
H09IB001EN-A - 77 -
8.2. Rapidflash-Simulation for flash points>ambient RT2>ambient
Program RT2>ambient is selected.
The empty cup with lid and multi detector is
placed into the device.
After program start the device cools down to 3°C
below expected flash point (autostart). After
attaining the auto start temperature it heats to
test temperature (expected flash point).
The result is similar to the test conduct in RT1<ambient either "noFP" (no flash point) or
FPinval (flash point).
According to standard the test has to be repeated if necessary with fresh sample and a
modified preselection.
For sample filling there will an acoustic sound for maximum 10min, after 10 min
without confirming the sample filling with <ENTER> a dip-in test will be carried out
and the test will be stopped.
- 78 - H09IB001EN-A
9. SAFETY MODE: DIP-IN TESTS EVERY 10°C
In TAG 4 a safety mode can be activated, that recognizes a wrong flash point preselection.
The safety mode is activated by inserting test code 1011 into program parameter 1 of any program.
1. Immediately after achieving the autostart temperature one flash point test is carried out.
The test is done with an active electric or gas igniter. A too low flash point can already be
detected here.
2. The active igniter dips in further at 10°C intervals until the test temperature is reached.
Samples with too high flash point preselection can be detected early enough to prevent any
hazard. The flash point is already detected at a lower temperature and the test will be stopped
then.
Every flashpoint detected during the safety mode is displayed as FPinval (invalid flash point).
H09IB001EN-A - 79 -
10. MAINTENANCE
We take regularly maintenance of the unit for granted which should be carried out by the user
himself or trained personnel at the given time intervals.
The given time intervals can be seen as reference to a normal operation of 8 hours every day.
Depending on the intensity of use the intervals might have to be extended or shortened.
After a certain number of tests on TAG 4 display the
message appears:
By pressing any key the display returns to the normal start display.
If the Inspection message occurs, please contact Anton Paar ProveTec service for further
information.
** The message "Change Ignitor" is only displayed at the TAG 4 – not at the PC
- 80 - H09IB001EN-A
11. TROUBLE SHOOTING
11.1. Calibration
Fig. 7
H09IB001EN-A - 81 -
Due to calibration lid in the calibration set it is possible to check the display of the Pt100 in
the STOP-mode as well as in the running program.
In the selected program the program parameter 29 has to be set to 0001 or 0002.
Remove the 4 fixing screws at the upper part of the device (multifunctional head) and
CAREFULLY lift up the cover.
Place the calibration lid on the cup filled with sample and insert the Pt100 to be checked into
the cup.
The calibration points for thermometer 109317 (Temperature range -5°C to +110°C) are 0°C;
35°C; 70°C and 105°C.
The calibration points for thermometer 109318 (Temperature range -20°C to +50°C) are
-20°C; 0°C; 25°C and 50°C.
Calculate the deviations by aid of the information given in the calibration certificate, for
example:
deviation acc. to certificate +0.3°C at 35°C. Temperature, at which you read: 35,3°C.
The program is started in the usual way. According to selected program following printout is
produced:
- 82 - H09IB001EN-A
The sample is heated up as stated in the program. About 5°C before the next calibration
point an acoustic signal is given. The user gets the chance to read the temperature at the
thermometer in time. As soon as the temperature which was calculated according to
calibration certificate is reached press <Enter>. The temperature at the Pt100 sensor is
printed out.
For controlling the actual temperature ramp is printed out during test
If one reading point was missed the program continues heating normally. The missing value
is not noted on the printout.
It is possible to start at a higher value and, for instance, to leave out the 0°C-point for the
lower temperature range.
If the comparison proves a constant deviation between thermometer and Pt100-sensor the
deviation can be set as offset in device parameter 1.
If it shows a fluctuating deviation first establish if this might result of reading errors at the
thermometer (always read in the same level as your eyes).
H09IB001EN-A - 83 -
11.1.2. Calibration of the device with flash point reference materials
In accordance with the various requirements for your laboratory it is necessary to recalibrate
the TAG 4 in suitable intervals of time.
It is possible to use reference calibration material of PTB or other certified reference material.
Internal reference materials should never be used for official certification. They just serve to
check the functioning of the device in normal laboratory working.
Standard Reference Materials are officially certified by national bodies (PTB) or other
approved calibration services.
Please for your reference tests take care to conduct the tests using gas ignition.
Therefore faults caused by aged or not fully functioning electric ignition can be prevented.
• Check fuse?
• Gas connected?
• Device in gas ignition mode? (see ignition symbol on the display)
• Is there air instead of gas in the connecting tube?
• Do you use special gas tight connecting tube?
Silicon is not gas tight. Using this material the gas ignition only has a slowly raising flame
size resp. can't be started within 55 sec in the next ignition period (Safety function),
because the gas outlet is not effective.
• Does the magnetic valve "click" while performing a manual test?
• Is the valve opened?
If the gas supply is opened too less or too much a gas flame can't develop.
- 84 - H09IB001EN-A
11.2.3. Gas flame is unstable
H09IB001EN-A - 85 -
11.2.8. Indication FP no GAS
When flashpoint tests are carried out using a gas ignition, the gas flame is checked during
immersion.
If the gas flame is off during an immersion you will get an error message after finishing the
test (FPnoGAS).
Even if a flashpoint was detected the operator shall be informed that there have been
irregularities in the gas supply during testing and that the test possibly has to be repeated.
When the temperature goes below the threshold, the signal switches off. On the display
"COOL" remains until the <STOP> key is pressed.
If the device is in test mode when the alarm appears the test will go on. The test, however,
will not proceed according to standard (temperature rise will not be correct)
If the device is in STOP mode when the alarm appears it will not be possible to start a test.
- 86 - H09IB001EN-A
11.3. Replacing the electric ignition
Since the ignition in the TAG 4 is run with smooth current and the working current between
the ignition tests is lowered to a minimum the ignition has a considerably longer life
expectancy than conventional ignitions.
The quality of the ignition is evaluated by the device according to a number of criteria
(voltage rise or drop).
Now the initial menu is displayed (depending as to whether a flashpoint was found, whether
the device is OVERFLO after reaching overflow etc.)
The printout under point IGNITION states: E-CH for "Change electric ignition".
The changed date signals that a new ignition has been installed.
H09IB001EN-A - 87 -
12. SPARE PARTS
135376 PC-Software
- 88 - H09IB001EN-A