VARTA Microbattery m o b i l i t y f o r yo u

SALES PROGRAM AND TECHNICAL HANDBOOK

PRIMARY LITHIUM CELLS

PRIMARY LITHIUM CELLS

Li-MnO2
 PRIMARY LITHIUM CELLS PAGE 02

CONTENTS

__ ________________________________
_ _ 1. General Information ________________________ 3–8
_ _ 1.1 Constructions of Lithium Cells ______________________ 4–5
_ _ 1.2 Characteristics and Applications ___________________ 6
_ _ 1.3 Applications for Primary
_ _ _ _ _ _ Lithium
_ _ _ _ _ _Cells
_______________________ 7
1.4 Selection Guide 8
__ _______________________
_ _ 2. CR Primary Lithium Button _ _ _Cells
___________________________ 9 –18
_ _ 2.1 Types – Technical
_ _ _ _ _Data
_________________________________ 10
_ _ 2.2 Assemblies _________________________________ 11–13
2.3 Performance Data 14 –18
__ _________
_ _ 3. CR High Capacity Primary _ _ _Lithium
_ _ _ _ _ _Cylindrical
_ _ _ _ _ _ _ _ Cells
_____________ 19 – 24
_ _ 3.1 Types – Technical
_ _ _ _ _Data
_________________________________ 20
_ _ 3.2 Assemblies _________________________________ 21
3.3 Performance Data 22 – 24
__ ___________
_ _ 4. CR High Power Primary_Lithium
_ _ _ _ _ _Cylindrical
_ _ _ _ _ _ _ _Cells
_______________ 25 – 28
_ _ 4.1 Types – Technical
_ _ _ _ _Data
_________________________________ 26
_ _ 4.2 Assemblies _________________________________ 26
4.3 Performance Data 27– 28
__ _______________________
_ _ 5. General Design Characteristics 29 – 35
5. Battery Selection,_ _Design-in
_ _ _ _ _ _ _Consideration,
__________________________
__ UL-Recognition
______________________________________ 29 – 30
_ _ 5.1 Safety Tests __________________________________ 31
_ _ 5.2 Safety Guidelines 32 – 33
5.3 Transportation_of _ _ _ _ _ _Microbattery
_ _VARTA _ _ _ _ _ _ _ _ _ Lithium
_ _ _ _ _ _Cells
_____________
__ and Batteries ______________________________ 34
5.4 Application Check List 35
 PRIMARY LITHIUM CELLS PAGE 03

1. GENERAL INFORMATION

The VARTA Microbattery lithium manganese dioxide cell chemistry was one of the
first solid cathode cells commercially developed and is still the most widely used
system today. These cells offer an excellent shelf life, good high-rate and low-rate
capability, a wide operating temperature range and availability in button and cylindri-
cal cell designs. Potential design-in applications for these products are electronic,
telecommunication, metering, instrumentation, office and other portable equipment
use. Based on the outstanding cell performance and reliablility of these products,
they have been able to meet and exceed the requirements of our customer base
worldwide.

ADVANTAGES FOR VARTA Microbattery Li-MnO 2 CELLS

+ High open circuit and load voltage (above 3.0 volts per cell)
+ High energy density (400 Wh / kg and 600 Wh / l)
+ High capacity and high rate cell contruction
+ Operation over a wide temperature range
+ Flat discharge profile under low to medium rate applications
+ Low self discharge (less than 1% per year at RT)
+ Superior shelf life and operational life
(Up to 10 years and more)

+ UL Recognition
+ Ability to provide a variety of laser welded termination tabs
for all cell types

ENERGY DENSITY FOR PRIMARY SYSTEMS

__________________________________________________________________________________
__
F I G. 1

Comparison of different A = Lithium

primary battery systems B = Silver-oxide
C = Alkaline
D = Zinc-chlorid

__________________________________________________________________________________
 PRIMARY LITHIUM CELLS PAGE 4

1.1 CONSTRUCTIONS OF LITHIUM CELLS

VARTA Microbattery offers a complete range of primary lithium manganese dioxide

cylindrical and button cells for memory backup and portable applications worldwide.
The cylindrical cell configurations, offer the high-capacity bobbin construction and
high-power spirally wound product. The bobbin construction is targeted at low to
moderate power requirements, dedicated for applications requiring up to a 10 years
operational life at 20 °C. Our spirally wound electrode product offers high-rate dis-
charge capability, with an operational life in excess of 5 years.
For compact and light weight equipment use we have a complete range of high per-
formance primary lithium button cells.

LITHIUM CYLINDRICAL BATTERIES

__________________________________________________________________________________
__
F I G. 2 Bobbin construction

Schematic construction of a Li /MnO2 – Neg. Contact

cylindrical cell (CR 1/ 2 AA). Sealing
Laser Welding
Lid
Insulation Disk
Neg. Collector
Electrolyt
MnO2 Ring

Lithium
Separator

Pos. Contact
+
__________________________________________________________________________________
__
F I G. 3 Spiral construction

Schematic construction of a Li /MnO2 + Positive Cap

cylindrical cell (CR 2 /3 AH). PTC Device
Lid

Positiv Tab

Anode (Lithium)
Electrolyt + Separator
Cathode (MnO2)

Negativ Tab
Negativ Can
– Insulator Plate
__________________________________________________________________________________
 PRIMARY LITHIUM CELLS PAGE 5

LITHIUM BUTTON CELLS

__________________________________________________________________________________
__
F I G. 4

Schematic construction of a Li / MnO2 Lid (Negative Terminal)

Button Cell Negative Electrode (Li)
Gasket

Can (Positive Terminal)

Organic Electrolyte + Separator
Positive Electrode (MnO2)

__________________________________________________________________________________

SEALING TECHNOLOGIES
__________________________________________________________________________________
__
F I G. 5 Crimp-sealing

CR High Power Cylindrical Cells Positive Cap

PTC Device
Lid

__________________________________________________________________________________
__
F I G. 6 Laser-sealing

CR High Capacity Cylindrical Cells Lid

Negative Contact
Laser Welding

__________________________________________________________________________________
 PRIMARY LITHIUM CELLS PAGE 6

1. 2 CHARACTERISTICS AND APPLICATIONS

MAIN APPLICATIONS
Both mechanical and electrical properties, together with reliability, ensure that VARTA Microbattery
lithium batteries meet the requirements of modern electronics. They are therefore ideally suited as
power sources for the long term supply of microelectronic circuitry.

MAIN CHARACTERISTICS
+ Long life expectancy and long operational life + High operating safety
+ Low self discharge rate + High reliability
+ High energy density + Resistance to corrosion with stainless steel
case and laser welded lid
+ High cell voltage (3 V)
+ No leakage problems with an organic
+ Wide temperature range non-corrosive electrolyte

TEMPERATURE CHARACTERISTICS
__________________________________________________________________________________
__
F I G. 7

Temperature characteristics A= – 40 °C
of CR 1/ 2 AA and CR AA B= +85 °C
cylindrical cells C= +60 °C
D= – 20 °C
(Load: 5.6 kΩ CR AA, E= +23 °C
12 kΩ CR 1/ 2 AA)

__________________________________________________________________________________

SYSTEM PROPERTIES OF VARTA Microbattery LITHIUM CELLS

Series

CR Series
Cylindrical
Cells

CR Series
Button
Cells

System Li / MnO 2 Li / MnO 2

Gravimetric energy density 250 – 300 Wh / kg 250 – 300 Wh / kg
Nominal voltage 3.0 V 3.0 V
Open circuit voltage 3.2 V 3.2 V
Available capacity range 950 – 2000 mAh 25 – 560 mAh
Storage life ≥ 10 years 1) ≥ 5 years 1)
Self discharge δ = 20 °C <1 % p. a. <1% p. a.
Operating temperature – 30 … +75 °C 2) – 20 … +65 °C
Maximum temperature
range (shor t term) 3) – 40 … + 85 °C 4) – 40 … + 80 °C 4)
Storage temperature 5) – 55 … +75 °C 2) – 55…+ 70 °C
__
TA B. 1 1) CR 2/3 AH, CR-P2, (> 5 years)
2) CR 2/3 AH (– 20 … +65 °C). CR 2 NP (– 20 … +70 °C)
3) max. two weeks
4) µA-range
5) Recommended room temperature
 PRIMARY LITHIUM CELLS PAGE 7

1.3 APPLICATIONS FOR PRIMARY LITHIUM CELLS

Applications

Button Cells Cylindrical Cells (Spirally wound) Cylindrical Cells (Bobbin construction)
Main power
source

Memory
backup

Main power
source

Memory
backup

Main power
source

Memory
backup
Telecommunications
Std. Telephone + + +
Cordless Telephone + + +
Cellular Telephone +
Mobile Radio + + +
PABX + +
Utility Meters
Gas Meter + +
Heat Distribution Meter +
Electric Meter +
Water Meter + +
Office Automation
Computer + +
Copy Machine + +
Printer +
Fax +
Vending Machine +
Electronic Typewriter +
Process Control Equipment
Taxi Meter +
Transponder +
Intelligent Tagging +
Electric Parking Meter + +
Data Logger +
Dive Computer +
Consumer Products
Electronic Games +
Watch / Clock + + +
Calculator +
Compass + +
Car Radio +
Video Recorder +
Automotive
Car lock system +
Dashboard + +
Security +
__
TA B. 2 Application list
 PRIMARY LITHIUM CELLS PAGE 8

1.4 SELECTION GUIDE

To enable battery selection the ______________________________________________________

following is required: __
F I G. 8 Capacity
+ discharge current and maximum Retention
discharge time Capacity retention
+ capacity
characteristics of
+ operating temperature range VARTA Microbattery
Lithium Cells
+ self discharge
+ surplus capacity requirement Cylindrical Cells
CR … AA, CR … A
+ cell size and CR 2 NP

______________________________________________________
__
F I G. 9 Storage
Behavior

Typical storage
behaviour at room
temperature 21°C
of CR 1/ 2 AA

__________________________________________________________________________________
__
F I G. 1 0 Battery Selection Diagramm

Discharge current /Operating time

__________________________________________________________________________________
 PRIMARY LITHIUM CELLS PAGE 9

2. CR PRIMARY LITHIUM BUTTON CELLS

 PRIMARY LITHIUM CELLS PAGE 10

2 .1 TYPES – TECHNICAL DATA

CR 1216 CR 1616 CR 2016 CR 2025 CR 2032

Type

Order No.

Nominal
voltage (V)

Typical
capacity 1)
(mAh)

Standard
load (kΩ)

Max.
discharge
current
(continuous)
(mA)

Max.
discharge
current
(pulse)
(mA)

Weight (g)
CR 1/3 N 6131 101 501 3 170 5.6 20 80 3.0
2 CR 1/3 N (V28 PXL) 6231 101 501 6 170 13 20 80 8.8
CR 1216 6216 101 501 3 25 39 2 5 0.7
CR 1220 6220 101 501 3 35 39 2 5 0.8
CR 1616 6616 101 501 3 55 39 3 8 1.2
CR 1620 6620 101 501 3 70 20 3 8 1.2
CR 2016 6016 101 501 3 90 15 3 10 1.8
CR 2025 6025 101 501 3 170 10 3 10 2.5
CR 2032 6032 101 501 3 230 5.6 3 10 3.0
CR 2320 6320 101 501 3 135 10 5 15 2.9
CR 2430 6430 101 501 3 280 5.6 3 20 4.0
CR 2450 6450 101 501 3 560 5.6 2 10 6.2
__
TA B. 3 Technical data, CR Primary Lithium Button Cells
1)Nominal capacity is determined to an end voltage of 2.0 V (type 2 CR 1/3 N: 4.0 V) when the battery is allowed to discharge at standard load level at 20 °C
 PRIMARY LITHIUM CELLS PAGE 11

2.2.1 ASSEMBLIES
Type

Order No.

Fig. No.

Remarks
CR 1/3 N 6131 101 501 11.6 10.8 0.4 – 7.8 – – – – – – 11 –
CR 1/3 N SLF 6131 201 501 13.0 1.0 10.0 1.0 ±0.3 11.5 ±0.5 12.0 ±0.15 – 1.0 ±0.3 3.0 – – 14 tag 0.25 mm
CR 1/3 N LF 6131 301 501 – – – – 11.5 12.0 – – – 19.0 4.0 13 tag 0.25 mm
180°
2 CR 1/3 N 6231 101 501 13.0 25.1 1.1 0.6 5.5 6.0 – – – – – 12 –
(V 28 PXL)
3 CR 1/3 N 6331 101 501 12.2 32.2 0.4 – 7.8 – – – – – – 11 –
__
TA B. 4 Tag material: nickel plated sheet-steel. SLF: tip tinned.
Custom made assemblies are available on request for large volume.

A
B
L
C
C C
D
B I
B

A E E

F D
A F
E F
H
E K K
B

__ __ __ __
F I G. 1 1 F I G. 1 2 F I G. 1 3 LF F I G. 1 4 SLF
 PRIMARY LITHIUM CELLS PAGE 12

2.2.2 ASSEMBLIES
Type

Order No.

Fig. No.

Remarks
CR 1216 6216 101 501 12.5 1.6 0.2 – 10.0 – – – – – – 15
CR 1220 6220 101 501 12.5 2.0 0.3 – 10.0 – – – – – – 15
CR 1616 6616 101 501 16.0 1.6 0.2 – 12.0 – – – – – – 15
CR 1620 6620 101 501 16.0 2.0 0.02 – 12.9 – – – – – – 15

CR 2016 6016 101 501 20.0 1.6 0.1 – – – – – – – – 15

CR 2016 SLF 6016 201 501 21.3 1.0 10.0 ±0.15 1.0 ±0.3 2.1 ±0.5 20.3 ±0.15 – 1.0 ±0.3 4.5 – – 16 tag 0.25 mm
CR 2016 LF 6016 301 501 20.0 – – – 1.9 20.0 – – – 10.0 4.0 17 tag 0.15 mm
CR 2016 PCB 6016 401 501 20.0 1.0 10.0 9.1 1.6 17.8 7.3 10.0 4.5 11.4 – 18 tag 0.15 mm

CR 2025 6025 101 501 20.0 2.5 0.2 – – – – – – – – 15

CR 2025 SLF 6025 201 501 21.3 1.0 10.0 ±0.2 1.0 ±0.3 3.0 ±0.5 20.3 ±0.15 – 1.0 ±0.3 4.5 – – 16 tag 0.25 mm
CR 2025 LF 6025 301 501 20.0 – – – 2.8 20.3 – – – 10.0 4.0 17 tag 0.15 mm
CR 2025 PCB 6025 401 501 20.0 1.0 10.0 10.0 2.5 17.8 7.3 10.0 4.5 11.4 – 18 tag 0.15 mm
__
TA B. 5 . 1 Tag material: nickel plated sheet-steel. SLF: tip tinned.
Custom made assemblies are available on request for large volume.

A
B L

C D
B
E E
A
F
E
F
H
K K

__ __ __
F I G. 1 5 F I G. 1 6 SLF F I G. 1 7 LF
 PRIMARY LITHIUM CELLS PAGE 13

2.2.3 ASSEMBLIES
Type

Order No.

Fig. No.

Remarks
CR 2032 6032 101 501 20.0 3.2 0.02 – 16.5 – – – – – – 15 –
CR 2032 SLF 6032 201 501 21.5 1.0 10.0 1.0 4.2 20.3 – 1.0 4.5 – – 16 tag 0.25 mm
CR 2032 LF 6032 301 501 – – – – 3.2 20.3 – – – 10 4.0 17 tag 0.15 mm
CR 2032 PCB 3 6032 401 501 20.0 1.0 10.0 11.0 3.2 17.8 7.5 10.0 4.5 11.4 – 18 tag 0.25 mm
CR 2032 PCB 2 6032 701 501 20.0 1.0 – 11.0 3.2 17.8 7.3 10.0 4.5 10.0 – 19 tag 0.20 mm
CR 2032 WC 1) 6032 101 013 20.7 – – – 5.5 30.0 – – – 96.0 2.0 20 tag 0.20 mm 2)

CR 2430 6430 101 501 24.5 3.0 0.3 – 20.0 – – – – – – 15 –

CR 2430 SLF 6430 201 501 25.8 1.0 10.0 1.0 4.0 25.0 – 1.0 4.5 – – 16 tag 0.25 mm
CR 2430 LF 6430 301 501 – – – – 3.2 25.0 – – – 10.0 4.0 17 tag 0.15 mm
CR 2430 PCB 3 6430 401 501 24.5 1.0 10.0 11.0 3.0 17.8 7.5 10.0 4.5 11.4 – 18 tag 0.25 mm
CR 2430 PCB 2 6430 701 501 24.5 1.0 – 11.0 3.0 20.0 7.5 10.0 4.5 11.4 – 19 tag 0.20 mm

CR 2450 6450 101 501 24.7 5.0 0.5 – 21.8 – – – – – – 15 –

CR 2450 SLF 6450 201 501 25.8 1.0 10.0 1.0 6.4 25.0 – 1.0 4.5 – – 16 tag 0.25 mm
CR 2450 PCB 3 6450 401 501 24.5 1.0 10.0 13.2 5.0 17.8 7.5 10.0 4.5 11.4 – 18 tag 0.25 mm
CR 2450 PCB 2 6450 701 501 24.7 1.0 – 12.7 5.0 17.8 7.5 10.0 4.5 11.4 – 19 tag 0.20 mm
__
TA B. 5 . 2 Tag material: nickel plated sheet-steel. SLF: tip tinned.
1)using Molex 51021-03 connector (Other wire connectors and wire length are available on request.)
2)in shrink sleeve with wire and connector
Custom made assemblies are available on request for large volume.

L
K H A
K H A

F
E
D
K
B I E
C

E
G F
G
F

A
D
I

__ __ __
F I G. 1 8 PCB 3 F I G. 1 9 PCB 2 F I G. 2 0 WC
 PRIMARY LITHIUM CELLS PAGE 14

2.3 CR PRIMARY LITHIUM BUTTON CELL PERFORMANCE DATA

__________________________________________________________________________________
__
F I G. 2 1 CR 1216

Discharge characteristics CR 1216

at room temperature (21°C)

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__
F I G. 2 2 CR 1216

Temperature characteristics CR 1216

Constant load 39 kΩ

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__
F I G. 2 3 CR 1216

Operating voltage vs. current drain CR 1216

Voltage at 50 % discharge

__________________________________________________________________________________
__
F I G. 2 4 CR 1216

Cell capacity vs. discharge current CR 1216

__________________________________________________________________________________
 PRIMARY LITHIUM CELLS PAGE 15

__________________________________________________________________________________
__
F I G. 2 5 CR 2016

Discharge characteristics CR 2016

at room temperature (21°C)

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__
F I G. 2 6 CR 2016

Temperature characteristics CR 2016

Constant load 15 kΩ

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__
F I G. 2 7 CR 2016

Operating voltage vs. current drain CR 2016

Voltage at 50 % discharge

__________________________________________________________________________________
__
F I G. 2 8 CR 2016

Cell capacity vs. discharge current CR 2016

__________________________________________________________________________________
 PRIMARY LITHIUM CELLS PAGE 16

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__
F I G. 2 9 CR 2025

Discharge characteristics CR 2025

at room temperature (21°C)

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__
F I G. 3 0 CR 2025

Temperature characteristics CR 2025

Constant load 10 kΩ

__________________________________________________________________________________
__
F I G. 3 1 CR 2025

Operating voltage vs. current drain CR 2025

Voltage at 50 % discharge

__________________________________________________________________________________
__
F I G. 3 2 CR 2025

Cell capacity vs. discharge current CR 2025

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 PRIMARY LITHIUM CELLS PAGE 17

__________________________________________________________________________________
__
F I G. 3 3 CR 2032

Discharge characteristics CR 2032

at room temperature (21°C)

__________________________________________________________________________________
__
F I G. 3 4 CR 2032

Temperature characteristics CR 2032

Constant load 5.6 kΩ

__________________________________________________________________________________
__
F I G. 3 5 CR 2032

Operating voltage vs. current drain CR 2032

Voltage at 50 % discharge

__________________________________________________________________________________
__
F I G. 3 6 CR 2032

Cell capacity vs. discharge current CR 2032

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 PRIMARY LITHIUM CELLS PAGE 18

__________________________________________________________________________________
__
F I G. 3 7 CR 2430

Load: cont. 5.6 kΩ : Ub CR 2430

Pulse: 2 s/2 h 390 Ω : Ut
(parallel)
Internal Resistance Ri calculated from
Ub and Ut at Rt = 390 Ω and Tt = 2 s
Temperature: δ = 20 °C

__________________________________________________________________________________
__
F I G. 3 8 CR 2430

Load: cont. 5.6 kΩ (B) CR 2430

cont. 15 kΩ (B)
cont. 270 kΩ (A)
Mean discharge I1 = 400 µA
current: I2 = 180 µA
I3 = 10 µA
Temperature: δ = 20 °C

__________________________________________________________________________________
__
F I G. 3 9 CR 2430

Discharge curves at different CR 2430

temperatures
Load: cont. R = 15 kΩ
Mean discharge
current at
temperature: δ= 0 °C ~175 µA
δ = –10 °C ~170 µA
δ = –20 °C ~155 µA

__________________________________________________________________________________
__
F I G. 4 0 CR 2450

Load: cont. 5.6 kΩ : Ub CR 2450

Pulse: 2 s/2 h 100 Ω : Ut
(parallel)
Internal Resistance Ri calculated from
Ub and Ut at Rt = 100 Ω and Tt = 2 s
Temperature: δ = 20 °C

__________________________________________________________________________________
 PRIMARY LITHIUM CELLS PAGE 19

3. CR HIGH CAPACITY PRIMARY LITHIUM CYLINDRICAL CELLS

 PRIMARY LITHIUM CELLS PAGE 20

3.1 TYPES – TECHNICAL DATA

CR 1/ 2 AA CR 2 /3 AA CR AA
Type

Order No.

Nominal
voltage
(V)

Nominal
capacity at
20 °C, down
to 2.0 V,
load (mAh)

Max.
continuous
discharge
current
(mA)

Weight (g)

CR 1 / 2 AA 6127 101 301 3 970 mAh – 5.6 kΩ 10 11.5

CR 2 / 3 AA 6237 101 301 3 1.350 mAh – 1.0 kΩ 15 15.0
CR AA 6117 101 301 3 2.000 mAh – 1.0 kΩ 20 21.5
CR 2 / 3 A 6238 101 301 3 1.350 mAh – 1.0 kΩ 15 17.0
__
TA B. 6 Technical data, CR High Capacity Primary Lithium Cylindrical Cells

A K C A F

D
L H
M

B B G B G

I C
E
A E

__ __ __
FIG .41 F I G. 4 2 F I G. 4 3

E E
A A A

D I

B G B G
B G

C C
E
E E
D

__ __ __
F I G. 4 4 F I G. 4 5 F I G. 4 6
 PRIMARY LITHIUM CELLS PAGE 21

3.2 ASSEMBLIES
Type

Order No.

A (Max.)

Fig. No.

Tags
CR 1 / 2 AA 6127 101 301 14.75 25.2 – – – – – – – – 7.0 0.6 41
CR 1 / 2 AA SLF 6127 201 301 14.75 25.2 10.0 1.0 1.0 – 25.4 – 3.0 5.0 – – 42
CR 1 / 2 AA LF 6127 301 301 14.75 25.2 10.0 – 3.5 2.1 25.4 2.5 – – – – 43
CR 1 / 2 AA CD 6127 501 301 14.75 25.4 45.0 – – – – – – – – – 48
CR 1 / 2 AA CD 6127 601 301 14.75 25.4 – 7.5 – – 33.5 – – – – – 47 (90°)
CR 1 / 2 AA SLF 6127 701 301 14.75 25.2 – 1.0 1.0 – 25.4 – 3.0 – – – 44 single pin
CR 1 / 2 AA LF 6127 801 301 14.75 25.2 14.5 – 3.0 – 25.4 – – – – – 46 (180°)
CR 1 / 2 AA SLF 6127 901 301 14.75 25.2 – – 1.0 – 25.4 – 3.0 – – – 45 shor t pin
CR 1 / 2 AA TP 6127 601 381 14.75 25.2 16.5 – 0.64 – 25.8 – – – – 49 terminal pin
CR 1 / 2 AA WC 1) 6127 201 390 17.5 27.0 50.0 – – – – – – – – – 50 wire &
connector

CR 2 / 3 AA 6237 101 301 14.75 33.5 – – – – – – – – 7.0 0.6 41

CR 2 / 3 AA SLF 6237 201 301 14.75 33.5 10.0 1.0 1.0 – 33.7 – 3.0 5.0 – – 42
CR 2 / 3 AA LF 6237 301 301 14.75 33.5 10.0 – 3.5 2.1 33.7 2.5 – – – – 43
CR 2 / 3 AA CD 6237 501 301 14.75 33.5 45.0 – – – – – – – – – 48
CR 2 / 3 AA SLF 6237 701 301 14.75 33.5 – 1.0 1.0 – 33.7 – 3.0 – – – 44 single pin
CR 2 / 3 AA SLF 6237 901 301 14.75 33.5 – – 1.0 – 33.7 – 3.0 – – – 45 shor t pin

CR AA 6117 101 301 14.75 50.0 – – – – – – – – 7.0 0.6 41

CR AA SLF 6117 201 301 14.75 50.0 10.0 1.0 1.0 – 50.2 – 3.0 5.0 – – 42
CR AA LF 6117 301 301 14.75 50.0 10.0 – 3.5 2.1 50.2 2.5 – – – – 43
CR AA CD 6117 501 301 14.75 50.2 45.0 – 3.5 – – – – – – – 48
CR AA SLF 6117 701 301 14.75 50.0 – 1.0 1.0 – 50.2 – 3.0 – – – 44 single pin
CR AA WC 1) 6117 201 390 18 51.0 50.0 – – – – – – – – – 50 wire &
connector

CR 2 / 3 A 6238 101 301 17 33.5 – – – – – – – – 7.0 0.6 41

CR 2 / 3 A LF 6238 301 301 17 33.5 10.0 – 3.5 2.1 33.7 2.5 – – – – 43
CR 2 / 3 A CD 6238 501 301 17 33.5 45.0 – – – – – – – – – 48
__
TA B. 7 Material: nickel plated sheet-steel, tag thickness: 0.15 mm till 0.25 mm. SLF: tip tinned, all types in green shrink sleeve.
1)
using connector: JST type: PHR2 (Other connector types available on request.)
Custom made assemblies are available on request for large volume.

Ni Ø 0,8 mm – tinned
D A
C
C
A
E

C
B
G B B G

A C

Ni Ø 0.8 mm – tinned A

__ __ __ __
F I G. 4 7 F I G. 4 8 F I G. 4 9 F I G. 5 0
 PRIMARY LITHIUM CELLS PAGE 22

3.3 PERFORMANCE DATA

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__
F I G. 5 1
__
CR 1 / 2 AA
F I G. 5 5
__
CR 2 / 3 AA __
F I G. 5 9 CR AA F I G. 5 1
CR 1/2 AA
Discharge characteristics
at room temperature (21 °C)

__________________________________________________________________________________
__
F I G. 5 2
__
CR 1 / 2 AA
F I G. 5 6
__
CR 2 / 3 AA __
F I G. 6 0 CR AA F I G. 5 2
CR 1/2 AA
Temperature characteristics
at 5.6 kΩ

__________________________________________________________________________________
__
F I G. 5 3
__
CR 1 / 2 AA
F I G. 5 7
__
CR 2 / 3 A __
F I G. 6 1 CR AA F I G. 5 3
CR 1/2 AA
Operating voltage vs. current drain,
Voltage at 50 % discharge

__________________________________________________________________________________
__
F I G. 5 4
__
CR 1 / 2 AA
F I G. 5 8
__
CR 2 / 3 AA __
F I G. 6 2 CR AA F I G. 5 4
CR 1/2 AA
Cell capacity vs. discharge current

__________________________________________________________________________________
 PRIMARY LITHIUM CELLS PAGE 23

__________________________________________________________________________________

__ __
F I G. 5 5 F I G. 5 9
CR 2/3 AA CR AA

__________________________________________________________________________________

__ __
F I G. 5 6 F I G. 6 0
CR 2/3 AA CR AA

__________________________________________________________________________________

__ __
F I G. 5 7 F I G. 6 1
CR 2/3 AA CR AA

__________________________________________________________________________________

__ __
F I G. 5 8 F I G. 6 2
CR 2/3 AA CR AA

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 PRIMARY LITHIUM CELLS PAGE 24

__________________________________________________________________________________
__
F I G. 6 3 CR 2 / 3 A

Discharge characteristics CR 2/3 A

at room temperature (21°C)

__________________________________________________________________________________
__
F I G. 6 4 CR 2 / 3 A

Temperature characteristics CR 2/3 A

Constant load 5.6 kΩ

__________________________________________________________________________________
__
F I G. 6 5 CR 2 / 3 A

Operating voltage vs. current drain CR 2/3 A

Voltage at 50 % discharge

__________________________________________________________________________________
__
F I G. 6 6 CR 2 / 3 A

Cell capacity vs. discharge current CR 2/3 A

__________________________________________________________________________________
 PRIMARY LITHIUM CELLS PAGE 25

4. CR HIGH POWER PRIMARY LITHIUM CYLINDRICAL CELLS

 PRIMARY LITHIUM CELLS PAGE 26

4.1 TYPES – TECHNICAL DATA

Type

Order No.

Nominal
voltage
(V)

Nominal
capacity at
20 °C, down
to 2.0 V
(respectivey
4.0 V), load
(mAh)

Max.
continuous
discharge
current 1)
(mA)

Weight (g)
CR 2 / 3 AH 6215 101 501 3 1.350 mAh – 200 Ω 1500 16
CR 2 NP 6202 101 501 3 1.400 mAh – 1.0 k Ω 15 13
__
TA B. 8 Technical data, CR High Power Primary Lithium Cylindrical Cells
1)Current value for obtaining 50 % capacity
2)in blister card (1 pc)

4.2 ASSEMBLIES
Type

Order No.

Fig. No.

Tags
CR 2 / 3 AH 6215 101 501 17.0 –1 33.9 –1.5 – – – – – – – – 6.3 ±0.2 1.0 67 –
CR 2 NP 6202 101 501 11.6 –0.4 60 –1 – – – – – – – – 3 1.5 67 –
CR 2 NP SLF 6202 201 501 11.6 –0.4 60 –1 10.0 ±0.15 pos 0.5 ±0.2 1.0 – 58.8 ±0.3 – 3.0 – – – 69 –
neg 0.7 ±0.2
CR 2 NP LF 6202 301 501 11.6 –0.4 60 –1 pos 11 – 4.0 – 58.8 ±0.3 – – – – – 68 –
neg 10
__
TA B. 9 Material: nickel plated sheet-steel, tag thickness: 0.15 mm till 0.25 m. SLF: tip tinned.
Custom made assemblies are available on request for large volume.

E G E E
G C
C C C E
I D
L

M B A
A
A B B
__ __ __
F I G. 6 7 F I G. 6 8 F I G. 6 9
 PRIMARY LITHIUM CELLS PAGE 27

4.3 PERFORMANCE DATA

__________________________________________________________________________________
__
F I G. 7 0 CR 2 / 3 AH

Discharge characteristics CR 2/3 AH

at room temperature (21°C)

__________________________________________________________________________________
__
F I G. 7 1 CR 2 / 3 AH

Temperature characteristics CR 2/3 AH

Constant load 5.6 kΩ

__________________________________________________________________________________
__
F I G. 7 2 CR 2 / 3 AH

Pulse discharge characteristics CR 2/3 AH

1) Load: 0.9 A, 3 sec. on, 27 sec. off

2) After storage at 60 °C /100 days

__________________________________________________________________________________
__
F I G. 7 3 CR 2 / 3 AH

Typical discharge curve CR 2/3 AH

Load: cont. 560 Ω
Pulse load: 2 sec./ min 3 Ω
(parallel)

__________________________________________________________________________________
 PRIMARY LITHIUM CELLS PAGE 28

__________________________________________________________________________________
__
F I G. 7 4 CR 2 NP

Discharge curve cont. 1 kΩ CR 2 NP

__________________________________________________________________________________
 PRIMARY LITHIUM CELLS PAGE 29

5. GENERAL DESIGN CHARACTERISTICS

BATTERY SELECTION
In order to ensure optimum battery performance for the primary CR Button,
the cylindrical CR High Power and cylindrical High Capacity cells, we
suggest consideration of the following design-in requirements. They are
the nominal and operating voltage, load current and profile, the duty cycle,
temperature requirements and shelf life for the application. These charac-
teristics for each battery type must be evaluated against the design
requirements to select the most appropriate product that fulfills these
requirements.

DESIGN-IN CONSIDERATIONS
VARTA Microbattery Primary Lithium Blocking diode D2 and D3
Batteries offer lightweight packaged prevents the battery from being
power for a variety of portable elec- charged through the power supply.
tric and electronic equipment. They The amount of accumulated reverse
are suitable as a main or standby current (IR) should we kept around
power source for memory (RAM) and 1 % of the cells typical capacity
Real-Time clock (RTC) applications. during it’s standby life time.
A maximum of 5 µA continuously
The Lithium Batteries are blocked must not be exceeded. F I G. 7 5
__

from the power supply by means of

a diode to prevent discharge of the In the absence of a DC supply volt-
battery into the DC supply during age, the lithium battery supplies the
shut down. load with the necessary power.

The voltage drop across D1 should As diodes fail at low current levels
be taken into account as the mini- by an alloy-effect causing a severe
mum voltage of the load that has to reduction in impedance, an addi-
be maintained under all circum- tional safety device must be incor-
stances. porated.
__
F I G. 7 6

__
F I G. 7 7

Using 2 cells when 6 V

is used in series
 PRIMARY LITHIUM CELLS PAGE 30

UL-RECOGNITION
All VARTA Microbattery Lithium Cells and Batteries listed in Tab.10 are recognized
by Underwriters Laboratories Inc. under UL-file number MH 13654 (N). Trademark of Underwriters
Laboratories
The cell are marked with the Recognized Component Mark.

Underwriters Laboratories requires for lithium cells/batteries a circuit, which must

contain a protective component to prevent charging. In case of diode failure a
current limiting resistor must be chosen according to the values listed in Tab. 10.

Please also pay attention to the Safety Guidelines on page 32.

“UL” requires either an additional diode, or a resistor, Button Cells Cylindrical Cells
Type

Max. safe
reverse
current
acc. to UL

Type

Max. safe
reverse
current
acc. to UL
limiting the current to a safe level of 4 mA (for all cylin-
drical CR … A(A) lithium mass cells).

It should be noted, that the value of the resistor has to CR 1216 3 mA High Capacity
be calculated using the higher power supply voltage – CR 1220 3 mA CR 1 / 2 AA 4 mA
CR 1616 4 mA CR 2 / 3 AA 4 mA
not the battery voltage. CR 1620 3 mA CR AA 4 mA
CR 2016 4 mA CR 2 / 3 A 4 mA
The supply voltage to the load can be calculated by the CR 2025 5 mA
CR 2032 5 mA High Power
battery voltage drop across the diode and the resistor. CR 2320 5 mA CR 2 NP 15 mA
CR 1 / 3 N 2 mA 2 CR 5 10 mA
__
TA B. 1 0 All listed cells /batteries are recognized by
UL-recognition. CR 2 /3 AH UL-Recognition pending.

PRINTED CIRCUIT BOARD MOUNTING

Never solder on the body of the battery directly, use a battery equipped with
PC-mount terminals. When using automatic soldering apply 250 –270 °C within
5 seconds. Make sure, that the battery is not suspended or dropped into the
soldering bath.

Do not heat above 80 °C to avoid leakage caused by deterioration in the battery’s

performance.
 PRIMARY LITHIUM CELLS PAGE 31

5.1 SAFETY TESTS

For safety aspects please consult VARTA Microbattery before performing these extreme tests:

COMPRESSION TEST IN SHORT CIRCUIT TEST AT 150 °C FOR PUNCTURE TEST

1120 KG CONDITION 24 h, 2 HOURS TOTAL PENETRATION
+ no significant electrolyte 0.1 Ω + no electrolyte creepage OF THE CELL BY A
loss + after 24 h the bottom of or loss NAIL Ø 3MM
+ no rupturing the cell is curved by only
0.1 mm; diameter + no rupture + no splashing or pressurized
electrolyte loss
unchanged
+ no fire + no rupturing
+ no electrolyte creepage + no explosion
or loss

+ no rupturing + open circuit voltage almost

unchanged at 3.2 V

+ the cell base bowed,

causing cell height to
increase by 1 mm,
diameter unchanged

SHORT CIRCUIT VIBRATION TEST

In table 11 is the temperature at short circuit at an
ambient temperature of 20 °C, 40 °C and 70 °C listed.
Vibration
test

Result
Ambient
temperature

CR 1 / 2 AA

CR 2 / 3 AA

CR AA

Frequency range Without changing of

5 Hz
55 Hz
500 Hz
55 Hz
5 Hz the electrical values
Amplitude at frequency range: the following Li-cell
20 °C 24 °C 28 °C 24 °C 5 to 55 Hz: ± 0.75 mm can be exposed to
40 °C 50 °C 50 °C 47 °C Acceleration at frequencey range: this vibration test:
70 °C 80 °C 84 °C 77 °C 55 Hz to 500 Hz: 100 m /s 2 + CR 1 / 2 AA
__ Cycle duration: 15 min + CR 2 / 3 AA
TA B. 1 1
Oscillation time of each main axis: 3 h + CR AA
__
TA B. 1 2

TEMPERATURE CHARACTERISTICS
__________________________________________________________________________________
__
F I G. 7 8

CR 1/ 2 AA, Temperature A = – 30 °C
characteristics B = 20 °C
C = 75 °C
Conditions: 20 h / 20 °C: 15 kΩ,
4 h /at various temp.: 270 kΩ

__________________________________________________________________________________
 PRIMARY LITHIUM CELLS PAGE 32

5.2 SAFETY GUIDELINES

SAFETY AND HANDLING ISSUES

We recommend that attention begins to the design and implementation of our Lithium-
Manganese Dioxide Button /Cylindrical Cells to ensure superior operating performance.
With our Lithium-Manganese Dioxide Batteries, the appropriate precautions must be
taken to avoid physical and electrical abuse otherwise, the batteries can be hazardous
if not used properly. To avoid such incidents, we would suggest you review the follow-
ing safety and handling precautions for your potential application:

+ DO NOT HEAT. NOR DISPOSE + DO NOT CHARGE + AVOID FORCED DISCHARGE

OF IN FIRE (LITHIUM PRIMARY When batteries are force-over dis-
If heated the plastic materials in BATTERY CR SERIES) charged with an external power
the cell such as the gasket and When a Lithium Primary Battery is source, the voltage drops to under
seperator may be damaged, caus- charged, gas is generated inside 0.0 V (reverse electrode), and inner
ing leakage. The heat generated by the battery and can result in gas is generated. This can lead to
a short circuit inside the batteries swelling, heat generation, leakage, swelling, heating, leakage violent
may lead to bursting or combustion. violent rupture or potential fire. rupture and/or potential fire.
If disposed of in fire, batteries may
violently rupture.

+ DO NOT SHORT CIRCUIT + DO NOT DISASSEMBLE, + DO NOT USE WITH OTHER

If the positive and negative termi- APPLY EXCESSIVE PRESSURE BATTERY TYPES OR OLD
nals come into contact with each OR DEFORM BATTERIES WITH FRESH CELLS
other or with a metal object, this can If a battery is forcefully disassem- If different typs of batteries are
cause a short circuit, generating bled, gas may be generated which used together, or fresh are used with
heat. If the batteries are stacked on may cause throat irritation, or the old ones, the difference in charac-
top of each other or mixed, the lithium metal may generate heat, teristics of voltage, capacity, etc.,
resulting short-circuit can lead to causing fire. If deformed under may cause overdischarge of the
heat generation, leakage, violent pressure or under impact, distortion battery which is exhausted first,
rupture or fire. of the seal may lead to leakage, leading to swelling, bursting or fire.
or a short circuit inside the battery
may lead to potential safety
hazards.
 PRIMARY LITHIUM CELLS PAGE 33

+ OBSERVE THE (+) AND (–) + DO NOT SWALLOW

POLARITY Store batteries in a safe location,
If the batteries cell polarity is out of the reach of babies and
reversed by inserting the battery small children. Also, make sure that
backwards, depending on the batteries cannot be easily removed
equipment, a short circuit or over from equipment in which they are
discharging may result a potential used. If swallowed by mistake,
safety hazard. consult a doctor immediately.

+ DO NOT STORE IN DIRECT + SOLDERING

SUNLIGHT OR RAIN Do not solder or weld directly to the
Store batteries in a place not sub- cells surface. Use preassembled
ject to direct sunlight. Make sure the cells with tabs or leads.
area is dry and is approximately
20 °C. Storage in areas with higher
temperature, humidity or exposure + DO NOT THROW INTO WATER
to rain may cause deterioration in This can result in corrosion and
battery quality and durability. the generation of combustible gas.

The safety guide lines have been prepared in accordance with ISO / IEC
guide lines. (second edition IEC 60086-4)
 PRIMARY LITHIUM CELLS PAGE 34

5.3 TRANSPORTATION OF VARTA Microbattery LITHIUM CELLS

AND BATTERIES

Lithium cells and batteries are considered non-dangerous if each cell or battery with
a solid cathode contains 1 gram or less of lithium and are therefore not subject to
national or international dangerous goods regulations for transport by road, rail, sea,
or air, provided that:

+ Cells and batteries are + Cells and batteries are packed + Details of specific transport
seperated so as to prevent short instrong packaging, except regulations are available on
circuits. when installed in electronic special request.
devices.

All VARTA Microbattery Lithium Cells listed in this catalogue contain less than 1.0 gram of Lithium and, as long
as they are packed as above, are therefore not subject to the dangerous goods regulations.
 PRIMARY LITHIUM CELLS PAGE 35

5.4 APPLICATION CHECK LIST

+
_ _ _ _CUSTOMER: +
_ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _APPLICATION:
_______________________________________

_ _Requested
_ _ _ _ _ _ quantity:
_ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _Batteries
_ _ _ _ _ _per
_ _annum:
_________________________________

_ _Type
_ _ _of_ _battery:
_ _ _ _ _ _ _ _ _ _ _ _ _ _ Primary
_ _ _ _ _power
_ _ _ _source:
_ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _MBU:
_____________________

_____________________U _ _: _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _U_min
_ max _ _: _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _U_cutoff
_ _: _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _

_ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ I_max
_ _: _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _I_min_: _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _Iaverage
_ _ _ :_ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _

_ _Current
_ _ _ _ _profile:
___________________________________________________________________________

_ _Operating
_ _ _ _ _ _temperature
_ _ _ _ _ _ _ _ _ _ _ _ _ max
_ _ _(°C):
_ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _min
_ _ _(°C):
_ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _average
_ _ _ _ _(°C):
________________

_ _Temperature
_ _ _ _ _ _ _ profile:
_________________________________________________________________________

_ _Storage
_ _ _ _ _temperature
_ _ _ _ _ _ _ _ _ _ _ _ _ _ max
_ _ _(°C):
_ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _min
_ _ _(°C):
_ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _average
_ _ _ _ _(°C):
________________

_ _Storage
_ _ _ _ _time:
_ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _Operating
_ _ _ _ _ _ time:
___________________________________

_ _Dimensions:
________________________________________________________________________________

+
_ _ _ _REMARKS:
______________________________________________________________________________

__________________________________________________________________________________

__________________________________________________________________________________

__________________________________________________________________________________

__________________________________________________________________________________

__________________________________________________________________________________

__________________________________________________________________________________

__________________________________________________________________________________

__________________________________________________________________________________

__________________________________________________________________________________
WWW.VARTA-MICROBATTERY.COM

__
Germany VARTA Microbattery GmbH Daimlerstraße 1 73479 Ellwangen Germany
Tel (+ 49) 79 61 921 - 0 Fax (+ 49) 79 61 921 - 553

__
France VARTA Microbattery France 157, Rue Jean Pier re Timbaud B.P. 15 92403 Courbevoie (Cédex) France
Tél (+ 33) (0) 1 - 46 91 66 27 Fax (+33) (0) 1 - 46 91 66 47
__
Great Britain VARTA Microbattery Ltd. Unit 1 - Cropmead Industrial Estate Crewker ne - Somerset TA18 7HQ Great Britain
Tel (+44) 14 60 - 7 33 66 Fax (+44) 14 60 - 7 23 20
__
Italy VARTA Microbattery Italia Stradone S. Fermo, 19 37121 Verona Italy
Tel (+390) 45 - 8 00 16 15 Fax (+390) 45 - 5 91 87 8
__
Nordic VARTA Microbattery Nordic Knud Bro Allee 1 Postbox 29 3660 Stenløse Denmark
Tel (+45) 47 - 19 33 33 Fax (+45) 47 - 19 33 30
__
America VARTA Batteries, Inc. 1311 Mamaroneck Avenue, Suite 120 White Plains, NY 10605 United States of America
Tel (+1) 914 - 592 25 00 Fax (+1) 914 - 345 04 88
__
Hong Kong VARTA Batteries Pte. Ltd. Rm. 1702-3, 17/F., Fuller ton Centre 19 Hung To Road Kwun Tong, Kowloon Hong Kong
Tel (+852) 28 98 83 73 Fax (+852) 28 97 76 09
__
Japan VARTA Batteries Pte. Ltd. Kyobashi, chuo-ku Tokyo 104 Japan
Tel (+81) (3) 35 67 - 81 71 Fax (+81) (3) 35 67 - 81 75
__
South Korea VARTA Batteries Pte. Ltd. 11th Floor Fkl Bldg. 28-1, Yoido-Dong Youngdeungpo-Ku, Seoul Korea
Tel (+82) 2 - 78 55 333/4 Fax (+82) 2 - 78 50 069
__
Taiwan VARTA Batteries Pte. Ltd. 200A Room, 2/F World Trading Building 50, Hsin Shen S. Rd., Section 1 Taipei 100 Taiwan
Tel (+886) 2 - 33 93 15 57 Fax (+886) 2 - 33 93 15 56
__
Asia Pacific VARTA Batteries Pte. Ltd. 300, Tampines Avenue 5, #05-01, Tampines Junction 529653 Singapore
Tel (+65) 260 58 01 Fax (+65) 260 58 12

__
Distributors
__
A Elbacom GmbH Industriestr. 9, Top 4 2353 Guntramsdorf Austria
Tel (+43) 22 36 - 86 68 86 - 0 Fax (+43) 22 36 - 86 68 86 - 44
__
B De Munter Batteries Staatskenstraat 16 9000 Gent Belgium
Tel (+32) 9 - 2 26 28 30 Fax (+32) 9 - 2 27 05 26
__
CH Telion AG Rütistr. 26 8952 Schlieren Switzerland
Tel (+41) 17 32 16 44 Fax (+41) 17 30 16 49
__

Subject to change without further notice. Errors excepted.

E INCOMEX, S.L. Paseo Panorámico, 8 08860 CASTELLDEFELS. Barcelona Spain
Tel (+34) 93 - 664 54 66 Fax (+34) 93 - 636 52 46
__
GR D.&J.Damkalidis S.A. 44 Zefyrou Str. 17564 Paleo Faliro, Athen Greece
Tel (+30) 1 - 9 41 08 88 Fax (+30) 1 - 9 42 70 58
__
NL Deltron Radikor De Steiger 131 1305 Am Almere-Haven Netherlands
Tel (+31) 365 31 - 25 54 Fax (+31) 365 31 - 24 65
__
P Interpilhas Lda. Largo de Santa Barbara, 7–1. 1100 Lisboa Por tugal
Tel (+3512) 1 - 357 23 11 Fax (+3512) 1 - 356 37 89
__
TR Aspilsan AS Organize Sanayi Bölgesi 7. cad. No.4 P.O.Box 501 38070 Kayseri Turkey
Tel (+90) 352 - 32 11 215 Fax (+90) 352 - 32 11 217
9179___10/02