Nandiyanto Et Al 2019 - How To Read and Interpret FTIR Spectroscope of Organic
Nandiyanto Et Al 2019 - How To Read and Interpret FTIR Spectroscope of Organic
Nandiyanto Et Al 2019 - How To Read and Interpret FTIR Spectroscope of Organic
Departemen Kimia, Universitas Pendidikan Indonesia, Jl. Dr. Setiabudi no 229 Bandung 40154, Indonesia
Correspondence: E-mail: [email protected]
| DOI: http://dx.doi.org/10.17509/ijost.v4i1.15806
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A.B.D. Nandiyanto, et al. Title – How to Read and Interpret FTIR Spectroscope of Organic...| 98
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99| Indonesian Journal of Science & Technology,Volume 4 Issue 1, April 2019 Page 97-118
Table 1. Functional group and its quantified frequencies. Data was adopted
from reference (Coates, 2000)
| DOI: http://dx.doi.org/10.17509/ijost.v4i1.15806
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A.B.D. Nandiyanto, et al. Title – How to Read and Interpret FTIR Spectroscope of Organic...| 100
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| DOI: http://dx.doi.org/10.17509/ijost.v4i1.15806
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| DOI: http://dx.doi.org/10.17509/ijost.v4i1.15806
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analysis, FTIR (FTIR-4600, Jasco Corp., Japan) (3) No triple bond region (2000-2500 cm-1)
was utilized. was detected, informing no C≡C bond in
the material.
4. RESULTS AND DISCUSSION
(4) Regarding the double bond region
4.1. FTIR analysis of sample gained from
(1500-2000 cm-1), there is a huge and
literature
sharp peak was detected at about 1700
Figure 2 shows the analysis of 2- cm-1. This informs some carbonyl double
propanone. To understand the appearance bond, which can be from ketones,
peaks in the FTIR below, step-by-step process aldehydes, esters, or carboxyl. Since
can be used. The results can be concluded as there is no specific peak for aldehyde at
follows: between 2700 and 2800 cm-1 (as
(1) Regarding the number of peaks, there desribed in the previous step), the
are more than five peaks, informing that prospective peak for carbonyl should be
the analyzed chemical is not a simple from ketone. No peak at about 1600 cm-
1, informing there is no C=C bonding in
chemical.
(2) The peaks contained single bond area the material.
(2500-4000 cm-1).
(5) Based on above interpretation,
- No broad absorption band was found,
several conclusions can be obtained,
informing there is no hydrogen bond
including the analyzed material has no
in the material.
hydrate component. This material has
- There is a sharp bond at about 3500
ketones-related component, no
cm-1, replying the existence of
double or triple bond in the material.
oxygen-related bonding.
Since the peaks were only about 10
- No other peaks between 3000 and
peaks, the material should be a small
3200 cm-1 was found, informing there
organic compound.
is no aromatic structure
- Narrow bond at less than 3000 cm-1 (6) The other example in the FTIR analysis
responded to the C-C bond. is shown in Figure 3. This figure is the
- No specific peak for aldehyde has FTIR analysis result of toluene
been found at between 2700 and
2800 cm-1.
(7) The result showed that a lot of numbers Based on the above analysis, the analysis
of peaks were detected, informing the showed that the material has aromatic ring,
complex structure material and simple functional bonding (methyl). This
(8) In the single bond area (2500-4000 cm-1), is in a good agreement with the chemical
several peaks were detected. compound of toluene.
- No broad absorption band in the range
of between 3650 and 3250 cm-1,
indicating no hydrogen bond. 4.2. FTIR analysis of the LR microparticles
- Peaks at between 3000 and 3200 cm-1,
replying the aromatic ring. FTIR analysis results of saw-milled LR
- Peaks at below 3000 cm-1, responding particles are shown in Figure 4. This figure
the single bond of carbon. shows the change of FTIR peak and pattern.
- No aldehyde peak was detected at There is a change in the peaks after the
between 2700 and 2800 cm-1. heating process. Informing there is a change
(9) Regarding the triple bond region (2000- in the chemical structure. In short, since LR is
2500 cm-1), no peak was detected, vulnerable against heat, this should be the
informing no C≡C bonding. decomposition of organic component into
(10) In the double bond region (1500-2000 carbon material. The change in the FTIR peak
cm-1), several peaks were detected: and pattern was found when heating at
- Above 1775 cm-1, informing active temperature that higher than 180°C, in which
carbonyl groups, in which this should the FTIR pattern was near to the carbon as
be from ring-carbonyl carbons. explained in the literature (Nandiyanto et al.,
- Range of between 1750 and 1700 cm-1, 2016, Nandiyanto et al., 2017).
describing simple carbonyl Using above interpreting method and
compounds, in which this is due to the compared to the literature for some organic
bonding between methyl (CH3) to the material, ftir peaks are shown in Table 2. The
benzene ring. results shows that these peaks contained
- Huge band at about 1600 cm-1, several organic materials. This can be used as
informing double bonds or aromatic a standard ftir peaks for organic materials,
compounds. related to protein, carbohydrate, fat, etc.
(11) In the fingerprint region (600-1500 cm1),
strong signal was found at about 1500
cm-1 (informing aromatic ring). Vinyl-
related compound was also found at
about 1000 cm-1.
| DOI: http://dx.doi.org/10.17509/ijost.v4i1.xxxx
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Wavenumber Possible
No Assignment Ref.
Exp. Lit. nutrient type
1 601 600-608 CH out-of-plane bending Organic material (Chiang et al., 1999)
vibrations
(Schulz and Baranska,
Ring deformation of phenyl 2007)
2 929** about 930 Carbon (Nandiyanto et al., 2016,
carbon-related component Nandiyanto et al., 2017)
3 1051 1045-1053 Gives an estimate carbohydrate Carbohydrate (Huleihel et al.,
concentrations (lower in 2002,Mordechai et al.,
malignant cells) 2001)
(Paluszkiewicz and
C-O-O-C Kwiatek, 2001)
C-O stretching coupled with C-O (Wang et al., 1997)
bending of the C-OH of
carbohydrates
Glycogen (Wood et al., 1998)
C-O-C stretching (nucleic acids (Fabian et al., 1995)
and phospholipids), C-O-C
stretching of DNA and RNA
Indicates a degree of oxidative (Andrus and Strickland,
damage to DNA 1998)
Phosphate, oligosaccharides, (Yoshida et al., 1997)
PO2- stretching modes, P-O-C
antisymmetric stretching mode of
phosphate ester, and C-OH
stretching of oligosaccharides
Phosphate I band for two (Dovbeshko et al., 2002)
different C-O vibrations of
deoxyribose in DNA in A and B
forms of helix or ordering
structure
C-O in carbohydrates (Fung et al., 1996)
| DOI: http://dx.doi.org/10.17509/ijost.v4i1.xxxx
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