MSC Chem Question Bank
MSC Chem Question Bank
MSC Chem Question Bank
:
P1857 [Total No. of Pages :3
[5223] - 101
M.Sc.
PHYSICAL CHEMISTRY
CHP-110: Fundamentals of Physical Chemistry - I
(2013 Pattern) (Credit System) (Semester - I)
d) Write Gibbs Helmholtz equation and explain the meaning of each term
in it.
c) Sketch the first four eigen functions for a particle in a one dimensional
box and compare these with the probability density curves.
i) e x (0, ∞)
ii) x e− x (0, ∞)
[5223] - 101 2
SECTION-II
Q4) Attempt the following: [10]
a) Determine the half-life for a first order reaction having rate constant 600
S -1 .
b) Write the expression for the rate constant for a second order reaction
with equal concentrations. Mention its unit.
c) What are consecutive reactions? Give one example.
d) What is the effect of ionic on reaction rates?
e) Write the Michaelis - Menten equation. Draw the Eadie plot for enzyme
catalyzed reactions.
EEE
[5223] - 101 3
Total No. of Questions :6] SEAT No. :
P1858 [Total No. of Pages :4
[5223] - 102
M.Sc. - I
INORGANIC CHEMISTRY
CHI-130: Molecular Symmetry & Chemistry of P-Block Elements
(2013 Pattern) (Semester - I) (Credit System) (New)
SECTION - I
d) Draw all possible isomers of Ma2b2c2 where M is the central atom and a,
b, and c are monodentate ligands. Which of the isomers is optically
active?
e) Find the product of C2z. S2z.
[5223] - 102 2
b) Find out the normalized SALC using projection operator of E4 irreducible
representation which operates on σ 1 of the [ptCl4]2 complex ion.
E4 2 0 2 0 0 2 0 2 0 0
SECTION - II
d) Explain the following species - BH4, CH4, NH4+ are isoelectronic or not.
e) Give the oxoanions of chlorine with name and oxidation state of chlorine.
[5223] - 102 3
Q6) Attempt any one of the following : [5]
i) ClF3.
ii) Sb 5O 10.
i) [B6 H6]2.
ii) XeF4.
iv) 2, 2, 2 crypt.
v) (TeO4)2.
R R R
[5223] - 102 4
Total No. of Questions : 6] SEAT No. :
P1859 [5223]-103
[Total No. of Pages : 4
M.Sc. (Part-I)
ORGANIC CHEMISTRY
CHO - 150 : Basic Organic Chemistry
(2013 Pattern) (Semester - I) (5 - Credits)
Time : 3 Hours] [Max. Marks : 50
Instructions to the candidates:
1) All questions are compulsory.
2) Figures to the right indicate full marks.
3) Answers to the two sections should be written in separate answer books.
SECTION - I
i) ii)
P.T.O.
Q2) a) Assign R/S configurational labels to the following: [4]
i) ii)
i) ii)
i) ii)
a)
b)
c)
d)
e)
[5223]-103 3
Q6) a) Attempt any two [4]
i) Explain Hofmann elimination with suitable example.
ii) -OH is not good leaving group but - OTs, - OAc are good leaving
groups.
iii) Cycloheptatrienyl cation is aromatic while cycloheptatrienyl anion
is not.
b) Predict the products: [4]
i)
ii)
t t t
[5223]-103 4
Total No. of Questions : 6] SEAT No. :
SECTION - I
d) Describe first aid kit with respect to its content and location.
P.T.O.
Q3) Answer any one of the following: [5]
SECTION - II
c) Define :
i) Fire
ii) SOP
ïïï
[5223]-104 2
Total No. of Questions :6] SEAT No. :
P1860 [5223]-201
[Total No. of Pages : 3
M.Sc. - I
PHYSICAL CHEMISTRY
CHP - 210 : Fundamentals of Physical Chemistry - II
(2013 Pattern) (5 Credit) (Semester - II)
[5223]-201 1 P.T.O.
SECTION - I
Q1) Attempt the following: [10]
c) Sketch and explain the polarizability ellipsoids for Co2 molecule. How
they decide the Raman activity?
b) Calculate the bond length of the HCl molecule. The frequency difference
between successive spectral lines observed for its rotational spectra is
20.7 cm1.
[5223]-201 2
SECTION - II
efef
[5223]-201 3
Total No. of Questions :6] SEAT No. :
P1861 [Total No. of Pages :5
[5223] - 202
M.Sc. - I
INORGANIC CHEMISTRY
CHI - 230 : Coordination and Bioinorganic Chemistry
(2013 Pattern) (Semester - II) (5 Credits)
SECTION - I
Q1) Answer the following: [10]
i) 2 (s1 p1)
ii) 3
T2g
b) Explain how would you justify the magnetic moment for the complex
[Fe (CN) 6 ]3 ; = %0
−
0bs
i) Ferrimagnetism.
ii) Paramagnetism.
[5223] - 202 1
Q2) Answer any two of the following: [10]
a) Prepare microstate table for s1p1 configuration and hence derive the
allowed R-S term for the same.
b) Assign the spin multiplicities to the states arising from eg2 configuration
when infinitely strong octahedral field is relaxed to strong field using
Bethes method of descending symmetry correlation table and direct
product table.
i) [Co(H2O)6]2+
ii) [Ni(NH3)6]2+
λ = +90cm−1
SECTION - II
Q4) Attempt the following: [10]
1) Porphyrin i) Chlorophyll
i) Adenin
ii) Thymine
iii) Aurinofin
iv) 18-crown-6
v) Chlorophyll
[5223] - 202 3
[5223] - 202 4
T T T
[5223] - 202 5
Total No. of Questions : 6] SEAT No. :
P1862 [5223]-203
[Total No. of Pages : 5
M.Sc. - I
ORGANIC CHEMISTRY
CHO-250 : Synthetic Organic Chemistry & Spectroscopy
(2013 Pattern) (Semester-II) (New - 5 Credits)
SECTION-I
Q1) Attempt any three of the following: [9]
a) Cyclohexanone on reaction with methylene triphenyl phosphorane gives
exo double bond (exo alkene) while reaction with dimethyl sulfonium
methylide forms epoxide.
b) Reformatsky reagent is prepared with Zinc (Zn) i.e. ZnBrCH2COOE+
and not with Magnesium(Mg) or Lithium(Li).
c) Ph2C(OH)C(OH)MePh on treatment with acid catalyst H+ forms triphenyl
methyl, methyl ketone ph3c co me
d) In P-Nitro acetanilide two doublet J = 8H2 are observed, One doublet is
observed at higher field than other.
1 P.T.O.
[5223]-203
Q3) a) Predict the product (any two). [4]
i)
ii)
iii)
i)
ii)
iii)
[5223]-203 2
SECTION-II
Q4) Attempt the following: [10]
a) Calculate the λ max for the following compounds.
Q5) Deduce the structure of any five of the following compounds using spectral
data and justify your answer, [10]
a) C6H 10O
IR : 1710 and 1620 Cm1
PMR : δ 1.90 (s, 30 mm) δ 2.10 (s, 20 mm) δ 6.00 (s, 10 mm)
b) C6H 10O 3
IR : 1740 and 1710 cm1
PMR : δ 1.28 (t, J = 7 Hz, 30 mm)
δ 2.21 (s, 30 mm)
δ 3.24 (s, 20 mm)
δ 4.20 (q, J = 7 Hz, 20 mm)
[5223]-203 3
c) C8H15NO
I R : 1715 cm1
PMR : δ1.08 (d, J = 7 Hz, 6H)
δ 2.45 (t, J = 5 Hz, 4H)
δ 2.8 (t, J = 5 Hz, 4 H)
δ 2.93 (septet, J = 7Hz, 1 H)
d) C7H7NO3
U. V. 265 mm
I R : 3600, 1520, 1360 cm1
PMR : δ 7.6 (m, 18 mm)
δ 8.15 (dd, J = 2 and 7Hz, 6 mm)
δ 2.9 (s, 6 mm, e×ch. D2o)
δ 5 (s, 12 mm)
e) C7H 12O 4
IR : 1742cm1
PMR : δ 2.6 (s, 10 mm)
δ 1.3 (t, J = 6.5 Hz, 30 mm)
δ 4.16 (q, J = 6.5 Hz, 20 mm)
[5223]-203 4
Q6) Attempt any two of the following. [5]
a) Assign the chemical shifts reasoning to the various carbon in the following
compound.
CMR : 29, (q), 50 (t), 55 (q)
114 (d), 126 (s), 130 (d)
150 (s), 207 (s)
PMR : δ 1.20 (9 H, S)
δ 3.67 (3 H, S)
Y Y Y
[5223]-203 5
Total No. of Questions : 3] SEAT No. :
PART - A
Modern Separation Methods and Hyphenated Techniques
Q1) Answer the following: [10]
a) What is the principle of Gas chromatography? Explain.
b) What is Normal phase chromatography?
c) How is the resolving power of HPLC column increased?
d) Define:
i) Theoretical plates. ii) Retention time.
e) Differentiate between gradient and isocratic elutions in HPLC.
P.T.O.
Q2) Answer any two of the following: [10]
a) Explain the inductively coupled plasma in Mass Spectrometry?
b) What are the properties of an ideal detector? Classify different types of
HPLC detectors and explain the working of refractive index detector.
c) With a proper schematic labelled diagram describe the components of
HPLC instrumentation.
d) Give a brief account of:
i) Carrier gases in GC.
ii) Columns used in GC.
Q Q Q
[5223]-204 2
Total No. of Questions : 6]
P1863 [5223]-204
M.Sc. - I
CHEMISTRY
CH - 290 (B) : Basic Biochemistry
(2013 Pattern) (Semester - II) (5 Credits)
PART-B
Time : 3 Hours] [Max. Marks : 50
SECTION-I
Q1) Answer any three of the following: [9]
a) What are ribosomes? Explain prokaryotic and Eukaryotic ribosomes.
b) What is primary active transport? Explain with suitable example.
c) Discuss the reactions in TCA cycle.
d) Give an account of globular proteins.
[5223]-204 3
SECTION-II
Q4) Answer any three of the following: [9]
a) Write a short note on Coenzymes.
b) Explain the post translational modification of protein.
c) Give an overview of diseases related to nutritional deficiencies.
d) Discuss different types of inhibition.
Q Q Q
[5223]-204 4
Total No. of Questions : 3]
P1863 [5223]-204
M.Sc. - I
ANALYTICAL CHEMISTRY
CHA - 290 : General Chemistry - II
(2013 Pattern) (Semester - II)
PART - C
Concept of Analytical Chemistry
Q1) Answer the folloiwng: [10]
a) Distinguish between accuracy and precision.
b) What is an analytical sample?
c) Explain in brief T test.
d) What is meant by sample handling?
e) Calculate the proper number of significant figures in each of the following.
i) 0.00123
ii) 24.0021
Q Q Q
[5223]-204 5
Total No. of Questions : 3]
P1863
[5223]-204
M.Sc. - I
ANALYTICAL CHEMISTRY
CHA - 290 : General Chemistry - II
(2013 Pattern) (Semester - II)
PART - D
Industrial Methods of Analysis
Q1) Answer the following: [10]
a) What are the benefits of quality system for chemical laboratory.
b) What is common ion effect. Give one example.
c) What is stability constant?
d) Calculate number of millimoles present in 0.2g of CaCO3. (Given atomic
weight Ca = 40, C = 12, O = 16).
e) Enlist different types of process analysers.
b) Define:
i) Buffer.
ii) Stepwise formation constant.
iii) Quality review.
Q Q Q
[5223]-204 6
Total No. of Questions : 3]
P1863
[5223]-204
M.Sc. - I
ANALYTICAL CHEMISTRY
CHA - 290 : General Chemistry - II
(2013 Pattern) (Semester - II)
PART - E
Organometallic and Inorganic Reaction Mechanism
ii) ⎡⎣ ( 3
& 5 + 5 5
& 5 + 5 ) H& R ⎤⎦
[5223]-204 7
Q3) Attempt any one of the following: [5]
Q Q Q
[5223]-204 8
Total No. of Questions : 3]
P1863
[5223]-204
M.Sc. - I
ANALYTICAL CHEMISTRY
CHA - 290 : General Chemistry - II
(2013 Pattern) (Semester - II)
PART - F
Mathematics for Chemists
Q1) Answer the following: [10]
a) For the matrices
⎡3 2⎤ ⎡ 4 −2⎤ ⎡1 3 ⎤
A=⎢ ⎥ B = ⎢1 2 ⎥ C = ⎢ 2 −1⎥ evaluate (A + B)C = AB + BC.
⎣1 3⎦ ⎣ ⎦ ⎣ ⎦
b) Give the derivatives of:
i) sec x
ii) cos x
iii) a x
iv) tan x
v) xn
c) Give the Kramers rule.
d) Define transpose of a matrix and give suitable example.
e) Twenty different metals are to be combined in alloys regardless of relative
compositions. How many different binary alloys (containing two metals)
are possible?
[5223]-204 9
b) A radioactive sample when measured using a scintillation counter four
times, showed the activity 1202, 1206, 1222, 1201 cpm. Find the average
activity and standard deviation.
c) Differentiate the following functions w.r.t. x
x2 + 2 x + 2
i) y=
x+4
ii) y=x2 log x.
d) Evaluate the following:
i) ∫ (x + x + 5)dx
3
ii) ∫ (x − 3) 2 dx
2
⎡4⎤
⎡2 8 6⎤
i) A= ⎢ ⎥ x = ⎢6⎥ Ax = ?
⎣1 2 3⎦ ⎢⎥
⎢⎣9⎥⎦
⎡5⎤
⎡2 9 1⎤
ii) B= ⎢ ⎥ y = ⎢1⎥ By = ?
⎣8 2 7⎦ ⎢ ⎥
⎢⎣5⎥⎦
Q Q Q
[5223]-204 10
Total No. of Questions : 3]
P1863
[5223]-204
M.Sc. - I
ANALYTICAL CHEMISTRY
CHA - 290 : General Chemistry - II
(2013 Pattern) (Semester - II)
PART - G
Pericyclic, Photochemistry and Free Radical Reactions
Q2) Predict the product/products indicating mechanism in any two of the following:
[10]
a)
b)
c)
d)
[5223]-204 11
Q3) Attempt any two of the following: [5]
Q Q Q
[5223]-204 12
Total No. of Questions :6] SEAT No. :
P1864 [Total No. of Pages :3
[5223] - 301
M.Sc.
PHYSICAL CHEMISTRY
CHP-310: Quantum Chemistry and Solid State Chemistry
(2013 Pattern) (Semester - III)
i) L = 2, S = ½ and
ii) L = 1, S = 3
2
i) ex
ii) 4x2
iii) sin x
iv) 3 cos x
v) cos x + sin x
Lˆ x ,Lˆ y and L̂ z .
c) State Huckels
(4m+2) rule. Explain the mnemonic model used for
monocyclic conjugated polyenes to deduce the separation of MO energy
levels.
d) Derive the expression for the first order correction to the energy of non
degenerate unperturbed level.
[5223] - 301 2
Q3) Attempt any one of the following: [5]
a) Derive the equation for linear momentum operator (Px).
b) Formulate the Hamiltonian operators for
i) Be+2 ion and
ii) H2 molecule, explain the terms involved in it.
SECTION-II
EEE
[5223] - 301 3
Total No. of Questions :6] SEAT No. :
P1865 [5223]-302
[Total No. of Pages : 3
M.Sc.
PHYSICAL CHEMISTRY
CHP - 311 : Nuclear, Radiation and Photo-Chemistry
(2013 Pattern) (Semester - III) (New)
[5223]-302 1 P.T.O.
SECTION - I
a) Discuss with the help of a typical fission yield curve, the distribution of
fission fragments.
a) Calculate the energies of the two peaks in the RBS spectrum correspond
to 65Cu & 197Au assuming on incident 4He+ ions of 2MeV energy & a
scattering angle of 160º.
b) If the number of uranium atoms fissioning per three seconds are 9.51×1017,
find the power generated in MW, Given : Energy released per uranium
nuclear fission is 200 MeV.
[5223]-302 2
SECTION - II
Q4) Attempt the following: [10]
a) Define quantum yield. Give the relation between quantum yield and
photoluminescent intensity.
o
b) Calculate the frequency of ultraviolet light having wavelength of 3000 A .
c) Explain lifetimes of excited electronic states of atoms and molecules.
d) Explain the terms stimulated emission and spontaneous emission.
e) Give two important characteristics of fluorescence.
R R R
[5223]-302 3
Total No. of Questions : 6] SEAT No. :
P1866 [5223]-303
[Total No. of Pages : 3
M.Sc.
PHYSICAL CHEMISTRY
CHP-312 : Physico-Chemical Methods of Analysis
(2013 Pattern) (Semester-III) (New)
1 P.T.O.
[5223]-303
SECTION-I
Q1) Answer precisely the following: [10]
a) Why does weight of empty crucible change when it is heated upto 1000°C
in TGA technique.
b) Define the terms binding energy and work function used in ESCA.
[5223]-303 2
SECTION-II
Q4) Attempt the following: [10]
a) Briefly describe quantitative analysis by chemiluminesance.
b) What are the different excitation signals used in voltammetry technique?
c) State the principle of coulometry.
d) Define plasma and give the advantages of using plasma is atomic emission
spectroscopy.
e) Briefly describe hydrodynamic voltammetry.
Q Q Q
[5223]-303 3
Total No. of Questions :6] SEAT No. :
P1867 [5223]-304
[Total No. of Pages : 3
M.Sc.
PHYSICAL CHEMISTRY
CHP - 313 : Polymer Chemistry
(2013 Pattern) (Semester - III)
1
[5223]-304 P.T.O.
SECTION - I
Q1) Attempt the following: [10]
SECTION - II
Q4) Attempt the following: [10]
T T T
3
[5223]-304
Total No. of Questions :6] SEAT No. :
P1868 [5223]-305
[Total No. of Pages : 3
M.Sc.
PHYSICAL CHEMISTRY
CHP - 314 : Modern Trends in Physical Chemistry
(2013 Pattern) (New) (Optional) (Semester - III)
1
[5223]-305 P.T.O.
SECTION - I
a) State the phase rule and describe the terms involved in it.
b) Define the term upper critical solution temperature. Give its examples.
c) Derive the equation showing the relation between total vapour pressure
of the mixture, P1 to the composition of the vapour YA.
2
[5223]-305
SECTION - II
T T T
3
[5223]-305
Total No. of Questions :4] SEAT No. :
P1869 [Total No. of Pages :2
[5223] -306
M.Sc. -II
INORGANIC CHEMISTRY
CHI-326: Organometallic Chemistry and Homogeneous Catalysis
(2013 Pattern) (Semester - III)
c) Consider the 18 e rule as a guide and determine the value of n in the
following . Complexes.
i) (η 5. C5H5) V (CO)n
i) Salvarsan
ii) Silatrane
i) What are the difference between Suzuki and Heck coupling reaction?
EEE
[5223] - 306 2
Total No. of Questions :4] SEAT No. :
P1870 [Total No. of Pages :3
[5223] - 307
M.Sc. - II
INORGANIC CHEMISTRY
CHI-330: Inorganic Reaction Mechanism, Photochemistry and
Magnetic Properties of Coordination Compounds
(2013 Pattern) (Semester - III) (4 Credit)
b) Propose an efficient route for the synthesis of cis & trans [Pt Cl2(NH3)
(pph3)] starting from [Pt Cl4]2.
+ +
cis ⎡⎣Co (en )2 Cl 2 ⎤⎦ → Trans ⎡⎣Co (en )2 Cl 2 ⎤⎦
i) Ferromagnetism.
ii) Antiferromagnetism.
d) What are mixed valence compounds? How they are classified? Comment
on their magnetic behaviour.
[5223] - 307 2
Q4) Write a note on (Any Two) : [10]
a) Chellate effect.
c) Insertion Reactions.
R R R
[5223] - 307 3
Total No. of Questions : 4] SEAT No. :
P1871 [5223]-308
[Total No. of Pages : 2
M.Sc. - II
INORGANIC CHEMISTRY
CHI-331 : Physical Methods in Inorganic Chemistry
(2013 Pattern) (Semester-III) (Credit System)
j) Define lattice.
1 P.T.O.
[5223]-308
Q2) Answer any two of the following: [10]
a) A cubic crystaline material of cell length 10.60A° is to be examined by
using cukα radiation ( λ = 1.54A° ). At what angle would you expect to
get the maximum reflection from the fourth order of (100) plane?
b) Explain the use of cyclic voltammetry for detection of 1, 2, 3, 4
tetrachlorobenzen.
c) How the quadrupole splitting occurs in the molecules? Explain whether
the natural 57Fe shows quadrupole splitting.
d) Explain the ESR-spectrum for benzene radical.
Q Q Q
[5223]-308 2
Total No. of Questions :4] SEAT No. :
P1872 [Total No. of Pages :2
[5223] - 309
M.Sc. - II
INORGANIC CHEMISTRY
CHI - 332 : Bioinorganic and Inorganic Medicinal Chemistry
(2013 Pattern) (Credit System) (Semester - III)
b) Name the type - 1 Copper proteins. What are the pathological disorders
caused due to Cu deficiency?
c) Enlist the functions of blue - copper proteins.
e) Which element is present at the active site centre of tyrosinase? Give the
functions of tyrosinase.
T T T
[5223] - 309 2
Total No. of Questions :6] SEAT No. :
P1873 [Total No. of Pages :4
[5223] - 310
M.Sc. -II
ORGANIC CHEMISTRY
CHO-350: Organic Reaction Mechanism
(2013 Pattern) (New) (Semester - III)
SECTION-I
a)
b)
d)
i)
ii)
iii)
[5223] - 310 2
SECTION-II
a)
b)
c)
d)
[5223] - 310 3
B) Write short notes on any two: [4]
a) Dimerisation of 1,3-butadiene.
b) Transannualar Reaction.
i)
ii)
iii)
EEE
[5223] - 310 4
Total No. of Questions :6] SEAT No. :
P1874 [Total No. of Pages :7
[5223] - 311
M.Sc.
ORGANIC CHEMISTRY
CHO-351: Spectroscopic Methods in Structure Determination
(2013 Pattern) (Semester - III)
SECTION - I
a)
c)
[5223] - 311 2
d) Deduce the structure :
M.F. : C6 H 6O 2
PMR : 2.3 (s, 3H) 5.85 (d, 2Hz, 1H) 6.2 (dd, 1.5 & 2Hz, 1H)
7.2(d, 1.5 Hz, 1H)
M.F. : C7H7O3N
d) Correlated Spectroscopy.
SECTION - II
Q4) A) Write the genesis of the ions indicated below (any three) : [6]
[5223] - 311 3
c) 130, 115, 100, 73, 43
Q5) A) Assign the signals to various carbon atoms in the following compound.[3]
17.9 (t) 19.1(q) 25.8(q) 31.1(t)
32.4(s) 32.8(t) 34.6(t) 38.4(t)
75.5(s) 81.3(d) 121.0(t) 126.7(s)
140.0(s) 144.7(s) 169.7(s)
B) Assign the signals given below to the various protons in compound X.
Justify your answer. [5]
7.35-7.28(m, 7H) 6.79(d, 8.7 Hz, 1H)
5.05(d, 11.7Hz, 1H) 5.0(d, 11.7Hz, 1H)
4.21(d, 17.5Hz, 1H) 4.30(m, 1H)
4.18(d, 17.5 Hz, 1H) 4.14(dd, 9.1 &
3Hz, 1H)
4.07(t, 9Hz, 1H) 2.29(m, 1H)
0.85(d, 7.1Hz, 3H) 0.77(d, 7Hz, 3H)
Decoupling Expt :
Irradiate at Change at
4.30 δ i) 2.29(m) → septet
ii) 4.14(dd) → d(9.1Hz)
iii) 4.07(t) → d(9.1Hz)
Q6) A compound exhibits following spectral data shown on the attached sheet.
Suggest the structure and explain the observed spectral data. [9]
[5223] - 311 4
[5223] - 311 5
[5223] - 311 6
R R R
[5223] - 311 7
Total No. of Questions :6] SEAT No. :
P1875 [Total No. of Pages :4
[5223] - 312
M.Sc.
ORGANIC CHEMISTRY
CHO-352: Organic Stereochemistry
(2013 Pattern) (Semester - III)
SECTION-I
c) Draw the stereo structures of most stable and least stable conformation
of perhydroanthracene. Give nomenclature of these isomers.
Q2) Predict the product in any four of the following and explain stereochemical
principles involved. Justify: [8]
a)
b)
c)
d)
e)
[5223] - 312 2
SECTION-II
i) Plain curves
[5223] - 312 3
d) Explain which of the following compound form an epoxide on treatment
with base
EEE
[5223] - 312 4
Total No. of Questions :6] SEAT No. :
P1876 [Total No. of Pages :3
[5223] - 313
M.Sc. - II
ORGANIC CHEMISTRY
CHO - 353 : Photochemistry, Pericyclic Reactions and Heterocyclic Chemistry
(2013 Pattern) (Semester - III)
SECTION - I
Q1) Explain any three of the following: [9]
a) Cyclobutanone undergoes three types of photoreactions.
b) Molecular orbitals of pentadienyl system and comment on their symmetry
and C2 axis of symmetry.
c) Irradiation of benzene yields a mixture of three products.
d) Correlation diagram of disrotatory interconversion of cyclobutene -
butadiene system.
Q2) Predict the product/s suggesting suitable mechanism for any two: [8]
c) Photoenolisation.
SECTION - II
c) The boiling point of pyrrole (130ºC) is higher than furan (32ºC) and
thiophene (84ºC).
Q5) Predict the product/s suggesting suitable mechanism for any two of the
following:
[8]
[5223] - 313 2
Q6) A) Complete the following sequence of reaction for any two: [4]
T T T
[5223] - 313 3
Total No. of Questions :6] SEAT No. :
P1877 [Total No. of Pages :3
[5223] - 314
M.Sc. -II
ANALYTICAL CHEMISTRY
CHA-390: Electroanalytical and Radioanalytical Methods of Analysis
(2013 Pattern) (Credit System) (Semester - III)
SECTION-I
SECTION-II
[5223] - 314 2
Q5) Attempt any two of the following [10]
a) Explain the absolute method used in neutron activation analysis.
b) Explain the construction and working of modern thermo balance.
c) State the principle of DSC. Draw and describe the DSC curve for
isothermal crystallization of polyethylene.
d) An impure sample of calcium oxalate monohydrate was analysed using
TGA technique. The TG curve of the sample indicates total mass change
from 100 mg to 45 mg, when the sample was heated upto 900oC. Calculate
the percentage purity of the sample.
[Given: At. Wt. of Ca = 40, C = 12, O = 16 and H = 1]
EEE
[5223] - 314 3
Total No. of Questions :6] SEAT No. :
P1878 [Total No. of Pages :3
[5223] - 315
M.Sc. - II
ANALYTICAL CHEMISTRY
CHA-391: Pharmaceutical Analysis
(2013 Pattern) (Semester - III) (Credit System)
SECTION - I
Q1) Answer the following : [10]
a) What is principle of Karl Fischers titration?
b) What is assay design?
c) What is stability of drugs?
d) Define drug?
e) What are limit tests? Why these are taken?
SECTION - II
[5223] - 315 2
Q6) Attempt any one of the following : [5]
R R R
[5223] - 315 3
Total No. of Questions :6] SEAT No. :
P1879 [Total No. of Pages :3
[5223] - 316
M.Sc. -II
ANALYTICAL CHEMISTRY
CHA-392: Advanced Analytical Techniques
(2013 Pattern) (Credit System) (Semester - III)
SECTION-I
SECTION-II
c) State the principle of AAS and explain its instrumentation with block
diagram.
[5223] - 316 2
Q6) Solve any one of the following [5]
EEE
[5223] - 316 3
Total No. of Questions : 9] SEAT No. :
P1880 [5223]-317
[Total No. of Pages : 3
M.Sc. - II
ANALYTICAL CHEMISTRY
CHA - 380 : I - Analytical Method Development and Validation
II - Geochemical and Alloy Analysis
III - Laboratory Automation and Sensor Based Techniques
(2013 Pattern) (Semester - III) (Credit System)
Time : 3 Hours] [Max. Marks : 50
Instructions to the candidates:
1) Answer to the two sections should be written in separate answer books.
2) All questions are compulsory.
3) Neat diagrams must be drawn wherever necessary.
4) Use of logarithmic table, non programmable calculator is allowed.
SECTION - I
SECTION - II
c) Enlist the constituent of brass alloy and mention the procedure used for
their estimation.
c) Discuss the method used for estimation of nitrogen from soil sample.
d) 0.225 gm of brass sample was dissolved in 20ml of conc HCl and diluted
to 100ml. A 10ml aliquote of this solution is withdrawn and 5% 10ml KI
is added to it. The liberated iodine is titrated with 0.025N Na2S2O3 and
the titre value obtained is 9.6ml. Calculate the percentage of copper in
given sample. [Given : At.wt cu = 63.54, O = 16, I = 127, Na = 23, S = 32]
[5223]-317 2
Q6) Attempt any one of the following. [5]
a) Discuss the outline for estimation of tin from solder alloy.
b) 0.250 gm of sample containing magnesium was dissolved in 5 ml of
conc HCl and diluted to 100 ml. A 10ml Aliquote of this solution titrated
against 0.01 m EDTA solution and the titre value obtained is 13.5ml
Calculate the percentage of magnesium in given sample. [Given At. wt
Mg = 24.31g].
SECTION - III
(Laboratory Automation & Sensor Based Techniques)
Q7) Answer the following: [10]
a) Give advantages of automation.
b) Define chemical sensors.
c) State any four achievements of biotransduction.
d) What is automatic titrations?
e) What is polymer replication?
O O O
[5223]-317 3
Total No. of Questions :6] SEAT No. :
P1881 [5223]-401
[Total No. of Pages : 3
M.Sc. -II
PHYSICAL CHEMISTRY
CHP - 410 : Molecular Structure & Spectroscopy
(New) (2013 Pattern) (Semester - IV)
[5223]-401 1 P.T.O.
SECTION - I
Q1) Attempt the following: [10]
1
14.4 T. The magnetogyric ratio is 6.73×107 T1s1. [I = for 13C]
2
b) Compare the number of lines in esr of radicals
< XH 2 and < XD 2 ⎡⎣ Xspin state is 5 ⎤ .
2⎦
SECTION - II
efef
[5223]-401 3
Total No. of Questions :6] SEAT No. :
P1882 [5223]-402
[Total No. of Pages : 3
M.Sc.
PHYSICAL CHEMISTRY
CHP - 411 : Surface Chemistry and Electrochemistry
(2013 Pattern) (Semester - IV) (New)
[5223]-402 1 P.T.O.
SECTION - I
(Surface Chemistry)
a) Write the equation for Gibbs monolayer and explain the terms involved
in it.
a) One gram of activated charcoal has surface area of 1000 m2, considering
complete coverage as well as monomolecular adsorption, how much
ammonia in cm3 at STP would be adsorbed on the surface of 25 g
charcoal? Diameter of ammonia molecule is 0.3nm.
[5223]-402 2
SECTION - II
(Electro Chemistry)
a) Write Bernal-Fowler equation for heat of solvation and explain the forms
involved in it.
T T T
[5223]-402 3
Total No. of Questions : 6] SEAT No. :
P1883 [5223]-403
[Total No. of Pages : 3
M.Sc. - II
PHYSICAL CHEMISTRY
CHP-412 : Materials Chemistry and Catalysis
(2013 Pattern) (Semester-IV) (New)
1 P.T.O.
[5223]-403
SECTION-I
Q1) Attempt the following: [10]
a) Draw the schematic cross sectional diagram of the RF-sputtering system.
b) What are the characteristics of 2-1-4 material?
c) Define rectifiers & draw the diagram of half wave rectifier.
d) What is Langmuir-Blodgett film?
e) Which are optical properties of solid devices?
SECTION-II
Q4) Attempt the following: [10]
a) Differentiate between physical and chemical adsorption.
b) Define catalytic activity.
c) Define support and promoters with example.
d) Define functionality with example.
e) Write the principles of green chemistry.
[5223]-403 2
Q5) Attempt any two of the following: [10]
a) Discuss hydrothermal method of preparation of catalyst.
b) Describe a method to determine pore size.
c) Discuss the FTIR method to determine solid particle size.
d) How are organic pollutants degraded using photocatalyst?
Q Q Q
[5223]-403 3
Total No. of Questions : 6] SEAT No. :
P1884 [5223]-404
[Total No. of Pages : 3
M.Sc. - II
PHYSICAL CHEMISTRY
CHP-413 : Biophysical Chemistry
(2013 Pattern) (Semester-IV) (New)
1 P.T.O.
[5223]-404
SECTION-I
Q1) Attempt the following: [10]
a) Explain Hendersons equation and its role in preparing buffers.
b) State and explain Braggs law.
c) Distinguish between active and passive transport.
d) Define electrophoresis and give one application.
e) Differentiate between reverse osmosis and osmosis.
SECTION-II
Q4) Attempt precisely the following: [10]
a) Explain the terms:
i) Channel proteins and
ii) Carrier proteins
b) Define - Axolemma and endocytosis.
c) Enlist the factors affecting enzyme activity.
d) Explain the term flow birefringence.
e) Draw a neat labelled diagram of a cross-section of cell membrane.
[5223]-404 2
Q5) Answer any two of the following: [10]
a) Derive Michaelis - Mention equation for enzyme catalysis.
b) What are biopolymers? State their characteristics and applications.
c) Discuss the applications of CD spectroscopy.
d) Discuss the Danielli and Davson model to describe the structure of a cell
membrane.
HC
× 103 2.84 2.91 3.08 3.32
τ
b) A polymer sample contains equal number of molecules with molecular
weights 15,000 and 25,000. Calculate Mn and Mw .
Q Q Q
[5223]-404 3
Total No. of Questions : 6] SEAT No. :
P1885 [5223]-405
[Total No. of Pages : 3
M.Sc. - II
PHYSICAL CHEMISTRY
CHP-414 : Special Topics in Nuclear and Radiation Chemistry
(2013 Pattern) (Semester-IV) (New)
1 P.T.O.
[5223]-405
SECTION-I
i) 40
20
Ca (n, ________
ii) 27
13
Al( Q ______
Given:- 7
Li=7.01822amu
1
1
H =1.00814amu
4
2
He= 4.00387amu
b) Discuss how compound nucleus theory is verified experimentally.
[5223]-405 2
SECTION-II
Q4) Attempt the following: [10]
a) What are the key conditions for characterizing a geological environment
required for radioactive waste disposal.
b) Explain the term geminate recombination.
c) What are the advantages of radiometric titration method.
d) Explain the term neutron star.
e) What is the advantages of using radical scavenging technique?
Q Q Q
[5223]-405 3
Total No. of Questions :4] SEAT No. :
P1886 [Total No. of Pages :2
[5223] - 406
M.Sc. II
INORGANIC CHEMISTRY
CHI-430: Inorganic Polymers & Heterogeneous Catalysis
(2013 Pattern) (Semester - IV)
d) Polysilanes.
R R R
[5223] - 406 2
Total No. of Questions :4] SEAT No. :
P1887 [Total No. of Pages :2
[5223] - 407
M.Sc. - II
INORGANIC CHEMISTRY
CHI - 431 : Material Science - I : Inorganic Solid State Materials
(2013 Pattern) (Semester - IV)
j) A piece of wood containing moisture weighed 210.3 gram and after oven
drying shared constant weight of 190.2 gram. Calculate the moisture
content.
c) Explain Meissner effect. What are type-I and type-II super conductors?
C
d) Derive the expression, X= T-V .
c
a) What are ferrates? How they are prepared? Explain hard and soft ferrates.
d) What is blended cement? What are the different types of blended cement?
a) Kirkendall effect.
c) BCS Theory.
T T T
[5223] - 407 2
Total No. of Questions : 4] SEAT No. :
P1888 [5223]-408
[Total No. of Pages : 2
M.Sc. - II
INORGANIC CHEMISTRY
CHI-432 : Material Science - II (Nanomaterials)
(2013 Pattern) (Semester-IV) (4 Credits)
b) What are the methods that can be used to stabilise collidal nano-
suspensions?
f) How silver nanoparticle acts as a drug? Give its mechanism to kill the
microbes.
1 P.T.O.
[5223]-408
Q2) Answer the following: (any two) [10]
a) What is nanoparticles? Name the various chemical & physical methods
for synthesis of nanoparticles.
b) Discuss the chemical reduction method for the synthesis of zero valent
iron nanoparticle.
c) Draw the typical Raman spectra for single wall carbon nanotube & explain.
c) What are Inorganic nanotubes? Give example and describe the synthesis
of any one?
d) List the methods for producing carbon nanotubes and explain any one
of the method.
Q Q Q
[5223]-408 2
Total No. of Questions : 9] SEAT No. :
P1889 [Total No. of Pages : 3
[5223]-409
M.Sc. - II
INORGANIC CHEMISTRY
CHI - 445 : Applications in Industry, Environment and Medicine
(2013 Pattern) (Semester - IV)
Time : 3 Hours] [Max. Marks : 50
Instructions to the candidates:
1) Attempt any two sections of the following.
2) Both sections should be written in the same answer book.
3) All questions are compulsory.
4) Figures to the right indicate full marks.
5) Neat diagram must be drawn wherever necessary.
6) Use of logarithmic table or calculators is allowed.
SECTION-I
(Applications in Industry)
Q1) Answer the following : [10]
a) What is pigment? Write the classification of pigments on the basis of its
origin.
b) What is purpose of food colour?
c) Draw the structure of anthocyanine and give its application.
d) Write the composition of tetrachromate electrolytic bath.
e) What is meant by sherardizing?
1 P.T.O.
[5223]-409
Q3) Write a note on any one. [5]
a) Addition agents.
b) Extender pigment.
c) Use of precious metal in electroplating.
SECTION-II
(Environment)
Q4) Answer the following. [10]
a) Define primary standard and secondary standard for surface drinking
water act.
b) How solar energy is the source of future energy?
c) What is powerball? How is the power ball manufactured.
d) Define active and passive solar heating system?
e) Explain the primary and secondary sludge process.
[5223]-409 2
SECTION-III
(Applications of Metal ions in Medicine)
Y Y Y
[5223]-409 3
Total No. of Questions :6] SEAT No. :
P1890 [Total No. of Pages :4
[5223] - 410
M.Sc. -II
ORGANIC CHEMISTRY
CHO-450: Chemistry of Natural Products
(2013 Pattern) (Semester - IV) (New Course)
SECTION - I
a)
b)
d)
e)
[5223] - 410 2
SECTION - II
a)
b)
c)
d)
e)
[5223] - 410 3
b) Complete the following biogenetic conversion :
a)
R R R
[5223] - 410 4
Total No. of Questions :6] SEAT No. :
P1891 [Total No. of Pages :4
[5223] - 411
M.Sc. - II
ORGANIC CHEMISTRY
CHO - 451 : Advanced Synthetic Organic Chemistry
(2013 Pattern) (Semester - IV)
SECTION - I
Q1) Predict the product/s of the following: [10]
[5223] - 411 2
Q3) Answer any two of the following: [5]
SECTION - II
[5223] - 411 3
Q5) Suggest the Mechanism any four of the following: [10]
T T T
[5223] - 411 4
Total No. of Questions : 6] SEAT No. :
P1892 [Total No. of Pages : 3
[5223] - 412
M.Sc. - II
ORGANIC CHEMISTRY
CHO - 452 : Carbohydrate, Chiron Approach, Chiral Drugs and
Medicinal Chemistry
(Semester - IV) (2013 Pattern)
SECTION - I
How will you distinguish between the two types of carbonyl goups?
Explain the formation of ⊗ with possible mechanism. Write any two biological
applications of Dextropropoxyphene hydrochloride.
[5223] - 412 2
SECTION - II
Q4) Answer the following. [10]
l l l
[5223] - 412 3
Total No. of Questions : 6] SEAT No. :
P1893 [Total No. of Pages : 5
[5223]-413
M.Sc. - II
ORGANIC CHEMISTRY
CHO - 453 : Designing Organic Synthesis and Asymmetric Synthesis
(2013 Pattern) (Semester - IV)
Time : 3 Hours] [Max. Marks : 50
Instructions to the candidates:
1) All questions are compulsory.
2) Figures to the right indicate full marks.
3) Answer to the two sections should be written in separate answer books.
SECTION-I
Q1) Answer the following: [10]
a) Why convergent method is more useful than the linear method for the
synthesis of a target molecule?
b) What is the use of t - Boc protecting group in organic synthesis?
c) Reaction of the pyrrolidine enamine of 2 - methyl cyclohexanone with
methyl iodide gives 2, 6 dimethyl cyclohexanone, explain.
d) Define umpolung. Explain acyl anion derived from nitroalkanes.
e) Give the synthetic equivalent to the following synthons.
Q2) a) How will you bring about following transformations (any two). [5]
i)
ii)
1 P.T.O.
[5223]-413
iii)
i)
ii)
iii)
[5223]-413 2
b) Arrange the given reagents in proper order to accomplish the following
conversion write the structures of the intermediates. [2]
SECTION-II
i)
ii)
iii)
[5223]-413 3
b) Name the suitable reagent for the following transformations and comment on
the formation of the product (any two). [4]
i)
ii)
iii)
i)
[5223]-413 4
ii)
iii)
Y Y Y
[5223]-413 5
Total No. of Questions :6] SEAT No. :
P1894 [Total No. of Pages :3
[5223] - 414
M.Sc. - II
ANALYTICAL CHEMISTRY
CHA-481: Analytical Toxicology and Food Analysis
(2013 Pattern) (Semester - IV)
SECTION - I
Q1) Answer the following : [10]
a) What is antidote?
b) State the principle for determination of barbiturate by procedure A.
c) Define the terms :
i) Psychotropic substance.
ii) Opium.
d) Explain Narcotics.
e) State principle of determination of caffeine.
i) Coca leaf.
ii) Addict.
iii) Cannabis.
v) Narcotic drugs.
SECTION - II
[5223] - 414 2
Q5) Answer any two of the following : [10]
a) What are amino acids? How are total free amino acids estimated?
R R R
[5223] - 414 3
Total No. of Questions :6] SEAT No. :
P1895 [Total No. of Pages :3
[5223] - 415
M.Sc. - II
ANALYTICAL CHEMISTRY
CHA - 490 : Analytical Spectroscopy
(2013 Pattern) (Semester - IV)
SECTION - I
Q1) Answer the following questions: [10]
a) State and explain the principle of XPS.
b) Explain the term electron shake up and electron shake off.
c) Discuss the role of collimator in X-ray analysis.
d) Draw the schematic diagram of X-ray tube.
e) Give the advantages of electron microscopy.
SECTION - II
[5223] - 415 2
d) The spin quantum number for a proton is ½, the allowed orientations in
the magnetic field correspond to MIL= +½ and MIH = ½, calculate ν
for allowed orientation.
T T T
[5223] - 415 3
Total No. of Questions : 6] SEAT No. :
P1896 [Total No. of Pages : 3
[5223] - 416
M.Sc. - II
ANALYTICAL CHEMISTRY
CHA - 491 : Analytical Methods for Analysis of Fertilizers, Detergents,
Water, Polymer, Paint and Pigment
(Semester - IV) (2013 Pattern)
SECTION - I
b) Enlist the methods used for determination of cyanide from polluted water.
c) What is active ingredient in detergent?
a) Give the analytical method for the estimation of chromium from waste
water.
SECTION - II
Q4) Answer the following. [10]
i) Pigment
ii) Binder
e) Enlist the electrical properties used for analysis and testing of polymer.
a) Differentiate between
i) Natural polymer and synthetic polymer.
[5223] - 416 2
b) Describe in detail an ebulliometric method used for the determination of
M n of polymer.
l l l
[5223] - 416 3
Total No. of Questions : 9] SEAT No. :
P1897 [Total No. of Pages : 3
[5223]-417
M.Sc. - II
ANALYTICAL CHEMISTRY
CHA - 492 : Method of Analysis and Application; Pollution Monitoring
and Control, Analysis of Body Fluids, Carbon Nanostructures and
Applications of Nanotechnology
(2013 Course) (Semester - IV)
Time : 3 Hours] [Max. Marks : 50
Instructions to the candidates:
1) Answers to the two sections should be written in separate answer books.
2) All the questions are compulsory
3) Neat diagrams must be drawn wherever necessary.
4) Use of logarithmic tables/ non-programmable calculator is allowed.
SECTION-I
(Pollution Monitoring and Control)
Q1) Answer the following : [10]
a) Discuss the sources of organic particulate matter.
b) What are the commonly used recovery techniques for the metals.
c) Mention any two methods for analysis of carbon monoxide (Co).
d) List the photochemical reactions in atmosphere.
e) Explain the role of zeolites in ion exchange method.
1 P.T.O.
[5223]-417
Q3) Attempt any one of the following: [5]
a) Outline the analytical method for the estimation of nitrates and nitrites.
b) Discuss the mechanisms involved during the separation of particulate
matter from polluted air.
SECTION-II
(Analysis of Body Fluid)
[5223]-417 2
SECTION-III
(Carbon Nanostructures and Applications of Nanotechnology)
Y Y Y
[5223]-417 3
Total No. of Questions :6] SEAT No. :
P1898 [Total No. of Pages :3
[5223] -1001
M.Sc. -I
PHYSICAL CHEMISTRY
CHP-110: Fundamentals of Physical Chemistry - I
(2014 Pattern) (Semester - I)
[5223] - 1001 2
SECTION-II
Q4) Attempt the following: [10]
a) Give, the main advantages of the stopped flow technique over continuous
flow method.
b) Define the term quantum yield. Give the processes on which high quantum
yield depends.
c) Distinguish between first and second order reaction with respect to rate
equation, unit and half-life.
d) What is stirling approximation. Calculate the value of ln 98!.
e) Write down equation for diffusion controlled reactions? What are diffusion
controlled limits.
EEE
[5223] - 1001 3
Total No. of Questions :6] SEAT No. :
P1899 [Total No. of Pages :3
[5223] - 1002
M.Sc. - I
INORGANIC CHEMISTRY
CHI-130: Molecular Symmetry and Chemistry of P - block Elements
(2014 Pattern) (Semester - I) (4 Credit System)
SECTION - I
Q1) Answer the following : [10]
c) Draw the structure of PCL5 molecule and identity different types of planes
in it.
d) Find out the product of C31 × C32 in BF3 molecule and also find whether
they commute with each other or not.
a) Explain all the symmetry elements present in the molecule XeOF4 and
assign the correct point group.
b) Define Abelian group. Prove that C2v point group is an Abelian group.
S2 = C 2 ( z ) × σ xy = i
SECTION - II
Q4) Answer the following : [10]
a) Alkali metal solution is a good conductor of electricity in liquid ammonia.
Explain.
b) Give classification of hydrides of Boron.
c) Give the preparation methods for dihydrogen.
d) What are allotropes of carbon? Draw the structure of Metal - fullerene.
e) What is activation of nitrogen? Explain any two methods of activation.
i) Ammonia.
ii) B4H10
i) ClF5
ii) B5Hg
iii) 18 - crown - 6
iv) Li4(CH3)4
v) PH3
A1g 1 1 1 1 1 1 1 1 1 1 x2+y2,z2
A2g 1 1 1 1 1 1 1 1 1 1 Rz
B1g 1 1 1 1 1 1 1 1 1 1 x2y2
B2g 1 1 1 1 1 1 1 1 1 1 xy
Eg 2 0 2 0 0 2 0 2 0 0 (Rx,Ry) (xz,yz)
A1u 1 1 1 1 1 1 1 1 1 1
A2u 1 1 1 1 1 1 1 1 1 1 z
B1u 1 1 1 1 1 1 1 1 1 1
B2u 1 1 1 1 1 1 1 1 1 1
Eu 2 0 2 0 0 2 0 2 0 0 (x,y)
R R R
[5223] - 1002 3
Total No. of Questions : 6] SEAT No. :
P1900 [5223]-1003
[Total No. of Pages : 4
M.Sc. (Part-I)
ORGANIC CHEMISTRY
CHO-150 : Basic Organic Chemistry
(2014 Pattern) (Semester-I) (4 Credits)
SECTION-I
b) Mustard gas (Cl - CH2 CH2 5CH2 CH2 Cl) undergoes rapid hydrolysis.
Justify.
e) Explain -
1 P.T.O.
[5223]-1003
Q2) Answer any five of the following: [10]
a) Determine the absolute configuration of chiral centres a & b in the
following.
[5223]-1003 2
Q3) Write note on: (any two) [5]
a) Structure and stability of carbanions.
b) Hyperconjugation.
c) Huckels Rule.
SECTION-II
Q4) Attempt the following: [10]
a) Neomenthyl Chloride reacts several times faster than menthyl chloride in
E2 elimination. Explain.
b) Explain the reaction -
a)
b)
[5223]-1003 3
c)
d)
e)
a)
b)
c)
Q Q Q
[5223]-1003 4
Total No. of Questions :6] SEAT No. :
P1901 [Total No. of Pages : 2
[5223] - 1004
M.Sc. - I
ANALYTICAL CHEMISTRY
CHA - 190 : Safety in Chemical Laboratory and Good Laboratory
Practices
(2014 - Pattern) (Semester - I) (Credit System) (4-Credits)
SECTION - I
Q1) Answer the following: [10]
a) Give any four responsibilities of students and workers.
b) How does exposure to toxic chemicals takes place through ingestion.
c) Describe what are heat and smoke detectors.
d) Define : i) Carcinogen.
ii) Irritants.
e) Mention the different types of gloves.
SECTION - II
Q4) Answer the following: [10]
a) Enlist various disposal options.
b) Describes the safety measures for corrosive gases.
c) Define and explain stock register.
d) Give the methods for reducing chemical exposure.
e) What are the steps for managing wastes?
l l l
[5223] - 1004 2
Total No. of Questions :6] SEAT No. :
P1902 [5223]-2001
[Total No. of Pages : 3
M.Sc.
PHYSICAL CHEMISTRY
CHP - 210 : Fundamentals of Physical Chemistry - II
(2014 Pattern) (Semester - II) (New 4 Credit)
[5223]-2001 1 P.T.O.
SECTION - I
1
b) Deduce the relation Vmax = − 1.
2xe
a) Determine the bond length of CO2 molecule from the following data.
[5223]-2001 2
SECTION - II
Q4) Attempt the following: [10]
a) How many atoms of 1μCi 38C1 will remain after 75m if its half life period
is 37.3m?
b) What is meant by spur, track and δ - rays?
c) How are thermalized neutrons obtained in the nuclear reactor?
d) Explain the use of radioisotope in solubility measurement of sparingly
soluable salt.
e) Define elementary separation factor.
abandance = 69.17%]
b) Calculate the number of atoms of 226Ra remaining after four half lives if
1g of it is present intially.
[Given t1/2(226Ra) = 1600y, activity of 1g 226Ra = 1 Ci]
R R R
[5223]-2001 3
Total No. of Questions :6] SEAT No. :
P1903 [Total No. of Pages :6
[5223] - 2002
M.Sc. - I
INORGANIC CHEMISTRY
CHI - 230 : Coordination and Bioinorganic Chemistry
(2014 Pattern) (Semester - II)
SECTION - I
Q1) Answer the following questions: [10]
a) state and explain Hunds rule to determine the ground state term symbols.
i) A2g
4
ii) 3
H
a) Prepare a table of microstates and hence derive the allowed R.S. terms
for vanadium (III) ion in ground state.
i) [Ni(H2o)6]+2
ii) [CoCl4]2
b) The free gas ion Ti+2 has a 3 Fλ ground R.S. term. The 1D and 3P terms
are above 3F by 10642 cm1 and 12920 cm1 respectively. The energies
of the terms are given in terms of Racah parameters.
( F) = A 8B
E 3
( P ) = A + 7B
E 3
E(D) = A 3B + 2C
[5223] - 2002 2
SECTION - II
Q4) a) Answer in short: [4]
ii) Uracil.
iii) 4 Fe - 4S.
iv) Cardiolyte.
b) Transferrin.
c) Structure of proteins.
d) Metals in medicine.
v) H+ ion 5) Siderophore
[5223] - 2002 3
[5223] - 2002 4
[5223] - 2002 5
T T T
[5223] - 2002 6
Total No. of Questions : 6] SEAT No. :
P1904 [Total No. of Pages : 4
[5223] - 2003
M.Sc. - I
ORGANIC CHEMISTRY
CHO - 250 : Synthetic Organic Chemistry and Spectroscopy
(Semester - II) (2014 Pattern)
SECTION - I
Q3) Predict the products and suggest the mechanism any two. [5]
a)
b)
c)
d)
SECTION - II
Q4) Attempt any five of the following: [10]
a) Explain the fundamental vibrations and overtones in IR.
b) Calculate λ max for following:
[5223] - 2003 2
d) The mass spectrum of n-propyl benzene has a base peak at m/z 91 (M -
29). However the mass spectrum of o-nitropropyl benzene exhibits no
M-29 peak.
e) Assign the IR absorption values 1720, 1769, 1928cm1., to the following
compounds with proper justification.
Q5) Deduce the structure of any five of the following compounds using spectral
data and justify your answer. [10]
a) MF : C4H7 BrO2
IR : 3300, 2700, 1720 cm1
PMR : δ 1.08 (t, J = 7Hz, 3H); 2.07(m, 2H), 4.23,
(t, J = 7Hz, 1H); 10.97 (s, 1H, Exchangeable with D2O).
b) MF :C8H8O2
IR : 1735 cm1
PMR : 4.0 (s, 3H); 7.3 (s, 5H)
c) MF :C5H8O2
IR : 1695, 1620, 990 and 910cm1
PMR : δ 1.6 (t, J = 6Hz, 3H); 4.3 (q, J = 6Hz, 2H)
5.8 (dd, J = 4Hz & 10Hz, 1H); 6.11 (dd, J = 10 & 16Hz, 1H);
6.4 (dd, J = 4Hz & 16Hz, 1H)
d) Two isomeric hydrocarbons A & B with MF : C5H10
shows following CMR data.
A : 13 (q) ; 17 (q); 26(q), 118(d), 132(s) ppm
B : 13(q), 22(q), 31(t), 108(t), 147 (s) ppm.
[5223] - 2003 3
e) How will you differentiate the following by M.S.
f) MF : C8H10O
UV : 250, 260nm
IR : 3360 cm1
PMR : 1.6 (br.s, 4mm); 2.8 (t, J = 7Hz, 8mm);
3.9 (t, J = 7 Hz, 8mm); 7.20 (s, 20mm).
0.9, d, 7Hz, 6H
1.5, d, 7Hz, 3H
1.85, m, 1H
2.45, d, 7Hz, 2H
b) Explain in brief the factors affecting chemical shift in PMR.
c) Deduce the structure of the compounds from the data provided.
i) A compound with Molecular formula C4H6O exhibits IR : 1620cm1.
CMR : 146, d; 100,d, 70, t, 38t.
ii) A compound exhibits MS : 53 (M+), 27, 26.
IR : 2250, 1610cm1
CMR : 138, 116, 107.
l l l
[5223] - 2003 4
Total No. of Questions : 3] SEAT No. :
P1905 [5223]-2004
[Total No. of Pages : 14
M.Sc. - I
ANALYTICAL CHEMISTRY
CHA - 290 : General Chemistry-II
(2014 Pattern) (Semester - II) (New 4 Credits)
New Course Based on Credit & Semester System
PART - A : Modern Separation Methods and Hyphenated Tech-
niques(2.0 Credit/ 25 Marks)
PART - B : Basic Biochemistry(4.0 Credit/ 50 marks)
PART - C : Concept of Analytical Chemistry(2.0 Credit/ 25
marks)
PART - D : Industrial Methods of Analysis(2.0 Credit/ 25 marks)
PART - E : Organometallic and Inorganic Reaction Mechanism
(2.0 Credit/ 25 marks)
PART - F : Mathematics for Chemists(2.0 Credit/ 25 marks)
PART - G : Pericyclic, Photochemistry and Free Radical
Reactions(2.0 Credit/ 25 marks)
Time : 3 Hours] [Max. Marks : 50
Instructions to the candidates:
1) All questions of respective section/part are compulsory.
2) Figures to the right hand side indicate full marks.
3) Neat labelled diagram must be drawn wherever necessary.
4) Use of log table/non programmable calculator is allowed.
5) Students should attempt any two parts from Part-A,C,D,E,F and G or full paper of
biochemistry(Part-B).
6) Write the answers of two parts on separate answer books.
PART - A
Modern Separation Methods and Hyphenated Techniques
Q1) Answer the following: [10]
a) Give any two applications of GLC.
b) What is meant by column switching technique in Gas Chromatography?
c) Compare the process of isocratic and gradient elution.
d) Explain the principle of MS.
e) How resolving power of HPLC column is increased.
P.T.O.
Q2) Attempt any two of the following: [10]
a) What are the characteristics of an ideal detector? Classify different HPLC
detectors and explain the working and limitations of the refractive index
detector.
b) Explain the inductively coupled plasma in Mass Spectrometry.
c) Compare GC and HPLC on the basis of following points
i) Principle
ii) Sample injection system
iii) Column
iv) Detector
v) Application
d) With a labelled schematic diagram explain the working of mass
spectrometer.
t t t
[5223]-2004 2
Total No. of Questions : 6]
P1905 [5223]-2004
M.Sc. - I
CHEMISTRY
CH - 290 (B) : Basic Biochemistry
(2014-15 Pattern) (Semester - II) (4 Credits)
PART - B
Time : 3 Hours] [Max. Marks : 50
Instructions to the candidates:
1) All questions are compulsory.
2) Answer to the two sections to be written in separate answer books.
3) Figures to the right indicate maximum marks.
SECTION-I
Q1) Answer any three of the following: [12]
a) What are the different methods for determination of end terminals of
peptide chain? Explain one method each for the amino & carboxy terminal.
b) Discuss the different forces responsible & thus the structural differences
between secondary & tertiary structures.
c) Discuss the structural features & function of Mitochondria and
Endoplasmic reticulum.
d) Give the important functions of lipids. Briefly elucidate their metabolism.
Q2) Differentiate & distinguish between the following (any four): [8]
a) Active & passive transport.
b) Essential and non essential amino acids.
c) Prokaryotes and Eukaryotes.
d) Glycogen and cellulose.
e) α-helix and β-pleated sheets.
f) Saturated and unsaturated fatty acids.
[5223]-2004 3
b) Describe Eukaryotic cell with its subcellular components and their role
in the cell.
c) Classify amino acids with suitable examples.
SECTION-II
Q4) Answer any three of the following: [12]
a) Derive Michaelis Menten equation and give its significance to understand
enzyme kinetics.
b) Explain what is Genetic code. Discuss different characteristics of Genetic
code.
c) Explain in brief DNA replication.
d) Describe the effects of competitive & non competitive inhibitors on the
kinetics of enzyme reactions.
t t t
[5223]-2004 4
Total No. of Questions : 3]
P1905 [5223]-2004
M.Sc. - I
ANALYTICAL CHEMISTRY
CHA - 290 : General Chemistry - II
(2014 Pattern) (Semester - II)
PART - C
Concept of Analytical Chemistry
[5223]-2004 5
Q3) Attempt any one of the following: [5]
i) SEM-EDAX and
ii) TEM.
t t t
[5223]-2004 6
Total No. of Questions : 3]
P1905 [5223]-2004
M.Sc. - I
ANALYTICAL CHEMISTRY
CHA - 290 : General Chemistry - II
(2014 Pattern) (Semester - II)
PART - D
Industrial Methods of Analysis
a) Define:
i) gmole
ii) ppb
c) How will you prepare 25 ppm sodium solution from NaCl(mol. wt. of
NaCl = 58)
i) quality audits
[5223]-2004 7
Q3) Answer any one of the following: [5]
t t t
[5223]-2004 8
Total No. of Questions : 3]
P1905 [5223]-2004
M.Sc. - I
ANALYTICAL CHEMISTRY
CH - 290 : General Chemistry - II
(2014 Pattern) (Semester - II)
PART - E
Organometallic and Inorganic Reaction Mechanism
[PtCl ]
2−
4
+ NO 2 → ? + NH 3 → ?
b) Explain the term outer sphere reaction mechanism with suitable example.
[5223]-2004 9
Q3) Answer any one of the following: [5]
a) Draw the structure of the following:
i) [Ir(CO) Cl(PPh)2]
i) [Fe(CO)4]2
iv) Co2(CO)8
v) ClMn(CO)5
t t t
[5223]-2004 10
Total No. of Questions : 3]
P1905 [5223]-2004
M.Sc. - I
ANALYTICAL CHEMISTRY
CHA - 290 : General Chemistry - II
(2014 Pattern) (Semester - II)
PART - F
Mathematics for Chemists
⎡ 1 3 5⎤
⎢ −2 5 6 ⎥
i) A= ⎢ ⎥
⎢⎣ 7 0 3 ⎥⎦
⎡2 8 5⎤
⎢ ⎥
ii) A = ⎢4 0 6⎥
⎢⎣ 3 2 7 ⎥⎦
d) Give derivatives of :
i) ax
ii) tanx
iii) sin1x
iv) xn
e) Differentiate the following function with respect to x
y = x2 logx.
[5223]-2004 11
Q2) Attempt any two of the following: [10]
a) What is a cusp? Describe the types of cusps.
b) Evaluate the following:
i) ∫ x( x + 3)5 dx
2
ii) ∫ tan
2
x dx
i) ( x3 + 2 x − 5)( x − 3)
ii) y = (5 x + 4 x 2 )5
d) Using Falks scheme evaluate the following:
⎡2 3 8 ⎤ ⎡2⎤
i) A= ⎢ ⎥ x = ⎢3⎥ Ax = ?
⎣9 6 7 ⎦ ⎢ ⎥
⎢⎣ 4 ⎥⎦
⎡4⎤
⎡7 1 1 ⎤ ⎢ ⎥
ii) B= ⎢ ⎥ y = ⎢8 ⎥ By = ?
⎣2 5 2⎦
⎢⎣ 2 ⎥⎦
t t t
[5223]-2004 12
Total No. of Questions : 3]
P1905 [5223]-2004
M.Sc. - I
ANALYTICAL CHEMISTRY
CHA - 290 : General Chemistry - II
(2014 Pattern) (Semester - II)
PART - G
Pericyclic, Photochemistry and Free Radical Reactions
Q2) Explain the mechanism for any three of the folloiwng: [9]
a)
b)
c)
[5223]-2004 13
d)
Q3) a) Predict the products for any two of the following indicating the mechanism
involved. [4]
i) ?
ii) ?
iii) ?+?
iv) ?
t t t
[5223]-2004 14