Chem 1002 DR Aung Kyaw Swar General Chemistry (For Zool, Bot, Geol, Phys)

Chem 1002 Dr Aung Kyaw Swar
GENERAL CHEMISTRY (FOR ZOOL, BOT, GEOL, PHYS)
1. (a) (i) What are the general characteristics of gases? (5 M)
(ii) State ideal gas law and ideal gas law equation. (2 M)
(b) (i) Define Dalton’s law of partial pressure. (2 M)
(ii) What pressure is exerted by a mixture of 2.00 g of H2 and 8.00 g of N2 at 237 K in a

10 dm3 vessel? (H = 1.008, N = 14) (4 M)
2. (a) (i) Define diffusion and effusion. (2 M)
(ii) 50 cm3 of gas A effuse through a pin hole in 146 s. The same volume of CO2 under
identical conditions was effuse in 115 s. Calculate the molar mass of A. (C = 12, O = 16)
(4 M)
(b) (i) Derive the relation between average velocity, RMS (root mean square velocity) and
most probable velocity. (3 M)
(ii) Calculate the root mean square velocity of methane molecule at 370 K (R = 8.314 JK-
1mol-1, C = 12, H = 1) (4 M)
3. (a) (i) Calculate the average kinetic energy per molecule of CO2 gas at 27 C. (R= 1.987
calK-1mol-1, C =12, O = 16) (3 M)
(ii) Calculate the most probable velocity of nitrogen molecules, N2, at 15 C. (N = 14)
(3 M)
4. (a) (i) Define unsaturated solution, saturated solution and supersaturated solution. (3M)
(ii) At constant temperature, 250 cm3 of nitrogen under 720 mm pressure and 300 cm3 of
oxygen under 650 mm pressure were put into a 1 dm3 flask. What will be final pressure
of the mixture?
(4 M)
(b) (i) Write the equation for molarity, molality and normality. (3 M)
(ii) 45 g of glucose, C6H12O6, are dissolved in 500 g of water. Calculate the molality of
the solution. (C = 12, O = 16, H = 1). (4 M)
5. (a) (i) Define solubility. (2 M)

(ii) At 20 C the solubility of nitrogen gas in water is 0.0150 gdm-3 when the partial
pressure of N2 is 580 torr. Find the solubility of N2 in H2O at 20 C when its partial
pressure is 800 torr. (4 M)
(b) (i) Describe the limitation of Henry’s Law. (4 M)
(ii) Define colligative property. (2 M)
6. (a) (i) Describe the properties of dilute solution containing non-volatile solute (4 M)
(ii) Calculate the vapour pressure lowering caused by the addition of 100 g of sucrose
(molecular mass = 342 amu) to 1000g of water if the vapour pressure of pure water at 25
C is 23.8 mmHg. (3 M)
(b) (i) The boiling point of a solution containing 0.20 g of a substance X in 20 g of ether is
0.17 K higher than that of pure ether. Calculate the molecular mass of X. Boiling point
constant of ether per 1 kg is 2.16 K. (4 M)
(ii) 0.440 g of a substance dissolved in 22.2 g of benzene lowered the freezing point of
benzene by 0.567 K. Calculate the molecular mass of the substance. (Kf = 5.12 Kkgmol-1)
(3 M)
7. (a) (i) CH3COOH + Zn  ? (2 M)
(ii) C6H5COOH + PCl5  ? (2 M)
(iii) CH3COOH + HOOCCH3 P2O5 ? (2 M)
(b) Write the symbol equations for
(i) acetic acid + ethyl alcohol  ? (2 M)
(ii) acetyl chloride + ethyl alcohol  ? (2 M)
(iii) acetic anhydride + ethyl alcohol  ? (3 M)
8. (a) Write the general equation for ester react with ammonia and amines to form 1, 2 and 3
amide. (6 M)
(b) (i) Arrange each of the following compounds in order of increasing acidity.
(a) Acetic acid, ethanol, formic acid
(b) Benzene, Benzoic acid, benzyl alcohol
(c) Butanoic acid, 2-chlorobutanoic acid, 3-chlorobutanoic acid

(d) Sulfuric acid, 1- butyne, butanoic acid (4 M)
(ii) Write down the word and symbol equation for preparation of ester (a) from
carboxylic acid (b) from acid chloride (3 M)
9. (a) How to prepare the carboxylic acid by (i) oxidation of primary alcohol (ii) oxidation of
aldehydes (iii) hydrolysis of nitriles (6 M)
(b) Complete the following in words and symbols

H+
(a) CH3COOH + C6H5CH2OH ?
H2O
(b) CH3COOC2H5 + NaOH
(c) RCONH2 KOBr
10. (i) Gases have ------- expansibility.
(ii) Ideal gas equation is ----------.
(iii) One mole of any gas at STP occupies a volume of 22.4 dm3, so the numerical value of R
is ------------.
(iv) Gas molecules are in constant random motion with --------- velocities.
(v) The intermolecular forces in liquids are collectively called -------- forces.
(vi) The general rule of thumb for solution is the idea that -------------.
(vii) In a solution, the sizes of particles are 0 to ---------nm. They never settle on standing.
(viii) The solubility of a gas in a solvent depends upon the --------- and ---------.
(ix) The name of formic acid is comes from formica, which is Latin word for -------.
(x) The boiling point of carboxylic acid was increase with ------------ in molecular weight.
(xi) The larger the ------------ value the grater is the ----------- of acid.
(xii) Ester are compounds containing the ------------ functional group.

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Chem 1002 Dr Aung Kyaw Swar

GENERAL CHEMISTRY (FOR ZOOL, BOT, GEOL, PHYS)

1. (a) (i) What are the general characteristics of gases? (5 M)

(b) (i) Define Dalton’s law of partial pressure. (2 M)

(ii) What pressure is exerted by a mixture of 2.00 g of H2 and 8.00 g of N2 at 237 K in a

2. (a) (i) Define diffusion and effusion. (2 M)

5. (a) (i) Define solubility. (2 M)

(b) (i) Describe the limitation of Henry’s Law. (4 M)

(ii) Define colligative property. (2 M)

7. (a) (i) CH3COOH + Zn  ? (2 M)

(ii) C6H5COOH + PCl5  ? (2 M)

(iii) CH3COOH + HOOCCH3 P2O5 ? (2 M)

(b) Write the symbol equations for

(i) acetic acid + ethyl alcohol  ? (2 M)

(ii) acetyl chloride + ethyl alcohol  ? (2 M)

(iii) acetic anhydride + ethyl alcohol  ? (3 M)

(a) Acetic acid, ethanol, formic acid

(b) Benzene, Benzoic acid, benzyl alcohol

(c) Butanoic acid, 2-chlorobutanoic acid, 3-chlorobutanoic acid

(b) Complete the following in words and symbols

(c) RCONH2 KOBr

10. (i) Gases have ------- expansibility.

(ii) Ideal gas equation is ----------.

(xii) Ester are compounds containing the ------------ functional group.

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