SAFETY DATA SHEET

Product Trade Name: HYFLO IV M SURFACTANT

Revision Date: 11-Apr-2017 Revision Number: 17

1. Identification
1.1. Product Identifier
Product Trade Name: HYFLO IV M SURFACTANT
Synonyms None
Chemical Family: Blend
Internal ID Code HM000918

1.2 Recommended use and restrictions on use

Application: Surfactant
Uses advised against Consumer use

1.3 Manufacturer's Name and Contact Details

Manufacturer/Supplier
Halliburton Energy Services, Inc.
P.O. Box 1431
Duncan, Oklahoma 73536-0431
Telephone: 1-281-871-6107

Halliburton Energy Services, Inc.

645 - 7th Ave SW Suite 1800
Calgary, AB
T2P 4G8
Canada

Prepared By Chemical Stewardship

Telephone: 1-281-871-6107
e-mail: [email protected]

1.4. Emergency telephone number:

Emergency Telephone Number 1-866-519-4752 or 1-760-476-3962
Global Incident Response Access Code: 334305
Contract Number: 14012

2. Hazards Identification
2.1 Classification in accordance with paragraph (d) of §1910.1200

Aspiration Toxicity Category 1 - H304

Skin Corrosion / Irritation Category 1 - H314
Serious Eye Damage/Irritation Category 1 - H318
Germ Cell Mutagenicity Category 1B - H340
Carcinogenicity Category 1B - H350
Specific Target Organ Toxicity - (Single Exposure) Category 3 - H335 + H336
Specific Target Organ Toxicity - (Repeated Exposure) Category 1 - H372
Acute Aquatic Toxicity Category 2 - H401
Chronic Aquatic Toxicity Category 2 - H411
Flammable liquids. Category 2 - H225

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2.2. Label Elements

Hazard Pictograms

Signal Word: Danger

Hazard Statements H225 - Highly flammable liquid and vapor

H304 - May be fatal if swallowed and enters airways
H314 - Causes severe skin burns and eye damage
H318 - Causes serious eye damage
H335 - May cause respiratory irritation
H336 - May cause drowsiness or dizziness
H340 - May cause genetic defects
H350 - May cause cancer
H372 - Causes damage to organs through prolonged or repeated exposure
H401 - Toxic to aquatic life
H411 - Toxic to aquatic life with long lasting effects

Precautionary Statements

Prevention P201 - Obtain special instructions before use

P202 - Do not handle until all safety precautions have been read and understood
P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition
sources. No smoking.
P233 - Keep container tightly closed
P240 - Ground and bond container and receiving equipment.
P241 - Use explosion-proof electrical/ventilating/lighting/equipment
P242 - Use only non-sparking tools
P243 - Take action to prevent static discharges.
P260 - Do not breathe dust/fume/gas/mist/vapors/spray
P264 - Wash face, hands and any exposed skin thoroughly after handling
P270 - Do not eat, drink or smoke when using this product
P271 - Use only outdoors or in a well-ventilated area
P273 - Avoid release to the environment
P280 - Wear protective gloves/protective clothing/eye protection/face protection
Response P301 + P330 + P331 - IF SWALLOWED: rinse mouth. Do NOT induce vomiting
P303 + P361 + P353 - IF ON SKIN (or hair): Take off immediately all
contaminated clothing. Rinse skin with water [or shower].
P363 - Wash contaminated clothing before reuse
P304 + P340 - IF INHALED: Remove person to fresh air and keep comfortable for
breathing.
P310 - Immediately call a POISON CENTER or doctor/physician
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several
minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P370 + P378 - In case of fire: Use CO2, dry chemical, or foam

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P391 - Collect spillage
Storage P403 + P233 - Store in a well-ventilated place. Keep container tightly closed
P403 + P235 - Store in a well-ventilated place. Keep cool
P405 - Store locked up
Disposal P501 - Dispose of contents/container in accordance with
local/regional/national/international regulations

2.3 Hazards not otherwise classified

None known

3. Composition/information on Ingredients
Substances CAS Number PERCENT (w/w) GHS Classification - US
Light aromatic solvent 64742-95-6 30 - 60% Skin Irrit. 2 (H315)
Muta. 1 (H340)
Carc. 1B (H350)
STOT SE 3 (H336)
Asp. Tox. 1 (H304)
Aquatic Acute 2 (H401)
Aquatic Chronic 3 (H412)
Flam. Liq. 3 (H226)
Isopropanol 67-63-0 10 - 30% Eye Irrit. 2 (H319)
STOT SE 3 (H336)
Flam. Liq. 2 (H225)
1,2,4 Trimethylbenzene 95-63-6 10 - 30% Skin Irrit. 2 (H315)
Eye Irrit. 2 (H319)
STOT SE 3 (H335)
STOT RE 1 (H372)
Aquatic Acute 2 (H401)
Aquatic Chronic 2 (H411)
Flam. Liq. 3 (H226)
Sulfonate salt Proprietary 10 - 30% Acute Tox. 4 (H302)
Acute Tox. 4 (H312)
Acute Tox. 4 (H332)
Skin Corr. 1A (H314)
Eye Corr. 1 (H318)
STOT SE 3 (H335)
Aquatic Acute 3 (H402)
Flam. Liq. 2 (H225)
Distillates (petroleum), catalytic reformer 68477-31-6 5 - 10% Skin Irrit. 2 (H315)
fractionator residue, low-boiling Carc. 1B (H350)
Asp. Tox. 1 (H304)
Aquatic Acute 2 (H401)
Aquatic Chronic 3 (H412)
Flam. Liq. 3 (H226)
Organic polymer Proprietary 1 - 5% Eye Irrit. 2 (H319)
Aquatic Acute 2 (H401)
Combustible Dust
Sulfuric acid, di(butylamine) salt 39085-66-0 1 - 5% Acute Tox. 4 (H302)
Acute Tox. 3 (H311)
Acute Tox. 3 (H331)
Skin Corr. 1 (H314)
Eye Corr. 1 (H318)
STOT SE 3 (H335)
Aquatic Acute 2 (H401)
Xylene 1330-20-7 1 - 5% Skin Irrit. 2 (H315)
Eye Irrit. 2 (H319)
STOT SE 3 (H335)
Asp. Tox. 1 (H304)
Aquatic Acute 2 (H401)

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Flam. Liq. 3 (H226)
Heavy aromatic petroleum naphtha 64742-94-5 1 - 5% Asp. Tox. 1 (H304)
Aquatic Acute 2 (H401)
Aquatic Chronic 2 (H411)
Naphthalene 91-20-3 1 - 5% Acute Tox. 4 (H302)
Carc. 2 (H351)
Aquatic Acute 1 (H400)
Aquatic Chronic 1 (H410)
Flam. Sol. 2 (H228)

The specific chemical identity of the composition has been withheld as proprietary.

The exact percentage (concentration) of the composition has been withheld as proprietary.

4. First Aid Measures

4.1. Description of first aid measures
Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory
irritation develops or if breathing becomes difficult.
Eyes In case of contact, immediately flush eyes with plenty of water for at least 30
minutes. Remove contact lenses after the first 5 minutes and continue washing.
Seek immediate medical attention/advice. Suitable emergency eye wash facility
should be immediately available
Skin In case of contact, immediately flush skin with plenty of soap and water for at least
30 minutes and remove contaminated clothing, shoes and leather goods
immediately. Get medical attention immediately.
Ingestion Do NOT induce vomiting. Rinse mouth. Never give anything by mouth to an
unconscious person. Obtain immediate medical attention.

4.2 Most important symptoms/effects, acute and delayed

Causes severe eye irritation which may damage tissue. Causes severe skin irritation with tissue destruction. May
cause respiratory irritation. May cause headache, dizziness, and other central nervous system effects. Aspiration into
the lungs may cause chemical pneumonitis including coughing, difficulty breathing, wheezing, coughing up blood and
pneumonia, which can be fatal. May cause heritable genetic damage. Carcinogen. May cause damage to organs
through prolonged or repeated exposure.

4.3. Indication of any immediate medical attention and special treatment needed
Notes to Physician Aspiration may cause severe lung damage. Evacuate stomach in a way which avoids
aspiration.

5. Fire-fighting measures
5.1. Extinguishing media
Suitable Extinguishing Media
Water fog, carbon dioxide, foam, dry chemical.
Extinguishing media which must not be used for safety reasons
Do NOT spray pool fires directly with water. A solid stream of water directed into hot burning liquid can cause
splattering.

5.2 Specific hazards arising from the substance or mixture

Special exposure hazards in a fire
Decomposition in fire may produce harmful gases.

5.3 Special protective equipment and precautions for fire-fighters

Special protective equipment for firefighters
Full protective clothing and approved self-contained breathing apparatus required for fire fighting personnel.

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6. Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures
Ensure adequate ventilation. Use appropriate protective equipment. Do not breathe dust/fume/gas/mist/vapors/spray.
Remove sources of ignition. Take precautionary measures against static discharges All equipment used when
handling the product must be grounded Avoid contact with skin, eyes and clothing.
See Section 8 for additional information

6.2. Environmental precautions

Prevent from entering sewers, waterways, or low areas.

6.3. Methods and material for containment and cleaning up

Dike far ahead of liquid spill for later disposal. Soak up with inert absorbent material. Pick up and transfer to properly
labeled containers. Remove ignition sources and work with non-sparking tools.

7. Handling and storage

7.1. Precautions for safe handling
Handling Precautions
Do not breathe dust/fume/gas/mist/vapors/spray. Ensure adequate ventilation. Use appropriate protective equipment.
Remove sources of ignition. Ground and bond containers when transferring from one container to another. Avoid
contact with eyes, skin, or clothing.
Hygiene Measures
Handle in accordance with good industrial hygiene and safety practice.

7.2. Conditions for safe storage, including any incompatibilities

Storage Information
Store in a cool well ventilated area. Keep from heat, sparks, and open flames.

8. Exposure Controls/Personal Protection

8.1 Occupational Exposure Limits

Substances CAS Number OSHA PEL-TWA ACGIH TLV-TWA

Light aromatic solvent 64742-95-6 Not applicable Not applicable
Isopropanol 67-63-0 TWA: 400 ppm TWA: 200 ppm
TWA: 980 mg/m3 STEL: 400 ppm
1,2,4 Trimethylbenzene 95-63-6 Not applicable Not applicable
Sulfonate salt Proprietary Not applicable Not applicable
Distillates (petroleum), catalytic 68477-31-6 Not applicable Not applicable
reformer fractionator residue,
low-boiling
Organic polymer Proprietary Not applicable Not applicable
Sulfuric acid, di(butylamine) salt 39085-66-0 Not applicable Not applicable
Xylene 1330-20-7 TWA: 100 ppm TWA: 100 ppm
TWA: 435 mg/m3 STEL: 150 ppm
Heavy aromatic petroleum 64742-94-5 Not applicable Not applicable
naphtha
Naphthalene 91-20-3 TWA: 10 ppm TWA: 10 ppm
TWA: 50 mg/m3

8.2 Appropriate engineering controls

Engineering Controls Ensure adequate ventilation, especially in confined areas

8.3 Individual protection measures, such as personal protective equipment

Personal Protective Equipment If engineering controls and work practices cannot prevent excessive exposures,

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the selection and proper use of personal protective equipment should be
determined by an industrial hygienist or other qualified professional based on the
specific application of this product.
Respiratory Protection If engineering controls and work practices cannot keep exposure below
occupational exposure limits or if exposure is unknown, wear a NIOSH certified,
European Standard EN 149, AS/NZS 1715:2009, or equivalent respirator when
using this product. Selection of and instruction on using all personal protective
equipment, including respirators, should be performed by an Industrial Hygienist or
other qualified professional.

Hand Protection Use gloves which are suitable for the chemicals present in this product as well as
other environmental factors in the workplace.
Skin Protection Wear impervious protective clothing, including boots, gloves, lab coat, apron, rain
jacket, pants or coverall, as appropriate, to prevent skin contact.
Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.
Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. Physical and Chemical Properties

9.1. Information on basic physical and chemical properties
Physical State: Liquid Color Amber
Odor: Hydrocarbon Odor No information available
Threshold:

Property Values
Remarks/ - Method
pH: 4-6
Freezing Point / Range No data available
Melting Point / Range No data available
Boiling Point / Range No data available
Flash Point 12.8 °C / 55 °F PMCC
Flammability (solid, gas) No data available
Upper flammability limit 12.7%
Lower flammability limit 2%
Evaporation rate No data available
Vapor Pressure No data available
Vapor Density No data available
Specific Gravity 0.91
Water Solubility Insoluble in water
Solubility in other solvents No data available
Partition coefficient: n-octanol/water No data available
Autoignition Temperature No data available
Decomposition Temperature No data available
Viscosity No data available
Explosive Properties No information available
Oxidizing Properties No information available

9.2. Other information

VOC Content (%) No data available

10. Stability and Reactivity

10.1. Reactivity
Not expected to be reactive.

10.2. Chemical stability

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Stable

10.3. Possibility of hazardous reactions

Will Not Occur

10.4. Conditions to avoid

Keep away from heat, sparks and flame.

10.5. Incompatible materials

Strong oxidizers.

10.6. Hazardous decomposition products

Oxides of nitrogen. Oxides of sulfur. Carbon monoxide and carbon dioxide.

11. Toxicological Information

11.1 Information on likely routes of exposure
Principle Route of Exposure Eye or skin contact, inhalation. Ingestion.

11.2 Symptoms related to the physical, chemical and toxicological characteristics

Acute Toxicity
Inhalation May cause respiratory irritation. May cause central nervous system depression
including headache, dizziness, drowsiness, incoordination, slowed reaction time,
slurred speech, giddiness and unconsciousness.
Eye Contact Causes serious eye damage.
Skin Contact Causes severe burns.
Ingestion May be fatal if swallowed and enters airways. Causes burns of the mouth, throat
and stomach.

Chronic Effects/Carcinogenicity May cause heritable genetic damage. Contains known or suspected carcinogens.
Causes damage to organs through prolonged or repeated exposure.

11.3 Toxicity data

Toxicology data for the components

Substances CAS Number LD50 Oral LD50 Dermal LC50 Inhalation
Light aromatic solvent 64742-95-6 8400 mg/kg (Rat) >2000 mg/kg (Rabbit) 5.2 mg/L (Rat) 4h
>5000 mg/kg (Rat) 3400 ppm (Rat) 4h
>8.53 mg/L (Rat) 4h
Isopropanol 67-63-0 5840 mg/kg-bw (rat) 12870 mg/kg-bw (rabbit) 72.6 mg/L (Rat, 4h, vapor)
1,2,4 Trimethylbenzene 95-63-6 3415 mg/kg-bw (rat) >3440 mg/kg-bw (rat) (similar >10.2 mg/L (rat, 4 h, aerosol)
substance) (similar substance)
Sulfonate salt Proprietary 371.8 mg/kg-bw (Rat) (similar 1100 mg/kg-bw (guinea pig) 4.2 mg/L (Rat, 4h, vapor) (similar
substance) (similar substance) substance)
Distillates (petroleum), 68477-31-6 2551 mg/kg ( Rat ) > 5000 mg/kg bw (rabbit) (similar >5.6 mg/l (rat,mist) (similar
catalytic reformer substance) substance)
fractionator residue,
low-boiling
Organic polymer Proprietary > 2000 mg/kg (Rat) (similar > 2000 mg/kg (Rat) (similar > saturated concentration (Rat)
substance) substance) 5h (similar substance)
Sulfuric acid, 39085-66-0 371.8 mg/kg-bw (rat)(similar 366 mg/kg-bw (guinea 4.2 mg/L (rat, 4 hr, vapor)(similar
di(butylamine) salt substance) pig)(similar substance) substance)
Xylene 1330-20-7 3523 mg/kg bw (Rat) >4200 mg/kg (rabbit) 27.6 mg/L (Rat, 4h, vapor)

Heavy aromatic 64742-94-5 >5000 mg/kg-bw (rat) >2000 mg/kg-bw (rabbit) > 4.778 mg/L (rat, 4 h, vapour,
petroleum naphtha saturated)
Naphthalene 91-20-3 490 mg/kg ( Rat ) 1110 mg/kg ( 1120 mg/kg ( Rabbit ) 20 g/kg ( 340 mg/m3 ( Rat ) 1 h
Rat ) Rabbit )

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Substances CAS Number Skin corrosion/irritation
Light aromatic solvent 64742-95-6 Causes moderate skin irritation. (Rabbit)
Isopropanol 67-63-0 Non-irritating to the skin (Rabbit)
1,2,4 Trimethylbenzene 95-63-6 Irritating to skin. (Rabbit) Causes moderate skin irritation. (similar substances)
Sulfonate salt Corrosive to skin (Rabbit) (similar substances)
Distillates (petroleum), 68477-31-6 Skin, rabbit: Causes moderate skin irritation. (similar substances)
catalytic reformer
fractionator residue,
low-boiling
Organic polymer Causes moderate skin irritation. (similar substances)
Sulfuric acid, di(butylamine) 39085-66-0 Skin, rabbit: Causes severe burns (similar substances)
salt
Xylene 1330-20-7 Causes skin irritation.
Heavy aromatic petroleum 64742-94-5 Non-irritating to the skin (Rabbit) (similar substances)
naphtha
Naphthalene 91-20-3 Non-irritating to the skin (Rabbit)

Substances CAS Number Serious eye damage/irritation

Light aromatic solvent 64742-95-6 Non-irritating to rabbit's eye
Isopropanol 67-63-0 Causes moderate eye irritation (Rabbit)
1,2,4 Trimethylbenzene 95-63-6 Irritating to eyes (Rabbit) May cause moderate eye irritation.
Sulfonate salt Causes severe eye irritation (Rabbit) (similar substances)
Distillates (petroleum), 68477-31-6 Non-irritating to the eye (Rabbit)
catalytic reformer
fractionator residue,
low-boiling
Organic polymer Causes moderate eye irritation (similar substances)
Sulfuric acid, di(butylamine) 39085-66-0 Eye, rabbit: Causes severe irritation and or burns (similar substances)
salt
Xylene 1330-20-7 Causes moderate eye irritation (Rabbit)
Heavy aromatic petroleum 64742-94-5 Non-irritating to rabbit's eye (similar substances)
naphtha
Naphthalene 91-20-3 May cause mechanical irritation to eye. (human) Non-irritating to rabbit's eye

Substances CAS Number Skin Sensitization

Light aromatic solvent 64742-95-6 Did not cause sensitization on laboratory animals (guinea pig)
Isopropanol 67-63-0 Did not cause sensitization on laboratory animals (guinea pig)
1,2,4 Trimethylbenzene 95-63-6 Did not cause sensitization on laboratory animals (guinea pig) (similar substances)
Sulfonate salt Did not cause sensitization on laboratory animals (guinea pig) (similar substances) No information
available
Distillates (petroleum), 68477-31-6 Did not cause sensitization on laboratory animals (guinea pig) (similar substances)
catalytic reformer
fractionator residue,
low-boiling
Organic polymer Did not cause sensitization on laboratory animals (mouse) (similar substances)
Sulfuric acid, di(butylamine) 39085-66-0 No data of sufficient quality are available.
salt
Xylene 1330-20-7 Did not cause sensitization on laboratory animals (mouse)
Heavy aromatic petroleum 64742-94-5 Patch test on human volunteers did not demonstrate sensitization properties (guinea pig) Did not
naphtha cause sensitization on laboratory animals (similar substances)
Naphthalene 91-20-3 Did not cause sensitization on laboratory animals (guinea pig)

Substances CAS Number Respiratory Sensitization

Light aromatic solvent 64742-95-6 No information available
Isopropanol 67-63-0 No information available
1,2,4 Trimethylbenzene 95-63-6 No information available
Sulfonate salt No information available
Distillates (petroleum), 68477-31-6 No information available
catalytic reformer
fractionator residue,
low-boiling
Organic polymer No information available
Sulfuric acid, di(butylamine) 39085-66-0 No information available
salt
Xylene 1330-20-7 No information available
Heavy aromatic petroleum 64742-94-5 No information available
naphtha

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Naphthalene 91-20-3 No information available

Substances CAS Number Mutagenic Effects

Light aromatic solvent 64742-95-6 Some in vivo tests have shown mutagenic effects. In vitro tests have shown mutagenic effects
Isopropanol 67-63-0 In vitro tests did not show mutagenic effects. In vivo tests did not show mutagenic effects.
1,2,4 Trimethylbenzene 95-63-6 In vivo tests did not show mutagenic effects. In vitro tests did not show mutagenic effects
Sulfonate salt In vivo tests did not show mutagenic effects. (similar substances)
Distillates (petroleum), 68477-31-6 The weight of evidence from available in vitro and in vivo studies indicates that this substance is not
catalytic reformer expected to be mutagenic. (similar substances)
fractionator residue,
low-boiling
Organic polymer While some in vitro tests were positive and/or equivocal, in vivo results were negative. (similar
substances)
Sulfuric acid, di(butylamine) 39085-66-0 In vitro tests did not show mutagenic effects (similar substances)
salt
Xylene 1330-20-7 In vitro tests did not show mutagenic effects In vivo tests did not show mutagenic effects.
Heavy aromatic petroleum 64742-94-5 In vitro tests did not show mutagenic effects In vivo tests did not show mutagenic effects. (similar
naphtha substances)
Naphthalene 91-20-3 In vitro tests did not show mutagenic effects.

Substances CAS Number Carcinogenic Effects

Light aromatic solvent 64742-95-6 Contains a known or suspected carcinogen
Isopropanol 67-63-0 Did not show carcinogenic effects in animal experiments
1,2,4 Trimethylbenzene 95-63-6 No information available
Sulfonate salt No information available
Distillates (petroleum), 68477-31-6 This substance is a potential carcinogen. (similar substances)
catalytic reformer
fractionator residue,
low-boiling
Organic polymer No data of sufficient quality are available.
Sulfuric acid, di(butylamine) 39085-66-0 No data of sufficient quality are available.
salt
Xylene 1330-20-7 Did not show carcinogenic effects in animal experiments
Heavy aromatic petroleum 64742-94-5 Did not show carcinogenic effects in animal experiments (similar substances) Not regarded as
naphtha carcinogenic.
Naphthalene 91-20-3 Substances which should be regarded as if they are carcinogenic to man

Substances CAS Number Reproductive toxicity

Light aromatic solvent 64742-95-6 No data of sufficient quality are available.
Isopropanol 67-63-0 Animal testing did not show any effects on fertility.
1,2,4 Trimethylbenzene 95-63-6 No significant toxicity observed in animal studies at concentration requiring classification. (similar
substances) Adverse developmental effects were only observed at maternally toxic doses.
Sulfonate salt Did not show teratogenic effects in animal experiments. Adverse developmental effects were only
observed at maternally toxic doses. (similar substances)
Distillates (petroleum), 68477-31-6 Did not show teratogenic effects in animal experiments. (similar substances)
catalytic reformer
fractionator residue,
low-boiling
Organic polymer No information available
Sulfuric acid, di(butylamine) 39085-66-0 No data of sufficient quality are available.
salt
Xylene 1330-20-7 Did not show teratogenic effects in animal experiments. Animal testing did not show any effects on
fertility.
Heavy aromatic petroleum 64742-94-5 Animal testing did not show any effects on fertility. Did not show teratogenic effects in animal
naphtha experiments. (similar substances)
Naphthalene 91-20-3 Animal testing did not show any effects on fertility. Did not show teratogenic effects in animal
experiments.

Substances CAS Number STOT - single exposure

Light aromatic solvent 64742-95-6 May cause headache, dizziness, and other central nervous system effects.
Isopropanol 67-63-0 May cause headache, dizziness, and other central nervous system effects.
1,2,4 Trimethylbenzene 95-63-6 May cause respiratory irritation. No information available
Sulfonate salt May cause respiratory irritation.
Distillates (petroleum), 68477-31-6 No significant toxicity observed in animal studies at concentration requiring classification. (similar
catalytic reformer substances)
fractionator residue,
low-boiling

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Organic polymer May cause respiratory irritation. (similar substances)
Sulfuric acid, di(butylamine) 39085-66-0 May cause respiratory irritation. (similar substances) No information available
salt
Xylene 1330-20-7 May cause respiratory irritation.
Heavy aromatic petroleum 64742-94-5 May cause headache, dizziness, and other central nervous system effects.
naphtha
Naphthalene 91-20-3 No data of sufficient quality are available.

Substances CAS Number STOT - repeated exposure

Light aromatic solvent 64742-95-6 No significant toxicity observed in animal studies at concentration requiring classification. (similar
substances)
Isopropanol 67-63-0 No significant toxicity observed in animal studies at concentration requiring classification. (similar
substances)
1,2,4 Trimethylbenzene 95-63-6 Causes damage to organs through prolonged or repeated exposure if inhaled: (Hematopoietic System)
Central Nervous System (CNS) (Central nervous system)
Sulfonate salt No information available No data of sufficient quality are available.
Distillates (petroleum), 68477-31-6 No significant toxicity observed in animal studies at concentration requiring classification. (similar
catalytic reformer substances)
fractionator residue,
low-boiling
Organic polymer No information available
Sulfuric acid, di(butylamine) 39085-66-0 No data of sufficient quality are available.
salt
Xylene 1330-20-7 No significant toxicity observed in animal studies at concentration requiring classification.
Heavy aromatic petroleum 64742-94-5 No significant toxicity observed in animal studies at concentration requiring classification.
naphtha
Naphthalene 91-20-3 No significant toxicity observed in animal studies at concentration requiring classification.

Substances CAS Number Aspiration hazard

Light aromatic solvent 64742-95-6 May be fatal if swallowed and enters airways
Isopropanol 67-63-0 Not applicable
1,2,4 Trimethylbenzene 95-63-6 Risk of serious damage to the lungs (by aspiration) Aspiration can be a hazard if this material is
swallowed.
Sulfonate salt Not applicable
Distillates (petroleum), 68477-31-6 Aspiration into the lungs may cause chemical pneumonitis including coughing, difficulty breathing,
catalytic reformer wheezing, coughing up blood and pneumonia, which can be fatal.
fractionator residue,
low-boiling
Organic polymer Not applicable
Sulfuric acid, di(butylamine) 39085-66-0 Not applicable
salt
Xylene 1330-20-7 Aspiration into the lungs may cause chemical pneumonitis including coughing, difficulty breathing,
wheezing, coughing up blood and pneumonia, which can be fatal.
Heavy aromatic petroleum 64742-94-5 Aspiration into the lungs may cause chemical pneumonitis including coughing, difficulty breathing,
naphtha wheezing, coughing up blood and pneumonia, which can be fatal.
Naphthalene 91-20-3 No information available

12. Ecological Information

12.1. Toxicity
Ecotoxicity effects
Toxic to aquatic life. Toxic to aquatic life with long lasting effects.

Substance Ecotoxicity Data

Substances CAS Number Toxicity to Algae Toxicity to Fish Toxicity to Toxicity to Invertebrates
Microorganisms
Light aromatic solvent 64742-95-6 EL50 (72h) 3.1 mg/L LC50 (96h) 1.03 mg/L No information available EC50 (48h) 1.2 mg/L
(Pseudokirchnerella (Oncorhynchus mykiss) (Daphnia magna)
subcapitata)
Isopropanol 67-63-0 EC50 (72h) > 1000 mg/L LC50 (96h) 9640 mg/L TT (16h) 1050 mg/L EC50 (48h) 13,299 mg/L
(Desmodesmus (Pimephales promelas) (Pseudomonas putida) (Daphnia magna)
subspicatus) LC50 (7d) 7060 mg/L EC50 (24h) > 10,000
EC50 (7d) 1800 mg/L (Poecilia reticulata) mg/L (Daphnia magna)
(Scenedesmus
quadricauda)
1,2,4 95-63-6 No information available LC50 (96 h) 7.72 mg/L No information available LC50 (48 h) 3.6 mg/L

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Trimethylbenzene (Pimephales promelas) (Daphnia magna)
Chronic Value (ChV) (16
d) 0.367 mg/L (Daphnia
sp.)
Sulfonate salt Proprietary EC50 (72 h) 5.6 mg/L LC50 (96 h) 32 mg/L No information available EC50 (48 h) 8.3 mg/L
(Desmodesmus (Lepomis macrochirus) (Ceriodaphnia dubia)
subspicatus) NOAEC (7 d) 3 mg/L
(Ceriodaphnia dubia)
Distillates (petroleum), 68477-31-6 EL50 (72h) 3.1 mg/L LL50 (96h) 4.1 mg/L No information available EL50 (48h) 4.5 mg/L
catalytic reformer (Pseudokirchnerella (Oncorhynchus mykiss (Daphnia magna)(similar
fractionator residue, subcapitata) (similar )(similar substance) substance)
substance) NOEL 0.48 mg/L
low-boiling
(Daphnia magna)(similar
substance)
Organic polymer Proprietary EC50 (72h) > 100 mg/L LC50 (96h) 3.6 mg/L EC50 (3h) 100 mg/L EC50 (48h) 2.8 mg/L
(Pseudokirchnerella (Salmo gairdneri) (similar (Activated sludge) (similar (Daphnia magna)
subcapitata) (similar substance) substance)
substance)
Sulfuric acid, 39085-66-0 EC50 (72 hour) 5.6 mg/L LC50 (96 hours) 32 mg/L No information available EC50 (48 hour) 8.3 mg/L
di(butylamine) salt (Desmodesmus (Lepomis macrochirus) (Ceriodaphnia dubia)
subspicatus) NOAEC (7 Days) 3 mg/L
(Ceriodaphnia dubia)
Xylene 1330-20-7 EC50 (72h) = 4.9 NOEC (56d) > 1.3 mg/L No information available LC50 (24h) =
mg/L(Pseudokirchnerella (Oncorhynchus mykiss) 1mg/L(Daphnia magna)
subcapitata) LC50 (96h) 2.6 mg/L
(Oncorhynchus mykiss)
Heavy aromatic 64742-94-5 EC50 (72h) 7.8 mg/L LL50 (96 h) =3.6 mg/L No information available EL50 (48h) 1.1 mg/L
petroleum naphtha (Pseudokirchneriella (Orcorhynchus mykiss) (Daphnia magna) (similar
subcapitata) LC50 (96 h) =357.7 mg/L substance)
(Scophthalmus maximus)
Naphthalene 91-20-3 EC50 (72 h) =0.4 mg/L LC50 (96 h) =1.6 mg/L IC50 (24 h) =29 mg/L EC50 (48 h) =2.16 mg/L
(Skeletonema costatum) (Oncorhynchus mykiss) (Nitrosomonas sp.) (Daphnia magna)
NOAEC (40 d) =0.37 NOAEC (125 d) =0.59
mg/L (Oncorhynchus mg/L (Daphnia pulex)
kisutch)

12.2. Persistence and degradability

Substances CAS Number Persistence and Degradability

Light aromatic solvent 64742-95-6 (77.05% @ 28d)
Isopropanol 67-63-0 Readily biodegradable (53% @ 5d)
1,2,4 Trimethylbenzene 95-63-6 Readily biodegradable
Sulfonate salt Proprietary No information available
Distillates (petroleum), catalytic reformer 68477-31-6 Readily biodegradable (77.05% @ 28d)
fractionator residue, low-boiling
Organic polymer Proprietary (5% @ 28d)
Sulfuric acid, di(butylamine) salt 39085-66-0 Readily biodegradable (85%% @ 14d) (similar
substances)
Xylene 1330-20-7 Readily biodegradable (87.8% @ 28d)
Heavy aromatic petroleum naphtha 64742-94-5 Readily biodegradable (58% @ 28d)
Naphthalene 91-20-3 Readily biodegradable (100% @ 7d)

12.3. Bioaccumulative potential

Substances CAS Number Log Pow

Light aromatic solvent 64742-95-6 3.20 - 3.63
BCF = 119 - 142
Isopropanol 67-63-0 0.05
1,2,4 Trimethylbenzene 95-63-6 LogPow 3.42
Sulfonate salt Proprietary No information available
Distillates (petroleum), catalytic reformer 68477-31-6 BCF > 3
fractionator residue, low-boiling
Organic polymer Proprietary 2.96
BCF = 31
Sulfuric acid, di(butylamine) salt 39085-66-0 Not expected to bioaccumulate
Xylene 1330-20-7 Log Pow 2.8-3.22.8-3.22.8

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Heavy aromatic petroleum naphtha 64742-94-5 LogPow 5.2
Naphthalene 91-20-3 LogPow 3.3

12.4. Mobility in soil

Substances CAS Number Mobility

Light aromatic solvent 64742-95-6 KOC = 372 - 617
Isopropanol 67-63-0 No information available
1,2,4 Trimethylbenzene 95-63-6 No information available
Sulfonate salt Proprietary No information available
Distillates (petroleum), catalytic reformer fractionator 68477-31-6 No information available
residue, low-boiling
Organic polymer Proprietary KOC = 47.1 (calculated)
Sulfuric acid, di(butylamine) salt 39085-66-0 No information available
Xylene 1330-20-7 KOC = 537
Heavy aromatic petroleum naphtha 64742-94-5 No information available
Naphthalene 91-20-3 No information available

12.5 Other adverse effects

No information available

13. Disposal Considerations

13.1. Waste treatment methods
Disposal methods Disposal should be made in accordance with federal, state, and local regulations.
Contaminated Packaging Follow all applicable national or local regulations.

14. Transport Information

US DOT
UN Number UN1993
UN proper shipping name: Flammable Liquid, N.O.S. (Contains Isopropanol, Aromatic Naphtha)
Transport Hazard Class(es): 3
Packing Group: II
Environmental Hazards: Marine Pollutant
NAERG: NAERG 128

Canadian TDG
UN Number UN1993
UN proper shipping name: Flammable Liquid, N.O.S. (Contains Isopropanol, Aromatic Naphtha)
Transport Hazard Class(es): 3
Packing Group: II
Environmental Hazards: Marine Pollutant
Not approved for transport in Canada

IMDG/IMO
UN Number UN1993
UN proper shipping name: Flammable Liquid, N.O.S. (Contains Isopropanol, Aromatic Naphtha)
Transport Hazard Class(es): 3
Packing Group: II
Environmental Hazards: Marine Pollutant
EMS: EmS F-E, S-E

IATA/ICAO
UN Number UN1993
UN proper shipping name: Flammable Liquid, N.O.S. (Contains Isopropanol, Aromatic Naphtha)
Transport Hazard Class(es): 3

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Packing Group: II
Environmental Hazards: Marine Pollutant

Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable
Special Precautions for User None

15. Regulatory Information

US Regulations
US TSCA Inventory All components listed on inventory or are exempt.

TSCA Significant New Use Rules - S5A2

Substances CAS Number TSCA Significant New Use Rules - S5A2
Light aromatic solvent 64742-95-6 Not applicable
Isopropanol 67-63-0 Not applicable
1,2,4 Trimethylbenzene 95-63-6 Not applicable
Sulfonate salt Proprietary Not applicable
Distillates (petroleum), catalytic reformer fractionator 68477-31-6 Not applicable
residue, low-boiling
Organic polymer Proprietary Not applicable
Sulfuric acid, di(butylamine) salt 39085-66-0 Not applicable
Xylene 1330-20-7 Not applicable
Heavy aromatic petroleum naphtha 64742-94-5 Not applicable
Naphthalene 91-20-3 Not applicable

EPA SARA Title III Extremely Hazardous Substances

Substances CAS Number EPA SARA Title III Extremely Hazardous
Substances
Light aromatic solvent 64742-95-6 Not applicable
Isopropanol 67-63-0 Not applicable
1,2,4 Trimethylbenzene 95-63-6 Not applicable
Sulfonate salt Proprietary Not applicable
Distillates (petroleum), catalytic reformer fractionator 68477-31-6 Not applicable
residue, low-boiling
Organic polymer Proprietary Not applicable
Sulfuric acid, di(butylamine) salt 39085-66-0 Not applicable
Xylene 1330-20-7 Not applicable
Heavy aromatic petroleum naphtha 64742-94-5 Not applicable
Naphthalene 91-20-3 Not applicable

EPA SARA (311,312) Hazard Class

Acute Health Hazard
Chronic Health Hazard
Fire Hazard

EPA SARA (313) Chemicals

Substances CAS Number Toxic Release Inventory (TRI) - Toxic Release Inventory (TRI) -
Group I Group II
Light aromatic solvent 64742-95-6 Not applicable Not applicable
Isopropanol 67-63-0 1.0% Not applicable
1,2,4 Trimethylbenzene 95-63-6 1.0% Not applicable
Sulfonate salt Proprietary Not applicable Not applicable
Distillates (petroleum), catalytic reformer 68477-31-6 Not applicable Not applicable
fractionator residue, low-boiling
Organic polymer Proprietary Not applicable Not applicable
Sulfuric acid, di(butylamine) salt 39085-66-0 Not applicable Not applicable
Xylene 1330-20-7 1.0% Not applicable
Heavy aromatic petroleum naphtha 64742-94-5 Not applicable Not applicable
Naphthalene 91-20-3 0.1% Not applicable

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EPA CERCLA/Superfund Reportable Spill Quantity
Substances CAS Number CERCLA RQ
Light aromatic solvent 64742-95-6 Not applicable
Isopropanol 67-63-0 Not applicable
1,2,4 Trimethylbenzene 95-63-6 Not applicable
Sulfonate salt Proprietary Not applicable
Distillates (petroleum), catalytic reformer fractionator 68477-31-6 Not applicable
residue, low-boiling
Organic polymer Proprietary Not applicable
Sulfuric acid, di(butylamine) salt 39085-66-0 Not applicable
Xylene 1330-20-7 100 lb
45.4 kg
Heavy aromatic petroleum naphtha 64742-94-5 Not applicable
Naphthalene 91-20-3 100 lb
45.4 kg
1 lb
0.454 kg

EPA RCRA Hazardous Waste Classification

If product becomes a waste, it does meet the criteria of a hazardous waste as defined by the US EPA, because of:

Ignitability D001
Corrosivity D002

California Proposition 65
Substances CAS Number California Proposition 65
Light aromatic solvent 64742-95-6 Not applicable
Isopropanol 67-63-0 Not applicable
1,2,4 Trimethylbenzene 95-63-6 Not applicable
Sulfonate salt Proprietary Not applicable
Distillates (petroleum), catalytic reformer fractionator 68477-31-6 Not applicable
residue, low-boiling
Organic polymer Proprietary Not applicable
Sulfuric acid, di(butylamine) salt 39085-66-0 Not applicable
Xylene 1330-20-7 Not applicable
Heavy aromatic petroleum naphtha 64742-94-5 Not applicable
Naphthalene 91-20-3 carcinogen

U.S. State Right-to-Know Regulations

Substances CAS Number MA Right-to-Know Law NJ Right-to-Know Law PA Right-to-Know Law
Light aromatic solvent 64742-95-6 Not applicable Not applicable Not applicable
Isopropanol 67-63-0 Present 1076 Environmental hazard
1,2,4 Trimethylbenzene 95-63-6 Present 2716 Environmental hazard
Sulfonate salt Proprietary Not applicable Not applicable Not applicable
Distillates (petroleum), catalytic 68477-31-6 Not applicable Not applicable Not applicable
reformer fractionator residue,
low-boiling
Organic polymer Proprietary Not applicable Not applicable Not applicable
Sulfuric acid, di(butylamine) salt 39085-66-0 Not applicable Not applicable Not applicable
Xylene 1330-20-7 Present 2014 Environmental hazard
Heavy aromatic petroleum naphtha 64742-94-5 Not applicable Not applicable Not applicable
Naphthalene 91-20-3 Present 1322 Environmental hazard

NFPA Ratings: Health 2, Flammability 3, Reactivity 0

HMIS Ratings: Health 2, Flammability 3, Physical Hazard 0 , PPE: H

Canadian Regulations
Canadian Domestic Substances All components listed on inventory or are exempt.
List (DSL)

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16. Other information

Preparation Information
Prepared By Chemical Stewardship
Telephone: 1-281-871-6107
e-mail: [email protected]

Revision Date: 11-Apr-2017

Reason for Revision SDS sections updated:

2

Additional information
For additional information on the use of this product, contact your local Halliburton representative.

For questions about the Safety Data Sheet for this or other Halliburton products, contact Chemical Stewardship at
1-580-251-4335.

Key or legend to abbreviations and acronyms used in the safety data sheet
bw–bodywei ght
CAS–Chemi calAbst ractsSer vi
ce
d - day
EC50–Ef fectiveConcent ration50%
ErC50–Ef fectiveConcent rationgrowt
hrate50%
h - hour
LC50–Let halConcent r
ati
on50%
LD50–Let halDose50%
LL50–Let halLoadi ng50%
mg/ kg–mi lli
gram/ kilogram
mg/ L–mi ll
igram/ li
ter
mg/m3 - milligram/cubic meter
mm - millimeter
mmHg - millimeter mercury
NIOSH–Nat i
onalI nstitut
ef orOccupationalSaf
etyandHeal
th
NTP–Nat i
onalTox i
cologyPr ogram
OEL–Occupat ionalEx posur eLimit
PEL–Per mi ssibleEx posur eLi mit
ppm –par tspermi l
li
on
STEL–Shor tTer m Ex posur eLi mit
TWA–Ti me- Wei ghtedAver age
UN–Uni tedNat ions
w/w - weight/weight

Key literature references and sources for data

www.ChemADVISOR.com/

Disclaimer Statement
This information is furnished without warranty, expressed or implied, as to accuracy or completeness. The
information is obtained from various sources including the manufacturer and other third party sources. The
information may not be valid under all conditions nor if this material is used in combination with other materials or in
any process. Final determination of suitability of any material is the sole responsibility of the user.

End of Safety Data Sheet

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