S H A N: Acids, Bases and Salts
S H A N: Acids, Bases and Salts
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taste. Soluble bases have a corrosive action on 15. On the pH scale, the concentration of H+(aq)
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the skin and can cause severe burns. ions is measured from 0 to 14. Zero (0) is for
3. Aqueous solutions of acids and bases are good highly acidic solution and 14 is for highly
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conductors of electricity. alkaline solution.
4. An acid is a compound, which on dissolving in 16. pH of distilled water and neutral salt solution
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water gives hydronium ions or H+(aq) ions as is 7.
the only positively charged ions. 17. If the pH of a solution is less than 7, then it is an
acidic solution. When the pH of a solution
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5. An alkali is a compound, which on dissolving
in water gives hydroxyl or OH– (aq) ions as the decreases from 7 to 0, the concentration of
only negatively charged ions. H+(aq) ions in it goes on increasing and so does
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the acidic character of the solution.
6. An oxide or a hydroxide of a metal which reacts
with acids to form salt and water as the only 18. If the pH of a solution increases from 7 to 14,
the concentration of H+(aq) ions decreases and
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13. Dilution of an acid/ alkali, lowers the 21. Acid-base indicators are organic dyes derived
concentration of H+(aq)/OH–(aq) ions per unit from plant materials which shows the presence
volume. of acids and bases.
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22. Litmus is a natural indicator, extracted from a 36. Substances which react with acids to form salt
plant, belonging to the thallophyta family. and water as the only products are called basic
23. The dyes from the plants, such as red cabbage substances. Thus, oxides and hydroxides of
leaves, coloured petals of plants such as metals are bases.
Petunia, and Turmeric are other natural 37. A chemical reaction in which an acid reacts
indicators. completely with a base to form salt and water as
24. Phenolphthalein and methyl orange are the only products, is called a neutralisation
synthetic indicators which show the presence of reaction.
acids and bases. 38. All oxides of metals are insoluble in water.
25. Blue litmus solution turns red in acidic 39. All hydroxides of metals are insoluble in water,
solutions, but is not affected in basic solutions. except the hydroxides of sodium, potassium,
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26. Red litmus solution turns blue in basic calcium and magnesium.
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solutions, but is not affected in acidic solutions. 40. Soluble hydroxides of metals are called
27. Phenolphthalein solution turns pink in basic alkalises.
41. An acid solution which produces more H+(aq)
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solutions, but turns colourless in acidic
solutions. ions for an aqueous solution of 1 molar
concentration is called a strong acid.
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28. Methyl orange solution is yellow in basic
solutions and pink in acidic solutions. 42. An acid which produces few H+(aq) ions for an
aqueous solution of 1 molar concentration is
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29. Turmeric solution turns brown in basic
called a weak acid.
solutions, but remains yellow in acidic
solutions. 43. Sulphuric acid, hydrochloric acid, nitric acid
and phosphoric acid are the examples of
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30. The substance whose smell changes in acidic or
strong acids.
basic medium are called olfactory indicators.
44. Carbonic acid, sulphurous acid, acetic acid,
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dioxide gas.
called a weak alkali.
Metal carbonate + Acid ⎯→ Metal salt + Water
Calcium hydroxide, magnesium hydroxide and
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50. The salts formed by the action of strong acids NaCl(s) + H2 O (l) + NH3(g) + CO2(g)
with strong bases, are called normal salts.
51. The salts formed by the action of strong acids NH4Cl(aq) + NaHCO3(s)
and weak bases are called acid salts. 61. Baking soda is used : (i) in making baking
52. The salts formed by the action of weak acids powder (ii) as a constituent of antacids and (iii)
and strong alkalises are called basic salts. in fire extinguishers.
53. Common salt is the most important and most 62. Soda ash (anhydrous sodium carbonate) is
abundant salt in nature. In addition to its use as prepared by strongly heating baking soda.
an edible salt it is also a raw material for
2NaHCO3(s) Na2CO3(s)+H2O(l)+ CO2(s)
producing chemicals, such as chlorine,
hydrogen, sodium and hydrochloric acid. 63. Washing soda (hydrated sodium carbonate) is
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54. When saturated common salt is electrolysed, the prepared by dissolving soda ash in water and
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products are sodium hydroxide, hydrogen and then crystallising it.
chlorine gas. Na2CO3(s) + 10H2O(l) Na2CO3.10H2O.
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55. Hydrogen gas is used in (i) oxy-hydrogen
64. Washing soda and soda ash is used (i) in
flame (ii) hydrogenating vegetable oils,
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softening of hard water (ii) in the manufacture
(iii) manufacture of ammonia and hydrochloric
of glass and dry soaps (iii) as a common
acid, (iv) as a rocket fuel.
cleansing agent in the household (iv) in the
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56. Chlorine gas is used in : (i) disinfecting water manufacture of caustic soda, boron and sodium
(ii) in the manufacture of bleaching powder, phosphate.
hydrochloric acid and pesticides (iii) in
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bleaching wood pulp and cotton fabrics (iv) in 65. The fixed number of water molecules, which
the manufacture of polyvinyl chloride and are in loose combination with one molecule of a
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hypochlorite. heat 1
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CaSO4.2H2O(s) CaSO4. H O
58. Bleaching powder is prepared by passing 100 C 2 2 (s)
chlorine gas through freshly prepared slaked
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lime paste, till it stops reacting. + H O
2 2 (g)
59. Bleaching powder is used : (i) for bleaching
cotton-fabrics and wood pulp (ii) making 67. Plaster of Paris reacts with water to give a hard
unshrinkable wool (iii) in the manufacture of mass called gypsum.
chloroform (iv) in sterilisation of drinking (CaSO4)2.H2O(s) + 3H2O(l) 2CaSO4.
water, and (v) in disinfecting laboratories, 2H2O(s)
drains, ditches, etc. 68. Plaster of Paris is used : (i) for keeping
60. Baking soda is prepared industrially from fractured bones in position (ii) in making
common salt, by passing carbon dioxide gas decorative toys and panelling ceilings (iii) in
through saturated ammonical common salt making fire proof materials and (iv) in making
solution. blackboard chalk.
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I. VERY SHORT ANSWER QUESTIONS (1 Mark)
A. IMPORTANT QUESTIONS
1. Blue and red litmus papers are placed 5. Name an alkali solution which has no metallic
simultaneously in a colourless aqueous solution. ion.
It is found that the colour of both litmus papers is 6. What is the pH of a neutral solution?
red. What is the nature of the solution and why? 7. What is a universal indicator?
2. A strip of absolutely clear cloth is sprayed with 8. What do you understand by the term salt?
onion juice. The strip is then rubbed with
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9. Write fully balanced equation when carbon
few drops of hydrochloric acid. Will the strip
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dioxide is passed through ammonical brine
smell like onion? Give a reason for your answer.
solution.
[HOTS]
10. Name a carbonate of a metal which has cleansing
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3. Name two metals which react with concentrated
properties.
sodium hydroxide solution to liberate hydrogen
gas. 11. Name the chemical which is used as a
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4. Write the general word equation for reaction preservative in pickles and curing fish.
between acids and bases.
4. Write the name and chemical formula of the 15. What effect does an increase in concentration of
H+ (aq) in a solution have on the pH of the
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5. Which one is a stronger acid, with pH = 5 or with 16. Name the gas usually liberated when a dilute
pH = 2? [2010 (T-I)] acid reacts with a metal. What happens when a
burning candle is brought near this gas? [2009]
6. A compound which is prepared from gypsum has
the property of hardening when mixed with 17. Name the gas evolved when dilute HCl reacts
proper quantity of water. Identify the compound with sodium hydrogen carbonate. How is it
and write its chemical formula. [2010 (T-I)] recognised? [2008]
18. How will you test for a gas which is liberated
7. Name the acid present in ant sting. [2010 (T-I)]
when hydrochloric acid reacts with an active
8. Name a salt which does not contain water of metal? [2008]
crystallisation. [2010 (T-I)]
19. On adding dilute hydrochloric acid to copper
9. Why is it advised not to use copper or brass oxide powder, the solution formed is
vessels to store pickles or curd? [2010 (T-I)] blue-green. Predict the new compound formed
10. What happens when water is added to quick which imparts blue-green colour to the solution.
lime? [2010 (T-I)] [2008]
4
20. How does the flow of acid rain into a river make 26. Write chemical equations to show the reactions
the survival of aquatic life in the river difficult? taking place when a glass rod dipped in
[2008] concentrated hydrochloric acid is introduced in a
21. How is the pH of a solution of an acid influenced jar containing ammonia gas. [2004]
when it is diluted? [2008] 27. Write the name and the chemical formula of the
22. How does the pH of the solution change when a organic acid present in vinegar. [2004]
solution of a base is diluted? [2008] 28. Write balanced chemical equation for the
23. What is the role of acid in our stomach? [2008] reaction taking place when dry blue crystals of
24. Choose strong acid and strong base from the copper sulphate are dropped into concentrated
following: [2008] sulphuric acid. [2004]
25. Dry ammonia gas has no action on litmus paper, 29. Which will be more acidic and why?
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but a solution of ammonia in water turns red (i) A solution with pH value of 6.0 or
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litmus paper blue. Why is it so? [2005] (ii) A solution with pH vlaue of 5.0. [2004]
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II. SHORT ANSWER QUESTIONS–I (2 Marks)
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A. IMPORTANT QUESTIONS
1. Why are all alkalis bases, but not all bases 8. Why does a bee sting cause pain and itching?
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alkalises? What is the common remedy to overcome such a
pain?
2. Why does nitric acid not produce hydrogen,
when treated with metals? 9. Do basic solutions also have H+(aq) ions? If yes,
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3. Metal hydroxides and metal oxides are called then why are these basic?
bases. Explain and support your answer by 10. Two solutions R and Q are tested with universal
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correct sources given in Column (B). [HOTS] more acidic; (ii) has more pH.
11. Name the acid present in ant sting and give its
Column A Column B
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(c) Citric acid (iii) Vinegar 12. How would you distinguish between baking
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(d) Oxalic acid (iv) Curd powder and washing soda by heating? [HOTS]
13. A sulphate salt of Group 2 element of the
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3. Classify the following salts into acidic, basic and which has detergent properties. Identify A, B and
neutral. C and also write balanced chemical equations for
Potassium sulphate, ammonium chloride, the conversions of A to B. [2010 (T-I)]
sodium carbonate, sodium chloride. [2010 (T-I)] 13. What are the three products of ‘Chlor-alkali
4. For making cake, baking powder is taken. If at process’? Write one commercially or industrially
home your mother uses baking soda instead of important material each that can be prepared
baking powder in cake. from each of these products? [2010 (T-I)]
(a) How will it affect the taste of the cake and 14. When a drop of orange juice is added to pure
why? water, how the pH value vary for water? If a drop
of lemon juice is also added, will there be any
(b) How can baking soda be converted into
more change in the pH value? [2010 (T-I)]
baking powder? [2010 (T-I)]
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15. Fresh milk has a pH of 6. How do you think the
5. In one of the industrial processes used for
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pH will change as it turns in to curd? Explain?
manufacture of sodium hydroxide, a gas X is
formed as by product. The gas X reacts with dry [2010 (T-I)]
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slaked lime to give a compound Y which is used 16. A milkman added a small amount of baking soda
as a bleaching agent in chemical industry. of fresh milk.
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Identify X and Y. [2010 (T-I)] (a) Why does he shifted the pH of fresh milk
6. How washing soda is prepared from baking soda. to slightly alkaline?
Write balanced chemical equation. Give two
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(b) Why does this milk take a longer time to
uses of washing soda. [2010 (T-I)] set as a curd? [2010 (T-I)]
7. What is amphoteric oxides? Give two examples 17. HCl and HNO 3 show acidic characters in
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of amphoteric oxide with balanced chemical aqueous solution while alcohol and glucose
equation. [2010 (T-I)] solution do not. Give reasons. [2010 (T-I)]
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8. Name two salts that are used in black and white 18. Write the chemical formula for bleaching
photography. Give reactions when they are powder. How is bleaching powder prepared? For
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exposed to light. [2010 (T-I)] what purpose is it used in paper factories? [2009]
9. While constructing a house, a builder selects 19. Write the name and chemical formula of the
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marble flooring and marble table tops for the calcium compound used for disinfecting
kitchen where vinegar and juices of lemon, drinking water. How is this compound
tamarind, etc. are more often used for cooking. manufactured? [2009]
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Will you agree to this selection and why? 20. A compound which is prepared from gypsum has
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immediately dipped into water containing drops Write the chemical equation for its preparation.
of blue litmus solution. If the colour of the For what purpose is it used in hospitals? [2009]
solution is changed to red, what inference can be 21. Describe an activity to show that acids produce
drawn about the nature of the fruit and why? ions only in aqueous solutions. [2008]
[2010 (T-I)] 22. What is ‘Baking Powder’? How does it make
cakes soft and spongy? [2008]
11. A person is suffering from indigestion due to the
intake of hot spicy food. What remedy you will 23. How is Plaster of Paris obtained? What reaction
prescribe to the patient? Give the name of a is involved in the setting of a paste of Plaster of
chemical that can give relief to him. [2010 (T-I)] Paris? [2007]
12. A white powder A is a mild non corrosive base 24. (i) An aqueous solution has a pH value of 7.0. Is
and is used in the preparation of cakes. When the this solution acidic, basic or neutral?
powder is heated it gives another powder B. The (ii) Which has a higher pH value, 1 M HCl or 1 M
powder B is re-crystallised to get a substance C NaOH solution? [2006]
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25. Given below are the pH values of four different left open in dry air? What is this change named
liquids: 7.0, 14.0, 4.0, 2.0. as? Name two industries based on the use of
Which of these could be that of washing soda. [2005]
(i) lemon juice 30. How is Plaster of Paris chemically different from
(ii) distilled water gypsum? How may they be interconverted?
(iii) 1 m sodium hydroxide solution Write one use of Plaster of Paris.
(iv) tomato juice [2006]
[2005, 2010 (T-I)]
26. A calcium compound which is a yellowish white
31. State the chemical property in each case on
powder is used as a disinfectant and also in the
which the following uses of baking soda are
textile industry. Name the compound. Which gas
based : (i) as an antacid. (ii) as a constituent of
is released when this compound is left exposed
baking powder. [2004]
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to air? [2006]
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32. How is chloride of lime chemically different
27. Name the gas evolved when dilute sulphuric acid from calcium chloride? Why does the chloride of
acts on sodium carbonate. Write the chemical lime gradually lose its chlorine when kept
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equation for the reaction involved. [2005] exposed to air? [2004]
28. “Sulphuric acid is a dibasic acid.” Write two 33. What is meant by the term ‘pH of a solution’?
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reaction equations to justify this statement and The pH of gastric juices extracted from the
name the reaction products in the two cases. stomach of two persons A and B were found to be
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[2005] 1 and 3 respectively. The stomach juice of which
29. What happens when crystals of washing soda are person is more acidic? [2004]
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A. IMPORTANT QUESTIONS
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1. What will you observe when a spoonful of black (iii) Why is effervescence produced during
copper oxide is placed in a beaker containing the chemical reaction?
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warm and dilute sulphuric acid? Write a 4. Describe your observations and explain by
balanced equation in support of your answer and writing chemical equations, when carbon
state the nature of copper (II) oxide in this dioxide gas is passed through limewater : (a) for
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2. In a test tube containing 4 ml of sodium 5. Identify the compound X on the basis of the
hydroxide solution two drops of phenolphthalein reactions given below. Also, write the name and
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and then hydrochloric acid is added drop by chemical formulae of A, B and C. [HOTS]
drop. State your observations and state the kind
of reaction taking place. + Zn A + H2(g)
Compound + HCl
3. A sodium salt is placed in a dry test tube. To this X B + H 2O
salt is added 5 ml of hydrochloric acid. Then a lot + CH3COOH
C + H2O
of effervescence takes place with the liberations
of a colourless gas. The gas on passing through a 6. A metal carbonate X on reacting with an acid
colourless solution, turns it milky. Answer the gives a gas which when passed through a
following questions. solution Y gives the carbonate back. On the other
(i) Which gas is produced during the hand, a gas (G) that is obtained at the anode
chemical reaction? during electrolysis of brine is passed on dry Y, it
(ii) What is the colourless solution and why gives a compound Z, used for disinfecting
does it turn milky? drinking water. Identify X, Y, G and Z. [HOTS]
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B. QUESTIONS FROM CBSE EXAMINATION PAPERS
1. Five solutions A, B, C, D and E when tested with 4. Your are given two solutions A & B. The pH of
universal indicator showed pH as 4, 1,11,7 and 9 solution A is 6 and pH of solution B is 8
respectively. Which solution is (a) neutral (b) (a) Which solution is acidic and which is basic?
strongly alkaline (c) strongly acidic (d) weakly
(b) Which solution has more H + ion
acidic (e) weakly alkaline.
concentration?
Arrange the pH in increasing order H-ion (c) Why is HCl a stronger acid than acetic acid?
concentration. [2010 (T-I)]
[2010 (T-I)]
2. What happens when chlorine is passed over dry 5. (a) An element ‘X’ on reacting with oxygen
slaked time? Write chemical equation of the forms an oxide X2O. The oxide dissolves in
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reaction involved. Mention three properties of water and turns blue litmus red. Predict the
the product.
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[2010 (T-I)]
nature of the element whether metal or non-
3. (i) What do you understand by the term metal?
hydrated salt?
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(b) A solution of copper sulphate was kept in an
(ii) Give two examples of hydrated salt which iron pot. After few days, the pot developed
are white and state their chemical formula.
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some holes in it. How will you account
[2010 (T-I)] for this.
7. A student prepared solutions of (i) an acid and (ii) solution respectively. If you are given only red
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a base in two separate beakers. She forgot to litmus paper, how will you identify the contents
label the solutions and litmus paper is not of each test tube? [2010 (T-I)]
available in the laboratory. Since both the
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15. What is observed when
(ii) Select the strong electrolytes from amongst
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(i) dilute sulphuric acid is added to solid
sodium carbonate? the following:
(ii) hot concentrated sulphuric acid is added to molten NaCl, glacial CH3 COOH, strong
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sulphur? NH4OH solution, dil. HCl. [2006]
(iii) sulphur dioxide is passed through lime 20. Identify the compound of calcium which is
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water? [2007] yellowish white powder and is used for
Also write chemical equations to represent the disinfecting drinking water. How is it
chemical reactions taking place in each case. manufactured? Write the chemical equation for
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16. (i) Name the raw materials used in the the reaction involved. What happens when it is
manufacture of sodium carbonate by Solvay left exposed to air? [2005]
process.
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21. A compound X of sodium forms a white powder.
(ii) How is the sodium hydrogen carbonate It is a constituent of baking powder and is used in
formed during Solvay process separated some antacid prescriptions. When heated, X
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from a mixture of NH4Cl and NaHCO3? gives out a gas and steam. The gas forms a white
(iii) How is sodium carbonate obtained from precipitate with limewater. Write the chemical
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sodium hydrogen carbonate? [2007] formula and name of X and the chemical
equation for its decomposition on heating. What
17. What are the salts among chemical substances? is its role in baking powder and in antacids?
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A. IMPORTANT QUESTIONS
1. (i) What do you understand by the term
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AS
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(a) In place of zinc granules, same amount of zinc dust is taken in the test tube.
(b) Instead of dilute sulphuric acid, dilute hydrochloric acid is taken.
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(a) Dry HCl gas does not change the colour recommnended that the acid should be
of dry blue litmus paper. added to water and not water to acid.
(b) Antacid tablets are used by a person (iii) A dry pellet of a common base ‘B’ when
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suffering from stomach pain. kept in open absorbs moisture and turns
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(c) Toothpaste is used for cleaning teeth. sticky. The compound is also formed by
[2010 (T-I)] Chloralkals process. Identify B. What
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the cotton thread, such that a part of it is
4. Now pour 4 drops of indicator in each of the above the baking soda solution.
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test tubes and shake well. You will observe :
6. Fix the lid on the jar. The lid will hold the
(i) In case of vinegar and lemon solution
cotton thread. Now, your working model of
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the colour changes to red, thereby
the fire extinguisher is ready.
showing the presence of acid.
(ii) In case of soap solution and washing 7. In order to use it, lift the lid for a moment.
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soda solution, which a re wea k The glass bottle will fall in the baking soda
alkalises, the colour changes to blue. solution. As the vinegar mixes with baking
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(iii) In case of caustic soda solution, which soda solution, it produces carbon dioxide
is a strong alkali, the colour changes gas, which forces out the contents of the
to green. bottle.
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2. Objective
B. Experiments
To prepare a soda acid fire extinguisher.
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Materials Required
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apparatus thoroughly, first with tap water and
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then with distilled water. Repeat the activity from
liquid (ii) to liquid (xii). Record your
2. Tie the ends of two connecting wires to the observations in the observation table.
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copper nails tightly.
7. On the basis of the observation table make a list
3. Place the cork in the 250 ml beaker. of (i) strong electrolytes (ii) weak electrolytes,
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4. Connect the other ends of the connecting wires (ii) non-electrolytes.
Observation Table
VI. Limewater
IX. Alcohol
X Ether
Precautions
1. After carrying out the activity with one liquid the apparatus with a clean towel or hot air
always wash the beaker and the cork with tap blower.
water and then with distilled water. Finally, dry 2. Once the activity is over, switch off the current.
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3. The copper nails must be partially dipped in the 7. Wait for few minutes. Take out each strip of cloth
liquid while performing the experiment. and check for the colour and stain.
Group Discussions 8. Record your observations in the observation
1. Discuss, why some liquids allow the current to table.
flow through them conveniently. What is nature S.No. Colour of cotton Colour of cotton
of these liquids? cloth dipped in cloth after treating
2. Discuss, why some liquids allow less current to sample chemical sample solution
flow through them? What is the nature of these with H2SO4
liquids? How does this nature differ from the
1. Sample A
nature of the compounds in Q. 1?
2. Sample B
3. Discuss, why some liquids not allow the current
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to flow through them? What is the nature of these 3. Sample C
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liquids. 4. Sample D
4. Discuss in which direction the cations and anions
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move in strong electrolytes or weak electrolytes? The chemical is bleaching powder in the beaker,
where the colour of flower petals is bleached.
5. Discuss what happens to cations and anions on
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reaching their respective electrodes and why? Bleaching powder reacts with dilute sulphuric acid to
liberate chlorine gas. The chlorine gas reacts with
2.Objective water to form nascent oxygen, which in turn bleaches
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To identify bleaching powder, among the given the colour of flowers.
sample of chemicals. CaOCl2(s) + H2SO4 (aq) → CaSO4(s) H2O(l) + Cl2
Cl2 + H2O → 2HCl + [O]
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Materials Required
Four samples of chemicals: (i) ammonium chloride,
(ii) sodium chloride, (iii) potassium chloride, Group Discussions
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(iv) bleaching powder, four beakers of 100 ml, conc. 1. Why does the stained cloth get bleached with
sulphuric acid, a dropper, a glass stirrer, white cotton bleaching powder? Discuss in detail.
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cloth strip (10 cm × 2 cm), petals of coloured flower. 2. Is it possible to bleach artificial dyes with
bleaching powder? Discuss in detail.
Procedure
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permanent in nature?
the flowers. Cut the strip into four equal pieces.
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with a glass tubing but at an angle of 120°, iron stand, 4. The dehydration reaction of copper sulphate
ordinary glass tube, a trough containing cold water, a crystals is given below.
bunsen burner and 10 g of copper sulphate crystals.
CuSO4.5H2O ⎯⎯⎯
100°C
→ CuSO4.H2O ⎯⎯⎯
250°C
→
Procedure CuSO4
1. Fill 1/3 of the hard glass test tube with copper
sulphate crystals. Clamp the test tube in an iron What is the colour of CuSO4.H2O?
stand. In the mouth of the test tube fit a delivery C. Classroom Discussions
tube whose other end goes into another test tube
placed in cold water. Discuss the importance of pH in:
1. Our digestive system
2. Heat the crystals of copper sulphate strongly.
You will notice : 2. Mouth and tooth decay
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3. Dairy industry
(i) The crystals give out stream of fumes. The
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fumes move to the test tube placed in water 4. Breweries
and condense to form a colourless liquid. 5. Fruit processing plants
6. Meat processing plants
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(ii) The crystals lose their blue colour and
change to a white powder. 7. In agriculture
8. Diagnostic purposes
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3. Allow the apparatus to cool. Remove the test
tube containing anhydrous copper sulphate. Add 9. Cosmetic industry
a few drops of water to the anhydrous copper
sulphate. You will notice that copper sulphate
regains its colour. PR
D. Research
Find out how large number of animals and plants save
themselves by chemical warfare.
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Thus, the activity proves that hydrated copper
sulphate contains water. E. Charts
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1. Why does copper sulphate lose its blue colour on 2. Make a chart showing :
strong heating? (i) Four strong inorganic acids
2. Discuss how the presence of water molecules in (ii) Four weak inorganic acids
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contain water of crystallisation and write their which can be obtained from common salt and
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