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THE REPORT OF

CRITICAL JOURNAL REVIEW

REVIEWER’S IDENTITY
Reviewer’s Name Aliyah Rumini Larasati
Class Mathematics Education Study Program (MESP) 2019
JOURNAL’S IDENTITY
Journal Theme Calculations of Freezing Point Depression, Boiling Point Elevation, Vapor
Pressure and Enthalpies of Vaporization of Electrolyte Solutions by a
Modified Three-Characteristic Parameter Correlation Model
Author’s Name 1. Xinle Ge
2. Xidong Wang
Publication Year 2009
Journal Name J Solution Chem
Pages 1097-1117
Publication Place Springer
DOI 10.1007/s10953-009-9433-0
JOURNAL ANALYSIS
Background The problem raised by the author is a method was proposed for calculating
the thermodynamic properties, freezing point depression, boiling point
elevation, vapor pressure and enthalpy of vaporization for single solute
electrolyte solutions, including aqueous and nonaqueous solutions, based on
a modified three-characteristic-parameter correlation model. When compared
with the corresponding literature values, the calculated results show that this
method gives a very good approximation, especially for 1-1 electrolytes.
Although the method is not very suitable for some solutions with very high
ionic strength, it is still a very useful technique when experimental data is
scarce.
Aim The aim of this journal is to demonstrate a newmethod to calculate these
properties for electrolyte solutions, including both aqueous and nonaqueous
solutions, based on this model without introducing any additional
parameters. And the aim is clearly stated in this journal.
Study of Literature The authors define the terms so well and so specifically and making readers
easily understand the terms. But the authors didn’t include footnotes to the
terms but only write citations on the terms.
Experimental Method The sample for this research is high and low concentrated electrolyte
solutions but in the calculation of this thermodynamic formula only low
concentrated solutions can use the formula.
Results and Discussion The authors use tables that are equipped with text to make it easier for
readers to understand the contacts of the journal.
The way of the authors conveying data is also good using good methodsin
presenting the data.
Conclusions and The conclusion of the authors is a new method for calculating the freezing
Suggestions point depression, boiling point elevation, vapor pressure and enthalpies of
vaporization of aqueous and nonaqueous electrolyte solutions is proposed,
based on the modified three-characteristic-parameter correlation model. The
calculation only needs the thermodynamic constants for the pure solvent
and adjustable parameters reported in the literature. This method was used
for calculation of 37 freezing point depressions, 50 boiling point elevations
(44 electrolytes in water and 6 electrolytes in methanol), 60 vapor pressures
(25 electrolytes in aqueous solutions and 35 electrolytes in nonaqueous
solutions), and 38 enthalpies of vaporization. The calculated results are
acceptable, especially for 1-1 type electrolytes or solutions in a concentration
range that is not very high. A very good performance is found for vapor
pressure calculations.
The present model is not suitable for solutions at very high concentrations,
due to the incomplete dissociation of electrolyte molecules or the association
of ions. This model also cannot fully describe some asymmetric electrolytes,
and calculations for concentrations far beyond the maximum applicable
range of the characteristic parameters can easily result in large deviations.
Outside of this shortcoming, this method can be considered to provide
a good first approximation for the calculation of freezing point depression,
boiling point elevation, vapor pressure and enthalpies of vaporization, at
least for the strong electrolytes or solutions within the applicable
concentration range of the characteristic parameters.
References  References cited by the authors amounted to 73
 Sized references section 8
 The references are important and are used asa a support or a rebuttal in
writing the journal
 The references used by the authors
1. On the molecular depression of the freezing-point of water produced
by some very concentrated saline solutions (1904)
2. The measurement of the freezing-point depression of dilute solutions
(1914)
3. The free energy of dilution and the freezing-point lowering in
solutions of some salts of various types of ionization, and of salt
mixtures (1916)
4. The Freezing points of concentrated solutions and the free energy of
solution of salts (1918)
5. The freezing point and activity coefficient of aqueous barium nitrate,
sodium sulfate and sulfuric acid (1927)
6. The boiling-points of aqueous solutions (1929)
7. The activity coefficient of potassium chloride in aqueous solution
from boiling
point data (1932)
8. The boiling point elevation. II. Sodium chloride 0.05 to 1.0 M and 60
°C to 100 °C.l (1939)
9. The boiling point elevation. IV. Potassium bromide in water (1941)
10. Thermodynamic properties of aqueous salt solutions. Latent heats of
va-
11. porization and other properties by the gas current method (1944)
12. Vapor pressure tables for water (1964)
13. Thermodynamic properties of organic oxygen compounds. XXV. Va-
14. por pressures and normal boiling temperatures of aliphatic alcohols
(1970)
15. Vapor pressure of D2O from 106 to 300 °C (1970)
16. A re-examination of the vapor pressure of aqueous sodium chloride
solutions at 25 °C (1972)
17. Thermodynamic properties of strong electrolytes in aqueous
solutions (1973)
18. Thermodynamics of electrolytes. I. Theoretical basis and general
equations (1973)
19. Thermodynamics and Its Applications (1974)
20. Cryoscopy of uranyl nitrate solutions and activity coefficients (1977)
21. Salt effect on the vapor pressure of pure solvents: methanol with
seven salts; at 24.9 °C (1979)
22. Thermodynamics of electrolytes. 12. Dielectric properties of water
and Debye-Hückel parameters to 350 °C and 1 kbar (1979)
23. Local composition model for excess Gibbs energy of electrolyte
systems (1982)
24. Osmotic and activity coefficients of sodium hydroxide in water from
150 to 250 °C (1984)
25. Vapor pressure of non-aqueous electrolyte solutions. Part 1. Alkali
metal salts in methanol (1985)
26. Vapor pressure of non-aqueous electrolyte solutions. Part 3.
Solutions of sodium iodide in ethanol, 2-propanol, and acetonitrile
(1986)
27. Vapor pressure measurements on non-aqueous electrolyte so-
28. lutions. Part 2. Tetraalkylammonium salts in methanol, activity
coefficients of various 1-1 electrolytes at high concentrations (1986)
29. A local composition model for excess Gibbs energy of electrolyte
systems (1986)
30. Vapor pressure and osmotic coefficients: electrolyte solutions of
methanol (1987)
31. The prediction of mineral solubilities in natural waters: a chemical
equilibrium model for the Na-Ca-Cl-SO4−H2O system, to high
temperature and concentration (1988)
32. Equation of state for small, large, poly disperse, and associating
molecules (1990)
33. Thermodynamic properties of aqueous electrolyte solutions. 1. Vapor
pressure of aqueous solutions of LiCl, LiBr, and LiI (1990)
34. The prediction of mineral solubilities in natural waters: a chemical
equilibrium model for the Na-K-Ca-Mg-Cl-SO4−H2O system at
temperatures below 25 °C (1990)
35. Thermodynamic properties of aqueous electrolyte solutions. 2. Vapor
pressure of aqueous solutions of NaBr, NaI, KCl, KBr, KI, RbCl,
CsCl, CsBr, CsI, MgCl2, CaCl2, CaBr2, CaI2, SrCl2, SrBr2, SrI2,
BaCl2, and BaBr2 (1991)
36. The vapour pressures of water over saturated aqueous solutions of
barium chloride, magnesium nitrate, calcium nitrate, potassium
carbonate, and zinc sulfate, at temperatures from 283 K to 313 K
(1992)
37. The vapour pressures of saturated aqueous solutions of potassium
bromide, ammonium
38. sulfate, copper(II) sulfate, iron(II) sulfate, and manganese(II)
dichloride, at temperatures from 283 K to 308 K (1993)
39. The vapour pressures of saturated aqueous lithium chloride, sodium
bromide, sodium nitrate, ammonium nitrate, and ammonium chloride
at temperatures from 283 K to 313 K (1993)
40. The vapour pressure of water over saturated aqueous solutions of
malic, tartaric, and citric acids, at temperatures from 288 K to 323 K
(1995)
41. Modification and application of the mean spherical approximation
method (1996)
42. Vapour pressures of H216O and H218O, and saturated aqueous
solutions of KCl from T = 298 K to T = 318 K by the isoteniscopic
method (1998)
43. The vapour pressures of saturated aqueous solutions of sodium
chloride, sodium bromide, sodium nitrate, sodium nitrite, potassium
iodate, and rubidium chloride at temperatures from 277 K to 323 K
(1998)
44. Vapour pressures of saturated aqueous solutions of ammonium
iodide, potassium iodide, potassium nitrate, strontium chloride,
lithium sulphate, sodium thiosulphate, magnesium nitrate, and uranyl
nitrate from T = (278 to 323) K (1998)
45. Osmotic and activity coefficients of nonaqueous electrolyte solutions.
1. Lithium perchlorate in the protic solvents methanol, ethanol, and
2-propanol (1998)
46. A three - characteristic - parameter correlation model for strong
electrolyte solutions (1998)
47. Isopiestic determination of osmotic coefficients and evaluation of
vapor pressures for electrolyte solutions of some lithium salts in
ethanol (1999)
48. Measurement and correlation of osmotic coefficients and evaluation
of vapor pressures for solutions of CaCl2 and Ca(NO3)2 in ethanol at
298 K (2000)
49. Solubilities and vapour pressures of saturated aqueous solu-
50. tions of sodium peroxydisulfate and potassium peroxydisulfate
(2001)
51. Physical Chemistry of Metallurgy and Materials (2001)
52. The molar enthalpies of solution and vapour pressures of saturated
aqueous solutions of aluminium chloride, aluminium nitrate and
aluminium sulphate (2002)
53. Vapour pressure measurements and thermodynamic properties of
aqueous solutions of sodium acetate (2002)
54. The molar enthalpies of solution and vapour pressures of saturated
aqueous solutions of some ammonium salts (2003)
55. Isopiestic determination of osmotic coefficients and evaluation of
vapor pressures for solutions of sodium bromide and sodium
thiocyanate in methanol at 25 °C (2003)
56. International Critical Tables of Numerical Data, Physics, Chemistry
and Technology, 1st electronic (2003)
57. Experimental and theoretical studies of thermodynamics of lithium
halide solutions–ethanol mixtures (2004)
58. Vapor pressures, osmotic and activity coefficients for
(LiBr+acetonitrile) between the temperatures (298.15 and 343.15) K
(2004)
59. Measurement and correlation of osmotic coefficients and evaluation
of vapor pressure for electrolyte solutions of LiClO4 and LiNO3 in
methanol at 25 °C (2004)
60. Vapor pressures and osmotic coefficients of aqueous LiOH solutions
at temperatures ranging from 298.15 to 363.15 K (2005)
61. Study of thermodynamic properties of binary solutions of lithium
bromide or lithium chloride with methanol (2005)
62. Application of the GV-MSA model to the electrolyte solutions
containing mixed salts and mixed solvents (2005)
63. The molar enthalpies of solution and vapour pressures of saturated
aqueous solutions of some cesium salts (2006)
64. Vapor pressures of lithium bromide or lithium chloride and ethanol
solutions (2006)
65. Investigation of the vapor pressure p of zinc bromide or zinc chloride
solutions with methanol by static method (2006)
66. Vapor pressure measurements of binary solutions of CaCl2 with
methanol and ethanol at (298.15 to 323.15) K using a static method
(2006)
67. Isopiestic study of the solutions of MnCl2, CoCl2 and NiCl2 in
methanol and ethanol at 298.15 K (2006)
68. The vapour pressures over saturated aqueous solutions of cadmium
chloride, cadmium bromide, cadmium iodide, cadmium nitrate, and
cadmium sulphate(2007)
69. The vapour pressures over saturated aqueous solutions of sodium and
potassium acetates, chlorates, and perchlorates (2007)
70. A new three-particle-interaction model to predict the thermodynamic
properties of different electrolytes (2007)
71. Correlation and prediction of thermodynamic properties of some
complex aqueous electrolytes by the modified three-characteristic-
parameter correlation model (2008)
72. Correlation and prediction of thermodynamic properties of non-
aqueous electrolytes by the modified TCPC model (2008)
73. A simple two-parameter correlation model for aqueous electrolyte
solutions across a wide range of temperature (2009)
REVIEWER’S CONCLUSIONS
Based on the analysis I have done in the journal the idea that arises is what method might be used to
calculate the thermodinamic properties of electrolyte solutions with high and low ionic concentrations.

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