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Tugas Process Synthesis and Simulation

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Tugas Process Synthesis and Simulation

Anggota Kelompok :
1. Ghiyar Ragil 5213417027
2. Atika Safitri 5213417046
3. Kega Amalania Salsabiil 5213417056
4. Immanuella Juan Shafira 5213417059
Contoh soal dan langkah menyelesaikannya dalam Aspen Plus V.10

1. In a treatment of the design of an acetic anhydride manufacturing facility, states that one of the
key steps is the vapor-phase cracking of acetone to ketene and methane:
CH3COCH3 CH2CO + CH4
He states further that this reaction is first-order with respect to acetone and that the specific
reaction rate can be expressed by
ln k = 34.34 - 34,222/T
where k is in reciprocal seconds and T is in Kelvin. In this design, it is desired to feed 7850 kg of
acetone per hour to a tubular reactor. If the reactor is adiabatic, the feed pure acetone, the inlet
temperature 1035K, and the pressure 162 kPa (1.6 atm), a tubular reactor of what volume is
required for 20% conversion?
Answer:
 Open Aspen Plus
 Select NEW

 Select “Blank Simulation”, and then select CREATE


 Under Component Name type the following in a column: ACETONE, KETENE,
METHANE

 Under Comp ID type in any id names for the above components: A, K, M

 Click Next
 From the Property method pull-down menu select Peng-Rob

 Click Next, and select “Go to simulation environment”

 At the MANIPULATOR section, choose DUPL


 At the REACTORS section, choose RPLUG

 At the REACTORS section, choose RCSTR

 And then add MATERIAL


 Rename 1 to FEED, and then click twice

 Fill Temperature to 1035 K

 Add pressure: 1.6 atm


 Composition: Change to MASS-FLOW KG/HR

 For a mass flowrate of A (acetone) type 8000. Leave ketene and methane at zero (no
mass flow in reactant stream).

 Total: Change to MASS-FLOW and enter 8000 KG/HR


 Click Next.

 Click NEXT again

 Choose Adiabatic reactor in “Reactor type”


 In CONFIGURATION section, fill length = 2,6 m and diameter= 1 m

 Click NEXT

 Choose NEW in REACTIONS section


 Reaction Name: enter a name for the reaction set

 Select Type: LHHW

 Select OK
 In Stoichiometry select: New

 Under Rectants: select acetone from the components pull-down menu and set the
coefficient to -1
 Under Products: select ketene and methane and set both coefficients to 1

 Click Next.

 Select the reaction from the pulldown menu


 Change Reacting Phase to Vapor

 Enter 1.125 for k

 Enter 1000 K for To


 Enter the activation energy E of the Arrhenius equation, 67999 CAL/MOL.

 Select “Driving Force”

 Under Reactants: set acetone exponent to 1


 Under Products: set ketene and methane exponent to 0

 Set constants to 0

 Select Term 2 from the pull-down menu


 Set all Exponents and constants B, C, and D to 0

 Set constant A to -1000000

 Click Next.
 Click Next again

 Fill SPESIFICATIONS for CSTR. Temerature = 1035K pressure= 1,6 atm

 Click on REACTION section, and choose R-1


 Click NEXT

 Click OK
 To see results, click STREAMS in “Results Summary”

4 = OUTPUT PFR
5= OUTPUT CSTR
 Result for Plug Flow Reactor

 Result for CSTR


 Balancing between PFR and CSTR

So, we are prefer to use the CSTR reactor for this case.

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