Introduction RFCC

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1.

0 Introduction

Over the past 80 years, UOP has been one of the world’s leading licensors of new
and innovative technology such as holding the residue fluid catalytic cracking (RFCC)
license. The term RFCC is used by UOP to design a new unit that utilizing a two stage
regenerator which is used specifically for the processing residue feeds. Apart from that,
residue processing in FCC unit began in mid-1970s. During this period, the reactors
temperature was increase to maximize the gasoline octane. The demand for higher
conversion lead to the significant increase of coke production and ultimately limited the FCC
regenerator capacity. Table 1.1 shows the brief summary of residue processing and UOP
activity in the area of residue processing.

Years Activity
1940s Residue component added to the feed
1950s Residue processing diminish
1975 Residue processing regains attractiveness
 Market condition favour increased
efficiency in the gasoline production
 Technology and catalyst advances
increase the residue processing
potential.
 UOP unit begins processing reresid/
gas oil blend
1976 UOP and Ashland oil Corporation
 Research and development for
reduced crude conversion.
 Semi-commercial demonstration
1983 First RFCC unit commissioned
1984-2006 8 new RFCC unit operating worldwide
Table 1.1: RFCC Processing Milestone by UOP

The purpose of designing Residue Fluid catalytic cracking (RFCC) is to convert


numerous residues from CDU could be further be cracked by using a catalyst to obtained
more valuable product. The advantage of this unit is the ability to regenerate spent catalyst
used and thus makes its more economically save to use RFCC. On the other hand, the ease
with which catalyst flows between the Reactor and the Regenerator when fluidized with an
appropriate vapor phase in the continuous process.

The product yield at RFCC are LPG (liquefied petroleum gas), gasoline, light cycle oil
(LCO), Heavy Crude oil (HCO) and Clarified oil (CLO). Table 1.2 shows the overall product
form by the RFCC unit. Apart from that, the byproduct produced from this unit includes fuel
gas, slurry oil and coke. Next, most of the RFCC reaction section of equipment handles
catalyst/ vapour product separation and removal of the coke from catalyst, where only a
small part of the system used the cracking system directly. RFCC unit is also provided with a
fractionation tower in order to distillate the vapour product from the reaction section.

Product Component
Light gas Primarily H2, C, and C2’s, normally
an undesirable by-product of thermal
cracking
LPG C3’s and C4’s – includes light olefins
valuable for alkylation (the PetroFCC
process targets maximum light olefin
production)
Gasoline C5+ high octane component for gasoline
pool or light fuel
LCO Light cycle oil blend component for diesel
pool or light fuel
HCO Optional heavy cycle oil product for fuel
oil or cutter stock
CLO Clarified oil or slurry for fuel oil
(potential carbon black feedstock)
Coke By-product consumed in the regenerator
to provide reactor heat demand
Table 1.2: The main products from the RFCC process

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