Properties of Liquid Fuels

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Properties of Liquid Fuels

1. Density

Density is the measurement of mass of fuel per unit volume. It is useful when

determining the quality and quantity of fuels. Pycnometer is the device used to measure

density of a substance. Liquid fuels specifically, diesel fuel, has the highest density

compared to other types of fuels. (Limalima, n.d)

Figure 1. Energy Density of Fuels


Source: http://sanafarastan.com/2017/09/17/about-clean-diesel/
2. Viscosity

Viscosity is measurement of a fuel’s resistance to flow. There are two types of

viscosity: dynamic and kinetic viscosity. Dynamic viscosity measures the ratio of the

shear stress to the shear rate for a fluid.

Shear Stress τ
μ= =
Mathematically, dynamic viscosity is represented as: Velocity gradient ∂ u
∂y
The unit of dynamic viscosity is generally expressed as Pa.s (Pascal-second).

However, in most of the flow and combustion systems, kinematic viscosity is referred as a

typical fluid characteristic. Kinematic viscosity also known as momentum diffusivity, is

defined as the ratio between dynamic viscosity and density.

Mathematically,

Dynamic viscosity μ
v= =
Density ρ

The unit of kinematic viscosity is expressed as m2/s. The typical unit is Stokes. One

stoke is 1cm2/s. The kinematic viscosity of typical engine fuels is in the order of Centi

Stokes or cSt. The kinematic viscosity of some selected petroleum and alternative fuels

such as gasoline, diesel, biodiesel, methanol, ethanol are 0.88cSt, 2-5 cSt, 5-7 cSt,

0.65cSt, 0.85cSt etc. respectively at 40⁰C. (Indian Institute of Technology New Delhi)

3. Flash Point

Flash Point is defined as the lowest temperature of a chemical substance where

enough fluid can evaporate to form a combustible concentration of gas. (Arshad, 2015)

LIQUID FUELS FLASH POINT (oF)


Diesel Fuel 1-D 100

Diesel Fuel 2-D 126

Diesel Fuel 4-D 130


Gasoline -45
Kerosene 100 to 162
Natural Gas 430
Liquified Petroleum Gas -76
Methanol 52
Ethanol 63
Butanol 99
Table 1. Flash Point of Liquid Fuels
Source: https://www.engineeringtoolbox.com/flash-point-fuels-d_937.html
4. Pour Point

According to the Filters Manufacturer Council, the Pour Point is the temperature

where the fuel crystallized to the point where the fuel gels and becomes resistant to flow.

Pour points also vary but they usually occur from 10°F (5.6°C) to 20°F (11.1°C) below

the cloud point.

LIQUID FUELS POUR POINT (°F)


Diesel Fuel -40
Gasoline 90 to -70
Kerosene -53
Liquified Petroleum Gas -306.4
Methanol -143.68
Ethanol -0.4 to -54.4
Table 2. Pour Point of Liquid Fuels
Source: https://www.engineeringtoolbox.com/pour-point-fuels-d_937.html
5. Calorific Value

The calorific value or heat of combustion of a fuel oil is a measure of the amount

of heat released during complete combustion of a unit mass of the fuel, expressed in

kilojoules per kilogram. Calorimeter is usually used to measure the calorific value.

(Engineering Toolbox)

LIQUID FUELS CALORIFIC VALUE (kg/l)


Diesel Fuel 0.846
Gasoline 0.737
Kerosene 0.821
Natural Gas 0.777
Liquified Petroleum Gas 0.537
Methanol 0.791
Ethanol 0.789
Butanol 0.810
Table 3. Calorific Value of Liquid Fuels
Source: https://www.engineeringtoolbox.com/fuels-higher-calorific-values-d_169.html
6. Specific Gravity
Specific Gravity is the ratio of density of the fuel to the density of the reference

substance such as water. It can be measured using hydrometer, a device used to measure

the relative density of liquids based on the buoyancy concept. (Limalima, n.d)

Mathematically, it can be expressed as

density of the object ρobject


Specific Gravity= =
density of water ρH 20 H

LIQUID FUELS SPECIFIC GRAVITY


Diesel Fuel 0.81-0.96 (60 F)
Gasoline 0.739 (60 F)
Kerosene 0.82 (60 F)
Natural Gas 0.713 (60 F)
Liquified Petroleum Gas 0.495 (25 C)
Methanol 0.466 (-164 C)
Ethanol 0.572 (-89 C)
Butanol 0.601 (25 C)
Table 4. Specific Gravity of Liquid Fuels
Source: https://www.engineeringtoolbox.com/fuels-higher-calorific-values-d_169.html
7. Carbon Content

The fuel carbon content is the carbon residue of the fuel as a percentage of its

mass. It is used to calculate the annual emissions of carbon dioxide, carbon monoxide,

and unburned hydrocarbons resulting from the consumption of this fuel in a generator,

boiler, or reformer. (Homer, n.d)

LIQUID FUELS CARBON CONTENT


Diesel Fuel 20.2 kg/GJ

Gasoline 18.9 kg/GJ


Kerosene 19.6 kg/GJ
Natural Gas 15.3 kg/GJ
Liquified Petroleum Gas 82.5%
Methanol 37.5%
Ethanol 52.2%
Butanol 64.8%
Table 5. Carbon Content of Liquid Fuels
Source: https://www.researchgate.net/figure/Net-heating-values-and-carbon-contents-of-
combusted-fossil-fuels_tbl1_321041120

References:

Limalima, V. (n.d.). DETERMINATION OF DENSITY, SPECIFIC GRAVITY AND


VISCOSITY OF LIQUID FUELS. Retrieved December 1, 2019, from
https://prezi.com/p/i3-vhfqj8sqe/determination-of-density-specific-gravity-and-viscosity-
of-liquid-fuels/.

Flash Point - Liquids. (n.d.). Retrieved December 1, 2019, from


https://www.engineeringtoolbox.com/flash-point-fuels-d_937.html.

Indian Institute of Technology New Delhi. (2018). TESTING OF FUELS: VISCOSITY OF


LIQUID FUELS. Retrieved from https://www.google.com/url?
sa=t&rct=j&q=&esrc=s&source=web&cd=19&cad=rja&uact=8&ved=2ahUKEwjr1Me9l
pzmAhXIA4gKHdCACAcQFjASegQIBxAC&url=http://web.iitd.ac.in/~pmvs/courses/m
cl241/Viscosity.pdf&usg=AOvVaw26c4PB3Ptoe_BMseEpIHDq

Fuels - Higher and Lower Calorific Values. (n.d.). Retrieved from


https://www.engineeringtoolbox.com/fuels-higher-calorific-values-d_169.html.

Calorific Value. (n.d.). Retrieved from


https://www.sciencedirect.com/topics/engineering/calorific-value.

Arshad, U. (2015, January 9). Liquid fuels presentation. Retrieved from


https://www.slideshare.net/usmanarshad9883/liquid-fuels-presentation.

HOMER Pro 3.13. (n.d.). Retrieved from


https://www.homerenergy.com/products/pro/docs/latest/fuel_carbon_content.html.

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