Recitation Worksheet – Due by Friday, April 3 at 11:59PM – Chapter 19 Material

Highly suggested that you do not wait until Friday to begin working on this worksheet. You have a number of days to
complete this assignment. No technology reasons or any other reasons will be accepted for a late assignment.

You are only required to complete one set of the problems below on this worksheet to receive full credit (10/10) on
your “Friday, April 3 Recitation Worksheet Assignment”. Use the other questions as extra practice. This worksheet
must be uploaded to the Canvas assignment of that name to receive credit. If you have the technology such as a tablet
you can write on you can download the assignment, write your answers on it, and then upload it. If you have access to a
printer/scanner, you can print the assignment, scan it in and upload it that way. Not to worry if you don’t have these
things – you can write your answers out on any sheet of paper, take a picture of it with your phone, and upload that into
Canvas.

You will be given credit for completion – if you have any questions about the material, use the discussion boards set up
for your recitation section to communicate with your TA and fellow classmates. You will not receive credit for writing “I
don’t know” on these worksheets. If you aren’t sure about something – ask!

Full answer keys will be posted for these problems sets on Saturday, April 4.

You will have an online quiz covering this material that will be made available on our Canvas page Wednesday, April 8-
Thursday, April 9.

Problems sets start on the next page.

Problem Set #1
1. Consider the titration of 30 mL of 0.45 M HI with 0.75 M RbOH.

A. What is the pH at the equivalence point?

B. What is pH after 5 mL of RbOH has been added?

2. Approximate value of the conjugate acid’s pKa in the pH titration to 12

the right?
10

3. In this titration, what type of compound is being titrated?

pH
6

A) monoprotic weak acid B) diprotic weak acid 4

C) monobasic weak base D) dibasic weak base 2

4. Consider the titration of 24mL of 2.5M CH3COOH with 2.5 M NaOH. 0

0 10 20 30 40 50
The Ka of acetic acid is 1.77x10-5. Volume titrant / mL

a. What is the pH of the system after the addition of 15mL of

NaOH?

4b. What is the pH of the system after the addition of 24 mL of NaOH (the equivalence point)?

5. Calculate the solubility of strontium fluoride, SrF2, in pure water. Ksp = 2.6  10–9
Problem Set #2
1. Consider the titration of 25 mL of 0.25 M NaOH with 0.50 M HCl.

A. What is the initial pH?

B. What is pH after 10 mL of HCl has been added?

C. What is pH after 20 mL of HCl has been added?

2. In the pH titration shown at the right, what type of compound is being 14

titrated? 12

10

A) monoprotic weak acid B) diprotic weak acid 8

pH
6
C) monobasic weak base D) dibasic weak base
4

3. Approximate value of the first conjugate acid’s pKa in the pH titration 2

shown? 0
0 5 10 15 20 25 30 35 40

Volume Titrant/mL

4. Consider the titration of 24mL of 2.5M NH3 with 2.5 M HCl. The Ka of NH4+ is 5.75x10-10.

a. What is the pH of the system after the addition of 15mL of HCl?

4b. What is the pH of the system after the addition of 24 mL of HCl (the equivalence point)?

5. The solubility of lead(II) chloride is 0.45 g/100 mL of solution. What is the Ksp of PbCl2?
Problem Set #3
1. Consider the titration of 30 mL of 0.25 M HNO3 with 0.45 M NaOH.

A. What is the initial pH?

B. What is pH after 10 mL of NaOH has been added to the 30mL of acid?

C. What is pH after 25 mL of NaOH has been added to the 30mL of acid?

14

12

10
2. In the pH titration shown at the right, what type of compound is being titrated?
8

pH
A) monoprotic weak acid B) diprotic weak acid 6

4
C) monobasic weak base D) dibasic weak base
2

3. Approximate value of the first buffer zone acid’s pKa in the pH titration shown? 0
0 5 10 15 20 25 30 35 40

Volume Titrant/mL

4. Consider the titration of 50 mL of 1.5 M NH3 with 1.5 M HCl. The Ka of NH4+ is 5.75x10-10.

a. What is the pH of the system after the addition of 50 mL of HCl (the equivalence point?

4b. What is the pH of the system after the addition of 25 mL of HCl (the ½ equivalence point)?

5. Calculate the solubility of barium carbonate, BaCO3, in pure water. Ksp = 2.0  10-9.
Problem Set #4
1. Consider the titration of 15 mL of 0.55 M HClO4 with 0.55 M KOH.

A. What is the pH at the equivalence point?

B. What is pH after 10 mL of KOH has been added to the 15 mL of acid?

C. What is pH after 20 mL of NaOH has been added to the 15 mL of acid? 14

12

10

pH
6
2. In the pH titration shown at the right, what type of compound is being
4
titrated?
2

A) monoprotic weak acid B) diprotic weak acid 0

0 10 20 30 40 50
Volume titrant / mL
C) monobasic weak base D) dibasic weak base
3. Approximate value of the acid’s pKa in the pH titration above?

4. Consider the titration of 50 mL of 1.5M CH3COOH with 1.5 M NaOH. The Ka of acetic acid is 1.77x10-5.
a. What is the pH of the system after the addition of 50 mL of NaOH (the equivalence point?

4b. What is the pH of the system after the addition of 25 mL of NaOH (the ½ equivalence point)?

5. The solubility of a mysterious compound DW2(s) = 3.75x10-4 M. What is the Ksp value?