CH 15 StudyGuideANSWERKEYstudy - GD - Ak

Name Date Class
CHAPTER 15 REVIEW
Acid-Base Titration and pH
SECTION 1
SHORT ANSWER Answer the following questions in the space provided.
1. Calculate the following values without using a calculator.

1 108 M a. The [H3O] is 1 106 M in a solution. Calculate the [OH].
1 105 M b. The [H3O] is 1 109 M in a solution. Calculate the [OH].
1 102 M c. The [OH] is 1 1012 M in a solution. Calculate the [H3O].
2 102 M d. The [OH] in part c is reduced by half, to 0.5 1012 M.
Calculate the [H3O].
inversely e. The [H3O] and [OH] are (directly, inversely, or not)
proportional in any system involving water.

12.0 a. The pH of a solution is 2.0. Calculate the pOH.
9.27 b. The pOH of a solution is 4.73. Calculate the pH.
3.0 c. The [H3O] in a solution is 1 103 M. Calculate the pH.
1 105 M d. The pOH of a solution is 5.0. Calculate the [OH].
1 1013 M e. The pH of a solution is 1.0. Calculate the [OH].
3. Calculate the following values.

4.631 a. The [H3O] is 2.34 105 M in a solution. Calculate the pH.
3.16 104 M b. The pOH of a solution is 3.5. Calculate the [OH].
2.2 107 M c. The [H3O] is 4.6 108 M in a solution. Calculate the [OH].
PROBLEMS Write the answer on the line to the left. Show all your work in the space
provided.
4. [H3O] in an aqueous solution 2.3 103 M.

4.3 1012 M
a. Calculate [OH] in this solution.
MODERN CHEMISTRY ACID-BASE TITRATION AND pH 125

Copyright © by Holt, Rinehart and Winston. All rights reserved.
Name Date Class
SECTION 1 continued
2.64 b. Calculate the pH of this solution.
11.36 c. Calculate the pOH of this solution.
d. Is the solution acidic, basic, or neutral? Explain your answer.

acidic because the pH is less than 7.0
5. Consider a dilute solution of 0.025 M Ba(OH)2 in answering the following questions.

a. What is the [OH] in this solution? Explain your answer.
0.050 M; in solution, Ba(OH)2 releases two OH ions per molecule, so [OH] is two
times the [Ba(OH)2].
12.70 b. What is the pH of this solution?
6. Vinegar purchased in a store may contain 6 g of CH3COOH per 100 mL of solution.

1M a. What is the molarity of the solute?
b. The actual [H3O] in the vinegar solution in part a is 4.2 103 M. In this solution, has more
than 1% or less than 1% of the acetic acid ionized? Explain your answer.
less than 1%; 1% of 1 M would equal 1 102 hydronium ions, but in fact, less than
that amount has been produced.
weak c. Is acetic acid strong or weak, based on the ionization information from
part b?
2.38 d. What is the pH of this vinegar solution?
126 ACID-BASE TITRATION AND pH MODERN CHEMISTRY

Name Date Class
CHAPTER 15 REVIEW
SECTION 2
1. Below is a pH curve from an acid-base titration. On it are labeled three points: X, Y, and Z.
Acid-Base Titration Curve

X
12
10
8
Y
pH
2
Z
15 30 45
mL of acid added
Y a. Which point represents the equivalence point?

Z b. At which point is there excess acid in the system?
X c. At which point is there excess base in the system?
7.5 103 mol d. If the base solution is 0.250 M and there is one equivalent of OH
ions for each mole of base, how many moles of OH ions are
consumed at the end point of the titration?
provided.
2. A standardized solution of 0.065 M HCl is titrated with a saturated solution of calcium hydroxide to
determine its molarity and its solubility. It takes 25.0 mL of the base to neutralize 10.0 mL of the
acid.
a. Write the balanced molecular equation for this neutralization reaction.
Ca(OH)2(aq) 2HCl(aq) → CaCl2(aq) 2H2O(l )

Name Date Class
SECTION 2 continued
0.013 M b. Determine the molarity of the Ca(OH)2 solution.
0.96 g/L c. Based on your answer to part b, calculate the solubility of the base
in grams per liter of solution. (Hint: What is the concentration of
Ca(OH)2 in the saturated solution?)
3. It is possible to carry out a titration without any indicator. Instead, a pH probe is immersed in a
beaker containing the solution of unknown molarity, and a solution of known molarity is slowly
added from a buret. Use the titration data below to answer the following questions.
Volume of KOH(aq) in the beaker 30.0 mL
Molarity of HCl(aq) in the buret 0.50 M
At the instant pH falls from 10 to 4, the volume of acid added to KOH 27.8 mL.
1:1 a. What is the mole ratio of chemical equivalents in this system?
0.46 M b. Calculate the molarity of the KOH solution, based on the above
data.

Name Date Class
CHAPTER 15 REVIEW
MIXED REVIEW

4.0 a. The [H3O] in a solution is 1 104 M. Calculate the pH.
1 1013 M b. The pH of a solution is 13.0. Calculate the [H3O].
1 109 M c. The [OH] in a solution is 1 105 M. Calculate the [H3O].
9.28 d. The pH of a solution is 4.72. Calculate the pOH.
14.00 e. The [OH] in a solution is 1.0 M. Calculate the pH.
2. Calculate the following values.

8.204 a. The [H3O] in a solution is 6.25 109 M. Calculate the pH.
4.6 103 M b. The pOH of a solution is 2.34. Calculate the [OH].
3 104 M c. The pH of milk of magnesia is approximately 10.5. Calculate the
[OH].
provided.
3. A 0.0012 M solution of H2SO4 is 100% ionized.

0.0024 M a. What is the [H3O] in the H2SO4 solution?
4.2 1012 M b. What is the [OH] in this solution?
2.62 c. What is the pH of this solution?

Name Date Class
MIXED REVIEW continued
4. In a titration, a 25.0 mL sample of 0.150 M HCl is neutralized with 44.45 mL of Ba(OH)2.

a. Write the balanced molecular equation for this reaction.
2HCl(aq) Ba(OH)2(aq) → BaCl2(aq) 2H2O(l )
0.0422 M b. What is the molarity of the base solution?
5. 3.09 g of boric acid, H3BO3, are dissolved in 200 mL of solution.

0.250 M a. Calculate the molarity of the solution.
b. H3BO3 ionizes in solution in three stages. Write the equation showing the ionization for each
stage. Which stage proceeds furthest to completion?
stage 1: H3BO3(s) H2O(l ) ← → H3O(aq) H2BO 3 (aq)
→ H3O(aq) HBO32(aq)
stage 2: H2BO 3(aq) H2O(l ) ←
→ H3O(aq) BO33(aq)
stage 3: HBO32(aq) H2O(l ) ←
Stage 1 proceeds furthest to completion.
1.3 105 M c. What is the [H3O] in this boric acid solution if the pH 4.90?
less than 1% d. Is the percentage ionization of this H3BO3 solution more than or less than
1%?


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Name Date Class

Acid-Base Titration and pH

1. Calculate the following values without using a calculator.

2. Calculate the following values without using a calculator.

3. Calculate the following values.

4. [H3O] in an aqueous solution  2.3 103 M.

MODERN CHEMISTRY ACID-BASE TITRATION AND pH 125

2.64 b. Calculate the pH of this solution.

11.36 c. Calculate the pOH of this solution.

d. Is the solution acidic, basic, or neutral? Explain your answer.

5. Consider a dilute solution of 0.025 M Ba(OH)2 in answering the following questions.

times the [Ba(OH)2].

12.70 b. What is the pH of this solution?

6. Vinegar purchased in a store may contain 6 g of CH3COOH per 100 mL of solution.

that amount has been produced.

126 ACID-BASE TITRATION AND pH MODERN CHEMISTRY

Acid-Base Titration and pH

Acid-Base Titration Curve

Y a. Which point represents the equivalence point?

MODERN CHEMISTRY ACID-BASE TITRATION AND pH 127

0.013 M b. Determine the molarity of the Ca(OH)2 solution.

128 ACID-BASE TITRATION AND pH MODERN CHEMISTRY

Acid-Base Titration and pH

1. Calculate the following values without using a calculator.

2. Calculate the following values.

3. A 0.0012 M solution of H2SO4 is 100% ionized.

4.2 1012 M b. What is the [OH] in this solution?

2.62 c. What is the pH of this solution?

MODERN CHEMISTRY ACID-BASE TITRATION AND pH 129

MIXED REVIEW continued

4. In a titration, a 25.0 mL sample of 0.150 M HCl is neutralized with 44.45 mL of Ba(OH)2.

0.0422 M b. What is the molarity of the base solution?

5. 3.09 g of boric acid, H3BO3, are dissolved in 200 mL of solution.

Stage 1 proceeds furthest to completion.

130 ACID-BASE TITRATION AND pH MODERN CHEMISTRY

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4. [H3O] in an aqueous solution 2.3 103 M.