PS-01 Painting System MSDS
PS-01 Painting System MSDS
PS-01 Painting System MSDS
R10 Flammable.
R20/22 Harmful by inhalation and if swallowed.
R37/38 Irritating to respiratory system and skin.
R41 Risk of serious damage to eyes.
Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
R51/53
environment.
R65 Harmful: may cause lung damage if swallowed.
2.2. Label elements
According to 1999/45/EC
Contains: Butan-1-ol,
R10 Flammable.
R20/22 Harmful by inhalation and if swallowed.
R37/38 Irritating to respiratory system and skin.
R41 Risk of serious damage to eyes.
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R65 Harmful: may cause lung damage if swallowed.
P. Phrases;
If the product contains substances that present a health hazard within the meaning of the Dangerous
Substances Directive 67/548/EC, or have occupational exposure limits detailed in EH40, these substances
are listed below.
67/548/EEC EC No. 1272/2008
Ingredient/Chemical Designations Weight % Notes
Classification Classification
Solvent naphtha (petroleum), light 25 - < 50 Xn;R65 N; R51/53 (Self Asp. Tox. 1;H304 H; P
aromatic Classification) Aquatic Chronic [1]
CAS Number: 0064742-95-6 2;H411 (Self
EC No. 265-199-0 Classification)
Index No.: 649-356-00-4
REACH Reg. No.:
Butan-1-ol 25 - < 50 R10 Xn;R22 Xi;R37/38- Flam. Liq. 3;H226
CAS Number: 0000071-36-3 41 R67 Acute Tox. 4;H302 [1][2]
EC No. 200-751-6 STOT SE 3;H335
Index No.: 603-004-00-6 Skin Irrit. 2;H315
REACH Reg. No.: 01-2119484630- Eye Dam. 1;H318
38-xxxx STOT SE 3;H336
1,2,4-trimethylbenzene 10 - < 25 R10 Xn;R20 Flam. Liq. 3;H226
CAS Number: 0000095-63-6 Xi;R36/37/38 N;R51-53 Acute Tox. 4;H332 [1][2]
EC No. 202-436-9 Eye Irrit. 2;H319
Index No.: 601-043-00-3 STOT SE 3;H335
REACH Reg. No.: Skin Irrit. 2;H315
Aquatic Chronic
2;H411
Xylene 2.5 - < 10 R10 Xn;R20/21 Xi;R38 Flam. Liq. 3;H226 C
CAS Number: 0001330-20-7 Acute Tox. 4;H332 [1][2]
EC No. 215-535-7 Acute Tox. 4;H312
Index No.: 601-022-00-9 Skin Irrit. 2;H315
REACH Reg. No.:
1,3,5-trimethylbenzene 2.5 - < 10 R10 Xi;R37 N;R51-53 Flam. Liq. 3;H226
CAS Number: 0000108-67-8 STOT SE 3;H335 [1]
EC No. 203-604-4 Aquatic Chronic
Index No.: 601-025-00-5 2;H411
REACH Reg. No.:
Ethylbenzene 1 - < 2.5 F;R11 Xn;R20 Flam. Liq. 2;H225
CAS Number: 0000100-41-4 Acute Tox. 4;H332 [1][2]
EC No. 202-849-4
Index No.: 601-023-00-4
REACH Reg. No.:
[1] Substance classified with a health or environmental hazard.
[2] Substance with a workplace exposure limit.
[3] PBT-substance or vPvB-substance.
Skin
Remove contaminated clothing. Wash skin thoroughly with soap and water or use a recognised skin
cleanser. Do NOT use solvents or thinners.
Eye
Irrigate copiously with clean fresh water for at least 10 minutes, holding the eyelids apart and seek medical
attention.
Ingestion
If accidentally swallowed obtain immediate medical attention. Keep at rest. Do NOT induce vomiting.
4.2. Most important symptoms and effects, both acute and delayed
No data available
4.3. Indication of any immediate medical attention and special treatment needed
No data available
Contain and absorb spillage with non-combustible materials e.g. sand, earth, vermiculite. Place in closed
containers outside buildings and dispose of according to the Waste Regulations. (See section 13).
If drains, sewers, streams or lakes are contaminated, inform the local water company immediately. In the
case of contamination of rivers, streams or lakes the Environmental Protection Agency should also be
informed.
In Storage
Handle containers carefully to prevent damage and spillage.
Naked flames and smoking should not be permitted in storage areas. It is recommended that fork lift trucks
and electrical equipment are protected to the appropriate standard.
Smoking, eating and drinking should be prohibited in all preparation and application areas.
Never use pressure to empty a container; containers are not pressure vessels.
Store in a well ventilated, dry place away from sources of heat and direct sunlight.
Store on concrete or other impervious floor, preferably with bunding to contain any spillage. Do not stack
more than 3 pallets high.
Keep container tightly closed. Containers which are opened must be carefully resealed and kept upright to
prevent leakage. Keep in the original container or one of the same material.
Material Short term (15 min. ave) Long term (8hr TWA) Comments
ppm mg/m3 ppm mg/m3
1,2,4-trimethylbenzene 25 125
1,3,5-trimethylbenzene 25 125
Butan-1-ol 50 154 - - +
Ethylbenzene 125 552 100 441 +
Xylene 100 441 50 220 +
DNEL/PNEC values
No Data Available
Eye/face protection
Wear safety eyewear, e.g. safety spectacles, goggles or visors to protect against the splash of liquids.
Eyewear should meet the requirements of standard EN 166.
Skin protection
For prolonged or repeated contact use protective gloves. Barrier creams may help to protect the exposed
areas of skin, they should however not be applied once exposure has occurred. Skin should be washed
after contact.
Use chemical resistant gloves classified under Standard EN 374: Protective gloves against chemicals and
micro-organisms. Recommended gloves: Viton® or Nitrile
Breakthrough Time: 480 min
When prolonged or frequently repeated contact may occur, a glove with a protection class of 6
(breakthrough time greater than 480 minutes according to EN 374) is recommended. When only brief
contact is expected, a glove with a protection class of 2 or higher (breakthrough time greater than 30
minutes according to EN 374) is recommended.
NOTICE: The selection of a specific glove for a particular application and duration of use in a workplace
should also take into account all relevant workplace factors such as, but not limited to: Other chemicals
which may be handled, physical requirements (cut/puncture protection, dexterity, thermal protection),
potential body reactions to glove materials, as well as the instructions/specifications provided by the glove
supplier.
The user must check that the final choice of type of glove selected for handling this product is the most
appropriate and takes into account the particular conditions of use, as included in the user's risk
assessment.
Other
Overalls which cover the body, arms and legs should be worn. Skin should not be exposed. Barrier creams
may help to protect areas which are difficult to cover such as the face and neck. They should however not
be applied once exposure has occurred. Petroleum jelly based types such as Vaseline should not be used.
All parts of the body should be washed after contact.
Respiratory protection
If workers are exposed to concentrations above the exposure limit they must use the appropriate,certified
respirators.For maximum protection when spraying this product it is recommended that a multi layer
combination type filter, such as ABEK1, is used. In confined spaces use compressed air or fresh air
respiratory equipment.
Thermal hazards
No Data Available
10.1. Reactivity
No data available
10.2. Chemical stability
Stable under recommended storage and handling conditions (see section 7).When exposed to high
temperatures may produce hazardous decomposition products such as carbon monoxide, carbon dioxide,
oxides of nitrogen and smoke.
Keep away from oxidising agents, strongly alkaline and strongly acid materials in order to avoid possible
exothermic reactions.
10.3. Possibility of hazardous reactions
May react exothermically with: oxidising agents, strong alkalis, strong acids.
10.4. Conditions to avoid
Stable under recommended storage and handling conditions (see section 7).
10.5. Incompatible materials
Keep away from the following materials: oxidising agents, strong alkalis, strong acids.
10.6. Hazardous decomposition products
Fire will produce dense black smoke. Decomposition products may include the following materials: carbon
monoxide, carbon dioxide, smoke, oxides of nitrogen.
Avoid exposure and use breathing apparatus as appropriate.
Acute toxicity
Exposure to solvent vapour concentrations from the component solvents in excess of the stated
occupational exposure limits may result in adverse health effects such as mucous membrane and
respiratory system irritation and adverse effects on the kidneys, liver and central nervous system.
Symptoms include headache, nausea, dizziness, fatigue, muscular weakness, drowsiness and in extreme
cases, loss of consciousness.
Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin
resulting in dryness, irritation and possible non-allergic contact dermatitis. Solvents may also be absorbed
through the skin. Splashes of liquid in the eyes may cause irritation and soreness with possible reversible
damage.
Inhalation
Inhalation
Oral LD50, Skin LD50, Dust/Mist
Ingredient Vapour LD50,
mg/kg mg/kg LD50,
mg/L/4hr
mg/L/4hr
1,2,4-trimethylbenzene - (95-63-6) 3,400.00, Rat 3,160.00, Rabbit 18.00, Rat Not
Available
Solvent naphtha (petroleum), light 6,800.00, Rat 3,400.00, Rabbit Not Available Not
aromatic - (64742-95-6) Available
12.1. Toxicity
The preparation has been assessed following the conventional method of the Dangerous Preparations
Directive 1999/45/EC and is classified for eco-toxicological properties accordingly. See Sections 2 and 3
for details.
1,3,5-trimethylbenzene - (108-67-8) 12.52, Carassius 6.00, Daphnia magna 25.00 (48 hr), Scenedesmus
auratus subspicatus
Ethylbenzene - (100-41-4) 4.20, Oncorhynchus 2.93, Daphnia magna
mykiss 3.60 (96 hr), Pseudokirchneriella
subcapitata
Using information provided in this data sheet advice should be obtained from the Waste Regulation
Authority, whether the special waste regulations apply.
The European Waste Catalogue Classification of this product, when disposed of as waste is 08 01 11
Waste paint and varnish containing organic solvents or other dangerous substances. If mixed with other
wastes this code may no longer apply and the appropriate code should be assigned. For further
information contact your local waste authority.
EU Legislation
REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL on
classification, labelling and packaging of substances and mixtures, amending and repealing Directives
67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006.
IMPORTANT NOTE: the information contained in this data sheet (as may be amended from time to time) is
not intended to be exhaustive and is presented in good faith and believed to be correct as of the date on
which it is prepared. It is the user's responsibility to verify that this data sheet is current prior to using the
product to which it relates.
Persons using the information must make their own determinations as to the suitability of the relevant
product for their purposes prior to use. Where those purposes are other than as specifically recommended
in this safety data sheet, then the user uses the product at their own risk.
MANUFACTURER’S DISCLAIMER: the conditions, methods and factors affecting the handling, storage,
application, use and disposal of the product are not under the control and knowledge of the manufacturer.
Therefore the manufacturer does not assume responsibility for any adverse events which may occur in the
handling, storage, application, use, misuse or disposal of the product and, so far as permitted by applicable
law, the manufacturer expressly disclaims liability for any and all loss, damages and/or expenses arising
out of or in any way connected to the storage, handling, use or disposal of the product. Safe handling,
storage, use and disposal are the responsibility of the users. Users must comply with all applicable health
and safety laws.
Unless we have agreed to the contrary, all products are supplied by us subject to our standard terms and
conditions of business, which include limitations of liability. Please make sure to refer to these and / or the
relevant agreement which you have with AkzoNobel (or its affiliate, as the case may be).
© AkzoNobel
The information in this Health & Safety Data Sheet is required pursuant to EC Regulation 1907(2006) and
the Chemicals (Hazard Information & Packaging for Supply) Regulations 2009.
The full text of the R, H & EUH phrases appearing in section 3 is:
End of document
Your attention is drawn to the disclaimer on the Product Data Sheet which with this Safety Data
Sheet and the package labelling comprise an integral information system about this product. Copies
of the Product Data Sheet are available from International Paint on request or from our Internet
sites : www.yachtpaint.com , www.international-marine.com, www.international-pc.com
International Paint Ltd.
Page 1 of 9
2.2. Label elements
According to 1999/45/EC
Contains: Xylene,
R11 Highly flammable.
R20/21 Harmful by inhalation and in contact with skin.
R37/38 Irritating to respiratory system and skin.
R41 Risk of serious damage to eyes.
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection.
P. Phrases;
If the product contains substances that present a health hazard within the meaning of the Dangerous
Substances Directive 67/548/EC, or have occupational exposure limits detailed in EH40, these substances
are listed below.
67/548/EEC EC No. 1272/2008
Ingredient/Chemical Designations Weight % Notes
Classification Classification
2-Methylpropan-1-ol 50 - 100 R10 Xi;R37/38-41 R67 Flam. Liq. 3;H226
CAS Number: 0000078-83-1 STOT SE 3;H335 [1][2]
EC No. 201-148-0 Skin Irrit. 2;H315
Index No.: 603-108-00-1 Eye Dam. 1;H318
REACH Reg. No.: STOT SE 3;H336
Xylene 25 - < 50 R10 Xn;R20/21 Xi;R38 Flam. Liq. 3;H226 C
CAS Number: 0001330-20-7 Acute Tox. 4;H332 [1][2]
EC No. 215-535-7 Acute Tox. 4;H312
Index No.: 601-022-00-9 Skin Irrit. 2;H315
REACH Reg. No.:
Ethylbenzene 2.5 - < 10 F;R11 Xn;R20 Flam. Liq. 2;H225
CAS Number: 0000100-41-4 Acute Tox. 4;H332 [1][2]
EC No. 202-849-4
Index No.: 601-023-00-4
REACH Reg. No.:
[1] Substance classified with a health or environmental hazard.
[2] Substance with a workplace exposure limit.
[3] PBT-substance or vPvB-substance.
Page 2 of 9
Never give anything by mouth to an unconscious person.
Inhalation
Remove to fresh air, keep patient warm and at rest. If breathing is irregular or stopped, give artificial
respiration. If unconscious place in the recovery position and obtain immediate medical attention. Give
nothing by mouth.
Skin
Remove contaminated clothing. Wash skin thoroughly with soap and water or use a recognised skin
cleanser. Do NOT use solvents or thinners.
Eye
Irrigate copiously with clean fresh water for at least 10 minutes, holding the eyelids apart and seek medical
attention.
Ingestion
If accidentally swallowed obtain immediate medical attention. Keep at rest. Do NOT induce vomiting.
4.2. Most important symptoms and effects, both acute and delayed
No data available
4.3. Indication of any immediate medical attention and special treatment needed
No data available
Contain and absorb spillage with non-combustible materials e.g. sand, earth, vermiculite. Place in closed
containers outside buildings and dispose of according to the Waste Regulations. (See section 13).
Page 3 of 9
If drains, sewers, streams or lakes are contaminated, inform the local water company immediately. In the
case of contamination of rivers, streams or lakes the Environmental Protection Agency should also be
informed.
In Storage
Handle containers carefully to prevent damage and spillage.
Naked flames and smoking should not be permitted in storage areas. It is recommended that fork lift trucks
and electrical equipment are protected to the appropriate standard.
Smoking, eating and drinking should be prohibited in all preparation and application areas.
Never use pressure to empty a container; containers are not pressure vessels.
Store in a well ventilated, dry place away from sources of heat and direct sunlight.
Store on concrete or other impervious floor, preferably with bunding to contain any spillage. Do not stack
more than 3 pallets high.
Keep container tightly closed. Containers which are opened must be carefully resealed and kept upright to
prevent leakage. Keep in the original container or one of the same material.
Material Short term (15 min. ave) Long term (8hr TWA) Comments
ppm mg/m3 ppm mg/m3
2-Methylpropan-1-ol 75 231 50 154
Ethylbenzene 125 552 100 441 +
Xylene 100 441 50 220 +
DNEL/PNEC values
No Data Available
Page 4 of 9
8.2. Exposure controls
Provide adequate ventilation.Where reasonably practicable this should be achieved by the use of local
exhaust ventilation and good general extraction. If these are not sufficient to maintain concentrations of
particulates and any vapour below occupational exposure limits suitable respiratory protection must be
worn.
Eye/face protection
Wear safety eyewear, e.g. safety spectacles, goggles or visors to protect against the splash of liquids.
Eyewear should meet the requirements of standard EN 166.
Skin protection
For prolonged or repeated contact use protective gloves. Barrier creams may help to protect the exposed
areas of skin, they should however not be applied once exposure has occurred. Skin should be washed
after contact.
Use chemical resistant gloves classified under Standard EN 374: Protective gloves against chemicals and
micro-organisms. Recommended gloves: Viton® or Nitrile
Breakthrough Time: 480 min
When prolonged or frequently repeated contact may occur, a glove with a protection class of 6
(breakthrough time greater than 480 minutes according to EN 374) is recommended. When only brief
contact is expected, a glove with a protection class of 2 or higher (breakthrough time greater than 30
minutes according to EN 374) is recommended.
NOTICE: The selection of a specific glove for a particular application and duration of use in a workplace
should also take into account all relevant workplace factors such as, but not limited to: Other chemicals
which may be handled, physical requirements (cut/puncture protection, dexterity, thermal protection),
potential body reactions to glove materials, as well as the instructions/specifications provided by the glove
supplier.
The user must check that the final choice of type of glove selected for handling this product is the most
appropriate and takes into account the particular conditions of use, as included in the user's risk
assessment.
Other
Overalls which cover the body, arms and legs should be worn. Skin should not be exposed. Barrier creams
may help to protect areas which are difficult to cover such as the face and neck. They should however not
be applied once exposure has occurred. Petroleum jelly based types such as Vaseline should not be used.
All parts of the body should be washed after contact.
Respiratory protection
If workers are exposed to concentrations above the exposure limit they must use the appropriate,certified
respirators.For maximum protection when spraying this product it is recommended that a multi layer
combination type filter, such as ABEK1, is used. In confined spaces use compressed air or fresh air
respiratory equipment.
Thermal hazards
No Data Available
Page 5 of 9
Initial boiling point and boiling range (°C) 108
Flash point (°C) 17
Evaporation rate (Ether = 1) Not Measured
Flammability (solid, gas) Not Applicable
Upper/lower flammability or explosive limits Lower Explosive Limit: Not Measured
Upper Explosive Limit: Not Measured
Vapour pressure (Pa) Not Measured
Vapour density Heavier than air.
Relative density 0.83
Solubility(ies) Immiscible
Partition coefficient n-octanol/water (Log Kow) Not Measured
Auto-ignition temperature (°C) Not Measured
Decomposition temperature (°C) Not Measured
Viscosity (cSt) 1
10.1. Reactivity
No data available
10.2. Chemical stability
Stable under recommended storage and handling conditions (see section 7).When exposed to high
temperatures may produce hazardous decomposition products such as carbon monoxide, carbon dioxide,
oxides of nitrogen and smoke.
Keep away from oxidising agents, strongly alkaline and strongly acid materials in order to avoid possible
exothermic reactions.
10.3. Possibility of hazardous reactions
May react exothermically with: oxidising agents, strong alkalis, strong acids.
10.4. Conditions to avoid
Stable under recommended storage and handling conditions (see section 7).
10.5. Incompatible materials
Keep away from the following materials: oxidising agents, strong alkalis, strong acids.
10.6. Hazardous decomposition products
Fire will produce dense black smoke. Decomposition products may include the following materials: carbon
monoxide, carbon dioxide, smoke, oxides of nitrogen.
Avoid exposure and use breathing apparatus as appropriate.
Acute toxicity
Exposure to solvent vapour concentrations from the component solvents in excess of the stated
occupational exposure limits may result in adverse health effects such as mucous membrane and
respiratory system irritation and adverse effects on the kidneys, liver and central nervous system.
Symptoms include headache, nausea, dizziness, fatigue, muscular weakness, drowsiness and in extreme
cases, loss of consciousness.
Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin
resulting in dryness, irritation and possible non-allergic contact dermatitis. Solvents may also be absorbed
through the skin. Splashes of liquid in the eyes may cause irritation and soreness with possible reversible
damage.
Page 6 of 9
Inhalation Inhalation
Oral LD50, Skin LD50,
Ingredient Vapour LD50, Dust/Mist LD50,
mg/kg mg/kg
mg/L/4hr mg/L/4hr
2-Methylpropan-1-ol - (78-83-1) 2,460.00, Rat 3,400.00, Rabbit Not Available Not Available
Ethylbenzene - (100-41-4) 3,500.00, Rat 15,433.00, Rabbit 17.20, Rat Not Available
Xylene - (1330-20-7) 4,299.00, Rat 1,548.00, Rabbit 20.00, Rat Not Available
12.1. Toxicity
The preparation has been assessed following the conventional method of the Dangerous Preparations
Directive 1999/45/EC and is not classified as dangerous for the environment
Aquatic Ecotoxicity
Using information provided in this data sheet advice should be obtained from the Waste Regulation
Authority, whether the special waste regulations apply.
The European Waste Catalogue Classification of this product, when disposed of as waste is 08 01 11
Waste paint and varnish containing organic solvents or other dangerous substances. If mixed with other
wastes this code may no longer apply and the appropriate code should be assigned. For further
information contact your local waste authority.
Page 7 of 9
SECTION 14: Transport information
EmS F-E,S-E
EU Legislation
REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL on
classification, labelling and packaging of substances and mixtures, amending and repealing Directives
67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006.
IMPORTANT NOTE: the information contained in this data sheet (as may be amended from time to time) is
not intended to be exhaustive and is presented in good faith and believed to be correct as of the date on
which it is prepared. It is the user's responsibility to verify that this data sheet is current prior to using the
product to which it relates.
Persons using the information must make their own determinations as to the suitability of the relevant
Page 8 of 9
product for their purposes prior to use. Where those purposes are other than as specifically recommended
in this safety data sheet, then the user uses the product at their own risk.
MANUFACTURER’S DISCLAIMER: the conditions, methods and factors affecting the handling, storage,
application, use and disposal of the product are not under the control and knowledge of the manufacturer.
Therefore the manufacturer does not assume responsibility for any adverse events which may occur in the
handling, storage, application, use, misuse or disposal of the product and, so far as permitted by applicable
law, the manufacturer expressly disclaims liability for any and all loss, damages and/or expenses arising
out of or in any way connected to the storage, handling, use or disposal of the product. Safe handling,
storage, use and disposal are the responsibility of the users. Users must comply with all applicable health
and safety laws.
Unless we have agreed to the contrary, all products are supplied by us subject to our standard terms and
conditions of business, which include limitations of liability. Please make sure to refer to these and / or the
relevant agreement which you have with AkzoNobel (or its affiliate, as the case may be).
© AkzoNobel
The information in this Health & Safety Data Sheet is required pursuant to EC Regulation 1907(2006) and
the Chemicals (Hazard Information & Packaging for Supply) Regulations 2009.
The full text of the R, H & EUH phrases appearing in section 3 is:
End of document
Your attention is drawn to the disclaimer on the Product Data Sheet which with this Safety Data
Sheet and the package labelling comprise an integral information system about this product. Copies
of the Product Data Sheet are available from International Paint on request or from our Internet
sites : www.yachtpaint.com , www.international-marine.com, www.international-pc.com
Page 9 of 9
International Paint Ltd.
R10 Flammable.
R20 Harmful by inhalation.
R36/38 Irritating to eyes and skin.
R43 May cause sensitisation by skin contact.
Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
R51/53
environment.
2.2. Label elements
According to 1999/45/EC
P. Phrases;
Contains epoxy constituents. See information supplied by the manufacturer.
If the product contains substances that present a health hazard within the meaning of the Dangerous
Substances Directive 67/548/EC, or have occupational exposure limits detailed in EH40, these substances
are listed below.
67/548/EEC EC No. 1272/2008
Ingredient/Chemical Designations Weight % Notes
Classification Classification
Epoxy resin (av.mol.wt.<700) 10 - < 25 R43 Xi;R36/38 N;R51- Eye Irrit. 2;H319
CAS Number: 0025068-38-6 53 Skin Irrit. 2;H315 [1]
EC No. 500-033-5 Skin Sens. 1;H317
Index No.: 603-074-00-8 Aquatic Chronic
REACH Reg. No.: 01-2119456619- 2;H411
26-xxxx
Xylene 10 - < 25 R10 Xn;R20/21 R65 Xi; Flam. Liq. 3;H226 C
CAS Number: 0001330-20-7 R36/37/38 Acute Tox. 4;H332 [1][2]
EC No. 215-535-7 Acute Tox. 4;H312
Index No.: 601-022-00-9 Skin Irrit. 2;H315
REACH Reg. No.: Eye Irrit. 2;H319
STOT SE 3;H335
Asp. Tox. 1;H304
Ethylbenzene 2.5 - < 10 F;R11 Xn;R20 R65 Flam. Liq. 2;H225
CAS Number: 0000100-41-4 R48/20 Xi; R36/37/38 Acute Tox. 4;H332 [1][2]
EC No. 202-849-4 Asp. Tox. 1;H304
Index No.: 601-023-00-4 Eye Irrit. 2;H319
REACH Reg. No.: Skin Irrit. 2;H315
STOT SE 3;H335
STOT RE 2;H373
Epoxy resin (av.mol.wt. 700-1100) 1 - < 2.5 R43 Xi;R36/38 Eye Irrit. 2;H319
CAS Number: 0025068-38-6 Skin Irrit. 2;H315 [1]
EC No. 500-033-5 Skin Sens. 1;H317
Index No.: 603-074-00-8
REACH Reg. No.:
Butan-1-ol 1 - < 2.5 R10 Xn;R22 Xi;R37/38- Flam. Liq. 3;H226
CAS Number: 0000071-36-3 41 R67 Acute Tox. 4;H302 [1][2]
EC No. 200-751-6 STOT SE 3;H335
Index No.: 603-004-00-6 Skin Irrit. 2;H315
REACH Reg. No.: 01-2119484630- Eye Dam. 1;H318
38-xxxx STOT SE 3;H336
Zinc phosphate 1 - < 2.5 N;R50-53 Aquatic Acute 1;H400
CAS Number: 0007779-90-0 Aquatic Chronic [1]
EC No. 231-944-3 1;H410
Index No.: 030-011-00-6
REACH Reg. No.: 01-2119485044-
40-xxxx
[1] Substance classified with a health or environmental hazard.
[2] Substance with a workplace exposure limit.
[3] PBT-substance or vPvB-substance.
Skin
Remove contaminated clothing. Wash skin thoroughly with soap and water or use a recognised skin
cleanser. Do NOT use solvents or thinners.
Eye
Irrigate copiously with clean fresh water for at least 10 minutes, holding the eyelids apart and seek medical
attention.
Ingestion
If accidentally swallowed obtain immediate medical attention. Keep at rest. Do NOT induce vomiting.
4.2. Most important symptoms and effects, both acute and delayed
No data available
4.3. Indication of any immediate medical attention and special treatment needed
No data available
Contain and absorb spillage with non-combustible materials e.g. sand, earth, vermiculite. Place in closed
containers outside buildings and dispose of according to the Waste Regulations. (See section 13).
If drains, sewers, streams or lakes are contaminated, inform the local water company immediately. In the
case of contamination of rivers, streams or lakes the Environmental Protection Agency should also be
informed.
In Storage
Handle containers carefully to prevent damage and spillage.
Naked flames and smoking should not be permitted in storage areas. It is recommended that fork lift trucks
and electrical equipment are protected to the appropriate standard.
Smoking, eating and drinking should be prohibited in all preparation and application areas.
Never use pressure to empty a container; containers are not pressure vessels.
Store in a well ventilated, dry place away from sources of heat and direct sunlight.
Store on concrete or other impervious floor, preferably with bunding to contain any spillage. Do not stack
more than 3 pallets high.
Keep container tightly closed. Containers which are opened must be carefully resealed and kept upright to
prevent leakage. Keep in the original container or one of the same material.
Prevent unauthorised access.
Activities such as sanding, burning off etc. of paint films may generate dust and/or fumes hazardous to the
skin and lungs. Sanding dust may contain levels of unreacted hazardous materials which may cause
irritation and sensitization; these are highest in the first 24/48 hours after application. Work in well
ventilated areas. Use local exhaust ventilation and personal skin and respiratory protective equipment as
appropriate.
Material Short term (15 min. ave) Long term (8hr TWA) Comments
ppm mg/m3 ppm mg/m3
Butan-1-ol 50 154 - - +
Ethylbenzene 125 552 100 441 +
Xylene 100 441 50 220 +
DNEL/PNEC values
No Data Available
Eye/face protection
Wear safety eyewear, e.g. safety spectacles, goggles or visors to protect against the splash of liquids.
Eyewear should meet the requirements of standard EN 166.
Skin protection
For prolonged or repeated contact use protective gloves. Barrier creams may help to protect the exposed
areas of skin, they should however not be applied once exposure has occurred. Skin should be washed
after contact.
Use chemical resistant gloves classified under Standard EN 374: Protective gloves against chemicals and
micro-organisms. Recommended gloves: Viton® or Nitrile
Breakthrough Time: 480 min
When prolonged or frequently repeated contact may occur, a glove with a protection class of 6
(breakthrough time greater than 480 minutes according to EN 374) is recommended. When only brief
contact is expected, a glove with a protection class of 2 or higher (breakthrough time greater than 30
minutes according to EN 374) is recommended.
NOTICE: The selection of a specific glove for a particular application and duration of use in a workplace
should also take into account all relevant workplace factors such as, but not limited to: Other chemicals
which may be handled, physical requirements (cut/puncture protection, dexterity, thermal protection),
potential body reactions to glove materials, as well as the instructions/specifications provided by the glove
supplier.
The user must check that the final choice of type of glove selected for handling this product is the most
appropriate and takes into account the particular conditions of use, as included in the user's risk
assessment.
Other
Overalls which cover the body, arms and legs should be worn. Skin should not be exposed. Barrier creams
may help to protect areas which are difficult to cover such as the face and neck. They should however not
be applied once exposure has occurred. Petroleum jelly based types such as Vaseline should not be used.
All parts of the body should be washed after contact.
Respiratory protection
If workers are exposed to concentrations above the exposure limit they must use the appropriate,certified
respirators.For maximum protection when spraying this product it is recommended that a multi layer
combination type filter, such as ABEK1, is used. In confined spaces use compressed air or fresh air
respiratory equipment.
Thermal hazards
No Data Available
10.1. Reactivity
No data available
10.2. Chemical stability
Stable under recommended storage and handling conditions (see section 7).When exposed to high
temperatures may produce hazardous decomposition products such as carbon monoxide, carbon dioxide,
oxides of nitrogen and smoke.
Keep away from oxidising agents, strongly alkaline and strongly acid materials in order to avoid possible
exothermic reactions.
10.3. Possibility of hazardous reactions
May react exothermically with: oxidising agents, strong alkalis, strong acids.
10.4. Conditions to avoid
Stable under recommended storage and handling conditions (see section 7).
10.5. Incompatible materials
Keep away from the following materials: oxidising agents, strong alkalis, strong acids.
10.6. Hazardous decomposition products
Fire will produce dense black smoke. Decomposition products may include the following materials: carbon
monoxide, carbon dioxide, smoke, oxides of nitrogen.
Avoid exposure and use breathing apparatus as appropriate.
Acute toxicity
Exposure to solvent vapour concentrations from the component solvents in excess of the stated
occupational exposure limits may result in adverse health effects such as mucous membrane and
respiratory system irritation and adverse effects on the kidneys, liver and central nervous system.
Symptoms include headache, nausea, dizziness, fatigue, muscular weakness, drowsiness and in extreme
cases, loss of consciousness.
Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin
resulting in dryness, irritation and possible non-allergic contact dermatitis. Solvents may also be absorbed
through the skin. Splashes of liquid in the eyes may cause irritation and soreness with possible reversible
damage.
Based on the properties of the epoxy constituents and considering toxicological data on similar
preparations this preparation may be an irritant and a skin and respiratory sensitiser. Low molecular weight
epoxy constituents are irritating to eyes, mucous membranes and skin. Repeated skin contact may lead to
irritation and sensitisation, possibly with cross-sensitisation to other epoxies. Skin contact with the
preparation and exposure to spray mist and vapour should be avoided.
Inhalation
Inhalation
Oral LD50, Skin LD50, Dust/Mist
Ingredient Vapour LD50,
mg/kg mg/kg LD50,
mg/L/4hr
mg/L/4hr
Butan-1-ol - (71-36-3) 2,292.00, Rat 3,430.00, Rabbit Not Available Not
Available
Epoxy resin (av.mol.wt. 700-1100) - Not Available Not Available Not Available Not
(25068-38-6) Available
Epoxy resin (av.mol.wt.<700) - (25068-38- 2,000.00, Rat 2,000.00, Rabbit Not Available Not
6) Available
Zinc phosphate - (7779-90-0) 5,000.00, Rat Not Available Not Available Not
Available
Aquatic Ecotoxicity
Using information provided in this data sheet advice should be obtained from the Waste Regulation
Authority, whether the special waste regulations apply.
The European Waste Catalogue Classification of this product, when disposed of as waste is 08 01 11
Waste paint and varnish containing organic solvents or other dangerous substances. If mixed with other
wastes this code may no longer apply and the appropriate code should be assigned. For further
information contact your local waste authority.
EmS F-E,S-E
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
EU Legislation
REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL on
classification, labelling and packaging of substances and mixtures, amending and repealing Directives
67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006.
IMPORTANT NOTE: the information contained in this data sheet (as may be amended from time to time) is
not intended to be exhaustive and is presented in good faith and believed to be correct as of the date on
which it is prepared. It is the user's responsibility to verify that this data sheet is current prior to using the
product to which it relates.
Persons using the information must make their own determinations as to the suitability of the relevant
product for their purposes prior to use. Where those purposes are other than as specifically recommended
in this safety data sheet, then the user uses the product at their own risk.
MANUFACTURER’S DISCLAIMER: the conditions, methods and factors affecting the handling, storage,
application, use and disposal of the product are not under the control and knowledge of the manufacturer.
Therefore the manufacturer does not assume responsibility for any adverse events which may occur in the
handling, storage, application, use, misuse or disposal of the product and, so far as permitted by applicable
law, the manufacturer expressly disclaims liability for any and all loss, damages and/or expenses arising
out of or in any way connected to the storage, handling, use or disposal of the product. Safe handling,
storage, use and disposal are the responsibility of the users. Users must comply with all applicable health
and safety laws.
Unless we have agreed to the contrary, all products are supplied by us subject to our standard terms and
conditions of business, which include limitations of liability. Please make sure to refer to these and / or the
relevant agreement which you have with AkzoNobel (or its affiliate, as the case may be).
© AkzoNobel
The information in this Health & Safety Data Sheet is required pursuant to EC Regulation 1907(2006) and
the Chemicals (Hazard Information & Packaging for Supply) Regulations 2009.
The full text of the R, H & EUH phrases appearing in section 3 is:
This is the first revision of this SDS format, changes from previous revision not applicable.
End of document
Your attention is drawn to the disclaimer on the Product Data Sheet which with this Safety Data
Sheet and the package labelling comprise an integral information system about this product. Copies
of the Product Data Sheet are available from International Paint on request or from our Internet
sites : www.yachtpaint.com , www.international-marine.com, www.international-pc.com
International Paint Ltd.
R10 Flammable.
R20 Harmful by inhalation.
R36/37/38 Irritating to eyes, respiratory system and skin.
R42/43 May cause sensitization by inhalation and skin contact.
Contains: Ethylenediamine,
R10 Flammable.
R20 Harmful by inhalation.
R36/37/38 Irritating to eyes, respiratory system and skin.
R42/43 May cause sensitization by inhalation and skin contact.
P. Phrases;
If the product contains substances that present a health hazard within the meaning of the Dangerous
Substances Directive 67/548/EC, or have occupational exposure limits detailed in EH40, these substances
are listed below.
67/548/EEC EC No. 1272/2008
Ingredient/Chemical Designations Weight % Notes
Classification Classification
Cashew nutshell liquid, polymer 10 - < 25 R36/37/38 Eye Dam. 2A;H319
with EDA and formaldehyde STOT SE 3;H335 [1]
CAS Number: 0068413-28-5 Skin Irrit. 2;H315
EC No.
Index No.:
REACH Reg. No.:
Xylene 10 - < 25 R10 Xn;R20/21 R65 Xi; Flam. Liq. 3;H226 C
CAS Number: 0001330-20-7 R36/37/38 Acute Tox. 4;H332 [1][2]
EC No. 215-535-7 Acute Tox. 4;H312
Index No.: 601-022-00-9 Skin Irrit. 2;H315
REACH Reg. No.: Eye Irrit. 2;H319
STOT SE 3;H335
Asp. Tox. 1;H304
Butan-1-ol 2.5 - < 10 R10 Xn;R22 Xi;R37/38- Flam. Liq. 3;H226
CAS Number: 0000071-36-3 41 R67 Acute Tox. 4;H302 [1][2]
EC No. 200-751-6 STOT SE 3;H335
Index No.: 603-004-00-6 Skin Irrit. 2;H315
REACH Reg. No.: 01-2119484630- Eye Dam. 1;H318
38-xxxx STOT SE 3;H336
Ethylbenzene 2.5 - < 10 F;R11 Xn;R20 R65 Flam. Liq. 2;H225
CAS Number: 0000100-41-4 R48/20 Xi; R36/37/38 Acute Tox. 4;H332 [1][2]
EC No. 202-849-4 Asp. Tox. 1;H304
Index No.: 601-023-00-4 Eye Irrit. 2;H319
REACH Reg. No.: Skin Irrit. 2;H315
STOT SE 3;H335
STOT RE 2;H373
2,4,6-Tris(dimethylaminomethyl) 2.5 - < 10 Xn;R22 Xi;R36/38 Acute Tox. 4;H302
phenol Eye Irrit. 2;H319 [1]
CAS Number: 0000090-72-2 Skin Irrit. 2;H315
EC No. 202-013-9
Index No.: 603-069-00-0
REACH Reg. No.: 01-2119560597-
27-xxxx
Ethylenediamine 1 - < 2.5 R10 C;R34 Xn;R21/22 Flam. Liq. 3;H226
CAS Number: 0000107-15-3 R42/43 Acute Tox. 4;H312 [1][2]
EC No. 203-468-6 Acute Tox. 4;H302
Index No.: 612-006-00-6 Skin Corr. 1B;H314
REACH Reg. No.: Resp. Sens. 1;H334
Skin Sens. 1;H317
E96096 0-<1 Xi; R43 R53 Skin Sens. 1;H317
CAS Number: Not Available Aquatic Chronic [1]
EC No. 434-43-9 4;H413
Index No.:
REACH Reg. No.:
[1] Substance classified with a health or environmental hazard.
[2] Substance with a workplace exposure limit.
[3] PBT-substance or vPvB-substance.
Skin
Remove contaminated clothing. Wash skin thoroughly with soap and water or use a recognised skin
cleanser. Do NOT use solvents or thinners.
Eye
Irrigate copiously with clean fresh water for at least 10 minutes, holding the eyelids apart and seek medical
attention.
Ingestion
If accidentally swallowed obtain immediate medical attention. Keep at rest. Do NOT induce vomiting.
4.2. Most important symptoms and effects, both acute and delayed
No data available
4.3. Indication of any immediate medical attention and special treatment needed
No data available
Contain and absorb spillage with non-combustible materials e.g. sand, earth, vermiculite. Place in closed
containers outside buildings and dispose of according to the Waste Regulations. (See section 13).
If drains, sewers, streams or lakes are contaminated, inform the local water company immediately. In the
case of contamination of rivers, streams or lakes the Environmental Protection Agency should also be
informed.
In Storage
Handle containers carefully to prevent damage and spillage.
Naked flames and smoking should not be permitted in storage areas. It is recommended that fork lift trucks
and electrical equipment are protected to the appropriate standard.
Smoking, eating and drinking should be prohibited in all preparation and application areas.
Never use pressure to empty a container; containers are not pressure vessels.
Store in a well ventilated, dry place away from sources of heat and direct sunlight.
Store on concrete or other impervious floor, preferably with bunding to contain any spillage. Do not stack
more than 3 pallets high.
Keep container tightly closed. Containers which are opened must be carefully resealed and kept upright to
prevent leakage. Keep in the original container or one of the same material.
Material Short term (15 min. ave) Long term (8hr TWA) Comments
ppm mg/m3 ppm mg/m3
Butan-1-ol 50 154 - - +
Ethylbenzene 125 552 100 441 +
Xylene 100 441 50 220 +
DNEL/PNEC values
No Data Available
Eye/face protection
Wear safety eyewear, e.g. safety spectacles, goggles or visors to protect against the splash of liquids.
Eyewear should meet the requirements of standard EN 166.
Skin protection
For prolonged or repeated contact use protective gloves. Barrier creams may help to protect the exposed
areas of skin, they should however not be applied once exposure has occurred. Skin should be washed
after contact.
Use chemical resistant gloves classified under Standard EN 374: Protective gloves against chemicals and
micro-organisms. Recommended gloves: Viton® or Nitrile
Breakthrough Time: 480 min
When prolonged or frequently repeated contact may occur, a glove with a protection class of 6
(breakthrough time greater than 480 minutes according to EN 374) is recommended. When only brief
contact is expected, a glove with a protection class of 2 or higher (breakthrough time greater than 30
minutes according to EN 374) is recommended.
NOTICE: The selection of a specific glove for a particular application and duration of use in a workplace
should also take into account all relevant workplace factors such as, but not limited to: Other chemicals
which may be handled, physical requirements (cut/puncture protection, dexterity, thermal protection),
potential body reactions to glove materials, as well as the instructions/specifications provided by the glove
supplier.
The user must check that the final choice of type of glove selected for handling this product is the most
appropriate and takes into account the particular conditions of use, as included in the user's risk
assessment.
Other
Overalls which cover the body, arms and legs should be worn. Skin should not be exposed. Barrier creams
may help to protect areas which are difficult to cover such as the face and neck. They should however not
be applied once exposure has occurred. Petroleum jelly based types such as Vaseline should not be used.
All parts of the body should be washed after contact.
Respiratory protection
If workers are exposed to concentrations above the exposure limit they must use the appropriate,certified
respirators.For maximum protection when spraying this product it is recommended that a multi layer
combination type filter, such as ABEK1, is used. In confined spaces use compressed air or fresh air
respiratory equipment.
Thermal hazards
No Data Available
10.1. Reactivity
No data available
10.2. Chemical stability
Stable under recommended storage and handling conditions (see section 7).When exposed to high
temperatures may produce hazardous decomposition products such as carbon monoxide, carbon dioxide,
oxides of nitrogen and smoke.
Keep away from oxidising agents, strongly alkaline and strongly acid materials in order to avoid possible
exothermic reactions.
10.3. Possibility of hazardous reactions
May react exothermically with: oxidising agents, strong alkalis, strong acids.
10.4. Conditions to avoid
Stable under recommended storage and handling conditions (see section 7).
10.5. Incompatible materials
Keep away from the following materials: oxidising agents, strong alkalis, strong acids.
10.6. Hazardous decomposition products
Fire will produce dense black smoke. Decomposition products may include the following materials: carbon
monoxide, carbon dioxide, smoke, oxides of nitrogen.
Avoid exposure and use breathing apparatus as appropriate.
Acute toxicity
Exposure to solvent vapour concentrations from the component solvents in excess of the stated
occupational exposure limits may result in adverse health effects such as mucous membrane and
respiratory system irritation and adverse effects on the kidneys, liver and central nervous system.
Symptoms include headache, nausea, dizziness, fatigue, muscular weakness, drowsiness and in extreme
cases, loss of consciousness.
Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin
resulting in dryness, irritation and possible non-allergic contact dermatitis. Solvents may also be absorbed
through the skin. Splashes of liquid in the eyes may cause irritation and soreness with possible reversible
damage.
Amine based materials may cause skin irritation and sensitisation.
Inhalation
Inhalation
Oral LD50, Skin LD50, Dust/Mist
Ingredient Vapour LD50,
mg/kg mg/kg LD50,
mg/L/4hr
mg/L/4hr
2,4,6-Tris(dimethylaminomethyl)phenol - 1,200.00, Rat 1,280.00, Rat Not Available Not
(90-72-2) Available
Cashew nutshell liquid, polymer with EDA Not Available Not Available Not Available Not
and formaldehyde - (68413-28-5) Available
E96096 - (Not Available) Not Available Not Available Not Available Not
Available
12.1. Toxicity
The preparation has been assessed following the conventional method of the Dangerous Preparations
Directive 1999/45/EC and is not classified as dangerous for the environment
Aquatic Ecotoxicity
Using information provided in this data sheet advice should be obtained from the Waste Regulation
Authority, whether the special waste regulations apply.
The European Waste Catalogue Classification of this product, when disposed of as waste is 08 01 11
Waste paint and varnish containing organic solvents or other dangerous substances. If mixed with other
wastes this code may no longer apply and the appropriate code should be assigned. For further
information contact your local waste authority.
EmS F-E,S-E
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
EU Legislation
REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL on
classification, labelling and packaging of substances and mixtures, amending and repealing Directives
67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006.
IMPORTANT NOTE: the information contained in this data sheet (as may be amended from time to time) is
not intended to be exhaustive and is presented in good faith and believed to be correct as of the date on
which it is prepared. It is the user's responsibility to verify that this data sheet is current prior to using the
product to which it relates.
Persons using the information must make their own determinations as to the suitability of the relevant
product for their purposes prior to use. Where those purposes are other than as specifically recommended
in this safety data sheet, then the user uses the product at their own risk.
MANUFACTURER’S DISCLAIMER: the conditions, methods and factors affecting the handling, storage,
application, use and disposal of the product are not under the control and knowledge of the manufacturer.
Therefore the manufacturer does not assume responsibility for any adverse events which may occur in the
handling, storage, application, use, misuse or disposal of the product and, so far as permitted by applicable
law, the manufacturer expressly disclaims liability for any and all loss, damages and/or expenses arising
out of or in any way connected to the storage, handling, use or disposal of the product. Safe handling,
storage, use and disposal are the responsibility of the users. Users must comply with all applicable health
and safety laws.
Unless we have agreed to the contrary, all products are supplied by us subject to our standard terms and
conditions of business, which include limitations of liability. Please make sure to refer to these and / or the
relevant agreement which you have with AkzoNobel (or its affiliate, as the case may be).
© AkzoNobel
The information in this Health & Safety Data Sheet is required pursuant to EC Regulation 1907(2006) and
the Chemicals (Hazard Information & Packaging for Supply) Regulations 2009.
The full text of the R, H & EUH phrases appearing in section 3 is:
End of document
Your attention is drawn to the disclaimer on the Product Data Sheet which with this Safety Data
Sheet and the package labelling comprise an integral information system about this product. Copies
of the Product Data Sheet are available from International Paint on request or from our Internet
sites : www.yachtpaint.com , www.international-marine.com, www.international-pc.com
International Paint Ltd.
R10 Flammable.
Harmful to aquatic organisms, may cause long-term adverse effects in the
R52/53
aquatic environment.
Contains:
R10 Flammable.
R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
P. Phrases;
Contains Fatty acids, C18 unsatd trimers compds. with oleylamine. May produce an allergic reaction.
If the product contains substances that present a health hazard within the meaning of the Dangerous
Substances Directive 67/548/EC, or have occupational exposure limits detailed in EH40, these substances
are listed below.
67/548/EEC EC No. 1272/2008
Ingredient/Chemical Designations Weight % Notes
Classification Classification
Solvent naphtha (petroleum), light 2.5 - < 10 Xn;R65 N; R51/53 (Self Asp. Tox. 1;H304 H; P
aromatic Classification) Aquatic Chronic [1]
CAS Number: 0064742-95-6 2;H411 (Self
EC No. 265-199-0 Classification)
Index No.: 649-356-00-4
REACH Reg. No.:
1,2,4-trimethylbenzene 2.5 - < 10 R10 Xn;R20 Flam. Liq. 3;H226
CAS Number: 0000095-63-6 Xi;R36/37/38 N;R51-53 Acute Tox. 4;H332 [1][2]
EC No. 202-436-9 Eye Irrit. 2;H319
Index No.: 601-043-00-3 STOT SE 3;H335
REACH Reg. No.: Skin Irrit. 2;H315
Aquatic Chronic
2;H411
Xylene 2.5 - < 10 R10 Xn;R20/21 Xi;R38 Flam. Liq. 3;H226 C
CAS Number: 0001330-20-7 Acute Tox. 4;H332 [1][2]
EC No. 215-535-7 Acute Tox. 4;H312
Index No.: 601-022-00-9 Skin Irrit. 2;H315
REACH Reg. No.:
1-Methoxy-2-propyl acetate 1 - < 2.5 R10 Flam. Liq. 3;H226
CAS Number: 0000108-65-6 [1]
EC No. 203-603-9
Index No.: 607-195-00-7
REACH Reg. No.:
1,3,5-trimethylbenzene 1 - < 2.5 R10 Xi;R37 N;R51-53 Flam. Liq. 3;H226
CAS Number: 0000108-67-8 STOT SE 3;H335 [1]
EC No. 203-604-4 Aquatic Chronic
Index No.: 601-025-00-5 2;H411
REACH Reg. No.:
Fatty acids, C18 unsatd trimers 0-<1 T; R48/25 Xi; R43 N; STOT RE 1;H372
compds. with oleylamine R51/53 Skin Sens. 1;H317 [1]
CAS Number: 0147900-93-4 Aquatic Chronic
EC No. 2;H411
Index No.:
REACH Reg. No.:
[1] Substance classified with a health or environmental hazard.
[2] Substance with a workplace exposure limit.
[3] PBT-substance or vPvB-substance.
Skin
Remove contaminated clothing. Wash skin thoroughly with soap and water or use a recognised skin
cleanser. Do NOT use solvents or thinners.
Eye
Irrigate copiously with clean fresh water for at least 10 minutes, holding the eyelids apart and seek medical
attention.
Ingestion
If accidentally swallowed obtain immediate medical attention. Keep at rest. Do NOT induce vomiting.
4.2. Most important symptoms and effects, both acute and delayed
No data available
4.3. Indication of any immediate medical attention and special treatment needed
No data available
Contain and absorb spillage with non-combustible materials e.g. sand, earth, vermiculite. Place in closed
containers outside buildings and dispose of according to the Waste Regulations. (See section 13).
Clean, preferably with a detergent. Do not use solvents.
If drains, sewers, streams or lakes are contaminated, inform the local water company immediately. In the
case of contamination of rivers, streams or lakes the Environmental Protection Agency should also be
informed.
In Storage
Handle containers carefully to prevent damage and spillage.
Naked flames and smoking should not be permitted in storage areas. It is recommended that fork lift trucks
and electrical equipment are protected to the appropriate standard.
Smoking, eating and drinking should be prohibited in all preparation and application areas.
Never use pressure to empty a container; containers are not pressure vessels.
Store in a well ventilated, dry place away from sources of heat and direct sunlight.
Store on concrete or other impervious floor, preferably with bunding to contain any spillage. Do not stack
more than 3 pallets high.
Keep container tightly closed. Containers which are opened must be carefully resealed and kept upright to
prevent leakage. Keep in the original container or one of the same material.
Material Short term (15 min. ave) Long term (8hr TWA) Comments
ppm mg/m3 ppm mg/m3
1,2,4-trimethylbenzene 25 125
1,3,5-trimethylbenzene 25 125
1-Methoxy-2-propyl acetate 100 548 50 274 +
Xylene 100 441 50 220 +
For Key to entries in 'Comments' column see Section 16
DNEL/PNEC values
No Data Available
Eye/face protection
Wear safety eyewear, e.g. safety spectacles, goggles or visors to protect against the splash of liquids.
Eyewear should meet the requirements of standard EN 166.
Skin protection
For prolonged or repeated contact use protective gloves. Barrier creams may help to protect the exposed
areas of skin, they should however not be applied once exposure has occurred. Skin should be washed
after contact.
Use chemical resistant gloves classified under Standard EN 374: Protective gloves against chemicals and
micro-organisms. Recommended gloves: Viton® or Nitrile
Breakthrough Time: 480 min
When prolonged or frequently repeated contact may occur, a glove with a protection class of 6
(breakthrough time greater than 480 minutes according to EN 374) is recommended. When only brief
contact is expected, a glove with a protection class of 2 or higher (breakthrough time greater than 30
minutes according to EN 374) is recommended.
NOTICE: The selection of a specific glove for a particular application and duration of use in a workplace
should also take into account all relevant workplace factors such as, but not limited to: Other chemicals
which may be handled, physical requirements (cut/puncture protection, dexterity, thermal protection),
potential body reactions to glove materials, as well as the instructions/specifications provided by the glove
supplier.
The user must check that the final choice of type of glove selected for handling this product is the most
appropriate and takes into account the particular conditions of use, as included in the user's risk
assessment.
Other
Overalls which cover the body, arms and legs should be worn. Skin should not be exposed. Barrier creams
may help to protect areas which are difficult to cover such as the face and neck. They should however not
be applied once exposure has occurred. Petroleum jelly based types such as Vaseline should not be used.
All parts of the body should be washed after contact.
Respiratory protection
If workers are exposed to concentrations above the exposure limit they must use the appropriate,certified
respirators.For maximum protection when spraying this product it is recommended that a multi layer
combination type filter, such as ABEK1, is used. In confined spaces use compressed air or fresh air
respiratory equipment.
Thermal hazards
No Data Available
10.1. Reactivity
No data available
10.2. Chemical stability
Stable under recommended storage and handling conditions (see section 7).When exposed to high
temperatures may produce hazardous decomposition products such as carbon monoxide, carbon dioxide,
oxides of nitrogen and smoke.
Keep away from oxidising agents, strongly alkaline and strongly acid materials in order to avoid possible
exothermic reactions.
10.3. Possibility of hazardous reactions
May react exothermically with: oxidising agents, strong alkalis, strong acids.
10.4. Conditions to avoid
Stable under recommended storage and handling conditions (see section 7).
10.5. Incompatible materials
Keep away from the following materials: oxidising agents, strong alkalis, strong acids.
10.6. Hazardous decomposition products
Fire will produce dense black smoke. Decomposition products may include the following materials: carbon
monoxide, carbon dioxide, smoke, oxides of nitrogen.
Avoid exposure and use breathing apparatus as appropriate.
Acute toxicity
Exposure to solvent vapour concentrations from the component solvents in excess of the stated
occupational exposure limits may result in adverse health effects such as mucous membrane and
respiratory system irritation and adverse effects on the kidneys, liver and central nervous system.
Symptoms include headache, nausea, dizziness, fatigue, muscular weakness, drowsiness and in extreme
cases, loss of consciousness.
Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin
resulting in dryness, irritation and possible non-allergic contact dermatitis. Solvents may also be absorbed
through the skin. Splashes of liquid in the eyes may cause irritation and soreness with possible reversible
damage.
Inhalation
Inhalation
Oral LD50, Skin LD50, Dust/Mist
Ingredient Vapour LD50,
mg/kg mg/kg LD50,
mg/L/4hr
mg/L/4hr
1,2,4-trimethylbenzene - (95-63-6) 3,400.00, Rat 3,160.00, Rabbit 18.00, Rat Not
Available
1-Methoxy-2-propyl acetate - (108-65-6) 8,532.00, Rat 5,000.00, Rabbit Not Available Not
Available
Fatty acids, C18 unsatd trimers compds. Not Available Not Available Not Available Not
with oleylamine - (147900-93-4) Available
Solvent naphtha (petroleum), light 6,800.00, Rat 3,400.00, Rabbit Not Available Not
aromatic - (64742-95-6) Available
12.1. Toxicity
The preparation has been assessed following the conventional method of the Dangerous Preparations
Directive 1999/45/EC and is classified for eco-toxicological properties accordingly. See Sections 2 and 3
for details.
Aquatic Ecotoxicity
Using information provided in this data sheet advice should be obtained from the Waste Regulation
Authority, whether the special waste regulations apply.
The European Waste Catalogue Classification of this product, when disposed of as waste is 08 01 11
Waste paint and varnish containing organic solvents or other dangerous substances. If mixed with other
wastes this code may no longer apply and the appropriate code should be assigned. For further
information contact your local waste authority.
EmS F-E,S-E
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
EU Legislation
REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL on
classification, labelling and packaging of substances and mixtures, amending and repealing Directives
67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006.
IMPORTANT NOTE: the information contained in this data sheet (as may be amended from time to time) is
not intended to be exhaustive and is presented in good faith and believed to be correct as of the date on
which it is prepared. It is the user's responsibility to verify that this data sheet is current prior to using the
product to which it relates.
Persons using the information must make their own determinations as to the suitability of the relevant
product for their purposes prior to use. Where those purposes are other than as specifically recommended
in this safety data sheet, then the user uses the product at their own risk.
MANUFACTURER’S DISCLAIMER: the conditions, methods and factors affecting the handling, storage,
application, use and disposal of the product are not under the control and knowledge of the manufacturer.
Therefore the manufacturer does not assume responsibility for any adverse events which may occur in the
handling, storage, application, use, misuse or disposal of the product and, so far as permitted by applicable
law, the manufacturer expressly disclaims liability for any and all loss, damages and/or expenses arising
out of or in any way connected to the storage, handling, use or disposal of the product. Safe handling,
storage, use and disposal are the responsibility of the users. Users must comply with all applicable health
and safety laws.
Unless we have agreed to the contrary, all products are supplied by us subject to our standard terms and
conditions of business, which include limitations of liability. Please make sure to refer to these and / or the
relevant agreement which you have with AkzoNobel (or its affiliate, as the case may be).
© AkzoNobel
The information in this Health & Safety Data Sheet is required pursuant to EC Regulation 1907(2006) and
the Chemicals (Hazard Information & Packaging for Supply) Regulations 2009.
This is the first revision of this SDS format, changes from previous revision not applicable.
End of document
Your attention is drawn to the disclaimer on the Product Data Sheet which with this Safety Data
Sheet and the package labelling comprise an integral information system about this product. Copies
of the Product Data Sheet are available from International Paint on request or from our Internet
sites : www.yachtpaint.com , www.international-marine.com, www.international-pc.com
International Paint Ltd.
R10 Flammable.
R20 Harmful by inhalation.
R37 Irritating to respiratory system.
R43 May cause sensitisation by skin contact.
Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
R51/53
environment.
2.2. Label elements
According to 1999/45/EC
P. Phrases;
Contains isocyanates. See information supplied by the manufacturer.
If the product contains substances that present a health hazard within the meaning of the Dangerous
Substances Directive 67/548/EC, or have occupational exposure limits detailed in EH40, these substances
are listed below.
67/548/EEC EC No. 1272/2008
Ingredient/Chemical Designations Weight % Notes
Classification Classification
Hdi homopolymer 50 - 100 Xn; R20 Xi; R37 R43 Skin Sens. 1;H317
CAS Number: 0028182-81-2 Acute Tox. 4;H332 [1]
EC No. 500-060-2 STOT SE 3;H335
Index No.:
REACH Reg. No.: 01-2119485796-
17-xxxx
Solvent naphtha (petroleum), light 25 - < 50 Xn;R65 N; R51/53 (Self Asp. Tox. 1;H304 H; P
aromatic Classification) Aquatic Chronic [1]
CAS Number: 0064742-95-6 2;H411 (Self
EC No. 265-199-0 Classification)
Index No.: 649-356-00-4
REACH Reg. No.:
Hexamethylene-1,6-diisocyanate 0-<1 T;R23 R42/43 Acute Tox. 3;H331 2
CAS Number: 0000822-06-0 Xi;R36/37/38 Eye Irrit. 2;H319 [1][2]
EC No. 212-485-8 STOT SE 3;H335
Index No.: 615-011-00-1 Skin Irrit. 2;H315
REACH Reg. No.: Resp. Sens. 1;H334
Skin Sens. 1;H317
Skin
Remove contaminated clothing. Wash skin thoroughly with soap and water or use a recognised skin
cleanser. Do NOT use solvents or thinners.
Eye
Irrigate copiously with clean fresh water for at least 10 minutes, holding the eyelids apart and seek medical
attention.
Ingestion
If accidentally swallowed obtain immediate medical attention. Keep at rest. Do NOT induce vomiting.
4.2. Most important symptoms and effects, both acute and delayed
No data available
4.3. Indication of any immediate medical attention and special treatment needed
No data available
Examination of lung function should be carried out on a regular basis on persons spraying this preparation.
In Storage
Handle containers carefully to prevent damage and spillage.
Naked flames and smoking should not be permitted in storage areas. It is recommended that fork lift trucks
and electrical equipment are protected to the appropriate standard.
Precautions should be taken to minimise exposure to atmospheric humidity or water as carbon dioxide
may be formed which, in closed containers can result in pressurisation. Care should be taken when re-
opening partly used containers.
Smoking, eating and drinking should be prohibited in all preparation and application areas.
Never use pressure to empty a container; containers are not pressure vessels.
Store in a well ventilated, dry place away from sources of heat and direct sunlight.
Store on concrete or other impervious floor, preferably with bunding to contain any spillage. Do not stack
more than 3 pallets high.
Keep container tightly closed. Containers which are opened must be carefully resealed and kept upright to
prevent leakage. Keep in the original container or one of the same material.
Material Short term (15 min. ave) Long term (8hr TWA) Comments
ppm mg/m3 ppm mg/m3
Hexamethylene-1,6-diisocyanate - 0.07 - 0.02 (as-NCO) S
DNEL/PNEC values
No Data Available
Persons with a history of asthma, allergies, chronic or recurrent respiratory disease should not be
employed in any process in which this preparation is used.
Examination of lung function should be carried out on a regular basis on persons spraying this preparation.
Eye/face protection
Wear safety eyewear, e.g. safety spectacles, goggles or visors to protect against the splash of liquids.
Eyewear should meet the requirements of standard EN 166.
Skin protection
For prolonged or repeated contact use protective gloves. Barrier creams may help to protect the exposed
areas of skin, they should however not be applied once exposure has occurred. Skin should be washed
after contact.
Use chemical resistant gloves classified under Standard EN 374: Protective gloves against chemicals and
micro-organisms. Recommended gloves: Viton® or Nitrile
Breakthrough Time: 480 min
When prolonged or frequently repeated contact may occur, a glove with a protection class of 6
(breakthrough time greater than 480 minutes according to EN 374) is recommended. When only brief
contact is expected, a glove with a protection class of 2 or higher (breakthrough time greater than 30
minutes according to EN 374) is recommended.
NOTICE: The selection of a specific glove for a particular application and duration of use in a workplace
should also take into account all relevant workplace factors such as, but not limited to: Other chemicals
which may be handled, physical requirements (cut/puncture protection, dexterity, thermal protection),
potential body reactions to glove materials, as well as the instructions/specifications provided by the glove
supplier.
The user must check that the final choice of type of glove selected for handling this product is the most
appropriate and takes into account the particular conditions of use, as included in the user's risk
assessment.
Other
Overalls which cover the body, arms and legs should be worn. Skin should not be exposed. Barrier creams
may help to protect areas which are difficult to cover such as the face and neck. They should however not
be applied once exposure has occurred. Petroleum jelly based types such as Vaseline should not be used.
All parts of the body should be washed after contact.
Respiratory protection
By spraying: air fed respirator.
By other operations than spraying: for situations where the atmospheric levels may exceed the level for
which an air-purifying respirator is effective, use a positive-pressure air-supplying respirator (air line or self-
contained breathing apparatus).
For emergency response or for situations where the atmospheric level is unknown, use an approved
positive-pressure self contained breathing apparatus or positive-pressure air line with auxiliary self-
contained air supply.
Thermal hazards
No Data Available
10.1. Reactivity
No data available
10.2. Chemical stability
Stable under recommended storage and handling conditions (see section 7). In a fire, hazardous
decomposition products such as smoke, carbon monoxide, carbon dioxide, oxides of nitrogen, hydrogen
cyanide may be produced.
Keep away from oxidising agents, strongly alkaline and strongly acid materials, amines, alcohols and
water. Uncontrolled exothermic reactions occur with amines and alcohols. The product reacts slowly with
water resulting in evolution of carbon dioxide. In closed containers, pressure build up could result in
distortion,blowing and in extreme cases bursting of the container.
10.3. Possibility of hazardous reactions
May react exothermically with: oxidising agents, strong alkalis, strong acids.
10.4. Conditions to avoid
Stable under recommended storage and handling conditions (see section 7).
10.5. Incompatible materials
Keep away from the following materials: oxidising agents, strong alkalis, strong acids.
10.6. Hazardous decomposition products
Fire will produce dense black smoke. Decomposition products may include the following materials: carbon
monoxide, carbon dioxide, smoke, oxides of nitrogen.
Avoid exposure and use breathing apparatus as appropriate.
Acute toxicity
Exposure to solvent vapour concentrations from the component solvents in excess of the stated
occupational exposure limits may result in adverse health effects such as mucous membrane and
respiratory system irritation and adverse effects on the kidneys, liver and central nervous system.
Symptoms include headache, nausea, dizziness, fatigue, muscular weakness, drowsiness and in extreme
cases, loss of consciousness.
Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin
resulting in dryness, irritation and possible non-allergic contact dermatitis. Solvents may also be absorbed
through the skin. Splashes of liquid in the eyes may cause irritation and soreness with possible reversible
damage.
Based on the properties of the isocyanate content of this product, respiratory exposure may cause acute
irritation and/or sensitisation of the respiratory system resulting in asthmatic symptoms, wheezing and a
tightness of the chest. Sensitised persons may subsequently show asthmatic symptoms when exposed to
airborne concentrations of isocyanates well below the occupational exposure limit. Repeated exposure
may lead to permanent respiratory disability.
Inhalation
Inhalation
Oral LD50, Skin LD50, Dust/Mist
Ingredient Vapour LD50,
mg/kg mg/kg LD50,
mg/L/4hr
mg/L/4hr
Hdi homopolymer - (28182-81-2) 5,000.00, Rat Not Available Not Available
3.00, Rat
Solvent naphtha (petroleum), light 6,800.00, Rat 3,400.00, Rabbit Not Available Not
aromatic - (64742-95-6) Available
12.1. Toxicity
The preparation has been assessed following the conventional method of the Dangerous Preparations
Directive 1999/45/EC and is classified for eco-toxicological properties accordingly. See Sections 2 and 3
for details.
Using information provided in this data sheet advice should be obtained from the Waste Regulation
Authority, whether the special waste regulations apply.
The European Waste Catalogue Classification of this product, when disposed of as waste is 08 01 11
Waste paint and varnish containing organic solvents or other dangerous substances. If mixed with other
wastes this code may no longer apply and the appropriate code should be assigned. For further
information contact your local waste authority.
EmS F-E,S-E
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
EU Legislation
REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL on
classification, labelling and packaging of substances and mixtures, amending and repealing Directives
67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006.
IMPORTANT NOTE: the information contained in this data sheet (as may be amended from time to time) is
not intended to be exhaustive and is presented in good faith and believed to be correct as of the date on
which it is prepared. It is the user's responsibility to verify that this data sheet is current prior to using the
product to which it relates.
Persons using the information must make their own determinations as to the suitability of the relevant
product for their purposes prior to use. Where those purposes are other than as specifically recommended
in this safety data sheet, then the user uses the product at their own risk.
MANUFACTURER’S DISCLAIMER: the conditions, methods and factors affecting the handling, storage,
application, use and disposal of the product are not under the control and knowledge of the manufacturer.
Therefore the manufacturer does not assume responsibility for any adverse events which may occur in the
handling, storage, application, use, misuse or disposal of the product and, so far as permitted by applicable
law, the manufacturer expressly disclaims liability for any and all loss, damages and/or expenses arising
out of or in any way connected to the storage, handling, use or disposal of the product. Safe handling,
storage, use and disposal are the responsibility of the users. Users must comply with all applicable health
and safety laws.
Unless we have agreed to the contrary, all products are supplied by us subject to our standard terms and
conditions of business, which include limitations of liability. Please make sure to refer to these and / or the
relevant agreement which you have with AkzoNobel (or its affiliate, as the case may be).
© AkzoNobel
The information in this Health & Safety Data Sheet is required pursuant to EC Regulation 1907(2006) and
the Chemicals (Hazard Information & Packaging for Supply) Regulations 2009.
The full text of the R, H & EUH phrases appearing in section 3 is:
End of document
Your attention is drawn to the disclaimer on the Product Data Sheet which with this Safety Data
Sheet and the package labelling comprise an integral information system about this product. Copies
of the Product Data Sheet are available from International Paint on request or from our Internet
sites : www.yachtpaint.com , www.international-marine.com, www.international-pc.com
International Paint Ltd.
P. Phrases;
If the product contains substances that present a health hazard within the meaning of the Dangerous
Substances Directive 67/548/EC, or have occupational exposure limits detailed in EH40, these substances
are listed below.
67/548/EEC EC No. 1272/2008
Ingredient/Chemical Designations Weight % Notes
Classification Classification
Zinc 25 - < 50 N;R50-53 Aquatic Acute 1;H400
CAS Number: 0007440-66-6 Aquatic Chronic [1]
EC No. 231-175-3 1;H410
Index No.: 030-001-01-9
REACH Reg. No.: 01-2119467174-
37-xxxx
Quartz 10 - < 25 Xn;R48/20 Acute Tox. 4;H332
CAS Number: 0014808-60-7 STOT RE 2;H373 [1][2]
EC No. 238-878-4
Index No.:
REACH Reg. No.:
Xylene 10 - < 25 R10 Xn;R20/21 Xi;R38 Flam. Liq. 3;H226 C
CAS Number: 0001330-20-7 Acute Tox. 4;H332 [1][2]
EC No. 215-535-7 Acute Tox. 4;H312
Index No.: 601-022-00-9 Skin Irrit. 2;H315
REACH Reg. No.:
Propan-2-ol 2.5 - < 10 F;R11 Xi;R36 R67 Flam. Liq. 2;H225
CAS Number: 0000067-63-0 Eye Irrit. 2;H319 [1][2]
EC No. 200-661-7 STOT SE 3;H336
Index No.: 603-117-00-0
REACH Reg. No.: 01-2119457558-
25-xxxx
Ethylbenzene 2.5 - < 10 F;R11 Xn;R20 Flam. Liq. 2;H225
CAS Number: 0000100-41-4 Acute Tox. 4;H332 [1][2]
EC No. 202-849-4
Index No.: 601-023-00-4
REACH Reg. No.:
1-methoxypropan-2-ol 2.5 - < 10 R10 R67 Flam. Liq. 3;H226
CAS Number: 0000107-98-2 STOT SE 3;H336 [1][2]
EC No. 203-539-1
Index No.: 603-064-00-3
REACH Reg. No.: 01-2119457435-
35-xxxx
Zinc oxide 1 - < 2.5 N;R50/53 Aquatic Acute 1;H400
CAS Number: 0001314-13-2 Aquatic Chronic [1][2]
EC No. 215-222-5 1;H410
Index No.: 030-013-00-7
REACH Reg. No.: 01-2119463881-
32-xxxx
[1] Substance classified with a health or environmental hazard.
[2] Substance with a workplace exposure limit.
[3] PBT-substance or vPvB-substance.
Skin
Remove contaminated clothing. Wash skin thoroughly with soap and water or use a recognised skin
cleanser. Do NOT use solvents or thinners.
Eye
Irrigate copiously with clean fresh water for at least 10 minutes, holding the eyelids apart and seek medical
attention.
Ingestion
If accidentally swallowed obtain immediate medical attention. Keep at rest. Do NOT induce vomiting.
4.2. Most important symptoms and effects, both acute and delayed
No data available
4.3. Indication of any immediate medical attention and special treatment needed
No data available
Contain and absorb spillage with non-combustible materials e.g. sand, earth, vermiculite. Place in closed
containers outside buildings and dispose of according to the Waste Regulations. (See section 13).
If drains, sewers, streams or lakes are contaminated, inform the local water company immediately. In the
case of contamination of rivers, streams or lakes the Environmental Protection Agency should also be
informed.
In Storage
Handle containers carefully to prevent damage and spillage.
Naked flames and smoking should not be permitted in storage areas. It is recommended that fork lift trucks
and electrical equipment are protected to the appropriate standard.
Smoking, eating and drinking should be prohibited in all preparation and application areas.
Never use pressure to empty a container; containers are not pressure vessels.
Store in a well ventilated, dry place away from sources of heat and direct sunlight.
Store on concrete or other impervious floor, preferably with bunding to contain any spillage. Do not stack
more than 3 pallets high.
Keep container tightly closed. Containers which are opened must be carefully resealed and kept upright to
prevent leakage. Keep in the original container or one of the same material.
Prevent unauthorised access.
Material Short term (15 min. ave) Long term (8hr TWA) Comments
ppm mg/m3 ppm mg/m3
1-methoxypropan-2-ol 150 560 100 375 +
Ethylbenzene 125 552 100 441 +
Propan-2-ol 500 1250 400 999
Quartz - - - 0.1
Xylene 100 441 50 220 +
DNEL/PNEC values
No Data Available
Eye/face protection
Wear safety eyewear, e.g. safety spectacles, goggles or visors to protect against the splash of liquids.
Eyewear should meet the requirements of standard EN 166.
Skin protection
For prolonged or repeated contact use protective gloves. Barrier creams may help to protect the exposed
areas of skin, they should however not be applied once exposure has occurred. Skin should be washed
after contact.
Use chemical resistant gloves classified under Standard EN 374: Protective gloves against chemicals and
micro-organisms. Recommended gloves: Viton® or Nitrile
Breakthrough Time: 480 min
When prolonged or frequently repeated contact may occur, a glove with a protection class of 6
(breakthrough time greater than 480 minutes according to EN 374) is recommended. When only brief
contact is expected, a glove with a protection class of 2 or higher (breakthrough time greater than 30
minutes according to EN 374) is recommended.
NOTICE: The selection of a specific glove for a particular application and duration of use in a workplace
should also take into account all relevant workplace factors such as, but not limited to: Other chemicals
which may be handled, physical requirements (cut/puncture protection, dexterity, thermal protection),
potential body reactions to glove materials, as well as the instructions/specifications provided by the glove
supplier.
The user must check that the final choice of type of glove selected for handling this product is the most
appropriate and takes into account the particular conditions of use, as included in the user's risk
assessment.
Other
Overalls which cover the body, arms and legs should be worn. Skin should not be exposed. Barrier creams
may help to protect areas which are difficult to cover such as the face and neck. They should however not
be applied once exposure has occurred. Petroleum jelly based types such as Vaseline should not be used.
All parts of the body should be washed after contact.
Respiratory protection
If workers are exposed to concentrations above the exposure limit they must use the appropriate,certified
respirators.For maximum protection when spraying this product it is recommended that a multi layer
combination type filter, such as ABEK1, is used. In confined spaces use compressed air or fresh air
respiratory equipment.
Thermal hazards
No Data Available
10.1. Reactivity
No data available
10.2. Chemical stability
Stable under recommended storage and handling conditions (see section 7).When exposed to high
temperatures may produce hazardous decomposition products such as carbon monoxide, carbon dioxide,
oxides of nitrogen and smoke.
Keep away from oxidising agents, strongly alkaline and strongly acid materials in order to avoid possible
exothermic reactions.
10.3. Possibility of hazardous reactions
May react exothermically with: oxidising agents, strong alkalis, strong acids.
10.4. Conditions to avoid
Stable under recommended storage and handling conditions (see section 7).
10.5. Incompatible materials
Keep away from the following materials: oxidising agents, strong alkalis, strong acids.
10.6. Hazardous decomposition products
Fire will produce dense black smoke. Decomposition products may include the following materials: carbon
monoxide, carbon dioxide, smoke, oxides of nitrogen.
Avoid exposure and use breathing apparatus as appropriate.
Acute toxicity
Exposure to solvent vapour concentrations from the component solvents in excess of the stated
occupational exposure limits may result in adverse health effects such as mucous membrane and
respiratory system irritation and adverse effects on the kidneys, liver and central nervous system.
Symptoms include headache, nausea, dizziness, fatigue, muscular weakness, drowsiness and in extreme
cases, loss of consciousness.
Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin
resulting in dryness, irritation and possible non-allergic contact dermatitis. Solvents may also be absorbed
through the skin. Splashes of liquid in the eyes may cause irritation and soreness with possible reversible
damage.
Inhalation
Inhalation
Oral LD50, Skin LD50, Dust/Mist
Ingredient Vapour LD50,
mg/kg mg/kg LD50,
mg/L/4hr
mg/L/4hr
1-methoxypropan-2-ol - (107-98-2) 5,000.00, Rat 13,000.00, Rabbit Not Available Not
Available
Ethylbenzene - (100-41-4) 3,500.00, Rat 15,433.00, Rabbit 17.20, Rat Not
Available
Propan-2-ol - (67-63-0) 4,710.00, Rat 12,800.00, Rat 72.60, Rat Not
Available
Quartz - (14808-60-7) Not Available Not Available Not Available Not
Available
Xylene - (1330-20-7) 4,299.00, Rat 1,548.00, Rabbit 20.00, Rat Not
Available
Zinc - (7440-66-6) Not Available Not Available Not Available Not
Available
Zinc oxide - (1314-13-2) 5,000.00, Rat Not Available Not Available
2.50, Mouse
12.1. Toxicity
The preparation has been assessed following the conventional method of the Dangerous Preparations
Directive 1999/45/EC and is classified for eco-toxicological properties accordingly. See Sections 2 and 3
for details.
Using information provided in this data sheet advice should be obtained from the Waste Regulation
Authority, whether the special waste regulations apply.
The European Waste Catalogue Classification of this product, when disposed of as waste is 08 01 11
Waste paint and varnish containing organic solvents or other dangerous substances. If mixed with other
wastes this code may no longer apply and the appropriate code should be assigned. For further
information contact your local waste authority.
EmS F-E,S-E
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
EU Legislation
REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL on
classification, labelling and packaging of substances and mixtures, amending and repealing Directives
67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006.
IMPORTANT NOTE: the information contained in this data sheet (as may be amended from time to time) is
not intended to be exhaustive and is presented in good faith and believed to be correct as of the date on
which it is prepared. It is the user's responsibility to verify that this data sheet is current prior to using the
product to which it relates.
Persons using the information must make their own determinations as to the suitability of the relevant
product for their purposes prior to use. Where those purposes are other than as specifically recommended
in this safety data sheet, then the user uses the product at their own risk.
MANUFACTURER’S DISCLAIMER: the conditions, methods and factors affecting the handling, storage,
application, use and disposal of the product are not under the control and knowledge of the manufacturer.
Therefore the manufacturer does not assume responsibility for any adverse events which may occur in the
handling, storage, application, use, misuse or disposal of the product and, so far as permitted by applicable
law, the manufacturer expressly disclaims liability for any and all loss, damages and/or expenses arising
out of or in any way connected to the storage, handling, use or disposal of the product. Safe handling,
storage, use and disposal are the responsibility of the users. Users must comply with all applicable health
and safety laws.
Unless we have agreed to the contrary, all products are supplied by us subject to our standard terms and
conditions of business, which include limitations of liability. Please make sure to refer to these and / or the
relevant agreement which you have with AkzoNobel (or its affiliate, as the case may be).
© AkzoNobel
The information in this Health & Safety Data Sheet is required pursuant to EC Regulation 1907(2006) and
the Chemicals (Hazard Information & Packaging for Supply) Regulations 2009.
The full text of the R, H & EUH phrases appearing in section 3 is:
End of document
Your attention is drawn to the disclaimer on the Product Data Sheet which with this Safety Data
Sheet and the package labelling comprise an integral information system about this product. Copies
of the Product Data Sheet are available from International Paint on request or from our Internet
sites : www.yachtpaint.com , www.international-marine.com, www.international-pc.com
International Paint Ltd.
Contains:
R11 Highly flammable.
R36 Irritating to eyes.
R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R67 Vapours may cause drowsiness and dizziness.
P. Phrases;
If the product contains substances that present a health hazard within the meaning of the Dangerous
Substances Directive 67/548/EC, or have occupational exposure limits detailed in EH40, these substances
are listed below.
67/548/EEC EC No. 1272/2008
Ingredient/Chemical Designations Weight % Notes
Classification Classification
Propan-2-ol 50 - 100 F;R11 Xi;R36 R67 Flam. Liq. 2;H225
CAS Number: 0000067-63-0 Eye Irrit. 2;H319 [1][2]
EC No. 200-661-7 STOT SE 3;H336
Index No.: 603-117-00-0
REACH Reg. No.: 01-2119457558-
25-xxxx
Ethanol 10 - < 25 F;R11 Flam. Liq. 2;H225
CAS Number: 0000064-17-5 [1][2]
EC No. 200-578-6
Index No.: 603-002-00-5
REACH Reg. No.:
[1] Substance classified with a health or environmental hazard.
[2] Substance with a workplace exposure limit.
[3] PBT-substance or vPvB-substance.
Skin
Remove contaminated clothing. Wash skin thoroughly with soap and water or use a recognised skin
cleanser. Do NOT use solvents or thinners.
Eye
Irrigate copiously with clean fresh water for at least 10 minutes, holding the eyelids apart and seek medical
attention.
Ingestion
If accidentally swallowed obtain immediate medical attention. Keep at rest. Do NOT induce vomiting.
4.2. Most important symptoms and effects, both acute and delayed
No data available
4.3. Indication of any immediate medical attention and special treatment needed
No data available
Contain and absorb spillage with non-combustible materials e.g. sand, earth, vermiculite. Place in closed
containers outside buildings and dispose of according to the Waste Regulations. (See section 13).
If drains, sewers, streams or lakes are contaminated, inform the local water company immediately. In the
case of contamination of rivers, streams or lakes the Environmental Protection Agency should also be
informed.
SECTION 7: Handling and storage
In Storage
Handle containers carefully to prevent damage and spillage.
Naked flames and smoking should not be permitted in storage areas. It is recommended that fork lift trucks
and electrical equipment are protected to the appropriate standard.
Smoking, eating and drinking should be prohibited in all preparation and application areas.
Never use pressure to empty a container; containers are not pressure vessels.
Store in a well ventilated, dry place away from sources of heat and direct sunlight.
Store on concrete or other impervious floor, preferably with bunding to contain any spillage. Do not stack
more than 3 pallets high.
Keep container tightly closed. Containers which are opened must be carefully resealed and kept upright to
prevent leakage. Keep in the original container or one of the same material.
Material Short term (15 min. ave) Long term (8hr TWA) Comments
ppm mg/m3 ppm mg/m3
Ethanol - - 1000 1920
Propan-2-ol 500 1250 400 999
DNEL/PNEC values
No Data Available
Skin protection
For prolonged or repeated contact use protective gloves. Barrier creams may help to protect the exposed
areas of skin, they should however not be applied once exposure has occurred. Skin should be washed
after contact.
Use chemical resistant gloves classified under Standard EN 374: Protective gloves against chemicals and
micro-organisms. Recommended gloves: Viton® or Nitrile
Breakthrough Time: 480 min
When prolonged or frequently repeated contact may occur, a glove with a protection class of 6
(breakthrough time greater than 480 minutes according to EN 374) is recommended. When only brief
contact is expected, a glove with a protection class of 2 or higher (breakthrough time greater than 30
minutes according to EN 374) is recommended.
NOTICE: The selection of a specific glove for a particular application and duration of use in a workplace
should also take into account all relevant workplace factors such as, but not limited to: Other chemicals
which may be handled, physical requirements (cut/puncture protection, dexterity, thermal protection),
potential body reactions to glove materials, as well as the instructions/specifications provided by the glove
supplier.
The user must check that the final choice of type of glove selected for handling this product is the most
appropriate and takes into account the particular conditions of use, as included in the user's risk
assessment.
Other
Overalls which cover the body, arms and legs should be worn. Skin should not be exposed. Barrier creams
may help to protect areas which are difficult to cover such as the face and neck. They should however not
be applied once exposure has occurred. Petroleum jelly based types such as Vaseline should not be used.
All parts of the body should be washed after contact.
Respiratory protection
If workers are exposed to concentrations above the exposure limit they must use the appropriate,certified
respirators.For maximum protection when spraying this product it is recommended that a multi layer
combination type filter, such as ABEK1, is used. In confined spaces use compressed air or fresh air
respiratory equipment.
Thermal hazards
No Data Available
10.1. Reactivity
No data available
10.2. Chemical stability
Stable under recommended storage and handling conditions (see section 7).When exposed to high
temperatures may produce hazardous decomposition products such as carbon monoxide, carbon dioxide,
oxides of nitrogen and smoke.
Keep away from oxidising agents, strongly alkaline and strongly acid materials in order to avoid possible
exothermic reactions.
10.3. Possibility of hazardous reactions
May react exothermically with: oxidising agents, strong alkalis, strong acids.
10.4. Conditions to avoid
Stable under recommended storage and handling conditions (see section 7).
10.5. Incompatible materials
Keep away from the following materials: oxidising agents, strong alkalis, strong acids.
10.6. Hazardous decomposition products
Fire will produce dense black smoke. Decomposition products may include the following materials: carbon
monoxide, carbon dioxide, smoke, oxides of nitrogen.
Avoid exposure and use breathing apparatus as appropriate.
Acute toxicity
Exposure to solvent vapour concentrations from the component solvents in excess of the stated
occupational exposure limits may result in adverse health effects such as mucous membrane and
respiratory system irritation and adverse effects on the kidneys, liver and central nervous system.
Symptoms include headache, nausea, dizziness, fatigue, muscular weakness, drowsiness and in extreme
cases, loss of consciousness.
Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin
resulting in dryness, irritation and possible non-allergic contact dermatitis. Solvents may also be absorbed
through the skin. Splashes of liquid in the eyes may cause irritation and soreness with possible reversible
damage.
Inhalation
Inhalation
Oral LD50, Skin LD50, Dust/Mist
Ingredient Vapour LD50,
mg/kg mg/kg LD50,
mg/L/4hr
mg/L/4hr
Ethanol - (64-17-5) 7,060.00, Rat 20,000.00, Rabbit 124.70, Rat Not
Available
12.1. Toxicity
The preparation has been assessed following the conventional method of the Dangerous Preparations
Directive 1999/45/EC and is classified for eco-toxicological properties accordingly. See Sections 2 and 3
for details.
Aquatic Ecotoxicity
Using information provided in this data sheet advice should be obtained from the Waste Regulation
Authority, whether the special waste regulations apply.
The European Waste Catalogue Classification of this product, when disposed of as waste is 08 01 11
Waste paint and varnish containing organic solvents or other dangerous substances. If mixed with other
wastes this code may no longer apply and the appropriate code should be assigned. For further
information contact your local waste authority.
EmS F-E,S-E
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
EU Legislation
REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL on
classification, labelling and packaging of substances and mixtures, amending and repealing Directives
67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006.
IMPORTANT NOTE: the information contained in this data sheet (as may be amended from time to time) is
not intended to be exhaustive and is presented in good faith and believed to be correct as of the date on
which it is prepared. It is the user's responsibility to verify that this data sheet is current prior to using the
product to which it relates.
Persons using the information must make their own determinations as to the suitability of the relevant
product for their purposes prior to use. Where those purposes are other than as specifically recommended
in this safety data sheet, then the user uses the product at their own risk.
MANUFACTURER’S DISCLAIMER: the conditions, methods and factors affecting the handling, storage,
application, use and disposal of the product are not under the control and knowledge of the manufacturer.
Therefore the manufacturer does not assume responsibility for any adverse events which may occur in the
handling, storage, application, use, misuse or disposal of the product and, so far as permitted by applicable
law, the manufacturer expressly disclaims liability for any and all loss, damages and/or expenses arising
out of or in any way connected to the storage, handling, use or disposal of the product. Safe handling,
storage, use and disposal are the responsibility of the users. Users must comply with all applicable health
and safety laws.
Unless we have agreed to the contrary, all products are supplied by us subject to our standard terms and
conditions of business, which include limitations of liability. Please make sure to refer to these and / or the
relevant agreement which you have with AkzoNobel (or its affiliate, as the case may be).
© AkzoNobel
The information in this Health & Safety Data Sheet is required pursuant to EC Regulation 1907(2006) and
the Chemicals (Hazard Information & Packaging for Supply) Regulations 2009.
The full text of the R, H & EUH phrases appearing in section 3 is:
End of document
Your attention is drawn to the disclaimer on the Product Data Sheet which with this Safety Data
Sheet and the package labelling comprise an integral information system about this product. Copies
of the Product Data Sheet are available from International Paint on request or from our Internet
sites : www.yachtpaint.com , www.international-marine.com, www.international-pc.com
International Paint Ltd.
R10 Flammable.
R36/38 Irritating to eyes and skin.
R43 May cause sensitisation by skin contact.
Very toxic to aquatic organisms, may cause long-term adverse effects in the
R50/53
aquatic environment.
P. Phrases;
Contains epoxy constituents. See information supplied by the manufacturer.
If the product contains substances that present a health hazard within the meaning of the Dangerous
Substances Directive 67/548/EC, or have occupational exposure limits detailed in EH40, these substances
are listed below.
67/548/EEC EC No. 1272/2008
Ingredient/Chemical Designations Weight % Notes
Classification Classification
Zinc 50 - 100 N;R50-53 Aquatic Acute 1;H400
CAS Number: 0007440-66-6 Aquatic Chronic [1]
EC No. 231-175-3 1;H410
Index No.: 030-001-01-9
REACH Reg. No.: 01-2119467174-
37-xxxx
Epoxy resin (av.mol.wt. 700-1100) 2.5 - < 10 R43 Xi;R36/38 Eye Irrit. 2;H319
CAS Number: 0025068-38-6 Skin Irrit. 2;H315 [1]
EC No. 500-033-5 Skin Sens. 1;H317
Index No.: 603-074-00-8
REACH Reg. No.:
Xylene 2.5 - < 10 R10 Xn;R20/21 Xi;R38 Flam. Liq. 3;H226 C
CAS Number: 0001330-20-7 Acute Tox. 4;H332 [1][2]
EC No. 215-535-7 Acute Tox. 4;H312
Index No.: 601-022-00-9 Skin Irrit. 2;H315
REACH Reg. No.:
Solvent naphtha (petroleum), light 2.5 - < 10 Xn;R65 N; R51/53 (Self Asp. Tox. 1;H304 H; P
aromatic Classification) Aquatic Chronic [1]
CAS Number: 0064742-95-6 2;H411 (Self
EC No. 265-199-0 Classification)
Index No.: 649-356-00-4
REACH Reg. No.:
1,2,4-trimethylbenzene 1 - < 2.5 R10 Xn;R20 Flam. Liq. 3;H226
CAS Number: 0000095-63-6 Xi;R36/37/38 N;R51-53 Acute Tox. 4;H332 [1][2]
EC No. 202-436-9 Eye Irrit. 2;H319
Index No.: 601-043-00-3 STOT SE 3;H335
REACH Reg. No.: Skin Irrit. 2;H315
Aquatic Chronic
2;H411
Butan-1-ol 1 - < 2.5 R10 Xn;R22 Xi;R37/38- Flam. Liq. 3;H226
CAS Number: 0000071-36-3 41 R67 Acute Tox. 4;H302 [1][2]
EC No. 200-751-6 STOT SE 3;H335
Index No.: 603-004-00-6 Skin Irrit. 2;H315
REACH Reg. No.: 01-2119484630- Eye Dam. 1;H318
38-xxxx STOT SE 3;H336
[1] Substance classified with a health or environmental hazard.
[2] Substance with a workplace exposure limit.
[3] PBT-substance or vPvB-substance.
Skin
Remove contaminated clothing. Wash skin thoroughly with soap and water or use a recognised skin
cleanser. Do NOT use solvents or thinners.
Eye
Irrigate copiously with clean fresh water for at least 10 minutes, holding the eyelids apart and seek medical
attention.
Ingestion
If accidentally swallowed obtain immediate medical attention. Keep at rest. Do NOT induce vomiting.
4.2. Most important symptoms and effects, both acute and delayed
No data available
4.3. Indication of any immediate medical attention and special treatment needed
No data available
Contain and absorb spillage with non-combustible materials e.g. sand, earth, vermiculite. Place in closed
containers outside buildings and dispose of according to the Waste Regulations. (See section 13).
If drains, sewers, streams or lakes are contaminated, inform the local water company immediately. In the
case of contamination of rivers, streams or lakes the Environmental Protection Agency should also be
informed.
In Storage
Handle containers carefully to prevent damage and spillage.
Naked flames and smoking should not be permitted in storage areas. It is recommended that fork lift trucks
and electrical equipment are protected to the appropriate standard.
Smoking, eating and drinking should be prohibited in all preparation and application areas.
Never use pressure to empty a container; containers are not pressure vessels.
Store in a well ventilated, dry place away from sources of heat and direct sunlight.
Store on concrete or other impervious floor, preferably with bunding to contain any spillage. Do not stack
more than 3 pallets high.
Keep container tightly closed. Containers which are opened must be carefully resealed and kept upright to
prevent leakage. Keep in the original container or one of the same material.
Activities such as sanding, burning off etc. of paint films may generate dust and/or fumes hazardous to the
skin and lungs. Sanding dust may contain levels of unreacted hazardous materials which may cause
irritation and sensitization; these are highest in the first 24/48 hours after application. Work in well
ventilated areas. Use local exhaust ventilation and personal skin and respiratory protective equipment as
appropriate.
Material Short term (15 min. ave) Long term (8hr TWA) Comments
ppm mg/m3 ppm mg/m3
1,2,4-trimethylbenzene 25 125
Butan-1-ol 50 154 - - +
Xylene 100 441 50 220 +
DNEL/PNEC values
No Data Available
Eye/face protection
Wear safety eyewear, e.g. safety spectacles, goggles or visors to protect against the splash of liquids.
Eyewear should meet the requirements of standard EN 166.
Skin protection
For prolonged or repeated contact use protective gloves. Barrier creams may help to protect the exposed
areas of skin, they should however not be applied once exposure has occurred. Skin should be washed
after contact.
Use chemical resistant gloves classified under Standard EN 374: Protective gloves against chemicals and
micro-organisms. Recommended gloves: Viton® or Nitrile
Breakthrough Time: 480 min
When prolonged or frequently repeated contact may occur, a glove with a protection class of 6
(breakthrough time greater than 480 minutes according to EN 374) is recommended. When only brief
contact is expected, a glove with a protection class of 2 or higher (breakthrough time greater than 30
minutes according to EN 374) is recommended.
NOTICE: The selection of a specific glove for a particular application and duration of use in a workplace
should also take into account all relevant workplace factors such as, but not limited to: Other chemicals
which may be handled, physical requirements (cut/puncture protection, dexterity, thermal protection),
potential body reactions to glove materials, as well as the instructions/specifications provided by the glove
supplier.
The user must check that the final choice of type of glove selected for handling this product is the most
appropriate and takes into account the particular conditions of use, as included in the user's risk
assessment.
Other
Overalls which cover the body, arms and legs should be worn. Skin should not be exposed. Barrier creams
may help to protect areas which are difficult to cover such as the face and neck. They should however not
be applied once exposure has occurred. Petroleum jelly based types such as Vaseline should not be used.
All parts of the body should be washed after contact.
Respiratory protection
If workers are exposed to concentrations above the exposure limit they must use the appropriate,certified
respirators.For maximum protection when spraying this product it is recommended that a multi layer
combination type filter, such as ABEK1, is used. In confined spaces use compressed air or fresh air
respiratory equipment.
Thermal hazards
No Data Available
10.1. Reactivity
No data available
10.2. Chemical stability
Stable under recommended storage and handling conditions (see section 7).When exposed to high
temperatures may produce hazardous decomposition products such as carbon monoxide, carbon dioxide,
oxides of nitrogen and smoke.
Keep away from oxidising agents, strongly alkaline and strongly acid materials in order to avoid possible
exothermic reactions.
10.3. Possibility of hazardous reactions
May react exothermically with: oxidising agents, strong alkalis, strong acids.
10.4. Conditions to avoid
Stable under recommended storage and handling conditions (see section 7).
10.5. Incompatible materials
Keep away from the following materials: oxidising agents, strong alkalis, strong acids.
10.6. Hazardous decomposition products
Fire will produce dense black smoke. Decomposition products may include the following materials: carbon
monoxide, carbon dioxide, smoke, oxides of nitrogen.
Avoid exposure and use breathing apparatus as appropriate.
Acute toxicity
Exposure to solvent vapour concentrations from the component solvents in excess of the stated
occupational exposure limits may result in adverse health effects such as mucous membrane and
respiratory system irritation and adverse effects on the kidneys, liver and central nervous system.
Symptoms include headache, nausea, dizziness, fatigue, muscular weakness, drowsiness and in extreme
cases, loss of consciousness.
Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin
resulting in dryness, irritation and possible non-allergic contact dermatitis. Solvents may also be absorbed
through the skin. Splashes of liquid in the eyes may cause irritation and soreness with possible reversible
damage.
Based on the properties of the epoxy constituents and considering toxicological data on similar
preparations this preparation may be an irritant and a skin and respiratory sensitiser. Low molecular weight
epoxy constituents are irritating to eyes, mucous membranes and skin. Repeated skin contact may lead to
irritation and sensitisation, possibly with cross-sensitisation to other epoxies. Skin contact with the
preparation and exposure to spray mist and vapour should be avoided.
Inhalation
Inhalation
Oral LD50, Skin LD50, Dust/Mist
Ingredient Vapour LD50,
mg/kg mg/kg LD50,
mg/L/4hr
mg/L/4hr
1,2,4-trimethylbenzene - (95-63-6) 3,400.00, Rat 3,160.00, Rabbit 18.00, Rat Not
Available
Epoxy resin (av.mol.wt. 700-1100) - Not Available Not Available Not Available Not
(25068-38-6) Available
Solvent naphtha (petroleum), light 6,800.00, Rat 3,400.00, Rabbit Not Available Not
aromatic - (64742-95-6) Available
12.1. Toxicity
The preparation has been assessed following the conventional method of the Dangerous Preparations
Directive 1999/45/EC and is classified for eco-toxicological properties accordingly. See Sections 2 and 3
for details.
Aquatic Ecotoxicity
Using information provided in this data sheet advice should be obtained from the Waste Regulation
Authority, whether the special waste regulations apply.
The European Waste Catalogue Classification of this product, when disposed of as waste is 08 01 11
Waste paint and varnish containing organic solvents or other dangerous substances. If mixed with other
wastes this code may no longer apply and the appropriate code should be assigned. For further
information contact your local waste authority.
EmS F-E,S-E
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
EU Legislation
REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL on
classification, labelling and packaging of substances and mixtures, amending and repealing Directives
67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006.
IMPORTANT NOTE: the information contained in this data sheet (as may be amended from time to time) is
not intended to be exhaustive and is presented in good faith and believed to be correct as of the date on
which it is prepared. It is the user's responsibility to verify that this data sheet is current prior to using the
product to which it relates.
Persons using the information must make their own determinations as to the suitability of the relevant
product for their purposes prior to use. Where those purposes are other than as specifically recommended
in this safety data sheet, then the user uses the product at their own risk.
MANUFACTURER’S DISCLAIMER: the conditions, methods and factors affecting the handling, storage,
application, use and disposal of the product are not under the control and knowledge of the manufacturer.
Therefore the manufacturer does not assume responsibility for any adverse events which may occur in the
handling, storage, application, use, misuse or disposal of the product and, so far as permitted by applicable
law, the manufacturer expressly disclaims liability for any and all loss, damages and/or expenses arising
out of or in any way connected to the storage, handling, use or disposal of the product. Safe handling,
storage, use and disposal are the responsibility of the users. Users must comply with all applicable health
and safety laws.
Unless we have agreed to the contrary, all products are supplied by us subject to our standard terms and
conditions of business, which include limitations of liability. Please make sure to refer to these and / or the
relevant agreement which you have with AkzoNobel (or its affiliate, as the case may be).
© AkzoNobel
The information in this Health & Safety Data Sheet is required pursuant to EC Regulation 1907(2006) and
the Chemicals (Hazard Information & Packaging for Supply) Regulations 2009.
The full text of the R, H & EUH phrases appearing in section 3 is:
End of document
Your attention is drawn to the disclaimer on the Product Data Sheet which with this Safety Data
Sheet and the package labelling comprise an integral information system about this product. Copies
of the Product Data Sheet are available from International Paint on request or from our Internet
sites : www.yachtpaint.com , www.international-marine.com, www.international-pc.com
International Paint Ltd.
R10 Flammable.
R20/21 Harmful by inhalation and in contact with skin.
R37/38 Irritating to respiratory system and skin.
R41 Risk of serious damage to eyes.
R43 May cause sensitisation by skin contact.
Harmful to aquatic organisms, may cause long-term adverse effects in the
R52/53
aquatic environment.
2.2. Label elements
According to 1999/45/EC
Harmful
P. Phrases;
If the product contains substances that present a health hazard within the meaning of the Dangerous
Substances Directive 67/548/EC, or have occupational exposure limits detailed in EH40, these substances
are listed below.
67/548/EEC EC No. 1272/2008
Ingredient/Chemical Designations Weight % Notes
Classification Classification
Butan-1-ol 10 - < 25 R10 Xn;R22 Xi;R37/38- Flam. Liq. 3;H226
CAS Number: 0000071-36-3 41 R67 Acute Tox. 4;H302 [1][2]
EC No. 200-751-6 STOT SE 3;H335
Index No.: 603-004-00-6 Skin Irrit. 2;H315
REACH Reg. No.: 01-2119484630- Eye Dam. 1;H318
38-xxxx STOT SE 3;H336
Xylene 10 - < 25 R10 Xn;R20/21 R65 Xi; Flam. Liq. 3;H226 C
CAS Number: 0001330-20-7 R36/37/38 Acute Tox. 4;H332 [1][2]
EC No. 215-535-7 Acute Tox. 4;H312
Index No.: 601-022-00-9 Skin Irrit. 2;H315
REACH Reg. No.: Eye Irrit. 2;H319
STOT SE 3;H335
Asp. Tox. 1;H304
Solvent naphtha (petroleum), light 10 - < 25 Xn;R65 N; R51/53 (Self Asp. Tox. 1;H304 H; P
aromatic Classification) Aquatic Chronic [1]
CAS Number: 0064742-95-6 2;H411 (Self
EC No. 265-199-0 Classification)
Index No.: 649-356-00-4
REACH Reg. No.:
1,2,4-trimethylbenzene 2.5 - < 10 R10 Xn;R20 Flam. Liq. 3;H226
CAS Number: 0000095-63-6 Xi;R36/37/38 N;R51-53 Acute Tox. 4;H332 [1][2]
EC No. 202-436-9 Eye Irrit. 2;H319
Index No.: 601-043-00-3 STOT SE 3;H335
REACH Reg. No.: Skin Irrit. 2;H315
Aquatic Chronic
2;H411
Ethylbenzene 2.5 - < 10 F;R11 Xn;R20 R65 Flam. Liq. 2;H225
CAS Number: 0000100-41-4 R48/20 Xi; R36/37/38 Acute Tox. 4;H332 [1][2]
EC No. 202-849-4 Asp. Tox. 1;H304
Index No.: 601-023-00-4 Eye Irrit. 2;H319
REACH Reg. No.: Skin Irrit. 2;H315
STOT SE 3;H335
STOT RE 2;H373
Triethylenetetramine 1 - < 2.5 C;R34 Xn;R21 R43 Acute Tox. 4;H312
CAS Number: 0000112-24-3 R52/53 Skin Corr. 1B;H314 [1]
EC No. 203-950-6 Skin Sens. 1;H317
Index No.: 612-059-00-5 Aquatic Chronic
REACH Reg. No.: 3;H412
1,3,5-trimethylbenzene 1 - < 2.5 R10 Xi;R37 N;R51-53 Flam. Liq. 3;H226
CAS Number: 0000108-67-8 STOT SE 3;H335 [1]
EC No. 203-604-4 Aquatic Chronic
Index No.: 601-025-00-5 2;H411
REACH Reg. No.:
[1] Substance classified with a health or environmental hazard.
[2] Substance with a workplace exposure limit.
[3] PBT-substance or vPvB-substance.
Skin
Remove contaminated clothing. Wash skin thoroughly with soap and water or use a recognised skin
cleanser. Do NOT use solvents or thinners.
Eye
Irrigate copiously with clean fresh water for at least 10 minutes, holding the eyelids apart and seek medical
attention.
Ingestion
If accidentally swallowed obtain immediate medical attention. Keep at rest. Do NOT induce vomiting.
4.2. Most important symptoms and effects, both acute and delayed
No data available
4.3. Indication of any immediate medical attention and special treatment needed
No data available
Contain and absorb spillage with non-combustible materials e.g. sand, earth, vermiculite. Place in closed
containers outside buildings and dispose of according to the Waste Regulations. (See section 13).
If drains, sewers, streams or lakes are contaminated, inform the local water company immediately. In the
case of contamination of rivers, streams or lakes the Environmental Protection Agency should also be
informed.
In Storage
Handle containers carefully to prevent damage and spillage.
Naked flames and smoking should not be permitted in storage areas. It is recommended that fork lift trucks
and electrical equipment are protected to the appropriate standard.
Smoking, eating and drinking should be prohibited in all preparation and application areas.
Never use pressure to empty a container; containers are not pressure vessels.
Store in a well ventilated, dry place away from sources of heat and direct sunlight.
Store on concrete or other impervious floor, preferably with bunding to contain any spillage. Do not stack
more than 3 pallets high.
Keep container tightly closed. Containers which are opened must be carefully resealed and kept upright to
prevent leakage. Keep in the original container or one of the same material.
Material Short term (15 min. ave) Long term (8hr TWA) Comments
ppm mg/m3 ppm mg/m3
1,2,4-trimethylbenzene 25 125
1,3,5-trimethylbenzene 25 125
Butan-1-ol 50 154 - - +
Ethylbenzene 125 552 100 441 +
Xylene 100 441 50 220 +
DNEL/PNEC values
No Data Available
Eye/face protection
Wear safety eyewear, e.g. safety spectacles, goggles or visors to protect against the splash of liquids.
Eyewear should meet the requirements of standard EN 166.
Skin protection
For prolonged or repeated contact use protective gloves. Barrier creams may help to protect the exposed
areas of skin, they should however not be applied once exposure has occurred. Skin should be washed
after contact.
Use chemical resistant gloves classified under Standard EN 374: Protective gloves against chemicals and
micro-organisms. Recommended gloves: Viton® or Nitrile
Breakthrough Time: 480 min
When prolonged or frequently repeated contact may occur, a glove with a protection class of 6
(breakthrough time greater than 480 minutes according to EN 374) is recommended. When only brief
contact is expected, a glove with a protection class of 2 or higher (breakthrough time greater than 30
minutes according to EN 374) is recommended.
NOTICE: The selection of a specific glove for a particular application and duration of use in a workplace
should also take into account all relevant workplace factors such as, but not limited to: Other chemicals
which may be handled, physical requirements (cut/puncture protection, dexterity, thermal protection),
potential body reactions to glove materials, as well as the instructions/specifications provided by the glove
supplier.
The user must check that the final choice of type of glove selected for handling this product is the most
appropriate and takes into account the particular conditions of use, as included in the user's risk
assessment.
Other
Overalls which cover the body, arms and legs should be worn. Skin should not be exposed. Barrier creams
may help to protect areas which are difficult to cover such as the face and neck. They should however not
be applied once exposure has occurred. Petroleum jelly based types such as Vaseline should not be used.
All parts of the body should be washed after contact.
Respiratory protection
If workers are exposed to concentrations above the exposure limit they must use the appropriate,certified
respirators.For maximum protection when spraying this product it is recommended that a multi layer
combination type filter, such as ABEK1, is used. In confined spaces use compressed air or fresh air
respiratory equipment.
Thermal hazards
No Data Available
10.1. Reactivity
No data available
10.2. Chemical stability
Stable under recommended storage and handling conditions (see section 7).When exposed to high
temperatures may produce hazardous decomposition products such as carbon monoxide, carbon dioxide,
oxides of nitrogen and smoke.
Keep away from oxidising agents, strongly alkaline and strongly acid materials in order to avoid possible
exothermic reactions.
10.3. Possibility of hazardous reactions
May react exothermically with: oxidising agents, strong alkalis, strong acids.
10.4. Conditions to avoid
Stable under recommended storage and handling conditions (see section 7).
10.5. Incompatible materials
Keep away from the following materials: oxidising agents, strong alkalis, strong acids.
10.6. Hazardous decomposition products
Fire will produce dense black smoke. Decomposition products may include the following materials: carbon
monoxide, carbon dioxide, smoke, oxides of nitrogen.
Avoid exposure and use breathing apparatus as appropriate.
Acute toxicity
Exposure to solvent vapour concentrations from the component solvents in excess of the stated
occupational exposure limits may result in adverse health effects such as mucous membrane and
respiratory system irritation and adverse effects on the kidneys, liver and central nervous system.
Symptoms include headache, nausea, dizziness, fatigue, muscular weakness, drowsiness and in extreme
cases, loss of consciousness.
Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin
resulting in dryness, irritation and possible non-allergic contact dermatitis. Solvents may also be absorbed
through the skin. Splashes of liquid in the eyes may cause irritation and soreness with possible reversible
damage.
Amine based materials may cause skin irritation and sensitisation.
Inhalation
Inhalation
Oral LD50, Skin LD50, Dust/Mist
Ingredient Vapour LD50,
mg/kg mg/kg LD50,
mg/L/4hr
mg/L/4hr
1,2,4-trimethylbenzene - (95-63-6) 3,400.00, Rat 3,160.00, Rabbit 18.00, Rat Not
Available
Solvent naphtha (petroleum), light 6,800.00, Rat 3,400.00, Rabbit Not Available Not
aromatic - (64742-95-6) Available
12.1. Toxicity
The preparation has been assessed following the conventional method of the Dangerous Preparations
Directive 1999/45/EC and is classified for eco-toxicological properties accordingly. See Sections 2 and 3
for details.
Aquatic Ecotoxicity
Solvent naphtha (petroleum), light 9.22, Oncorhynchus 6.14, Daphnia magna 19.00 (72 hr), Selenastrum
aromatic - (64742-95-6) mykiss capricornutum
1,2,4-trimethylbenzene - (95-63-6) 7.72, Pimephales 3.60, Daphnia magna Not Available
promelas
Ethylbenzene - (100-41-4) 4.20, Oncorhynchus 2.93, Daphnia magna
mykiss 3.60 (96 hr), Pseudokirchneriella
subcapitata
Triethylenetetramine - (112-24-3) 495.00, Pimephales 33.90, Daphnia 20.00 (72 hr), Selenastrum
promelas magna capricornutum
1,3,5-trimethylbenzene - (108-67-8) 12.52, Carassius 6.00, Daphnia magna 25.00 (48 hr), Scenedesmus
auratus subspicatus
Using information provided in this data sheet advice should be obtained from the Waste Regulation
Authority, whether the special waste regulations apply.
The European Waste Catalogue Classification of this product, when disposed of as waste is 08 01 11
Waste paint and varnish containing organic solvents or other dangerous substances. If mixed with other
wastes this code may no longer apply and the appropriate code should be assigned. For further
information contact your local waste authority.
EmS F-E,S-E
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
EU Legislation
REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL on
classification, labelling and packaging of substances and mixtures, amending and repealing Directives
67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006.
IMPORTANT NOTE: the information contained in this data sheet (as may be amended from time to time) is
not intended to be exhaustive and is presented in good faith and believed to be correct as of the date on
which it is prepared. It is the user's responsibility to verify that this data sheet is current prior to using the
product to which it relates.
Persons using the information must make their own determinations as to the suitability of the relevant
product for their purposes prior to use. Where those purposes are other than as specifically recommended
in this safety data sheet, then the user uses the product at their own risk.
MANUFACTURER’S DISCLAIMER: the conditions, methods and factors affecting the handling, storage,
application, use and disposal of the product are not under the control and knowledge of the manufacturer.
Therefore the manufacturer does not assume responsibility for any adverse events which may occur in the
handling, storage, application, use, misuse or disposal of the product and, so far as permitted by applicable
law, the manufacturer expressly disclaims liability for any and all loss, damages and/or expenses arising
out of or in any way connected to the storage, handling, use or disposal of the product. Safe handling,
storage, use and disposal are the responsibility of the users. Users must comply with all applicable health
and safety laws.
Unless we have agreed to the contrary, all products are supplied by us subject to our standard terms and
conditions of business, which include limitations of liability. Please make sure to refer to these and / or the
relevant agreement which you have with AkzoNobel (or its affiliate, as the case may be).
© AkzoNobel
The information in this Health & Safety Data Sheet is required pursuant to EC Regulation 1907(2006) and
the Chemicals (Hazard Information & Packaging for Supply) Regulations 2009.
The full text of the R, H & EUH phrases appearing in section 3 is:
End of document
Your attention is drawn to the disclaimer on the Product Data Sheet which with this Safety Data
Sheet and the package labelling comprise an integral information system about this product. Copies
of the Product Data Sheet are available from International Paint on request or from our Internet
sites : www.yachtpaint.com , www.international-marine.com, www.international-pc.com