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From Classroom/Integrated School Programs 7 in Top 20, 23 in Top 100, 54 in Top 300, 106 in Top 500 All India Ranks & 2314 Students from Classroom
FULL TEST – IV
/Integrated School Programs & 3723 Students from All Programs have been Awarded a Rank in JEE (Advanced), 2013
Paper 2
ALL INDIA TEST SERIES
INSTRUCTIONS
A. General Instructions
1. Attempt ALL the questions. Answers have to be marked on the OMR sheets.
2. This question paper contains Three Parts.
3. Part-I is Physics, Part-II is Chemistry and Part-III is Mathematics.
4. Each part is further divided into three sections: Section-A, Section-B & Section-C
5. Rough spaces are provided for rough work inside the question paper. No additional sheets will be
provided for rough work.
6. Blank Papers, clip boards, log tables, slide rule, calculator, cellular phones, pagers and electronic
devices, in any form, are not allowed.
2. Section – B (01 – 02) contains 2 Matrix Match Type questions containing statements given in 2
columns. Statements in the first column have to be matched with statements in the second
column. Each question carries +8 marks for all correct answer. For each correct row +2 mark will
be awarded. There may be one or more than one correct choice. No marks will be given for any
wrong match in any question. There is no negative marking.
3. Section – C (01 – 08) contains 8 Numerical based questions with answers as numerical value
and each question carries +4 marks for correct answer and – 1 mark for wrong answer.
Enrolment No.
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AITS-FT-IV(Paper-2)-PCM-JEE(Advanced)/14 2
Useful Data
PHYSICS
2
Acceleration due to gravity g = 10 m/s
2 2
Permittivity of free space 0 = 8.85 1012 C /N-m
CHEMISTRY
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3 AITS-FT-IV(Paper-2)-PCM-JEE(Advanced)/14
Physics PART – I
SECTION – A
Single Correct Choice Type
This section contains 4 multiple choice questions. Each question has four choices (A), (B), (C) and (D)
out of which ONLY ONE is correct.
A T2 B
2. A block pulley arrangement is shown in the figure.
50 kg 50 kg
If f 1 and f 2 represents frictional force acting on the
block A and B respectively then choose the correct T3 1 = 0.3 2 = 0.9 T1
statement. (given g = 10 m/s2)
5 kg D
(A) T1 = 100 N, T2 = 10 N 50 kg C
(B) f 1 = 10 N , f2 = 450 N
(C) T2 = 50 N, T3 = 50 N
(D) f 1 = 50 N, T2 = 50 N
u
3. A simple pendulum of bob of mass m and length has one of its ends fixed at
P
the centre O of a vertical circle, as shown in the figure. If = 60 at the point P, m
the minimum speed u that should be given to the bob so that it completes O
vertical circle is
(A) g (B) 2g
5g 3g
(C) (D)
2 2
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AITS-FT-IV(Paper-2)-PCM-JEE(Advanced)/14 4
4. A rod of mass m and length is lying along the y-axis such that one of its ends is at the origin.
Suddenly an impulse is given to the rod such that immediately after the impulse, the end on the
origin has a velocity v0 î and the other end has a velocity 2v 0 î . The magnitude of angular
momentum of the rod about the origin at this instant is
2 3
(A) mv0 (B) mv0
3 2
5 7
(C) mv0 (D) mv0
6 8
This section contains 5 multiple choice questions. Each question has four choices (A), (B), (C) and (D)
out of which ONE or MORE are correct.
6. Consider one dimensional collision between two identical particles A and B. B is stationary and A
has momentum P before impact. During impact, B gives impulse J to A. Choose the correct
alternative(s)
(A) the total momentum of the (A + B) system is P before and after the impact and (P J) during
the impact.
(B) During the impact, A give impulse J to B.
2J
(C) The coefficient of restitution is 1
P
J
(D) The coefficient of restitution is 1
P
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5 AITS-FT-IV(Paper-2)-PCM-JEE(Advanced)/14
rd st
8. Energy liberated in the de–excitation of hydrogen atom from 3 level to 1 level falls on a photo–
cathode. Later when the same photo–cathode is exposed to a spectrum of some unknown
nd
hydrogen like gas, excited to 2 energy level, it is found that the de–Broglie wavelength of the
fastest photoelectrons, now ejected has decreased by a factor of 3. For this new gas, difference
of energies of 2nd Lyman line and 1st Balmer line is found to be 3 times the ionization potential of
the hydrogen atom. Select the correct statement(s) :
(A) The gas is lithium.
(B) The gas is helium.
(C) The work function of photo–cathode is 8.5 eV.
(D) The work function of photo–cathode is 5.5 eV.
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SECTION - B
Matrix – Match Type
1. Longitudinal waves are produced in five identical rods in different situations. Their mode of
vibration and fixed points (with bold point) are shown in the column II, and their frequencies are
given in the column I, match the frequency in the column I with the appropriate situation in the
column II. Each of the rods has length 1 m young’s modulus of elasticity, 2 1012 N/m2 and
density 5 103 kg/m3.
Column-I Column-II
(A) 10 KHz (p)
Second overtone
0.5 m
(B) 15 KHz (q)
Fundamental mode
0.5 m
(C) 25 KHz (r)
First harmonic
2/3 m
(D) 45 KHz (s)
Fundamental mode
2/3 m
(t)
Third harmonic
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AITS-FT-IV(Paper-2)-PCM-JEE(Advanced)/14 8
SECTION – C
Integer Answer Type
X Y Z W
0 0 0 0
1 1 1 1
This section contains 8 questions. The answer to each of the questions is a single-digit
2 2 2 2
integer, ranging from 0 to 9. The appropriate bubbles below the respective question
3 3 3 3
numbers in the ORS have to be darkened. For example, if the correct answers to question 4 4 4 4
numbers X, Y, Z and W (say) are 6, 0, 9 and 2, respectively, then the correct darkening of 5 5 5 5
bubbles will look like the as shown. 6 6 6 6
7 7 7 7
8 8 8 8
9 9 9 9
2. Two particles A and B are located at points (0, 103) and (0, 0) in xy plane. They start moving
simultaneously at time t = 0 with constant velocities v A 5iˆ m/s and vB 5 3 ˆj m/s,
respectively. Time when they are closest to each other is found to be K/2 second. Find K. All
distances are given in meter.
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9 AITS-FT-IV(Paper-2)-PCM-JEE(Advanced)/14
5. Two sound waves of frequencies 100 Hz and 102 Hz and having same amplitude ‘A’ are
interfering. A stationary detector, which can detect waves of amplitude greater than or equal to A,
So, in a given time interval of 12 seconds, find the total duration in which detector is active.
6. Two identical metallic sheets each behaves like a black body are kept parallel to each other with
small separation between them in vacuum. Thermal energy is generated at a constant rate P in
one of the sheets by a passing electricity in it. In steady state, temperature of the other sheet is
found to be constant is 300K. Find the value of P in Kilo-Watt.
103 2 17
(Given area of the plates A = m and = 108 w/m2K4)
17 27 3
A B
7. In the adjacent figure, ABCD are four points in a smooth horizontal plane
Y1
representing the four corners of a square of diagonal 20 cm. A very small Y2
object of mass 14 gm placed at the centre of the square connected to Y4
points A, B, C and D by four elastic strings of same dimensions but of Y3
different moduli of elasticity as shown in the figure. Natural length and D C
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AITS-FT-IV(Paper-2)-PCM-JEE(Advanced)/14 10
Chemistry PART – II
SECTION – A
This section contains 4 multiple choice questions numbered 1 to 4. Each question has 4 choices (A), (B),
(C) and (D), out of which ONLY ONE is correct.
1. The correct order of reagents required to bring the following change is:
COOH
CH3
OH
(A) H3O ; KCN ; NBS ; K2Cr2O7/H+
+
(B) K2Cr2O7/H+ ; Cl2/KOH; CH3MgBr ; H3O+
(C) conc. H2SO4 ; NBS ; KCN ; H3O+ (D) Conc. H2SO4 ; NBS ; CH3MgBr ; K2Cr2O7/H+
2. 1 mole of a gas AB3 present in 10 lt container at pressure 2.5 atm and 273 K temperature. On
increasing the temperature to 546 K, AB3 dissociates into AB2(g) and B2(g). If the degree of
dissociation of AB3 is 80%, then final pressure at 546 K is :
(A) 5 atm (B) 1.25 atm
(C) 10 atm (D) 6.25 atm
3. 1 mole of each of CaC2, Al4C3, Mg2C3 reacts with excess water in separate open flasks work
done during dissolution shows the order :
(A) CaC2 = Mg2C3 < Al4C3 (B) CaC2 = Mg2C3 = Al4C3
(C) Mg2C3 < CaC2 < Al4C3 (D) Mg2C3 < Al4C3 < CaC2
4. In which of the following pairs the two species are not isostructural?
(A) PCl4+ and SiCl4 (B) PF5 and BrF5
3–
(C) AlF6 and SF6 (D) CO32– and NO3–
Rough Work
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11 AITS-FT-IV(Paper-2)-PCM-JEE(Advanced)/14
This section contains 5 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for
its answer, out which ONE OR MORE is/are correct.
5. Which of the following reactions are correctly matched with products (major)?
O
C O
Ph
(i) C Ph
(A) PhMgBr
ii H3 O
Ph
OH
(i) CH3CN (i) CH3Li
(B)PhMgBr (X) Ph C CH3
+ +
(ii) H3O (ii) H 3O
CH3
O
(i) H CH3
(C) PhMgBr Pure enatiomer
+
(ii) H3O
CH2 CH2
(i) O
(D) PhMgBr + PhCH2CH2OH
(ii) H3O
Rough Work
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AITS-FT-IV(Paper-2)-PCM-JEE(Advanced)/14 12
O
||
8. NH2 — CH — C — NH — CH2 — CO2H
|
CH3
Identify the amino acids obtained by hydrolysis of the above compound :
(A) Glycine (B) Phenylalonine
(C) Alanine (D) Glutamic acid
Rough Work
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13 AITS-FT-IV(Paper-2)-PCM-JEE(Advanced)/14
SECTION-B
(Matrix Type)
Rough Work
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AITS-FT-IV(Paper-2)-PCM-JEE(Advanced)/14 14
SECTION – C
X Y Z W
0 0 0 0
1 1 1 1
This section contains 8 questions. The answer to each of the questions is a single-digit
2 2 2 2
integer, ranging from 0 to 9. The appropriate bubbles below the respective question
3 3 3 3
numbers in the ORS have to be darkened. For example, if the correct answers to question 4 4 4 4
numbers X, Y, Z and W (say) are 6, 0, 9 and 2, respectively, then the correct darkening of 5 5 5 5
bubbles will look like the as shown. 6 6 6 6
7 7 7 7
8 8 8 8
9 9 9 9
1. The total number of cyclic, structural isomers for a compound with molecular formula C5H10
is______.
2. The equivalent weight of Zn(OH)2 in the following reaction is equal to its M/x :
X is equal to ___________.
3. The number of ions formed when cuprammonium sulphate is dissolved in water is _______.
4. How many visible lines are emitted during transition from 5th orbit to ground state in hydrogen
emission spectrum?
5. The half life of two samples of a substance is 50 sec and 200 sec at 0.4 M and 0.1M
concentrations, respectively the order of reaction is __________.
Rough Work
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15 AITS-FT-IV(Paper-2)-PCM-JEE(Advanced)/14
Et Ph CH3 Ph
H2SO 4
6. HO OH + HO OH
Et Ph CH3 Ph
7. The total number of pi-bonds in pyrene responsible for its aromatic behaviour are:
8. O
OH /H2 O
O
Double bond equivalent of final product is ...............
Rough Work
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AITS-FT-IV(Paper-2)-PCM-JEE(Advanced)/14 16
SECTION – A
This section contains 4 multiple choice questions numbered 1 to 4. Each question has 4 choices (A),
(B), (C) and (D), out of which ONLY ONE is correct.
1. If a1, a2,a3 ….. are in A.P. and bk = ak + ak+1 + ….. + ak+n1 (k = 1, 2, 3 …..), then b1 + b2 + ….. + bn
is equal to
(A) n(n + 1)an (B) (n 1)nan
2
(C) n an (D) (n + 1)2an
3. Tangents PA and PB are drawn to the circle x 2 + y2 = 4 from an external point P lying on the line
2
y = x such that the angle between the tangents satisfies . The co-ordinates of the
3 3
point P, if the perimeter of PAB is maximum for all are
2 2 2 2
(A) 2 2, 2 2 (B) ,
3
3
(C) (2, 2) (D) none of these
2i
4. The reflection of the complex number in the straight line z(1 + i) = z (1 – i) is
3i
2i 2 i
(A) (B)
3i 3 i
2 i 2i
(C) (D)
3 i 3 i
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This section contains 5 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for
its answer, out which ONE OR MORE is/are correct.
5. Two players A and B toss a coin which has a probability p of showing head (0 < p < 1), in the
cyclic order A, A, B, A, A, B, ….. till a head appears. Let x denotes the probability that A gets the
head first and y that of B, then
(A) x + y = 1 (B) x > y for all p
1 1
(C) x > for all p (D) y > for all p
2 2
7. A plane meets the co-ordinates axes in A, B, C such that the centroid of the triangle ABC is the
point (1, r, r2). If all such planes must pass through the point (t, t, t) for all r R – {0}, then t can
satisfy
(A) 0 t 4 (B) 1 < t 4
(C) 2 < t < 3 (D) 0 < t 4, t 3
8. The value(s) of satisfying the equation [sin(cot–1 cos tan–1 x)] = sin , (where x R and [.]
denotes the greatest integer function) is/are
(A) 0 (B)
2
3
(C) (D)
2
9. Let f(x) = (ax + b)cos x + (cx + d)sin x and f(x) = x cos x for all x R, then
(A) a = – 1 (B) b = 1
(C) c = 1 (D) d = – 1
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SECTION-B
(Matrix Type)
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SECTION – C
X Y Z W
0 0 0 0
1 1 1 1
This section contains 8 questions. The answer to each of the questions is a single-digit
2 2 2 2
integer, ranging from 0 to 9. The appropriate bubbles below the respective question
3 3 3 3
numbers in the ORS have to be darkened. For example, if the correct answers to question 4 4 4 4
numbers X, Y, Z and W (say) are 6, 0, 9 and 2, respectively, then the correct darkening of 5 5 5 5
bubbles will look like the as shown. 6 6 6 6
7 7 7 7
8 8 8 8
9 9 9 9
1. If the function f(x) = 2x 3 – 9ax2 + 12a2x + 1 has a local maximum at x = x 1 and a local minimum at
x = x2 such that x2 = x12 , then a is equal to _____
xy yz
2. If positive numbers x, y, z are in A.P., then the minimum value of is equal to
2y x 2y z
_____
3. The number of odd proper divisors of 24300 is N + 11, then N is equal to _____
5. The number of normal(s) to hyperbola which can touch its conjugate is equal to _____
logex2 1 3 2ln x d2 y
7. For y cot 1 2 tan , the value of at x = 1, is equal to _____
loge / x 1 6ln x dx 2
x8
8. For real valued function f(x), f(x) + f(x + 4) = f(x + 2) + f(x + 6), g(x) =
f(x) dx . Then g(x) is
x
equal to _____
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