Iv) - C V) - C: N C N N .CH CHCH OH OCN

Tutorial 01
Lewis structures
01. Draw the plausible lewis structures for following molecules/ ions, hence deduce the shape around
the central atom according to the VESPR theory.
i). OF2 ii). ClO3- iii). NO2-
iv). SF4 v). ClF3 vi). XeF2
vii). IF5 viii). XeF4 ix). SOCl2
x). N2F2 xi). ClF2- xii). IF4-
xiii). BrF6+ xiv). IF4+ xv) SnCl5-
xvi). COCl2 xvii). BH4- xviii). N3-
xix). XeO4 xx) TeCl4 xxi). XeO3
02. Complete the following table correctly for each compound given below.
Atom a Atom b Atom c Atom d Atom e
No of electron pairs
VSEPR pairs
Electron geometry
Hybridization
Shape
Bond angle
The relevant skeletons of the compounds with named atoms are given below.
i). CaH3 -CbHNcO2-CdOeNfH2
ii). CaH3- CbH(OH) - CcN
iii). CaH3 –Cb = Cc – CdHO
iv). CaH3 – CbH =CcBr –Od- C6H5
v). CaH3 – C6H5 – SbO3- NcH4+
03. Draw all the possible resonance structures for following compounds
i). NO V). CH3NCS

-
II). N3 VI). CH3NCONH2
0III). C2N2 VII). CH2N2
IV).CH2CHCH2OH VIII). CH3OCN
Tutorial 2
Chemical Bonding
1). Identify the intermolecular forces in following substances.

I). methane VI) dimethyl ether
II). trichloromethane VII). Solid ammonia
III). Butanol VIII). Dilute hydrochloric acid
IV). Carbondioxide IX). Copper sulphate solutio
V). sulfur dioxide X). sodium iodide solution
2). Complete the following table.

Substance Primary attractions Secondary attractions Lattice type
solid Iodine
solid Sodium chloride
Ice
Zinc metal
Diamond
Quartz
graphite
Dry Ice
3). Fill the following table to compare the properties of the different types of lattice.
Lattice type Example Melting point Hardness Electrical
Conductivity
4). Define followings.

i). triple point of a substance
ii). Critical point of a substance
iii). Critical pressure
5). For questions i to iv) refer the phase diagram below.
i). At this point, the substance represented by the
phase diagram will be solely in the solid phase
at equilibrium.
ii).This point represents a boiling point of the

substance.
iii).At this point, the substance represented by

the phase diagram will be undergoing
sublimation.
Iv). .At this point, the substance represented by

the phase diagram will be solely in the liquid
phase at equilibrium.
v). When a substance undergoes a phase change from liquid to solid, which of
the following will occur?
1.) Energy will be released by the substance because intermolecular forces are being
weakened.
2). Energy will be released by the substance because intermolecular forces are being
strengthened.
3). Energy will be absorbed by the substance because intermolecular forces are being
weakened.
4). Energy will be absorbed by the substance because intermolecular forces are being
strengthened.
5). The energy of the substance will not be changed.
vi). .During which of the following phase changes must heat be added to overcome intermolecular
forces?
A.Vaporization B.Sublimation C.Deposition
1). A only 2). B only 3). A and B only 4). A and C only 5). C only
vii). As pressure on the substance depicted in the diagram is increased at constant temperature,
which of the following phase changes CANNOT occur?
A.Condensation B.Melting C.Freezing

1.A only 2.B only 3. C only 4. A and B only 5. A and C only
viii). At a temperature of 50°C and a pressure of 0.2 atmospheres, the substance depicted in the
diagram is
a.in the gas phase b. in the liquid phase c. in the solid phase
d. at its triple point e. at its critical point
ix). Which of the following lists the three phases of the substance shown in the diagram in
order of increasing density at -5°C?
a.Solid, gas, liquid b. Solid, liquid, gas
c. Gas, liquid, solid d. Gas, solid, liquid e.Liquid, solid, gas
x). When the temperature of the substance depicted in the diagram is decreased from 10°C
to10°C at a constant pressure of 0.3 atmospheres, which phase change will occur?
a.Gas to liquid b. Liquid to solid c. Gas to solid
d.Liquid to gas e. Solid to liquid
xi). Which of the following processes can occur when the temperature of a substance is
increased at constant pressure?
I.Sublimation II. Melting III. Boiling
a. I only b. II only c. I and II only
d. II and III only e. I, II, and III
6. State, whether the following statements are true or false. Justify your answer briefly
i). acetone is more volatile than propanol
ii). p-nitrophenol has higher boiling point than o- nitrophenol.
iii). HF has has higher boiling point than HBr.
iv). Methane is a gas but methanol is a liquid.
v). group 16 hydride shows higher boiling point than the other hydrides of the second period.
vi). Iodine is a solid at room temperature but chlorine is a gas.
vii). Magnesium is harder than Sodium.

Iv) - C V) - C: N C N N .CH CHCH OH OCN

Uploaded by

Copyright:

Available Formats

Iv) - C V) - C: N C N N .CH CHCH OH OCN

Uploaded by

Document Information

Original Description:

Original Title

Copyright

Available Formats

Share this document

Share or Embed Document

Sharing Options

Did you find this document useful?

Is this content inappropriate?

Copyright:

Available Formats

Iv) - C V) - C: N C N N .CH CHCH OH OCN

Uploaded by

Copyright:

Available Formats

Tutorial 01

i). NO V). CH3NCS

1). Identify the intermolecular forces in following substances.

2). Complete the following table.

4). Define followings.

ii).This point represents a boiling point of the

iii).At this point, the substance represented by

Iv). .At this point, the substance represented by

A.Condensation B.Melting C.Freezing

You might also like