Examen2 de Wilson y NRTL
Examen2 de Wilson y NRTL
Examen2 de Wilson y NRTL
A 12
ln γ 1 =
x 1 A 12
(
( 1+
x 2 A 21
)2
)
T(ªC) = 60 A 12 A 21
x 1 A 12 x2 A 2
T(K) = 333.15
γ 1 =e
( 1+
( x 2 A 21 )
)2
γ 2 =e
(
( 1+
x1 A 1
T x1 x2 A 12= A 21 =
A 12= 0.4262 333.15 0.001 0.999 0.4262 0.4394
333.15 0.1 0.9 0.4262 0.4394
A 21 = 0.4394 333.15 0.2 0.8 0.4262 0.4394
333.15 0.3 0.7 0.4262 0.4394
333.15 0.4 0.6 0.4262 0.4394
333.15 0.5 0.5 0.4262 0.4394
333.15 0.6 0.4 0.4262 0.4394
333.15 0.7 0.3 0.4262 0.4394
333.15 0.8 0.2 0.4262 0.4394
333.15 0.9 0.1 0.4262 0.4394
333.15 0.999 0.001 0.4262 0.4394
1
METIL ACETATO METANOL 0.9
VP_A= -8.05406 VP_A= -8.54796
0.8
VP_B= 2.56375 VP_B= 0.76982
0.7
VP_C= -5.12994 VP_C= -3.1085
Y1
A 21
ln γ 2 =
x 2 A21
(
( 1+
x 1 A12
)2
)
A 21
x 2 A 21
γ2 =e
( ( 1+
x 1 A 12 )
)2
γ 1= γ 2= Pvp1 Pvp2 P y1 y2
1.530161956 1.00000041 1.1259659 0.846540765 0.84741748 0.00203313 0.99796687
1.415249081 1.00416758 1.1259659 0.846540765 0.92441413 0.17238185 0.82761815
1.317947317 1.01687721 1.1259659 0.846540765 0.98545515 0.30117327 0.69882673
1.236956246 1.03861229 1.1259659 0.846540765 1.03329051 0.4043695 0.5956305
1.170214355 1.07011078 1.1259659 0.846540765 1.07058402 0.49230006 0.50769994
1.11608213 1.11240598 1.1259659 0.846540765 1.09918372 0.57163803 0.42836197
1.073278907 1.16688325 1.1259659 0.846540765 1.12021097 0.64727564 0.35272436
1.040835325 1.23535711 1.1259659 0.846540765 1.1340956 0.72336191 0.27663809
1.018059065 1.32017492 1.1259659 0.846540765 1.14055621 0.80402862 0.19597138
1.004512307 1.4243557 1.1259659 0.846540765 1.13851946 0.8940927 0.1059073
1.000000453 1.55037134 1.1259659 0.846540765 1.1261529 0.99883457 0.00116543
1 1.2
0.9
0.8 1
0.7
0.8
Y1
0.5 DIAGONA
0.6
L
0.4
0.3 0.4
0.2
0.2
0.1
0 -1.66533453693773E-16
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1 0 0.1 0.2 0.3
X1 X-Y
L
0.4
0.3 0.4
0.2
0.2
0.1
0 -1.66533453693773E-16
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1 0 0.1 0.2 0.3
X1 X-Y
y1+y2
1
1
1
1
1
1
1
1
1
1
1
1.2
0.8
Xvs P
0.6 Y vs P
0.4
0.2
-1.66533453693773E-16
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
X-Y
0.4
0.2
-1.66533453693773E-16
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
X-Y
FIQ-UNCP "Termodinámica de los Procesos Quimicos II - VI Semestre" Joseph Christian Cruz Huanca
A 12
ln γ 1 =
x 1 A 12
(
( 1+
x 2 A 21
)2
)
A 12 A 21
x 1 A 12 x2 A
P (bar) = 1
γ 1 =e
( 1+
( x 2 A 21 )
)2
γ 2 =e
(
( 1+
x1 A
Presion T x1 x2
A 12= 0.4262 1 337.2891981 0.001 0.999
1 319.0608738 0.1 0.9
A 21 = 0.4394 1 315.7886142 0.2 0.8
1 316.7261775 0.3 0.7
1 317.798954 0.4 0.6
1 318.8957644 0.5 0.5
1 320.0858628 0.6 0.4
1 321.3120116 0.7 0.3
1 322.6289676 0.8 0.2
1 324.0635178 0.9 0.1
1 325.633086 0.999 0.001
A 21
ln γ 2 =
x 2 A21
(
( 1+
x 1 A12
)2
)
A 21
x 2 A 21
γ2 =e
( ( 1+
x 1 A 12
)2
)
1 340
0.9
335
0.8
0.7 330
0.6 325
T
y
VAN
0.5 LAAR
0.4 320
0.3 315
0.2
310
0.1
0 305
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1 -0.8 0.2
x X-Y
y2 y1+y2
0.99806664 1.000045967
0.902906076 0.999063712
0.812741379 1.000737626
0.726349041 0.999930251
0.641466323 0.999798469
0.555683105 0.999513349
0.466317023 0.99998859
0.370260724 0.999967144
0.263788189 0.999910449
0.142302434 0.999834907
0.001548922 0.999995004
340
335
330
325 X vs
T
320
315
310
305
0.2 1.2
X-Y
x
0.342003125
0.377563648
0.3839473
0.382118265
0.380025451
0.37788575
0.37556406
0.373172041
0.370602872
0.367804296
0.364742322
FIQ-UNCP "Termodinámica de los Procesos Quimicos II - VI Semestre" Joseph Christian Cruz Huanca
Λ12 Λ21
ln γ 1 =−ln ( x1 + Λ12 x2 ) +x 2
[ −
x1 + Λ12 x2 Λ21 x 1 + x2 ]
Volúmenes:
Λ12 Λ21
v 1=
v 2=
79.84
40.73
ln γ 2 =−ln ( x2 + Λ21 x1 ) −x1
[ −
x 1 + Λ 12 x 2 Λ 21 x 1 +x 2 ]
Parámetros de Wilson:
v2 λ12
λ12 = -31.19 Λ 12 =
v1
exp −
RT ( )
λ21 = 813.18
Λ12 Λ21
−
x1 + Λ12 x2 Λ21 x 1 + x2 ] [
γ 1 =exp −ln ( x1 + Λ12 x2 ) + x 2
[ Λ 12
x1 + Λ12 x2
−
Λ21
Λ21 x 1 + x2 ]]
Λ12 Λ21
−
x 1 + Λ 12 x 2 Λ 21 x 1 +x 2 ] [
γ 2 =exp −ln ( x 2 + Λ21 x 1 ) −x1
Λ12
[ −
Λ21
x 1 + Λ 12 x 2 Λ 21 x 1 + x 2 ]]
λ12
(
p −
RT ) Λ 21 =
v1
v2
exp −
λ21
RT ( )
v 1= v 2= λ12 = λ21 = Λ12= Λ21= γ 1=
79.84 40.73 -31.19 813.18 0.5347570733 0.5738620162 2.856714343
79.84 40.73 -31.19 813.18 0.5347570733 0.5738620162 2.295664146
79.84 40.73 -31.19 813.18 0.5347570733 0.5738620162 1.906163501
79.84 40.73 -31.19 813.18 0.5347570733 0.5738620162 1.629974553
79.84 40.73 -31.19 813.18 0.5347570733 0.5738620162 1.42954109
79.84 40.73 -31.19 813.18 0.5347570733 0.5738620162 1.282210923
79.84 40.73 -31.19 813.18 0.5347570733 0.5738620162 1.17389711
79.84 40.73 -31.19 813.18 0.5347570733 0.5738620162 1.095743458
79.84 40.73 -31.19 813.18 0.5347570733 0.5738620162 1.042323858
79.84 40.73 -31.19 813.18 0.5347570733 0.5738620162 1.010695634
79.84 40.73 -31.19 813.18 0.5347570733 0.5738620162 1.000001099
0.8
Y1
0.6 WILSON
DIAGONAL
0.4
0.2
0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
X1
0.8
Y1
0.6 WILSON
DIAGONAL
0.4
0.2
0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
X1
DIAGONAL:
0 0
0.2 0.2
0.4 0.4
0.6 0.6
0.8 0.8
1 1
Λ 12 Λ21
x1 + Λ12 x2
−
Λ21 x 1 + x2 ]]
Λ12 Λ21
−
x 1 + Λ 12 x 2 Λ 21 x 1 + x 2 ]]
1.4
1.2
1
WILSON
P
0.8 X1 vs
DIAGONAL P
0.6
0.4
0.2
0
0 0.2 0.4 0.6 0.8 1 1.2
X-Y
1.2
1
WILSON
P
0.8 X1 vs
DIAGONAL P
0.6
0.4
0.2
0
0 0.2 0.4 0.6 0.8 1 1.2
X-Y
X1 vs
P
X1 vs
P
FIQ-UNCP "Termodinámica de los Procesos Quimicos II - VI Semestre" Joseph Christian Cruz Huanca
etanol agua
Λ12 Λ21
v
Λ
57.141
0.6848
18.06
0.3781
ln γ 1 =−ln ( x1 + Λ12 x2 ) +x 2
[ −
x1 + Λ12 x2 Λ21 x 1 + x2 ]
λ 382.3 955.45
A 8.04494 7.96681
B 1554.3 1668.21 Λ12 Λ21
C
Presión(mmHg)=
222.65
520
228 ln γ 2 =−ln ( x2 + Λ21 x1 ) −x1
[ −
x 1 + Λ 12 x 2 Λ 21 x 1 +x 2 ]
t 60
T 333.15
v2 λ12
R 1.987
Λ12 =
v1
exp −
RT ( )
T(ºC) T (K) x1 x2 v 1= v 2= λ12 =
60 333.15 0.001 0.999 57.141 18.06 382.3
60 333.15 0.1 0.9 57.141 18.06 382.3
60 333.15 0.2 0.8 57.141 18.06 382.3
60 333.15 0.3 0.7 57.141 18.06 382.3
60 333.15 0.4 0.6 57.141 18.06 382.3
60 333.15 0.5 0.5 57.141 18.06 382.3
60 333.15 0.6 0.4 57.141 18.06 382.3
60 333.15 0.7 0.3 57.141 18.06 382.3
60 333.15 0.8 0.2 57.141 18.06 382.3
60 333.15 0.9 0.1 57.141 18.06 382.3
60 333.15 0.999 0.001 57.141 18.06 382.3
Λ21
−
Λ21 x 1 + x2 ] [
γ 1 =exp −ln ( x1 + Λ12 x2 ) + x 2
[ Λ 12
x1 + Λ12 x2
−
Λ21
Λ21 x 1 + x2 ]]
Λ12 Λ21
−
Λ21
Λ 21 x 1 +x 2 ] [
γ 2 =exp −ln ( x 2 + Λ21 x 1 ) −x1
[ −
x 1 + Λ 12 x 2 Λ 21 x 1 + x 2 ]]
λ12 v1 λ
RT ) Λ 21 =
v2
exp − 21
RT ( )
λ21 = Λ12= Λ21= γ 1= γ 2= Pvp1 Pvp2
955.45 0.1774011375 0.7471247729 7.18890029538 1.0000048365 351.48996844 149.4218698
955.45 0.1774011375 0.7471247729 3.57299327897 1.0345258985 351.48996844 149.4218698
955.45 0.1774011375 0.7471247729 2.36010583792 1.1112840282 351.48996844 149.4218698
955.45 0.1774011375 0.7471247729 1.79396897393 1.2164845876 351.48996844 149.4218698
955.45 0.1774011375 0.7471247729 1.47964415783 1.3485143586 351.48996844 149.4218698
955.45 0.1774011375 0.7471247729 1.28772661981 1.5100382386 351.48996844 149.4218698
955.45 0.1774011375 0.7471247729 1.16474414412 1.7063660887 351.48996844 149.4218698
955.45 0.1774011375 0.7471247729 1.08513933381 1.9453118748 351.48996844 149.4218698
955.45 0.1774011375 0.7471247729 1.03551168202 2.2376687186 351.48996844 149.4218698
955.45 0.1774011375 0.7471247729 1.00848084168 2.5981517782 351.48996844 149.4218698
955.45 0.1774011375 0.7471247729 1.00000082292 3.0418838665 351.48996844 149.4218698
VP_A VP_B VP_C VP_D Pc Tc
-8.54796 0.76982 -3.1085 1.54481 80.9 512.6
-8.54796 0.76982 -3.1085 1.54481 80.9 512.6
-8.54796 0.76982 -3.1085 1.54481 80.9 512.6
-8.54796 0.76982 -3.1085 1.54481 80.9 512.6
-8.54796 0.76982 -3.1085 1.54481 80.9 512.6
-8.54796 0.76982 -3.1085 1.54481 80.9 512.6
-8.54796 0.76982 -3.1085 1.54481 80.9 512.6
-8.54796 0.76982 -3.1085 1.54481 80.9 512.6
-8.54796 0.76982 -3.1085 1.54481 80.9 512.6
-8.54796 0.76982 -3.1085 1.54481 80.9 512.6
-8.54796 0.76982 -3.1085 1.54481 80.9 512.6
DIAGONAL:
0 0
0.2 0.2
0.4 0.4
0.6 0.6
0.8 0.8
1 1
X i γ i PSat
i
.
=Y i PT
y1 y2 y1+y2
0.0048592814 0.2870637882 0.2919230697
0.2415137106 0.2675436821 0.5090573927
0.3190590486 0.2554617498 0.5745207985
0.3637858258 0.2446895792 0.6084754049
0.4000615987 0.232497158 0.6325587567
0.4352144125 0.2169545549 0.6521689673
0.4723798644 0.1961295473 0.6685094117
0.5134440637 0.167695464 0.6811395278
0.5599568745 0.1285987092 0.6885555837
0.6135073256 0.0746578263 0.6881651519
0.6752668604 0.0008740846 0.676140945
x
0.3500780336
0.3500780336
0.3500780336
0.3500780336
0.3500780336
0.3500780336
0.3500780336
0.3500780336
0.3500780336
0.3500780336
0.3500780336
FIQ-UNCP "Termodinámica de los Procesos Quimicos II - VI Semestre" Joseph Christian Cruz Huanca
2
G 21 2
τ 12 G
γ 1 =exp( (x 2 ) (τ 21 .( )+
x 1 + x 2 G 21 ( x 2 + x1
2
G 12 2
τ 21 G
γ 2 =exp(( x1 ) (τ 12 . ( )+
Volúmenes: x 2 + x 1 G 12 ( x 1 +x 2
v1= 79.84
Λ 12 Λ 21
v 2= 40.73
τ 12 =
R.T
τ 21 =
R.T
G12=exp ( ¿α12 . τ 12 )
Parámetros del NRTL: Λ12 = g ¿ Λ 21 = g ¿
Λ12= 381.46
Λ21= 346.54
0.8
Y1
0.6
METIL ACETATO METANOL 1
VP_A= -8.05406 VP_A= -8.54796
VP_B= 2.56375 VP_B= 0.76982 0.8
VP_C= -5.12994 VP_C= -3.1085
Y1
0.6
VP_D= 0.16125 VP_D= 1.54481
Pc= 46.9 Pc= 80.9 0.4
Tc= 506.8 Tc= 512.6
T= 333.15 T= 333.15 0.2
x= 0.342640095 x= 0.350078034
0
0 0.1
tian Cruz Huanca
2
τ 12 G 12
)+ 2
))
G 21 (x 2 + x1 G 12 )
2
τ 21 G 21
)+ 2
))
G 12 ( x 1 + x 2 G 21 )
=exp ( ¿α12 . τ 12 ) G21=exp ( ¿α12 .τ 21 )
1 1.4
1.2
0.8
1
Y1
0.6 NRTL
P
DIAGONA 0.8
Metil Acetato (1) - Metanól (2) Metil Acet
1 1.4
1.2
0.8
1
Y1
0.6 NRTL
P
DIAGONA 0.8
L 0.6
0.4
0.4
0.2
0.2
0 0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1 0 0.2 0.4
X1
Diagonal
x y
0 0
0.1 0.1
0.2 0.2
0.3 0.3
0.4 0.4
0.5 0.5
0.6 0.6
0.7 0.7
0.8 0.8
0.9 0.9
1 1
4
2
1
8 X1 vs
Metil Acetato (1) - Metanól (2)
4
2
1
8 X1 vs
P
6
4
2
0
0 0.2 0.4 0.6 0.8 1 1.2
X-Y
FIQ-UNCP "Termodinámica de los Procesos Quimicos II - VI Semestre"TORRES DE LA CRUZ JHYNO
2
G21 2
τ1
γ 1 =exp((x 2 ) (τ 21 .( )+
x 1 + x 2 G 21 (x 2 +
Presion(bar)= 1.013
2
G12 2
τ2
γ 2 =exp( ( x1 ) (τ 12 . ( )+
Volúmenes: x 2 + x 1 G 12 ( x 1+
v1= 79.84
Λ 12 Λ 21
v 2= 40.73
τ 12 =
R.T
τ 21 =
R.T
G12=exp ( −α12 .τ 12 )
Parámetros del NRTL: Λ12 = g ¿ Λ 21 = g ¿
Λ12= 206.7
Λ21= 5270.3
α 12 = 0.4
Cálculo del coeficiente de actividad:
Asumimos la temperatura de:
R Presion T (K) x1
T ( ºC )= 60 8.314 101.3 372.808115 0.001
8.314 101.3 358.8013361 0.1
T ( K )= 333.15 8.314 101.3 355.6426474 0.2
8.314 101.3 354.2923113 0.3
La constante será: 8.314 101.3 353.3782637 0.4
8.314 101.3 352.6084888 0.5
R= 8.314 8.314 101.3 352.0147078 0.6
8.314 101.3 351.561963 0.7
8.314 101.3 351.3038864 0.8
8.314 101.3 351.2688406 0.9
8.314 101.3 351.4651792 0.999
G21 2
τ 12 G12
)+ 2
))
x 1 + x 2 G 21 (x 2 + x1 G12 )
G 12 2
τ 21 G21
)+ 2
))
x 2 + x 1 G 12 ( x 1 + x 2 G 21 )
G12=exp ( −α12 .τ 12 ) G21=exp ( −α12 .τ 21 )
POTENCIA(10;(B$13-(B$14/(B$15+A28))))
0.9
0.8
0.7
0.6
Y1
NRTL
DIAGONA
Metil Acetato (1) - Metanól (2)
0.9
0.8
0.7
0.6
Y1
NRTL
0.5 DIAGONA
x L
0.272711442 0.4
0.30003641
0.306198503 0.3
0.308832791 0.2
0.310615951
0.312117657 0.1
0.313276028
0
0.314159261 0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
0.314662727
X1
0.314731095
0.31434807
COMPONENTE 1 CONPONENTE2
y1+y2 A 7.28781 7.19621
0.999956643
0.999682695 B 1623.22 1730.63
1.000041268
1.000064594 C -44.17 -39.724
1.000054387
0.999177958
0.999933527
0.999953967
0.999974494
0.999961942
0.999934157
375
370
365
NRTL 360
T
X1 vs
DIAGONA
Metil Acetato (1) - Metanól (2)
375
370
365
NRTL T 360
X1 vs
DIAGONA
T
L
355
350
345
340
1 0 0.2 0.4 0.6 0.8 1 1.2
X-Y
X1 vs
X1 vs
T
FIQ-UNCP "Termodinámica de los Procesos Quimicos II - VI Semestre" Joseph Christian Cruz Huanca
Presion Total 1
DATOS EXPERIMENTALES:
x y T (K)
0 0 349.85
0.002 0.02 349.25
0.002 0.027 349
0.004 0.12 345.5
0.013 0.2415 340.75
0.017 0.264 340 Presion T x1
0.03 0.333 335.15 1 345.7995517 0.001
0.0505 0.445 332.55 1 321.9016854 0.1
0.107 0.49 330.35 1 324.0167872 0.2
0.124 0.5 330.1 1 325.0375458 0.3
0.248 0.522 329.4 1 325.426516 0.4
0.401 0.5365 328.95 1 325.5164608 0.5
0.505 0.5483 328.85 1 325.5160035 0.6
0.55 0.552 328.8 1 325.7511579 0.7
0.603 0.561 328.85 1 326.7186232 0.8
0.727 0.595 329.15 1 329.5135658 0.9
1 1 337.85 1 337.1684589 0.999
Φ1 z θ1 r1 τ 21 τ 12
ln γ 1 =ln
( )
+ q 1 ln
x1 2 Φ1( ) ( )
+Φ 2 l 1 − l 2 −q 1 ln ( θ 1 +θ 2 τ 21 ) +θ 2 q1
r2 ( −
θ1 +θ 2 τ 21 θ 2 +θ1 τ 12 )
Φ2 z θ r τ 12 τ 21
ln γ 2 =ln
( )
x2 2 Φ2 ( ) ( r1 )
+ q2 ln 2 +Φ 1 l 2− 2 l 1 −q2 ln ( θ 2 +θ 1 τ 12 ) +θ 1 q 2
(
−
θ2 +θ1 τ 12 θ 1 +θ 2 τ 21 )
−a 12
z Φi =
r i xi qi x i
τ 12 =exp ( )
T
θi =
li= ( r i−q i ) −( r i−1 ) NC NC
−a
=exp (
T )
2 ∑
j
rj x j ∑ qj xj
j
τ 21 21
r1= 1.43
r2= 3.33
q1= 1.43
q2= 2.82
a21 = 1127.95
a12 = -29.64
z= 10
l1 l2 Φ1 Φ2 θ1 θ2 τ 12
l1 l2 Φ1 Φ2 θ1 θ2 τ 12
-0.43 0.22 0.000429675 0.999570325 0.000507342 0.999492658 1.089495121
-0.43 0.22 0.045541401 0.954458599 0.053338307 0.946661693 1.096450126
-0.43 0.22 0.096949153 0.903050847 0.112509835 0.887490165 1.09579129
-0.43 0.22 0.155434783 0.844565217 0.178526841 0.821473159 1.09547654
-0.43 0.22 0.222568093 0.777431907 0.252650177 0.747349823 1.095357145
-0.43 0.22 0.300420168 0.699579832 0.336470588 0.663529412 1.095329579
-0.43 0.22 0.391780822 0.608219178 0.432024169 0.567975831 1.095329719
-0.43 0.22 0.5005 0.4995 0.541959935 0.458040065 1.095257724
-0.43 0.22 0.632044199 0.367955801 0.669789227 0.330210773 1.094962663
-0.43 0.22 0.794444444 0.205555556 0.820267686 0.179732314 1.094120422
-0.43 0.22 0.997674419 0.002325581 0.998029887 0.001970113 1.091888296
x2 ln γ 1 = ln γ 2 = γ 1= γ 2= Pvp1 Pvp2
0.999 4.3196057214 1.78004E-05 75.15898887 1.000017801 1.385109266 0.896786026
0.9 2.44357009283 0.093025438 11.51407377 1.097489653 0.52682858 0.398632486
0.8 1.5833902672 0.238401396 4.871443341 1.26921855 0.577589438 0.430749685
0.7 1.07622785133 0.404551198 2.933592706 1.498629761 0.603520627 0.446971577
0.6 0.73126734426 0.588747283 2.077712116 1.801729944 0.613655939 0.453279807
0.5 0.48207205698 0.791707434 1.619426472 2.207161794 0.616019848 0.454748568
0.4 0.29847082254 1.015481212 1.347796211 2.760691554 0.61600781 0.454741091
0.3 0.16488894625 1.262988446 1.17926215 3.535972778 0.622224138 0.45859895
0.2 0.07293002191 1.538173578 1.075655262 4.656078537 0.648356167 0.474746205
0.1 0.01838004486 1.846378474 1.018549998 6.336828928 0.729076 0.523951315
0.001 1.8806835E-06 2.191647234 1.000001881 8.949943633 0.994313101 0.679683927
0.8
τ 12 τ 21
q2
( −
θ2 +θ1 τ 12 θ 1 +θ 2 τ 21 ) 0.7
Y1
0.6
0.5
−a 12
τ 12 =exp
T( ) 0.4
−a 0.3
=exp (
T )
21
τ 21
0.2
0.1
0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
X1
τ 21
τ 21
0.038317032
0.030076228
0.030772102
0.031110357
0.031239665
0.031269599
0.031269446
0.031347762
0.031670835
0.032611964
0.035247511
y1 y2 y1+y2
0.10410341194 0.895905187 1.000008599
0.60659431362 0.393745526 1.00033984
0.56273884463 0.437372393 1.000111238
0.53114511264 0.468891436 1.000036548
0.51000015175 0.49001268 1.000012832
0.49879942473 0.501851833 1.000651258
0.49815179581 0.502159956 1.000311752
0.51363576224 0.486478021 1.000113783
0.5579261778 0.442091123 1.0000173
0.66834032259 0.332018985 1.000359308
0.99332065557 0.006083133 0.999403788
355
350
345
340
UNIQUAC 335
T
DAT. EXP.
330
DIAGONAL
325
320
315
310
305
0.5 0.6 0.7 0.8 0.9 1 0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9
1 X-Y
x
0.37850547868
0.42145635255
0.41765494745
0.41582037063
0.41512128693
0.41495963193
0.41496045381
0.41453781829
0.41279902378
0.40777576245
0.39401786682
1) - TETRACLORURO DE CARBONO (2)
X1 vs T
(CALC.)
Y1 vs T
(CALC.)
X1 vs T (EXP.)
Temperatura 328
DATOS EXPERIMENTALES:
x y P(bar) x1 x2 ln γ 1 =
0.005587 0.0514 0.43427 0.001 0.999 4.572531345
0.0234 0.3692 0.75861 0.1 0.9 2.446826149
0.0343 0.3926 0.79019 0.2 0.8 1.59334703
0.0525 0.4326 0.85891 0.3 0.7 1.085663334
0.1734 0.5084 0.96216 0.4 0.6 0.739189221
0.545 0.5535 0.99515 0.5 0.5 0.488301086
0.8699 0.6724 0.91647 0.6 0.4 0.30299331
0.7 0.3 0.167770557
0.8 0.2 0.074361866
0.9 0.1 0.018762579
0.999 0.001 1.9154E-06
Φ1 z θ1 r1 τ 21 τ 12
ln γ 1 =ln
( )+ q 1 ln
x1 2 Φ1( ) ( )
+Φ 2 l 1 − l 2 −q 1 ln ( θ 1 +θ 2 τ 21 ) +θ 2 q1
r2 ( −
θ1 +θ 2 τ 21 θ 2 +θ1 τ 12 )
Φ2 z θ2 r2 τ 12 τ 21
ln γ 2 =ln
( )+ q2 ln
x2 2 Φ2 ( ) ( )
+Φ 1 l 2− l 1 −q2 ln ( θ 2 +θ 1 τ 12 ) +θ 1 q 2
r1 ( −
θ2 +θ1 τ 12 θ 1 +θ 2 τ 21 )
−a 12
z Φi =
r i xi qi x i
τ 12 =exp ( )
T
θi =
li= ( r i−q i ) −( r i−1 ) NC NC
−a
=exp (
T )
2 ∑
j
rj x j ∑ qj xj
j
τ 21 21
r1= 1.43
r2= 3.33
q1= 1.43
q2= 2.82
a21 = 1127.95
a12 = -29.64
z= 10
l1 l2 Φ1 Φ2 θ1 θ2 τ 12 τ 21
-0.43 0.22 0.000429675 0.999570325 0.000507342 0.999492658 1.084608955 0.032100876
-0.43 0.22 0.045541401 0.954458599 0.053338307 0.946661693 1.084608955 0.032100876
-0.43 0.22 0.096949153 0.903050847 0.112509835 0.887490165 1.084608955 0.032100876
-0.43 0.22 0.155434783 0.844565217 0.178526841 0.821473159 1.084608955 0.032100876
-0.43 0.22 0.222568093 0.777431907 0.252650177 0.747349823 1.084608955 0.032100876
-0.43 0.22 0.300420168 0.699579832 0.336470588 0.663529412 1.084608955 0.032100876
-0.43 0.22 0.391780822 0.608219178 0.432024169 0.567975831 1.084608955 0.032100876
-0.43 0.22 0.5005 0.4995 0.541959935 0.458040065 1.084608955 0.032100876
-0.43 0.22 0.632044199 0.367955801 0.669789227 0.330210773 1.084608955 0.032100876
-0.43 0.22 0.794444444 0.205555556 0.820267686 0.179732314 1.084608955 0.032100876
-0.43 0.22 0.997674419 0.002325581 0.998029887 0.001970113 1.084608955 0.032100876
ln γ 2 = γ 1= γ 2= Pvp1 Pvp2 P y1
2.137181E-05 96.78880578 1.000021372 0.68437917 0.496826262 0.562580285 0.11774362567
0.09075665113 11.55162534 1.095002505 0.68437917 0.496826262 1.280192577 0.61753925939
0.23642186959 4.920189419 1.266708583 0.68437917 0.496826262 1.176922302 0.57221706889
0.40345348206 2.961403567 1.496985594 0.68437917 0.496826262 1.128636104 0.53871825678
0.58873302543 2.094236862 1.801704255 0.68437917 0.496826262 1.110381228 0.51630991202
0.79314541856 1.62954541 2.210337942 0.68437917 0.496826262 1.106690436 0.50385676917
1.01901914371 1.353905407 2.770475992 0.68437917 0.496826262 1.106528887 0.50242772838
1.26971482904 1.182665225 3.559837255 0.68437917 0.496826262 1.097160202 0.51640044023
1.54969911507 1.077196536 4.710052785 0.68437917 0.496826262 1.05778428 0.5575510127
1.86486575052 1.018939702 6.455069238 0.68437917 0.496826262 0.948311788 0.66181503194
2.21931448401 1.000001915 9.201021256 0.68437917 0.496826262 0.688267409 0.99335823703
τ 12
21
−
θ 2 +θ1 τ 12 )
METANOL (1) - TETRACLORURO DE CARBONO
τ 21
−
12 θ 1 +θ 2 τ 21
)
1
0.9
0.8
0.7
Y1
0.6
0.5
0.4
0.3
0.2
0.1
0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
X1
0.6
0.5
0.4
0.3
0.2
0.1
0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
X1
DIAGONAL:
x y
0 0
0.1 0.1
0.2 0.2
0.3 0.3
0.4 0.4
0.5 0.5
0.6 0.6
0.7 0.7
0.8 0.8
0.9 0.9
y2 y1+y2 1 1
0.88225637433 1
0.38246074061 1
0.42778293111 1
0.46128174322 1
0.48369008798 1
0.49614323083 1
0.49757227162 1
0.48359955977 1
0.4424489873 1
0.33818496806 1
0.00664176297 1
1.4
1.2
0.8
P
UNIQUAC
DAT.EXP.
DIAGONAL 0.6
0.4
0.2
0
.5 0.6 0.7 0.8 0.9 1 0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
1 X-Y
DAT.EXP.
DIAGONAL 0.6
0.4
0.2
0
.5 0.6 0.7 0.8 0.9 1 0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
1 X-Y
ACLORURO DE CARBONO (2)
X1 vs P
(CALC.)
Y1 vs P(CALC)
X1 vs P (EXP)
Y1 vs P (EXP)
DATOS EXPERIMENTALES
x y T (K)
0 0 349.85
0.002 0.02 349.25
0.002 0.027 349
0.004 0.12 345.5
0.013 0.2415 340.75
0.017 0.264 340
0.03 0.333 335.15
0.0505 0.445 332.55
0.107 0.49 330.35 T x1 x2 γ 1=
0.124 0.5 330.1 348.3160334 0.001 0.999 20.27130067
0.248 0.522 329.4 328.3428421 0.1 0.9 7.505293705
0.401 0.5365 328.95 327.9782059 0.2 0.8 3.866465684
0.505 0.5483 328.85 328.2441135 0.3 0.7 2.51258245
0.55 0.552 328.8 328.3297906 0.4 0.6 1.858673253
0.603 0.561 328.85 328.3144127 0.5 0.5 1.494498073
0.727 0.595 329.15 328.3578238 0.6 0.4 1.275432079
1 1 337.85 328.6979679 0.7 0.3 1.139720569
329.7157587 0.8 0.2 1.057595363
332.0831504 0.9 0.1 1.01367919
337.2209776 0.999 0.001 1.000001331
Grupos funcionales:
Me tan ol=CH 3 OH . .. . .. . . .. . . .. . . .. . . .. . . .. Un∗subgrupoCH 3 OH
Tetracloruro . . de . .Carbono=CCl4 . .. . . .. Un∗subgrupoCCl4
Sub-Grupo k Rk Qk v k 1 ( me tan ol ) v k 2 (tertracloruro)
CH 3 OH 1 1.4311 1.432 1 0
CCl4 2 3.39 2.91 0 1
NSG NSG r i xi qi x i
Φi = θi =
Parte combinatorial: NC
r i= ∑ v ki . R k qi = ∑ v ki . Q k NC
∑ rj x ∑ qj xj
j
k k j j
1
0.9
0.8
0.7
0.6 UNIFAC
y1
z Φi z θi Φi NC
qi x i li (ri q i ) ( ri 1) ln γ Ci =ln ( )+ q ln ( )+l ¿ ) ∑ x j l j
θi = NC 2 xi 2 i Φi xi j
∑ qj xj
j
Φ1 = Φ2 = θ1 = θ2 = l1 = l2=
0.000422397 0.999577603 0.000492346 0.999507654 -0.4356 0.01
0.044804343 0.955195657 0.051842734 0.948157266 -0.4356 0.01
0.095463308 0.904536692 0.109547124 0.890452876 -0.4356 0.01
0.153204655 0.846795345 0.174166869 0.825833131 -0.4356 0.01
0.219625236 0.780374764 0.247024323 0.752975677 -0.4356 0.01
0.29684097 0.70315903 0.329801935 0.670198065 -0.4356 0.01
0.387716399 0.612283601 0.424673784 0.575326216 -0.4356 0.01
0.496227901 0.503772099 0.534499307 0.465500693 -0.4356 0.01
0.62806109 0.37193891 0.663116462 0.336883538 -0.4356 0.01
0.791639777 0.208360223 0.815799468 0.184200532 -0.4356 0.01
0.997634431 0.002365569 0.997969972 0.002030028 -0.4356 0.01
355
350
345
340 X1 vs T (CALC)
Y1 vs T (CALC)
T
335 X1 vs T (EXP)
330 Y1 vs T (EXP)
325
320
315
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
X-Y
320
315
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
X-Y
X .Q Θmi Ψ
Φi
xi
NC
)∑ x j l j
j
v mi
X mi= NSG
∑ v ni
n
Θ mi= NSG mi m
∑ X ni . Qn
n
Ψ mn =EXP
−a mn
( )
T [
Ln Γ ki=Q k 1−Ln ∑ Θmi Ψ mk −∑
( m ) m (∑
n
Θn
ln γ C
1=
C
ln γ 2 = Ψ 11 = Ψ 12 = Ψ 21 = Ψ 22 = Ln Γ 11= Ln Γ 12=
-0.204277755 -1.3145327E-07 1 1.214886693 0.084643307 1 0 3.228333088
-0.178267174 -0.00140816381 1 1.229357262 0.072837959 1 0 3.422710241
-0.152102161 -0.00605876979 1 1.229639519 0.072626141 1 0 3.426476464
-0.126253854 -0.0147194679 1 1.229433618 0.072780593 1 0 3.423729164
-0.101007992 -0.02837487165 1 1.229367353 0.072830375 1 0 3.422844904
-0.076758575 -0.04830303347 1 1.229379244 0.072821439 1 0 3.423003584
-0.05405332 -0.07618489491 1 1.22934568 0.072846665 1 0 3.422555677
-0.033661692 -0.11426350284 1 1.229083031 0.073044392 1 0 3.419050192
-0.016678554 -0.16557924387 1 1.228300693 0.073636789 1 0 3.408603687
-0.004684877 -0.2343216312 1 1.226501409 0.075018992 1 0 3.384549992
-5.30312E-07 -0.32529605197 1 1.22269215 0.078038493 1 0 3.333496839
X 11 = 1 Θ 11= 1
X 12 = 0 Θ 12= 0
Θ 21 =
X 21 = 0 Θ 21
21
= 0
X 22 = 1 Θ 22 = 1
Θmi Ψ km ∑ x j v nj x m .Q m
( ∑ )]
Θm Ψ km
∑ Θmi Ψ mk −∑
( m ) m
n
Θni Ψ nm X m= j
∑ ∑ x j v nj
n j
Θ m=
∑ x n Qn
n
[
Ln Γ k =Qk 1−Ln
(∑ Θm Ψ mk )−∑
m m (∑ )]
n
Θn Ψ nm
Ln Γ 21= Ln Γ 22= X 1= X 2= Θ1 = Θ2 = Ln Γ 1= Ln Γ 2=
2.097254103 0 0.001 0.999 0.000492346 0.999507654 3.213483881 7.4201255E-06
2.097151327 0 0.1 0.9 0.051842734 0.948157266 2.193875773 0.05800133283
2.097099665 0 0.2 0.8 0.109547124 0.890452876 1.504442991 0.17717772923
2.097137528 0 0.3 0.7 0.174166869 0.825833131 1.047564943 0.32769194461
2.097149511 0 0.4 0.6 0.247024323 0.752975677 0.720870921 0.50252242216
2.097147368 0 0.5 0.5 0.329801935 0.670198065 0.478548988 0.7000800775
2.097153409 0 0.6 0.4 0.424673784 0.575326216 0.297338326 0.92098952439
2.09719981 0 0.7 0.3 0.534499307 0.465500693 0.164444809 1.16718628981
2.097328803 0 0.8 0.2 0.663116462 0.336883538 0.07267636 1.44178910937
2.097572449 0 0.9 0.1 0.815799468 0.184200532 0.018271351 1.74949578773
2.097837621 0 0.999 0.001 0.997969972 0.002030028 1.86139E-06 2.0941165495
Θm Ψ km
∑ Θm Ψ mk )−∑
m (∑ )]
n
Θn Ψ nm
R
Lnγ i =∑ v kj ( Ln Γ k −Ln Γ kj )
k
C
Lnγ i=Lnγ i +Ln γi
R
Ln γ R
1= Ln γ R
2=
Ln γ 1= Ln γ 2= γ 1= γ 2=
3.213483881 7.4201255E-06 3.009206126 7.2886723E-06 20.27130067 1.000007289
2.193875773 0.05800133283 2.015608599 0.05659316902 7.505293705 1.058225204
1.504442991 0.17717772923 1.35234083 0.17111895944 3.866465684 1.186631902
1.047564943 0.32769194461 0.921311089 0.31297247672 2.51258245 1.367483893
0.720870921 0.50252242216 0.619862928 0.47414755051 1.858673253 1.606644031
0.478548988 0.7000800775 0.401790414 0.65177704403 1.494498073 1.918947856
0.297338326 0.92098952439 0.243285007 0.84480462948 1.275432079 2.327523041
0.164444809 1.16718628981 0.130783118 1.05292278697 1.139720569 2.866015641
0.07267636 1.44178910937 0.055997806 1.2762098655 1.057595363 3.583033778
0.018271351 1.74949578773 0.013586475 1.51517415653 1.01367919 4.550213507
1.86139E-06 2.0941165495 1.33108E-06 1.76882049753 1.000001331 5.863932758
FIQ-UNCP "Termodinámica de los Procesos Quimicos II - VI Semestre" Joseph Christian Cruz Huanca
Temperatura 328
DATOS EXPERIMENTALES:
x y P(bar) T x1 x2 γ 1=
0.005587 0.0514 0.43427 328 0.001 0.999 24.6412256
0.0234 0.3692 0.75861 328 0.1 0.9 7.512383307
0.0343 0.3926 0.79019 328 0.2 0.8 3.866403286
0.0525 0.4326 0.85891 328 0.3 0.7 2.512614806
0.1734 0.5084 0.96216 328 0.4 0.6 1.858559129
0.545 0.5535 0.99515 328 0.5 0.5 1.494384994
0.8699 0.6724 0.91647 328 0.6 0.4 1.27533507
328 0.7 0.3 1.139601485
328 0.8 0.2 1.057450636
328 0.9 0.1 1.013582496
328 0.999 0.001 1.000001306
Grupos funcionales:
NSG NSG r i xi qi x i
Parte combinatorial: Φi = θi =
r i= ∑ v ki . R k qi = ∑ v ki . Q k NC
∑ rj x j
NC
∑ qj xj
k k j j
R1 R2 Q1 Q2 v 11 = v 12= v 21 =
1.4311 3.39 1.432 2.91 1 0 0
1.4311 3.39 1.432 2.91 1 0 0
1.4311 3.39 1.432 2.91 1 0 0
1.4311 3.39 1.432 2.91 1 0 0
1.4311 3.39 1.432 2.91 1 0 0
1.4311 3.39 1.432 2.91 1 0 0
1.4311 3.39 1.432 2.91 1 0 0
1.4311 3.39 1.432 2.91 1 0 0
1.4311 3.39 1.432 2.91 1 0 0
1.4311 3.39 1.432 2.91 1 0 0
1.4311 3.39 1.432 2.91 1 0 0
z Φi z θi Φi NC
qi x i li (ri q i ) ( ri 1) ln γ Ci =ln ( )+ q ln ( )+l ¿ ) ∑ x j l j
θi = NC 2 xi 2 i Φi xi j
∑ qj xj
j Φ1 = Φ2 = θ1 = θ2 = l1 = l2 =
0.000422397 0.999577603 0.000492346 0.999507654 -0.4356 0.01
0.044804343 0.955195657 0.051842734 0.948157266 -0.4356 0.01
0.095463308 0.904536692 0.109547124 0.890452876 -0.4356 0.01
0.153204655 0.846795345 0.174166869 0.825833131 -0.4356 0.01
0.219625236 0.780374764 0.247024323 0.752975677 -0.4356 0.01
0.29684097 0.70315903 0.329801935 0.670198065 -0.4356 0.01
0.387716399 0.612283601 0.424673784 0.575326216 -0.4356 0.01
0.496227901 0.503772099 0.534499307 0.465500693 -0.4356 0.01
0.62806109 0.37193891 0.663116462 0.336883538 -0.4356 0.01
0.791639777 0.208360223 0.815799468 0.184200532 -0.4356 0.01
0.997634431 0.002365569 0.997969972 0.002030028 -0.4356 0.01
1 1.2
0.9
1
0.8
0.7
0.8
Y1
0.6 UNIFAC
P
v 22 = r1 r2 q1 q2 X 11 = X 12 = X 21 =
1 1.4311 3.39 1.432 2.91 1 0 0
1 1.4311 3.39 1.432 2.91 1 0 0
1 1.4311 3.39 1.432 2.91 1 0 0
1 1.4311 3.39 1.432 2.91 1 0 0
1 1.4311 3.39 1.432 2.91 1 0 0
1 1.4311 3.39 1.432 2.91 1 0 0
1 1.4311 3.39 1.432 2.91 1 0 0
1 1.4311 3.39 1.432 2.91 1 0 0
1 1.4311 3.39 1.432 2.91 1 0 0
1 1.4311 3.39 1.432 2.91 1 0 0
1 1.4311 3.39 1.432 2.91 1 0 0
X .Q Θmi Ψ
Φi
xi
NC
)∑ x j l j
j
v mi
X mi= NSG
∑ v ni
n
Θ mi= NSG mi m
∑ X ni . Qn
n
Ψ mn =EXP
−a mn
( )
T [
LnΓ ki=Q k 1−Ln ∑ Θmi Ψ mk −∑
( m ) m (∑
n
Θn
ln γ C
1=
C
ln γ 2 = Ψ 11 = Ψ 12 = Ψ 21= Ψ 22 = Ln Γ 11= Ln Γ 12=
-0.204277755 -1.3145327E-07 1 1.22962263 0.072638798 1 0 3.426251126
-0.178267174 -0.00140816381 1 1.22962263 0.072638798 1 0 3.426251126
-0.152102161 -0.00605876979 1 1.22962263 0.072638798 1 0 3.426251126
-0.126253854 -0.0147194679 1 1.22962263 0.072638798 1 0 3.426251126
-0.101007992 -0.02837487165 1 1.22962263 0.072638798 1 0 3.426251126
-0.076758575 -0.04830303347 1 1.22962263 0.072638798 1 0 3.426251126
-0.05405332 -0.07618489491 1 1.22962263 0.072638798 1 0 3.426251126
-0.033661692 -0.11426350284 1 1.22962263 0.072638798 1 0 3.426251126
-0.016678554 -0.16557924387 1 1.22962263 0.072638798 1 0 3.426251126
-0.004684877 -0.2343216312 1 1.22962263 0.072638798 1 0 3.426251126
-5.30312E-07 -0.32529605197 1 1.22962263 0.072638798 1 0 3.426251126
1.2
0.8 X1 vs P (CALC.)
P
Y1 vs P (CALC.)
0.6 X1 vs P (EXP.)
Y1 vs P (EXP.)
0.4
0.2
0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
X-Y
X 22 = Θ 11= Θ 12 = Θ 21 = Θ 22 = a11 = a12 = a21 =
1 1 0 0 1 0 -67.8 860.1
1 1 0 0 1 0 -67.8 860.1
1 1 0 0 1 0 -67.8 860.1
1 1 0 0 1 0 -67.8 860.1
1 1 0 0 1 0 -67.8 860.1
1 1 0 0 1 0 -67.8 860.1
1 1 0 0 1 0 -67.8 860.1
1 1 0 0 1 0 -67.8 860.1
1 1 0 0 1 0 -67.8 860.1
1 1 0 0 1 0 -67.8 860.1
1 1 0 0 1 0 -67.8 860.1
Θmi Ψ km ∑ x j v nj x m .Q m
( ∑ )]
Θm Ψ km
∑ Θmi Ψ mk −∑
( m ) m
n
Θni Ψ nm X m= j
∑ ∑ x j v nj
n j
Θ m=
∑ x n Qn
n
[
Ln Γ k =Qk 1−Ln
(∑ Θm Ψ mk )−∑
m m (∑ )]
n
Θn Ψ nm
Ln Γ 21= Ln Γ 22 = X 1= X 2= Θ1 = Θ2 = Ln Γ 1= Ln Γ 2=
2.097102806 0 0.001 0.999 0.000492346 0.999507654 3.408698633 8.7688366E-06
2.097102806 0 0.1 0.9 0.051842734 0.948157266 2.194819941 0.05810556597
2.097102806 0 0.2 0.8 0.109547124 0.890452876 1.504426852 0.17716385854
2.097102806 0 0.3 0.7 0.174166869 0.825833131 1.04757782 0.32790115042
2.097102806 0 0.4 0.6 0.247024323 0.752975677 0.720809518 0.50284601866
2.097102806 0 0.5 0.5 0.329801935 0.670198065 0.478473322 0.70040164646
2.097102806 0 0.6 0.4 0.424673784 0.575326216 0.297262264 0.92134238661
2.097102806 0 0.7 0.3 0.534499307 0.465500693 0.164340318 1.16779233652
2.097102806 0 0.8 0.2 0.663116462 0.336883538 0.072539504 1.44292199038
2.097102806 0 0.9 0.1 0.815799468 0.184200532 0.018175957 1.75091976239
2.097102806 0 0.999 0.001 0.997969972 0.002030028 1.83658E-06 2.09343135778
a22 =
0
0
0
0
0
0
0
0
0
0
0
Θm Ψ km
∑ Θm Ψ mk )−∑
m (∑ )]
n
Θn Ψ nm
R
Lnγ i =∑ v kj ( Ln Γ k −Ln Γ kj )
k
C
Lnγ i=Lnγ i +Ln γi
R
Ln γ R
1= Ln γ R
2=
Ln γ 1= Ln γ 2= γ 1= γ 2=
3.408698633 8.7688366E-06 3.204420878 8.63738E-06 24.6412256 1.000008637
2.194819941 0.05810556597 2.016552767 0.056697402 7.512383307 1.058335512
1.504426852 0.17716385854 1.352324691 0.171105089 3.866403286 1.186615442
1.04757782 0.32790115042 0.921323966 0.313181683 2.512614806 1.367770008
0.720809518 0.50284601866 0.619801526 0.474471147 1.858559129 1.607164019
0.478473322 0.70040164646 0.401714747 0.652098613 1.494384994 1.919565029
0.297262264 0.92134238661 0.243208944 0.845157492 1.27533507 2.328344481
0.164340318 1.16779233652 0.130678627 1.053528834 1.139601485 2.867753107
0.072539504 1.44292199038 0.055860951 1.277342747 1.057450636 3.587095229
0.018175957 1.75091976239 0.013491081 1.516598131 1.013582496 4.556697511
1.83658E-06 2.09343135778 1.30626E-06 1.768135306 1.000001306 5.859916216