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    Cee Mno2 FTIR

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    Muhammad Usman
    This document summarizes the phase transformation of cerium-doped manganese dioxide (Ce-doped MnO2) materials for use as pseudocapacitive electrode materials. It includes SEM images of Ce-doped MnO2 materials with different cerium amounts and an IR spectrum comparison. It also includes a table comparing the specific capacitances of reported MnO2 electrode materials to the cerium-doped MnO2 nanorods reported in this work, which achieved a specific capacitance of 101.1 F/g at a current density of 1 A/g. References are provided for other works investigating MnO2 materials for supercapacitor applications.

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    Cee Mno2 FTIR

    Uploaded by

    Muhammad Usman
    31 views4 pages
    This document summarizes the phase transformation of cerium-doped manganese dioxide (Ce-doped MnO2) materials for use as pseudocapacitive electrode materials. It includes SEM images of Ce-doped MnO2 materials with different cerium amounts and an IR spectrum comparison. It also includes a table comparing the specific capacitances of reported MnO2 electrode materials to the cerium-doped MnO2 nanorods reported in this work, which achieved a specific capacitance of 101.1 F/g at a current density of 1 A/g. References are provided for other works investigating MnO2 materials for supercapacitor applications.

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    cee mno2 FTIR

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    This document summarizes the phase transformation of cerium-doped manganese dioxide (Ce-doped MnO2) materials for use as pseudocapacitive electrode materials. It includes SEM images of Ce-doped MnO2 materials with different cerium amounts and an IR spectrum comparison. It also includes a table comparing the specific capacitances of reported MnO2 electrode materials to the cerium-doped MnO2 nanorods reported in this work, which achieved a specific capacitance of 101.1 F/g at a current density of 1 A/g. References are provided for other works investigating MnO2 materials for supercapacitor applications.

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    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    31 views4 pages

    Cee Mno2 FTIR

    Uploaded by

    Muhammad Usman
    This document summarizes the phase transformation of cerium-doped manganese dioxide (Ce-doped MnO2) materials for use as pseudocapacitive electrode materials. It includes SEM images of Ce-doped MnO2 materials with different cerium amounts and an IR spectrum comparison. It also includes a table comparing the specific capacitances of reported MnO2 electrode materials to the cerium-doped MnO2 nanorods reported in this work, which achieved a specific capacitance of 101.1 F/g at a current density of 1 A/g. References are provided for other works investigating MnO2 materials for supercapacitor applications.

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    of 4

    Supporting Information

    Phase Transformation of Ce3+ Doped MnO2 for Pseudocapacitive

    Electrode Materials

    Kunfeng Chen, Wei Pan and Dongfeng Xue*


    State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied
    Chemistry, Chinese Academy of Sciences, Changchun 130022, China
    *E-mail: [email protected]; Tel: +86 411 85262294

    a b c

    d e f

    Fig. S1 SEM images of Ce-doped MnO2 materials with different Ce3+ amounts.

    S1
    Fig. S2 SEM images of β-MnO2 materials.

    3+
    0.5 mmol Ce
    Transmittance

    3+
    0 0.00 mmol Ce
    4000 3500 3000 2500 2000 1500 1000 500
    -1
    Wavenumber (cm )

    Fig. S3 IR spectrum of Ce-doped MnO2 materials with different Ce3+ amounts.

    S2
    Table S1 Comparison of specific capacitances of the reported MnO2 electrodes and the
    present work. All values are measured using the three-electrode system.

    Samples Phase of Specific capacitance Current density Electrolyte Ref.


    −1 −1
    MnO2 (F g ) (A g )
    0.5V-MnO2 α 439 0.5 0.5 M Na2SO4 (1)
    nanosheets
    0.125V-MnO2 α 102 0.5 0.5 M Na2SO4 (1)
    nanorods
    MnO2 spheres α 257.3 0.05 0.5 M Na2SO4 (2)
    Y/ZrO2@MnO2 α 282.1 0.05 0.5 M Na2SO4 (2)
    spheres
    α-MnO2 hollow α 123 2 mV/s 0.5 M Na2SO4 (3)
    urchins
    CeO2 δ 255.2 0.25 1.0 M Na2SO4 (4)
    nanowire@MnO2
    nanostructure
    α- MnO2 α 258.7 0.1 1.0 M Na2SO4 (5)
    spherical-like
    particle
    Mesoporous α-MnO2 α 283 2 mV/s 1.0 M Na2SO4 (6)
    network
    α-MnO2 ultralong α 345 1 A/g 0.5 M Na2SO4 (7)
    nanowire
    α-MnO2 spheres α 200 1 A/g 0.5 M Na2SO4 (8)
    Ce doped MnO2 α 101.1 1 A/g 1.0 M Li2SO4 This
    nanorods work

    References:
    (1) Hu, Z.; Xiao, X.; Huang, L.; Chen, C.; Li, T.; Su, T.; Cheng, X.; Miao, L.; Zhang, Y.;
    Zhou, J. 2D Vanadium Doped Manganese Dioxides Nanosheets for Pseudocapacitive
    Energy Storage. Nanoscale 2015, 7, 16094-16099.
    (2) Zhang, Y.; Zhai, Y. Preparation of Y-doped ZrO2 Coatings on MnO2 Electrodes and
    Their Effect on Electrochemical Performance for MnO2 Electrochemical
    Supercapacitors. RSC Adv. 2016, 6, 1750–1759.
    (3) Wang, J. G.; Yang, Y.; Huang, Z. H.; Kang, F. Shape-Controlled Synthesis of
    Hierarchical Hollow Urchin-Shape Α-MnO2 Nanostructures and Their Electrochemical
    Properties. Mater. Chem. Phys. 2013, 140, 643-650.
    (4) Zhu, S.; Jia, J.; Wang, T.; Zhao, D.; Yang, J.; Dong, F.; Shang, Z.; Zhang, Y. X.
    Rational Design of Octahedron and Nanowire CeO2@MnO2 Core–Shell
    Heterostructures with Outstanding Rate Capability for Asymmetric Supercapacitors.
    Chem. Commun. 2015, 51, 14840-14843.
    (5) Zhang, Y.; Li, G.; Lv, Y.; Wang, L.; Zhang, A.; Song, Y.; Huang, B. Electrochemical
    S3
    Investigation of MnO2 Electrode Material for Supercapacitors. Int. J. Hydrogen
    Energy, 2011, 36, 11760-11766.
    (6) Yu, L. L.; Zhu, J. J.; Zhao, J. T. Three-Dimensional Network Mesoporous
    Nanostructured α-Manganese Dioxide with High Supercapacitive Performance: Facile,
    Environmental and Large-Scale Synthesis. Eur. J. Inorganic Chem. 2013, 2013,
    3719-3725.
    (7) Li, W.; Liu, Q.; Sun, Y.; Sun, J.; Zou, R.; Li, G.; Hu, X.; Song, G.; Ma, G.; Yang, J.
    MnO2 Ultralong Nanowires with Better Electrical Conductivity and Enhanced
    Supercapacitor Performances. J. Mater. Chem. 2012, 22, 14864-14867.
    (8) Zhang, Y.; Sun, C.; Lu, P.; Li, K.; Song, S.; Xue, D. Crystallization Design of MnO2
    Towards Better Supercapacitance. CrystEngComm 2012, 14, 5892−5897.

    S4

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