GHENT UNIVERSITY – DEPARTMENT OF TEXTILES, EA11

THESIS SUBJECTS 2014

Development of a Textile Based Energy Storage Device

Supervisor: Prof. Gilbert De Mey ([email protected]; tel: +32 9 264 3386),

Prof. Lieva Van Langenhove ([email protected]; tel: + 32 9 264 5419),

Dr. Carla Hertleer ([email protected]; tel. +32 9 264 5409)

Coach: MSc Sheilla Atieno Odhiambo ([email protected]; tel: + 32 9 264 5408)

Description

Textiles are part of our daily life as we use them intensely in various applications. These
applications vary from clothing and upholstery to new technical applications in different
industries. A new class of textiles, the so-called smart textiles, is able to respond to stimuli from
the user environment. Smart textile systems consist of five main components i.e. sensors,
actuators, a data processor, an energy supply and an interconnection between them. Smart
textile systems are mostly applicable in leisure and fun (mp3s, displays on shirts) and for
monitoring in sports, personal protective equipment, health and telemonitoring.

The challenge is to produce as many components as possible from textile materials, since their
characteristics are : lightweight, flexible, durable and compatible to the skin and body.

This research focuses on the development of an energy supply/storage device of the smart textile
system. In addition, portable energy storage devices are becoming indispensable with the current
increase in the use of portable gadgets that consume power to function like watches, mobile
phones, ipods, computers etc. It will be “a dream come true” if we are able to power these
devices at any time with stored power in our textiles.

Purpose

A battery is composed of an anode (negative electrode), a cathode (positive electrode) and an

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 electrolyte that allows for the ionic conductivity. Often, separators are used to separate the
anode from the cathode to prevent a short circuit. An electrochemical capacitor consists of the
electrodes (cathode and anode) and the electrolyte.

An energy storage device which is either a battery or a capacitor is to be developed from poly
PEDOT:PSS (3,4 ethylenedioxythiophene) (semi) conductive polymer and conductive yarns (silver
coated yarns, copper coated yarns and pure stainless steel filament yarns). The device should be
simple and well integrated into the textile matrix.

Alternatively, a solid state battery is to be developed from isolative and conductive

formulations/inks by screen printing technology, based on a pre-informed design.

In both cases, the student will design and develop the device according to definite specifications,
and conduct charge-discharge measurements. We aim at obtaining batteries with energy
densities of 70Wh/kg that could supply enough energy to support the e-textile circuit.

Development and Characterization of a Fibre with Transistor Properties

Supervisor: Prof. Lieva Van Langenhove ([email protected]; tel. +32 9 264 5419)

Coach: MSc Lina Rambausek ([email protected]); tel. +32 9 264 5409)

Description

During recent years, intensive research has been carried out in the area of electronic textiles. There is an
emerging trend to create garments that host electronic components embedded in the textile substrate
as well as electronic textiles made from yarns or fibres already possessing electronic properties. The
creation of passive devices, such as textile electrodes that measure body parameters, has proved
successful. However, there is a great need for the development of textiles possessing additional active
functions.

Hence, we investigated the possibility of developing a textile substrate possessing integrated switching
and amplification functions by depositing parts of an organic thin film transistor (OTFT) on fibrous
substrates of varying geometries and origins.

Purpose

In our lab we are currently developing an OTFT based on polymeric textile substrates. For that
purpose, different functional layers are coated on top of each other using chemical deposition,
dip-coating and thermal evaporation. The thesis topic will focus on the development of the
semiconductive layer via different techniques as well as their characterization.

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Feel of Fabrics

Supervisor: Prof. L. Van Langenhove ([email protected]; tel: + 32 9 2645419)

Coach: Dr. Benny Malengier ([email protected]; tel: + 32 9 2645407)

The feel or touch of fabrics is one of the most important properties of textile products. It is tested
either by user panels or by a set of mechanical properties presumed to be correlated with touch.
The objective of the proposed research is to carry out simulations using a skin model, in order to
understand how mechanical parameters of a textile translate into impulses at the level of
mechanoreceptors underneath the skin.

The work is conducted within the framework of an industrial project. It comprises computer
simulations as well as lab tests.

Contact Resistance in Textile Structures

Supervisor: Prof. L. Van Langenhove ([email protected]; tel: + 32 9 2645419)

Coach: Dr. Carla Hertleer ([email protected] ; tel: + 32 9 2645409)

Contact between fibres is of crucial importance for the transmission of signals. The durability of
this contact is determining for the life span of the product and consequently also for defining
possible application fields from purely decorative applications to personal protection means.
This contact needs to be guaranteed during the whole life span of the product, which is still a
challenge at the moment.

Several production techniques with which various structures can be produced, can be applied :
weaving or braiding, embroidering, printing, etc. Braided structures are often used because
they are more elastic than fabrics, which can be important if a good skin contact is required
without affecting the wearing comfort too much. The contact between fibres in knitwear is
limited though because of the rather loose structure. With embroidering too, the structure
tends to become more loose which leads to less good contacts.

Contacts are sometimes required between two fibres, sometimes between a fibre and a
component or a conductive zone, or combinations thereof. Depending on the actual

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 application, different conditions apply and consequently different solutions can be
recommended.

Purpose:

The purpose is to study the stability of contacts using advanced weaving patterns. In the first
phase the contact resistance will be studied on yarn level, considering a range of conditions of
contact. Based on this, appropriate weaving patterns can be selected showing stable contacts for a
variety of applications.

The work consists of a considerable part of lab tests that will provide the base for understanding
of the phenomena.

It is part of an industrial project.

Repair of Tendon Rupture using Textile Structures

Supervisor: Prof. Lieva Van Langenhove ([email protected]; tel: + 32 9 2645419) and

Benedict Verhegghe ([email protected]; tel +32 9 332 4226)

Coach: Jerry Ochola (jerry.ochola@UGent) and Matthieu Debeule ([email protected]; tel:

+32 9 332 4226)

Introduction

Today rupture of tendons is being repaired by sewing. This procedure is time consuming and
causes additional damage. In patent literature the principle of Chinese fingertrap is described as a
solution for fast and efficient tendon repair. Such structures are basically braided tubular
structures.

At the same time, such structures can be used as artificial muscles. Artificial muscles in the form
of fibres offer many application possibilities. The topic of this research work is an artificial
muscle based on the structure of a specific type of worm.

Some worms move forward through local contraction / expansion. This effect is obtained due to
the specific structure : a core wrapped with “fibres”. Swelling of the core leads to tensile forces
in the fibres, which in its turn causes contraction. Such structures are very analogous to certain
types of yarns (wrapped yarns). Yarn models allow the simulation of the properties and
behaviour of such structures.

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 Purpose

The aim of this project is to simulate the mechanical behaviour of tubular braided structures in
order to study the influence of the structure, composition and properties of the filaments. In
addition lab tests have to be carried out for validation purposes. The thesis supports the PhD work
of Jerry Ochola and is conducted with the university hospital.

3D-Analysis/Reconstruction of the Cocoon Spinning in Silkmoths

Supervisor: Prof. Lieva Van Langenhove ([email protected]; tel: + 32 9 2645419)

Coach: Benny Malengier ([email protected]; tel: + 32 9 2645407)

Introduction

Silk is known as a luxury product. In order to obtain the continuous silk fibre for use in cloths
however, countless silkmoths are killed as these break-up the cocoon fibre when emerging. By
introducing a new video technique we will be able to reconstruct the cocoon and the spinning
thereof.

Purpose

The main goal is to completely reconstruct a silk cocoon built up by a 1.2km silk fibre. This will
enable us to get a better insight in how cocoons are spun and how to change this spinning
behaviour so that the silkworms can be removed from the cocoon without killing them. This
would ultimately lead to a cocoon with a hole. A good knowledge of Matlab is recommended.

3D-printing on Textiles

Supervisor: Prof. Lieva Van Langenhove ([email protected]; tel: + 32 9 2645419) and

Prof. Ludwig Cardon ([email protected])

Coach: Benny Malengier ([email protected]; tel: + 32 9 2645407)

Introduction

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 3D printing is a novel technique for printing 3D shapes starting from a digital form. 3D printing
on textiles offers new possibilities and functionalities.

Purpose

The main goal is to explore the possibilities and difficulties of 3D printing on textile substrates.
Aspects that can be addressed are:

 Creation of digital form

 Appropriate polymers

 Adhesion

 Applications

Realistic Numerical Modelling of the Yarn Behaviour in a Weaving Loom

Supervisor 1: Prof. Wim Van Paepegem

Supervisor 2: Prof. Lieva Van Langenhove ([email protected]; tel: + 32 9 264 5419)

Coach: Dr. Simon De Meulemeester ([email protected]; tel: +32 9 264 5417)

Description

During the weaving process of textiles the weft yarns are woven in transversal direction towards
the warp yarns. Weaving of the weft yarns can be done in different ways : (1) the weft yarn can
be accelerated by a rapier towards the middle of the weaving machine and consequently be
taken by a rapier from the other side; (2) the weft yarn can be blown into the fabric. In both
cases the weft yarn is taken from the bobbin at a very high speed. For weaving manufacturers
(Picanol, Van de Wiele, …) it is very important to know the exact path of the yarn, and to
calculate the friction when the bobbin is unwound or when interaction with other yarns occurs.

The Department of Textiles developed a code for the simulation of the unwinding of the yarn
from a bobbin. The results are validated with high speed images during the weaving process.
The calculation times for the simulation of one single yarn are rising significantly though and
the weaving manufacturers are also interested in simulating the interaction of several yarns.

Purpose

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 The aim of the project is to examine whether the unwinding can also be simulated in the
commercial finite element code Abaqus and whether the calculation times can be reduced. To
that purpose there will be cooperation with the research group Mechanics of Materials and
Constructions, which has experience with finite element simulations of materials for more than
10 years. Although the research is reconnoitering, the promoters already have a number of
concrete ideas how the yarn could be simulated and which are the advantages and disadvantages
of the different ways of modelling.

Picanol weaving loom with bobbins of yarn at the left side

RFID tags as Enablers of Smart Textile Applications

Supervisor: Prof. Lieva Van Langenhove ([email protected]; tel: + 32 9 264 5419), Dr. Benny
Malengier ([email protected]; tel +32 9 264 5407), Dr. Carla Hertleer ([email protected]; tel.
+32 9 264 5409)

Coach: Dr. Benny Malengier ([email protected]; tel +32 9 264 5407)

Description

RFID tags already exist several years and can be added to textiles in different ways. With the growth of
smartphones with NFC chips (RFID reader), more and more consumers have access to a device that can
read these tags.

RFID tags can make it possible to use textile in more innovative ways and allow to stay connected with
consumers after purchase via applications that offer an added value: clothing advice, comparable
products, … . To launch this innovative industry branch however, the common problem of lack of
demand (the consumer does not know what he misses) and the lack of supply (producers do not offer
RFID tags due to lack of added value) have to be tackled. The research aims at breaking this barrier.

First, a literature study must be performed concerning the possibilities: which RFID tags are mostly
suited, what is existing today?

Secondly, a consumer questionnaire must be performed: what would customers like, what is most
important, how do they see possible privacy problems, … . This is meant to build a dossier towards
producers.

Thirdly, a standard for data storage on the RFID chip must be proposed: which properties of the textile
should be stored on the RFID tag to make the data useful and how should it be done. Probably it will be
required to work with unique IDs/barcodes which allow to obtain extra data via a search module. To

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 make this workable for the consumer, producers should work together to define a uniform open data
store.

Finally, a use case must be developed, in which the learned knowledge is converted to a specific
application. We propose an application that reads the RFID tags, and using the weather forecast and a
simple textile network model for thermal properties, informs if you are dressed too warm or too cold.
The student is allowed to propose a different application.

Numerical and Experimental Investigation of Epoxy based Composites toughened with Nanofibres

Nature Experimental and numerical

Promoter Prof. K. De Clerck and Prof. W. Van Paepegem
Coach Lode Daelemans
More info [email protected] (09 264 54 11)
Website http://www.composites.ugent.be
http://www.ugent.be/ea/textiles/nl

Description

Fibre reinforced polymers are ideally suited for structural applications which require high
strength and high stiffness at low weight. Applications for these composite materials are
increasing rapidly and include for example wind turbine blades, aeronautical applications, racing
bicycle frames, tennis rackets.

Fibre reinforced polymers consist out of a matrix, the polymer (e.g. epoxy resin), and reinforcing
fibres (e.g. glass fibres, carbon fibres, Kevlar fibres). Layers of these fibre reinforced polymers
can be stacked under certain angles, forming a layered structure which is called a laminate.

Epoxy resins are commonly used as a matrix for composites due to their good properties
(chemical resistance, high stiffness, low thermal expansion, high temperature resistance, …).
However, the brittle behaviour of epoxy resins is an important disadvantage for most
applications. Not only does the brittleness of the epoxy result in a brittle failure behaviour
without “warning”, it also limits the resistance against impact for the final composite. During
impact, delaminations can occur between the different layers in a laminate, resulting in a
macroscopic decrease of the stiffness and the strength of the laminate. A possible way to
increase the delamination resistance consists of adding tough particles to the brittle resin. Very
recently it has been discovered that adding tough nanofibres (see picture) between the layers in
a laminate increases the toughness of epoxy based composites. In order to understand the
toughening behaviour of nanofibres in composites, it is also necessary to investigate their
toughening effect on the epoxy resin (without reinforcing fibres).

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Purpose

The purpose of this master thesis is to experimentally and numerically investigate the toughening
effect of nanofibres on an epoxy resin and on an epoxy based composite. This includes the
following topics:

Experimental

- Making nanofibres by means of electrospinning. Nanofibres are produced by injecting a

polymer solution (e.g. polyamide) into an electric field. This process results in a nanofibrous
web which can be placed between the layers of the laminate. This part of the research will
mostly be done at the department of Textiles.

- Using the produced nanofibres to make nanofibre-epoxy composites and investigate their
effect on the toughness of epoxy resin. The toughness is determined by single edge notch
bending (SENB) fracture toughness experiments which will form the main focus of the
experimental characterization. The department of Materials Science and Engineering has a
setup specially designed for SENB testing that uses digital image correlation.

- Toughened laminates will also be made using the produced nanofibres. Their toughness will be
determined by mode I fracture toughness experiments.

Numerical

The toughening of the epoxy resin and laminates will be modeled using finite element analysis
software (Abaqus). The experimental data will be used as input for the numerical models.

- Simulating SENB experiments of nanofibre toughened epoxy resin. The simulation will help to
understand the toughening effect of the nanofibres because it delivers a lot of information
about the crack propagation, the stresses and strains in the specimen, …

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 - Simulating mode I experiments. Adding nanofibres in the interlayers of a laminate can change
the geometry of the final structure (e.g. interlayer thickness increases, local stiffness increases,
… ) which can influence the results of the mode I experiments. Simulating the mode I tests is
an effective way to understand the effects these changes have on the final fracture toughness
of the laminate.

Polymer Modifications for the Production of Colour Changing Nanofibres

Supervisor: Prof. Karen De Clerck ([email protected]; tel: + 32 9 2645740), Prof. Richard

Hoogenboom ([email protected])

Coach: ir. Iline Steyaert (Iline.Steyaert@UGent; tel: + 32 9 2645747), Gertjan Vancoillie

([email protected])

Description

Over the last ten years the production, morphology and applicability of nanofibres have been
intensively studied for various applications such as biotechnology, environmental technology,
production and storage of energy, composites and biomedical applications, including regenerative
medicine and innovative wound bandages. Nanofibres that undergo a change of colour under the
influence of an external impulse can be used as a flexible sensor within several applications
because a change of colour gives an easy and quick signal. Especially in the biomedical sector
halochromic nanofibres (nanofibres changing colour under the influence of the pH value) could
offer an added value. Wound healing is linked with specific changes in the pH value. In addition,
nanofibres mimic the natural structure of human tissue. As such, pH-sensitive nanofibres can
both monitor and stimulate wound healing. The dyes providing the pH-sensitivity may not
migrate from the fibres, though, since this causes sustainability and cytotoxicity problems. A
possible solution for this problem is the use of polymer modifications resulting in a stronger dye-
fibre interaction. The use of functionalized polymers, for instance, results in nanofibres
containing covalently bonded dyes, which inhibits dye migration to the human body.

Purpose

The purpose of this thesis is to obtain a better insight in the possibilities of functionalized
polymers for the production of colour changing nanofibres. The research will focus on the
development of new functionalized polymers via new reaction mechanisms and new dyes,
combined with research on the performance of colour changing nanofibres produced using these
functionalized polymers.

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 Several polymers will be synthesized via free radical polymerization with variations in e.g.
length, type of the monomer and composition. Each of these polymers will be fully characterized
and the stability will be examined. In addition, research will be done on the development of a
new pH-sensitive dye monomer, starting from existing pH-sensitive dyes, which can be
integrated in the polymer.

Further, a spectral analysis of the dye-fibre systems is essential in order to characterize and
understand the colour change. Possible interactions of the dye with the environment, the impulse
sensitivity of the nanofibres produced, etc. are essential to obtain a fundamental knowledge that
can be used in future development of new materials.

Depending on the existing competences / background and the interest of the student, focus can be
on the production / characterization of functionalized polymers or on the production /
characterization of colour changing nanofibres.

Electrospinning of Gelatine-containing Polymer Mixtures for Biomedical Applications

Supervisor: Prof. Karen De Clerck ([email protected]; tel. + 32 9 264 5740)

Coach: ir. Iline Steyaert ([email protected]; tel. +32 9 264 57 47)

Description

Nanofibres have a diameter smaller than 500 nm. Because of this, membranes consisting of
nanofibres have some very unique properties, making them interesting for use in a wide range of
applications. In the medical sector, for instance, nanofibres have got much attention since they
form ideal substrates for tissue engineering, wound healing and controlled drug release. Within
this biomedical field, more and more applications demand the use of natural materials, also for
the production of nanofibres. One of the possibilities is the use of gelatin, a natural biopolymer
having excellent biocompatibility and biodegradability. Gelatin is derived from collagen, which
is the main structural protein of various connective tissues in animals (skin, bones, cartilage).
Also, gelatin is produced in mass quantities for food applications. Those two aspects make gelatin
nanofibres a very interesting and industrial relevant product. However, the materials requirements
are becoming more and more demanding, making research into polymer blends crucial. By
electrospinning a blend with a natural component, several properties such as biocompatibility and
mechanical strength can be combined. The process of blend electrospinning has not yet been fully
researched, even though these insights are highly necessary to obtain a reproducible and stable
product.

Purpose

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 This thesis aims at furthering our knowledge of the electrospinning process of gelatin-containing
polymer mixtures. At first, the electrospinning parameters will be studied and the preconditions
for obtaining a reproducible membrane without drops or other irregularities will be determined.
Subsequently, an extensive characterization of the obtained nanofibres will be performed. Fibre
morphology is mainly studied through scanning electron microscopy (SEM), which will
determine whether the nanofibre diameter is influenced by the polymer mixture. The composition
of the obtained fibres is another important factor deserving the necessary attention. On the one
hand, the nanofibre structure can consist of fibres that are each composed of one polymer but on
the other hand, one fibre can also be made out of different polymers. By dissolving for example
one of the two polymers found in the structure, SEM can provide information on the composition
of the fibres. Other analysis techniques will be used to study the crystal morphology and
composition of the fibres (DSC, DMA, XRD etc.). The results obtained from this research can
help forcing the breakthrough of nanofibre mixtures since such profound studies, although
indispensable, are still very limited in number. Depending on the student’s interests, this thesis
can focus on different aspects of polymer mixture electrospinning. A possible approach can be
the study and optimization of the electrospinning process for an innovative polymer blend.
Another perspective is the morphological characterization of nanofibres from polymer mixtures
and the comparison with nanofibres consisting of only one component.

Sol-gel Coating of Nanofibrous Membranes for Innovative Nanofibre Composites

Promotor: Prof. Karen De Clerck ([email protected]; 09/264 57 40), Prof. Klaartje De

Buysser ([email protected]; 09/264 44 41)

Supervisor: Jozefien Geltmeyer ([email protected]; tel 09/264 57 47), Sam van der
Heijden ([email protected]; tel. +32 9 264 54 11)

Description

Electrospinning is a relatively simple and versatile technique to produce nanofibres with different
compositions. These nanofibrous structures have unique properties such as a small pore size, a
high specific surface area and a high porosity due to their small nanofibre diameters. The sol-gel
process is a well-known process in material science. It is used to produce dense ceramic
materials, aerogels, fibres, coatings, etc. Furthermore, the sol-gel process offers various
possibilities to functionalize materials. Sol-gel coating of conventional fibres is well-known. Via
sol-gel coating of nanofibres unique structures can be obtained, which can be used in multiple
applications such as composites, sensors, etc. During this master thesis focus will be given to
functionalization of nanofibrous structures via sol-gel coating for application in composites. The
use of nanofibrous structures in composites (glass fibre reinforced epoxy resins) can be important
for increasing the toughness of composites. This will result in an increased impact resistance of
those composites. Glass fibres used in composites often have coatings to improve the adherence

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 to the matrix. The application of an analogous coating on nanofibrous structures may lead to an
improved adherence as well.

Purpose:

During this master thesis nanofibrous membranes will be produced via electrospinning, after this
a sol-gel coating will be applied on the nanofibrous membranes. First, focus will be given to the
optimization of the sol-gel coating. Both the non-coated and the coated nanofibres will be
characterized via SEM. After optimization of the coating and correct functionalization of the
nanofibres, the next step will be producing composites containing the coated nanofibrous
structures. Characterisation of the composites will be done by mechanical testing (bend, tension
and impact testing) and via microscopic techniques (optical and electron microscope). The
fibre/resin adherence before and after rupture can, for example, be evaluated via microscopic
techniques.

pH-sensitive Nanofibrous Structures via Sol-gel Technology

Promotor: Prof. Karen De Clerck ([email protected]; +32 9 264 5740), Prof. Klaartje De
Buysser ([email protected]; +32 9 264 4441)
Supervisor: Jozefien Geltmeyer ([email protected]; tel +32 9 264 5747)

Analoog onderwerp wordt ook ingediend bij de vakgroep Anorganische en fysische chemie

Description :

pH-sensitive textile materials, which reversibly change colour under the influence of pH, are
innovative and valuable materials. These pH-sensitive textile materials can be used for multiple
applications such as protective clothing, wound dressings, etc. Nanofibrous structures, produced
by electrospinning, have, due to their small nanofibre diameters, unique characteristics such as a
small pore size, a high specific surface area and a high porosity. As a consequence these
nanofibrous structures can be used for sensor applications. The use of nanofibrous structures can
improve the sensitivity and the response time, both important parameters for sensor systems. The
addition of pH-sensitive dyes to solutions of polymers before electrospinning has led to
promising results, however a high dye release was sometimes noticed. This can be prevented
using sol-gel technology. The sol-gel process is a well-known process in materials science and is
used to produce dense ceramic materials, aerogels, fibres, coatings, etc. Furthermore, the sol-gel
method offers various possibilities for functionalization, including functionalization with pH-
sensitive dyes. The application of a sol-gel coating on conventional textiles showed to be suitable
for the production of pH-sensitive structures. To benefit from the unique characteristics of
nanofibrous structures, sol-gel coating of nanofibrous structures will be studied in this master

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 thesis.

Purpose:

The goal of this masterthesis is functionalization of nanofibres with colourants via sol-gel
coatings to produce colorimetric sensors. The focus will be on pH-sensitive colourants. Polymer
nanofibrous membranes will be produced via electrospinning. Next, a dye containing sol-gel
coating will be applied on these membranes. The application of this coating will be optimized.
The sol-gel coated nanofibrous membranes will be characterized in detail. The fibre diameters
and irregularities will be examined via SEM. Furthermore, the influence of the sol-gel coating on
the nanofibrous structure will be examined visually and via SEM. Next to this, focus will be on a
limited dye release and the colour changing characteristics of the nanofibrous structures. These
properties will be characterized via UV-Vis spectroscopy.

Design and Mechanical Characterisation of Innovative Nanofibre Composites

Supervisors: Prof. Karen De Clerck ([email protected]; tel. + 32 9 264 5740), Prof. Wim Van
Paepegem

Coach: ir. Sam van der Heijden ([email protected]; tel. +32 9 264 5411)

Description:

Thermoset matrix fibre reinforced composites are widely used in industry, due to their light
weight, high stiffness and strength. However, these composites still face a serious problem as
the thermoset matrix is a brittle material. This can lead to failure of the composite due to
relatively low out of plane impacts. It is also the main cause of delamination. Furthermore, it
negatively affects the fatigue properties of the composite. Several solutions have been proposed
to enhance the toughness of epoxy composites. Most of them make use of nano- or microsized
filler particles, in general it is proven to be difficult to obtain a homogeneous dispersion of these
particles. This leads to agglomerations which can induce stress concentrations and may even
reduce the overall performance of the composite. Furthermore, there is a growing concern
about health issues involved in the use of nanoparticles.

Thermoplastic nanofibres have the potential to provide a solution for these problems.
Nanofibrous webs can be readily embedded in the resin; they have the large benefit of their
inherent nanoscale distribution, which may improve the traditional limitations in (nano) particle
dispersion. The nanofibres will mainly contribute to the ductility and fracture toughness of the
composite in order to prevent delaminations, while the primary reinforcing glass of carbon

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 fibres will provide for the stiffness and strength of the composite.

Purpose:

During this thesis nanofibrous structures will be produced (Department of Textiles). The
nanofibre properties will be modified by using different polymers as a raw material. The focus
will both be on creating nanofibres with different mechanical properties such as different
elongation at break as well as different chemical properties such as the introduction of
functional groups onto the nanofibres which can promote the fibre matrix adhesion.

In addition, one can modify the production parameters to obtain nanofibres with different fibre
diameters and different areal densities of the nanofibrous nonwoven. These nanofibres will then
be incorporated into glassfibre epoxy composites using resin infusion (Department of Material
Science and Engineering).

To evaluate the effect of the produced nanofibres on the fracture toughness of the composites,
traditional composite laminates will be compared to laminates that contain nanofibres in
between the layers of glassfibre. These composites will be characterized by mechanical testing
(mode 1, mode 2, bending-, tensile- and impact tests). In addition, thermal analysis will be used
to analyse the effect of the nanofibres on the stiffness and damping factor of the laminates in
function of temperature (dynamic mechanical analysis) and to evaluate if the nanofibres have a
significant influence on the curing behavior and glass transition temperature of the epoxy matrix
due to the presences of functional groups (using modulated temperature differential scanning
calorimetry).

Colour Changing Textile Materials used as New Sensor Materials

Supervisor: Prof. Karen De Clerck ([email protected]; tel. + 32 9 264 5740)

Coach: ir. Thierry De Meyer ([email protected]; tel. +32 9 264 65 61)

Description:

Textile materials which undergo a colour change upon a certain impulse of the environment,
can be used as novel flexible sensors. A colour change can be captured quickly and easily by
the human eye and can therefore serve ideally as a (warning) signal. For dye manufacturers
these colour changing properties of certain dyes are well-known. It was always seen as a
negative property, because for textile materials the colour needed to be as stable as possible.
Recently, however, there is an increasing interest in these dyes in literature, especially when
applied onto textile materials. This indicates a general increase of interest in intelligent textile
materials. This is also part of a bigger research field, namely intelligent polymers. In order to
intelligently apply these colour sensitive materials, a lot of further research is still needed.

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An important step in this research is the use of molecular modelling. This technique allows to
look at the systems at a molecular level and therefore gaining more fundamental insight into the
pH-sensitive properties.

Only after an in-depth analysis these materials will be used in a wide range of high-quality
applications.

Purpose:

The goal of this master thesis is to gain a more in-depth insight into pH-sensitive textile
materials. A very important factor is the interaction between the dye and the polymer (textile)
environment. pH sensitive dyes will be applied onto several textile materials. This will mainly
happen using classic dyeing processes, but is also possible via electrospinning.

The difference in pH-sensitivity of the dye in solution or dyed onto a textile material can in first
instance be examined visually. To have a more quantitative interpretation, spectroscopy will be
used. This will also allow to gain more insight on a molecular level. The main spectroscopic
techniques will be infra-red and UV/Vis.

These experimental spectra can be linked to spectra calculated by a molecular model. From this
comparison, it is possible to analyse which interactions are important and which effect they
have on the colour and the colour change.

This master thesis project is challenging because it combines two different disciplines. The
fundamental knowledge resulting from this work will be essential to fully understand the
properties of pH sensitive textile materials. The possible applications are very broad, containing
and not limited to medical applications and protective clothing. Depending on the student's pre-
knowledge and interests, the emphasis can be put on the experimental spectroscopy or the
molecular modelling analysis.

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